ATE9153T1 - PROCESS FOR THE PRODUCTION OF FLUOROVINYL ETHERS AND OBTAINED POLYMERS. - Google Patents

PROCESS FOR THE PRODUCTION OF FLUOROVINYL ETHERS AND OBTAINED POLYMERS.

Info

Publication number
ATE9153T1
ATE9153T1 AT81104467T AT81104467T ATE9153T1 AT E9153 T1 ATE9153 T1 AT E9153T1 AT 81104467 T AT81104467 T AT 81104467T AT 81104467 T AT81104467 T AT 81104467T AT E9153 T1 ATE9153 T1 AT E9153T1
Authority
AT
Austria
Prior art keywords
group
integer greater
vinyl ethers
acid
production
Prior art date
Application number
AT81104467T
Other languages
German (de)
Inventor
Bobby Ray Ezzell
William Paul Carl
William August Mod
Original Assignee
The Dow Chemical Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Dow Chemical Company filed Critical The Dow Chemical Company
Application granted granted Critical
Publication of ATE9153T1 publication Critical patent/ATE9153T1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F216/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F216/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
    • C08F216/14—Monomers containing only one unsaturated aliphatic radical
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
    • C07C59/235—Saturated compounds containing more than one carboxyl group
    • C07C59/305—Saturated compounds containing more than one carboxyl group containing ether groups, groups, groups, or groups
    • C07C59/315—Saturated compounds containing more than one carboxyl group containing ether groups, groups, groups, or groups containing halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C07C43/14—Unsaturated ethers
    • C07C43/15—Unsaturated ethers containing only non-aromatic carbon-to-carbon double bonds
    • C07C43/16—Vinyl ethers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/40—Esters thereof
    • C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4006—Esters of acyclic acids which can have further substituents on alkyl
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F16/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
    • C08F16/12—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical by an ether radical
    • C08F16/14—Monomers containing only one unsaturated aliphatic radical

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polyethers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Novel vinyl ethers are prepared in decarboxylation reactions of novel acid fluoride compounds according to the following reaction: <CHEM> wherein a is 0 or an integer greater than 0; b is 0 or an integer greater than 0; n = 1 or an integer greater than 1; Rf and R<1> are independently selected from the group consisting of F, Cl, perfluoroalkyl or fluorochloroalkyl; X = F, Cl, Br or mixtures thereof when n > 1 X min = Cl or Br; Y is an acid group or an acid derivative easily convertible to an acid group; Z = F, Cl, Br, OH, NRR min or OA; R and R min are independently selected from the group consisting of hydrogen, an alkyl having one or more than one carbon atoms, and aryl; and A = alkali metal, quaternary nitrogen, or R. These vinyl ethers may be homopolymerized with themselves or copolymerized with other vinyl ethers.
AT81104467T 1980-06-11 1981-06-10 PROCESS FOR THE PRODUCTION OF FLUOROVINYL ETHERS AND OBTAINED POLYMERS. ATE9153T1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US15853280A 1980-06-11 1980-06-11
EP81104467A EP0041737B1 (en) 1980-06-11 1981-06-10 Process to produce novel fluorocarbon vinyl ethers and resulting polymers

Publications (1)

Publication Number Publication Date
ATE9153T1 true ATE9153T1 (en) 1984-09-15

Family

ID=22568562

Family Applications (1)

Application Number Title Priority Date Filing Date
AT81104467T ATE9153T1 (en) 1980-06-11 1981-06-10 PROCESS FOR THE PRODUCTION OF FLUOROVINYL ETHERS AND OBTAINED POLYMERS.

Country Status (9)

