ATE62259T1 - LIQUID AND POLYMERIZABLE COMPOSITION FOR THE MANUFACTURE OF ORGANIC LENSES WITH HIGH ABRASION RESISTANCE. - Google Patents
LIQUID AND POLYMERIZABLE COMPOSITION FOR THE MANUFACTURE OF ORGANIC LENSES WITH HIGH ABRASION RESISTANCE.Info
- Publication number
- ATE62259T1 ATE62259T1 AT87200662T AT87200662T ATE62259T1 AT E62259 T1 ATE62259 T1 AT E62259T1 AT 87200662 T AT87200662 T AT 87200662T AT 87200662 T AT87200662 T AT 87200662T AT E62259 T1 ATE62259 T1 AT E62259T1
- Authority
- AT
- Austria
- Prior art keywords
- component
- gps
- esp
- prod
- pentaerythritol
- Prior art date
Links
- 238000005299 abrasion Methods 0.000 title abstract 2
- 239000007788 liquid Substances 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- JKJWYKGYGWOAHT-UHFFFAOYSA-N bis(prop-2-enyl) carbonate Chemical compound C=CCOC(=O)OCC=C JKJWYKGYGWOAHT-UHFFFAOYSA-N 0.000 abstract 4
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 abstract 3
- 229920005862 polyol Polymers 0.000 abstract 3
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 abstract 2
- 150000003077 polyols Chemical class 0.000 abstract 2
- JHQVCQDWGSXTFE-UHFFFAOYSA-N 2-(2-prop-2-enoxycarbonyloxyethoxy)ethyl prop-2-enyl carbonate Chemical compound C=CCOC(=O)OCCOCCOC(=O)OCC=C JHQVCQDWGSXTFE-UHFFFAOYSA-N 0.000 abstract 1
- WMYINDVYGQKYMI-UHFFFAOYSA-N 2-[2,2-bis(hydroxymethyl)butoxymethyl]-2-ethylpropane-1,3-diol Chemical compound CCC(CO)(CO)COCC(CC)(CO)CO WMYINDVYGQKYMI-UHFFFAOYSA-N 0.000 abstract 1
- PTJWCLYPVFJWMP-UHFFFAOYSA-N 2-[[3-hydroxy-2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)COCC(CO)(CO)CO PTJWCLYPVFJWMP-UHFFFAOYSA-N 0.000 abstract 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 1
- 230000001476 alcoholic effect Effects 0.000 abstract 1
- -1 aliphatic polyol Chemical class 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- 239000011521 glass Substances 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- 125000005395 methacrylic acid group Chemical group 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 abstract 1
- 150000003254 radicals Chemical class 0.000 abstract 1
- 238000010555 transalkylation reaction Methods 0.000 abstract 1
- 238000005809 transesterification reaction Methods 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F218/24—Esters of carbonic or haloformic acids, e.g. allyl carbonate
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
- G02B1/041—Lenses
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Optics & Photonics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Physics & Mathematics (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Dental Preparations (AREA)
- Polyesters Or Polycarbonates (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Liq. compsns. polymerisable to organic glasses with high abrasion strength contain (i) 20-80, esp. 35-70wt.% oligomeric prods. with 2 terminal allyl gps. (Component A) of formula (I) CH2=CHCH2OCOO(CH2CH2OCH2 CH2OCOO)nCH2CH=CH2 (I) where n = 2-5; (ii) 20-50, esp. 25-45,wt.% monomer prod. (Component B) of formula (II). R = Me, Et, -CH2-OCOOCH2CH=CH2; n = 0, 1; R1 = -CH2OCOOCH2CH=CH2; (iii) 0-35, esp. 0-25,wt.% of reactive diluent contg. allyl, vinyl or methacrylic gps. Pref. component A is the transesterification prod. of diallyl carbonate and diethylene glycol in a mutual molar ratio of about 2:1. Component B is the transalkylation prod. of diallyl carbonate (DAC) and an aliphatic polyol with at least 4 alcoholic OH gps. in a 4:1 molar ratio of DAC:OH gps. of the polyol. Component C may be diethylene glycol bis(allylcarbonate), vinyl acetate or methyl methacrylate. The compsn. may contain 1-6 pts. wt. of a free radical initiator per 100 pts. wt. of (A+B+C). Pref. the polyol is di-trimethylolpropane, pentaerythritol, di-pentaerythritol or tri-pentaerythritol.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT20124/86A IT1190320B (en) | 1986-04-17 | 1986-04-17 | Abrasion resistant lenses etc. |
| EP87200662A EP0241997B1 (en) | 1986-04-17 | 1987-04-07 | Liquid and polymerizable composition suitable for the production of organic glasses endowed with high abrasion strenght |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ATE62259T1 true ATE62259T1 (en) | 1991-04-15 |
Family
ID=11164002
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AT87200662T ATE62259T1 (en) | 1986-04-17 | 1987-04-07 | LIQUID AND POLYMERIZABLE COMPOSITION FOR THE MANUFACTURE OF ORGANIC LENSES WITH HIGH ABRASION RESISTANCE. |
Country Status (10)
| Country | Link |
|---|---|
| KR (1) | KR900007767B1 (en) |
| AT (1) | ATE62259T1 (en) |
| BR (1) | BR8702192A (en) |
| DE (1) | DE3768998D1 (en) |
| ES (1) | ES2022872B3 (en) |
| GR (1) | GR3001840T3 (en) |
| IN (1) | IN169366B (en) |
| IT (1) | IT1190320B (en) |
| MX (1) | MX169473B (en) |
| PT (1) | PT84707B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111689859B (en) * | 2020-05-25 | 2023-01-24 | 江苏乾元新材料科技有限公司 | Low-shrinkage resin and preparation method and application thereof |
-
1986
- 1986-04-17 IT IT20124/86A patent/IT1190320B/en active
-
1987
- 1987-03-31 IN IN233/MAS/87A patent/IN169366B/en unknown
- 1987-04-07 ES ES87200662T patent/ES2022872B3/en not_active Expired - Lifetime
- 1987-04-07 AT AT87200662T patent/ATE62259T1/en not_active IP Right Cessation
- 1987-04-07 DE DE8787200662T patent/DE3768998D1/en not_active Expired - Fee Related
- 1987-04-14 KR KR1019870003557A patent/KR900007767B1/en not_active Expired
- 1987-04-15 MX MX006076A patent/MX169473B/en unknown
- 1987-04-15 BR BR8702192A patent/BR8702192A/en not_active IP Right Cessation
- 1987-04-16 PT PT84707A patent/PT84707B/en not_active IP Right Cessation
-
1991
- 1991-04-24 GR GR91400531T patent/GR3001840T3/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE3768998D1 (en) | 1991-05-08 |
| KR870010121A (en) | 1987-11-30 |
| IT8620124A0 (en) | 1986-04-17 |
| MX169473B (en) | 1993-07-07 |
| GR3001840T3 (en) | 1992-11-23 |
| KR900007767B1 (en) | 1990-10-19 |
| IT1190320B (en) | 1988-02-16 |
| IT8620124A1 (en) | 1987-10-17 |
| PT84707A (en) | 1987-05-01 |
| IN169366B (en) | 1991-10-05 |
| BR8702192A (en) | 1988-02-17 |
| PT84707B (en) | 1989-11-30 |
| ES2022872B3 (en) | 1991-12-16 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| UEP | Publication of translation of european patent specification | ||
| REN | Ceased due to non-payment of the annual fee |