AU2009242512B2 - Metal utilization in supported, metal-containing catalysts - Google Patents

Metal utilization in supported, metal-containing catalysts Download PDF

Info

Publication number
AU2009242512B2
AU2009242512B2 AU2009242512A AU2009242512A AU2009242512B2 AU 2009242512 B2 AU2009242512 B2 AU 2009242512B2 AU 2009242512 A AU2009242512 A AU 2009242512A AU 2009242512 A AU2009242512 A AU 2009242512A AU 2009242512 B2 AU2009242512 B2 AU 2009242512B2
Authority
AU
Australia
Prior art keywords
metal
catalyst
platinum
support
noble
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
AU2009242512A
Other languages
English (en)
Other versions
AU2009242512A1 (en
Inventor
Kam-To Wan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Technology LLC
Original Assignee
Monsanto Technology LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Technology LLC filed Critical Monsanto Technology LLC
Publication of AU2009242512A1 publication Critical patent/AU2009242512A1/en
Application granted granted Critical
Publication of AU2009242512B2 publication Critical patent/AU2009242512B2/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/393—Metal or metal oxide crystallite size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8906—Iron and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913—Cobalt and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8926—Copper and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/392—Metal surface area
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/396—Distribution of the active metal ingredient
    • B01J35/397—Egg shell like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/617—500-1000 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C227/00—Preparation of compounds containing amino and carboxyl groups bound to the same carbon skeleton
    • C07C227/02—Formation of carboxyl groups in compounds containing amino groups, e.g. by oxidation of amino alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/18—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/15—X-ray diffraction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0211—Impregnation using a colloidal suspension
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
AU2009242512A 2008-05-01 2009-05-01 Metal utilization in supported, metal-containing catalysts Active AU2009242512B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US4946508P 2008-05-01 2008-05-01
US61/049,465 2008-05-01
PCT/US2009/042562 WO2009135150A2 (en) 2008-05-01 2009-05-01 Metal utilization in supported, metal-containing catalysts

Publications (2)

Publication Number Publication Date
AU2009242512A1 AU2009242512A1 (en) 2009-11-05
AU2009242512B2 true AU2009242512B2 (en) 2014-10-23

Family

ID=41130542

Family Applications (1)

Application Number Title Priority Date Filing Date
AU2009242512A Active AU2009242512B2 (en) 2008-05-01 2009-05-01 Metal utilization in supported, metal-containing catalysts

Country Status (8)

Country Link
EP (1) EP2293874A2 (de)
CN (2) CN102076409A (de)
AR (2) AR071623A1 (de)
AU (1) AU2009242512B2 (de)
BR (1) BRPI0911514B1 (de)
CA (1) CA2725434C (de)
MX (1) MX304650B (de)
WO (1) WO2009135150A2 (de)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102229621B (zh) * 2011-05-07 2013-10-02 安徽国星生物化学有限公司 一种紫外光源存在下催化氧化双甘膦制备草甘膦的方法
JP2015501212A (ja) * 2011-10-28 2015-01-15 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 担持銀触媒を生成するための方法
CN104437449A (zh) * 2014-12-09 2015-03-25 黑龙江大学 黑二氧化钛可见光光催化剂的制备方法
US10118155B2 (en) 2015-08-14 2018-11-06 Sabic Global Technologies B.V. Method of metallic clusters fabrication with desired size using scanning tunneling microscopy tip induced reactions
CN110339860B (zh) * 2019-07-29 2022-03-01 湖北工程学院 交联降冰片烯共聚物复合炭黑三维网络固载铂纳米催化剂及其制备方法和应用
JP7175857B2 (ja) 2019-08-02 2022-11-21 日清紡ホールディングス株式会社 金属担持触媒、電池電極及び電池
JP7130311B2 (ja) 2019-08-02 2022-09-05 日清紡ホールディングス株式会社 金属担持触媒、電池電極及び電池
JP7158350B2 (ja) 2019-08-02 2022-10-21 日清紡ホールディングス株式会社 金属担持触媒、電池電極及び電池
CN111054329A (zh) * 2019-11-25 2020-04-24 广东工业大学 一种铝负载贵金属的整体催化剂及其制备方法和应用
CN111430731A (zh) * 2020-04-01 2020-07-17 安徽师范大学 多孔碳载铂材料及其制备方法和应用
CN112794508B (zh) * 2021-01-05 2022-07-05 江山市双氧水有限公司 一种蒽醌法生产双氧水废水的预处理方法
CN113337719A (zh) * 2021-06-07 2021-09-03 林西金易来砷业有限公司 一种含砷烟尘综合利用及无害化处理工艺
CN114177903B (zh) * 2021-10-21 2025-06-06 江苏大学 一种制备微孔材料负载单原子和双原子催化剂的方法
CN116272972B (zh) * 2021-12-20 2025-05-27 中国石油化工股份有限公司 一种用于催化甲烷制烯烃的分散型催化剂及其制备方法和应用
CN114566661A (zh) * 2022-03-09 2022-05-31 昆明理工大学 一种碳材料表面负载铂钴纳米颗粒的制备方法
CN114540889B (zh) * 2022-03-25 2023-03-24 江阴纳力新材料科技有限公司 镀铜添加剂、镀铜液及其应用
CN117065778B (zh) * 2023-07-26 2025-06-27 浙江工业大学 一种双原子催化剂的制备方法及焦油催化重整方法
CN117185909B (zh) * 2023-08-30 2025-08-01 南京理工大学 一种通过表面偶合反应合成1,2-二酮类化合物的方法
CN118002116B (zh) * 2024-03-20 2026-04-10 福州大学 一种氧化铝为载体的钌基氨合成催化剂及其制备方法
CN120115147B (zh) * 2025-05-12 2025-07-29 中科鸿景(宁波)环保科技有限公司 一种高活性铂炭催化剂及其制备方法与其在甲醛催化净化中的应用