Country Link
EP (1) EP0041737B1 (en)
JP (2) JPS5728025A (en)
KR (1) KR840001981B1 (en)
AT (1) ATE9153T1 (en)
AU (1) AU541096B2 (en)
BR (1) BR8103714A (en)
CA (1) CA1169439A (en)
DE (1) DE3165764D1 (en)
ZA (1) ZA813896B (en)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4851161A (en) * 1981-07-02 1989-07-25 E. I. Du Pont De Nemours And Company β-substituted polyfluoropropionate salts and derivatives
US4474700A (en) * 1981-07-02 1984-10-02 E. I. Du Pont DeNemours and Company β-Substituted polyfluoropropionate salts and derivatives
US4766248A (en) * 1982-07-19 1988-08-23 E. I. Du Pont De Nemours And Company β-substituted polyfluoroethyl compounds
US4576752A (en) * 1982-07-19 1986-03-18 E. I. Du Pont De Nemours And Company β-Substituted polyfluoroethyl compounds
US4686300A (en) * 1983-03-07 1987-08-11 E. I. Du Pont De Nemours And Company Polyfluoro gamma-ketoesters and 5-hydroxy gamma lactone analogues thereof
US4513128A (en) * 1983-06-23 1985-04-23 E. I. Du Pont De Nemours And Company Fluorinated vinyl ether copolymers having low glass transition temperatures
US4675453A (en) * 1983-12-27 1987-06-23 E. I. Du Pont De Nemours And Company Process and intermediates for fluorinated vinyl ether monomer
US4595476A (en) * 1984-07-26 1986-06-17 E. I. Du Pont De Nemours And Company Ion exchange membranes pre-expanded with di- and poly ether-glycols
JPH0641494B2 (en) * 1984-08-31 1994-06-01 旭化成工業株式会社 Crosslinkable fluorine-containing copolymer
US5252193A (en) * 1991-11-04 1993-10-12 E. I. Du Pont De Nemours And Company Controlled roughening of reinforced cation exchange membrane
WO1998043952A1 (en) * 1997-03-31 1998-10-08 Daikin Industries, Ltd. Process for producing perfluorovinyl ethersulfonic acid derivatives and copolymer of the same
DE69818061T2 (en) * 1997-07-23 2004-06-03 E.I. Du Pont De Nemours And Co., Wilmington POLYMERIZATION OF OLEFINS
US6326436B2 (en) 1998-08-21 2001-12-04 Dupont Dow Elastomers, L.L.C. Fluoroelastomer composition having excellent processability and low temperature properties
DE69914923T2 (en) 1998-08-21 2004-12-09 Dupont Dow Elastomers L.L.C., Wilmington FLUOROELASTOMER COMPOSITION WITH EXCELLENT PROCESSABILITY AND GOOD PROPERTIES AT LOW TEMPERATURES
JP3786838B2 (en) * 1999-04-15 2006-06-14 有限会社 ミレーヌコーポレーション Phosphorus-containing atomic fluorinated cation exchange membrane, process for producing the same, and proton conducting fuel cell using the same
JP2004010744A (en) * 2002-06-06 2004-01-15 Japan Atom Energy Res Inst Fluoropolymer copolymer having large ion exchange capacity and excellent oxidation resistance and method for producing the same
AU2003241664A1 (en) * 2002-06-14 2004-02-02 Daikin Industries, Ltd. Method of purifying water-soluble fluorinated vinyl ether
US7005545B2 (en) 2002-06-14 2006-02-28 Daikin Industries, Ltd. Process for producing fluorinated fluorosulfonylalkyl vinyl ether
US9139669B2 (en) 2009-03-24 2015-09-22 W. L. Gore & Associates, Inc. Expandable functional TFE copolymer fine powder, the expandable functional products obtained therefrom and reaction of the expanded products
US8658707B2 (en) 2009-03-24 2014-02-25 W. L. Gore & Associates, Inc. Expandable functional TFE copolymer fine powder, the expanded functional products obtained therefrom and reaction of the expanded products
JP5375273B2 (en) * 2009-03-31 2013-12-25 ダイキン工業株式会社 1,3-dichloro-1,2,3,3-tetrafluoropropylene oxide and process for producing the same

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1341087A (en) * 1961-12-08 1963-10-25 Du Pont New fluorocarbon polyethers
GB1038189A (en) * 1963-08-13 1966-08-10 Du Pont Fluorocarbon ethers and the preparation thereof
US3282875A (en) * 1964-07-22 1966-11-01 Du Pont Fluorocarbon vinyl ether polymers
US3321532A (en) * 1963-10-08 1967-05-23 Du Pont Fluorocarbon ethers
US3351619A (en) * 1966-08-01 1967-11-07 Du Pont Crosslinkable polymers formed from iodine-containing perfluoroalkyl vinyl ethers
JPS604806B2 (en) * 1975-10-28 1985-02-06 旭化成工業株式会社 Production method of perfluorovinylcarboxylic acid
JPS5278827A (en) * 1975-12-26 1977-07-02 Asahi Glass Co Ltd Preparation of ester-group-containing fluorovinyl ethers
JPS52105118A (en) * 1976-02-27 1977-09-03 Asahi Glass Co Ltd Preparation fluorovinylether containing ester group
GB1550874A (en) * 1976-10-28 1979-08-22 Asahi Glass Co Ltd Process for producing fluorinated copolymer having ion-exchange groups
JPS54109918A (en) * 1978-02-17 1979-08-29 Asahi Glass Co Ltd Preparation of perfluorovinyl ether having fluorocarbonyl group

Also Published As

Publication number Publication date
KR830006157A (en) 1983-09-17
JPH02270842A (en) 1990-11-05
EP0041737A1 (en) 1981-12-16
ZA813896B (en) 1983-01-26
JPH0258281B2 (en) 1990-12-07
AU7160481A (en) 1981-12-17
KR840001981B1 (en) 1984-10-26
AU541096B2 (en) 1984-12-13
JPS5728025A (en) 1982-02-15
BR8103714A (en) 1982-03-02
EP0041737B1 (en) 1984-08-29
JPH0556338B2 (en) 1993-08-19
DE3165764D1 (en) 1984-10-04
CA1169439A (en) 1984-06-19

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Legal Events

Date Code Title Description
UEP Publication of translation of european patent specification
REN Ceased due to non-payment of the annual fee