AU2001237172A1 - Surface purification of natural graphite and effect of impurities on grinding and particle size distribution - Google Patents

Surface purification of natural graphite and effect of impurities on grinding and particle size distribution

Info

Publication number
AU2001237172A1
AU2001237172A1 AU2001237172A AU3717201A AU2001237172A1 AU 2001237172 A1 AU2001237172 A1 AU 2001237172A1 AU 2001237172 A AU2001237172 A AU 2001237172A AU 3717201 A AU3717201 A AU 3717201A AU 2001237172 A1 AU2001237172 A1 AU 2001237172A1
Authority
AU
Australia
Prior art keywords
graphite
grinding
impurities
purification
effect
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
AU2001237172A
Inventor
Michel Armand
Fernand Brochu
Michel Gauthier
Abdelbast Gherfi
Monique Masse
Gabrielle Nadeau
Karim Zaghib
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hydro Quebec
Original Assignee
Hydro Quebec
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CA002299626A external-priority patent/CA2299626A1/en
Priority claimed from CA002307118A external-priority patent/CA2307118A1/en
Application filed by Hydro Quebec filed Critical Hydro Quebec
Publication of AU2001237172A1 publication Critical patent/AU2001237172A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/20—Graphite
    • C01B32/21—After-treatment
    • C01B32/215—Purification; Recovery or purification of graphite formed in iron making, e.g. kish graphite
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Environmental & Geological Engineering (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inert Electrodes (AREA)
  • Polishing Bodies And Polishing Tools (AREA)
  • Secondary Cells (AREA)

Abstract

The present invention relates to the physical or chemical specific purification of natural mineral graphite. This purification is preferably applied to the surface of natural graphite in order to allow the formation of a passivation film during the first electrical discharge or the insertion of lithium in the graphite when the latter is used in a lithium-ion cell. The grinding to a small size before purification allows the optimization of the distribution of the particles, resulting in a more uniform electrode. This grinding is carried out in the presence of the natural impurities of the graphite that play the role of a micro-abrasive and result in a hardness of the graphite that increases its mechanical properties.
AU2001237172A 2000-02-25 2001-02-23 Surface purification of natural graphite and effect of impurities on grinding and particle size distribution Abandoned AU2001237172A1 (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
CA002299626A CA2299626A1 (en) 2000-02-25 2000-02-25 Surface purification of natural graphite and use of purified graphite in a carbon-lithium anode
CA2299626 2000-02-25
CA002307118A CA2307118A1 (en) 2000-04-28 2000-04-28 Surface purification of natural graphite and use of purified graphite in a carbon-lithium anode
CA2307118 2000-04-28
PCT/CA2001/000233 WO2001062666A1 (en) 2000-02-25 2001-02-23 Surface purification of natural graphite and effect of impurities on grinding and particle size distribution

Publications (1)

Publication Number Publication Date
AU2001237172A1 true AU2001237172A1 (en) 2001-09-03

Family

ID=25681570

Family Applications (1)

Application Number Title Priority Date Filing Date
AU2001237172A Abandoned AU2001237172A1 (en) 2000-02-25 2001-02-23 Surface purification of natural graphite and effect of impurities on grinding and particle size distribution

Country Status (9)