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020016503A1 (en) * 1999-12-21 2002-02-07 Leiber Mark A. Use of a supplemental promoter in conjunction with a carbon-supported, noble-metal containing catalyst in liquid phase oxidation reactions
US6417133B1 (en) * 1998-02-25 2002-07-09 Monsanto Technology Llc Deeply reduced oxidation catalyst and its use for catalyzing liquid phase oxidation reactions
WO2008025751A1 (en) * 2006-08-30 2008-03-06 Umicore Ag & Co. Kg Core/shell-type catalyst particles comprising metal or ceramic core materials and methods for their preparation

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1005249B (zh) * 1985-04-01 1989-09-27 孟山都公司 应用经热解的活性炭催化剂生产仲胺或伯胺的方法
CN1054838C (zh) * 1993-04-12 2000-07-26 孟山都公司 氨基羧酸盐的制备方法
TW200624171A (en) * 2004-09-15 2006-07-16 Monsanto Technology Llc Oxidation catalyst and its use for catalyzing liquid phase oxidation reactions

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6417133B1 (en) * 1998-02-25 2002-07-09 Monsanto Technology Llc Deeply reduced oxidation catalyst and its use for catalyzing liquid phase oxidation reactions
US20020016503A1 (en) * 1999-12-21 2002-02-07 Leiber Mark A. Use of a supplemental promoter in conjunction with a carbon-supported, noble-metal containing catalyst in liquid phase oxidation reactions
WO2008025751A1 (en) * 2006-08-30 2008-03-06 Umicore Ag & Co. Kg Core/shell-type catalyst particles comprising metal or ceramic core materials and methods for their preparation

Also Published As

Publication number Publication date
WO2009135150A3 (en) 2010-05-06
CN102076409A (zh) 2011-05-25
BRPI0911514B1 (pt) 2018-03-27
AR071623A1 (es) 2010-06-30
MX304650B (es) 2012-10-26
CA2725434A1 (en) 2009-11-05
AR096669A2 (es) 2016-01-27
AU2009242512A1 (en) 2009-11-05
CA2725434C (en) 2017-02-28
BRPI0911514A2 (pt) 2015-10-06
MX2010012009A (es) 2010-11-30
WO2009135150A2 (en) 2009-11-05
EP2293874A2 (de) 2011-03-16
CN105363475A (zh) 2016-03-02

Similar Documents

Publication Publication Date Title
US9944667B2 (en) Metal utilization in supported, metal-containing catalysts
CA2725434C (en) Metal utilization in supported, metal-containing catalysts
US8703639B2 (en) Oxidation catalyst and its use for catalyzing liquid phase oxidation reactions
EP1505071B1 (de) Verwendung eines zusätzlichen promoters in verbindung mit einem kohlenstoff geträgerten edelmetall enthaltenden katalysator für oxidationsreaktionen in flüssiger phase
CN102276644B (zh) 含有过渡金属-碳化物和氮化物的催化剂、它们的制备方法和作为氧化和脱氢催化剂的用途
CA2610653C (en) Deeply reduced oxidation catalyst and its use for catalyzing liquid phase oxidation reactions
WO2009029539A1 (en) Mixtures and catalyst systems including transition metal-containing catalysts and noble metal-containing catalysts, processes for their preparation, and processes for their use in oxidation reactions
JP4582992B2 (ja) 脂環式アミン化合物の製造方法

Legal Events

Date Code Title Description
FGA Letters patent sealed or granted (standard patent)