Country Link
US (2) US20050207966A1 (en)
EP (1) EP1257501B1 (en)
JP (2) JP2003528019A (en)
AT (1) ATE402907T1 (en)
AU (1) AU2001237172A1 (en)
DE (1) DE60135094D1 (en)
ES (1) ES2307591T3 (en)
PT (1) PT1257501E (en)
WO (1) WO2001062666A1 (en)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2321345A1 (en) 2000-10-02 2002-04-02 Abdelbast Guerfi Use of graphite in a composite to reduce ice accretion
CA2324431A1 (en) 2000-10-25 2002-04-25 Hydro-Quebec New process for obtaining natural graphite particles in spherical shape: modelling and application
CA2374132A1 (en) * 2002-03-01 2003-09-01 Hydro Quebec Procedure for the surface purification of graphite containing impurities by means of a diluted aqueous solution of nh4f and h2so4
US6830595B2 (en) * 2002-12-20 2004-12-14 Advanced Energy Technology Inc. Method of making composite electrode and current collectors
US7537682B2 (en) 2004-03-17 2009-05-26 California Institute Of Technology Methods for purifying carbon materials
US8377586B2 (en) 2005-10-05 2013-02-19 California Institute Of Technology Fluoride ion electrochemical cell
US7794880B2 (en) * 2005-11-16 2010-09-14 California Institute Of Technology Fluorination of multi-layered carbon nanomaterials
US7563542B2 (en) * 2005-10-05 2009-07-21 California Institute Of Technology Subfluorinated graphite fluorides as electrode materials
US20070218364A1 (en) * 2005-10-05 2007-09-20 Whitacre Jay F Low temperature electrochemical cell
US8232007B2 (en) 2005-10-05 2012-07-31 California Institute Of Technology Electrochemistry of carbon subfluorides
US8658309B2 (en) * 2006-08-11 2014-02-25 California Institute Of Technology Dissociating agents, formulations and methods providing enhanced solubility of fluorides
WO2008113023A1 (en) * 2007-03-14 2008-09-18 California Institute Of Technology High discharge rate batteries
JP4513822B2 (en) * 2007-03-30 2010-07-28 Ｔｄｋ株式会社 Electrode and electrochemical device
KR101131937B1 (en) * 2008-10-10 2012-04-03 강원대학교산학협력단 Negative active material for lithium rechargeable battery, method of preparing the same, and lithium rechargeable battery comprising the same
WO2010095716A1 (en) * 2009-02-20 2010-08-26 三菱化学株式会社 Carbon material for lithium ion secondary batteries
WO2012036372A2 (en) * 2010-09-16 2012-03-22 전자부품연구원 Anode active material, non-aqueous lithium secondary battery including the same, and manufacturing method thereof
KR20120029314A (en) 2010-09-16 2012-03-26 전자부품연구원 Anode active material, lithium secondary battery having the anode active material and manufacturing method thereof
JP5951896B2 (en) * 2012-06-29 2016-07-13 オーシャンズ キング ライティング サイエンスアンドテクノロジー カンパニー リミテッド Graphene film, and production method and use thereof
CN104003382B (en) * 2014-06-17 2016-10-05 鸡西市同泰石墨制品有限公司 A kind of high purity graphite chemical purification continuous producing method
JP6783505B2 (en) * 2014-07-18 2020-11-11 積水化学工業株式会社 Flaked graphite, electrode material and flake graphite-resin composite material
WO2017027731A1 (en) * 2015-08-11 2017-02-16 Metoxs Pte Ltd Method for cost-efficient industrial production of graphite oxide, graphene oxide and graphene
KR102460964B1 (en) 2015-12-03 2022-10-31 삼성에스디아이 주식회사 Carbonaceous material, anode active material including the same, lithium battery including the anode active material, and method of preparing the carbonaceous material
US10710094B2 (en) 2016-05-18 2020-07-14 Syrah Resources Ltd. Method and system for precision spheroidisation of graphite
CN105926007B (en) * 2016-05-27 2018-01-16 中南大学 The water logging method for floating of charcoal and electrolyte is reclaimed in a kind of cathode carbon pieces from aluminum cell waste
CN105821445B (en) * 2016-05-27 2018-01-16 中南大学 A kind of method that charcoal and electrolyte are reclaimed in cathode carbon pieces from aluminum cell waste
US10710882B2 (en) * 2016-06-27 2020-07-14 Syrah Resources Ltd. Purification process modeled for shape modified natural graphite particles
KR102475986B1 (en) 2019-01-17 2022-12-09 주식회사 엘지에너지솔루션 Negative electrode active material for secondary battery, negative electrode including same and manufacturing method thereof
EP3986833A4 (en) 2020-05-18 2022-11-02 Ecograf Limited PURIFIED GRAPHITE PRODUCTION METHOD

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT220123B (en) * 1960-04-26 1962-03-12 Grafitbergbau Kaisersberg Fran Process for processing microcrystalline, so-called dense or earthy graphites up to a carbon content of at least 99%
JPS57161129A (en) * 1981-03-27 1982-10-04 Shohei Tamura Production of carbon fiber and its derivative
JPH06102529B2 (en) * 1989-07-19 1994-12-14 関西熱化学株式会社 Graphite purification method
US5686138A (en) * 1991-11-12 1997-11-11 Sanyo Electric Co., Ltd. Lithium secondary battery
JP3162531B2 (en) * 1993-03-18 2001-05-08 株式会社東芝 Lithium secondary battery
JP3241850B2 (en) * 1992-06-01 2001-12-25 株式会社東芝 Lithium secondary battery
DE69327196T2 (en) * 1992-06-01 2000-05-25 Kabushiki Kaisha Toshiba, Kawasaki Process for the production of carbon-containing material for negative electrodes and lithium secondary batteries containing the same
JP3069509B2 (en) * 1995-04-10 2000-07-24 株式会社日立製作所 Non-aqueous secondary battery and method for producing graphite powder
US5756062A (en) * 1996-05-29 1998-05-26 Ucar Carbon Technology Corporation Chemically modified graphite for electrochemical cells
JP3873325B2 (en) * 1996-07-25 2007-01-24 大阪瓦斯株式会社 Carbon material for lithium secondary battery negative electrode and method for producing the same

Also Published As

Publication number Publication date
US20050207966A1 (en) 2005-09-22
PT1257501E (en) 2008-09-19
ES2307591T3 (en) 2008-12-01
DE60135094D1 (en) 2008-09-11
US20070194158A1 (en) 2007-08-23
JP2013091598A (en) 2013-05-16
EP1257501A1 (en) 2002-11-20
EP1257501B1 (en) 2008-07-30
US7993621B2 (en) 2011-08-09
ATE402907T1 (en) 2008-08-15
WO2001062666A1 (en) 2001-08-30
JP5739859B2 (en) 2015-06-24
JP2003528019A (en) 2003-09-24

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