AU643077B2 - Detergent compositions - Google Patents

Detergent compositions Download PDF

Info

Publication number: AU643077B2
Authority: AU; Australia
Prior art keywords: tablet; bleach activator; sodium; detergent; bleach
Prior art date: 1990-10-19
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Ceased

Application number

AU85843/91A

Other languages

English (en)

Other versions

AU8584391A (en

Inventor

Michael Joseph Garvey

Peter Stanford Sims

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Unilever PLC

Original Assignee

Unilever PLC

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1990-10-19

Filing date

1991-10-15

Publication date

1993-11-04

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=26297822&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=AU643077(B2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

1990-10-19 Priority claimed from GB909022723A external-priority patent/GB9022723D0/en

1991-10-15 Application filed by Unilever PLC filed Critical Unilever PLC

1992-06-11 Publication of AU8584391A publication Critical patent/AU8584391A/en

1993-11-04 Application granted granted Critical

1993-11-04 Publication of AU643077B2 publication Critical patent/AU643077B2/en

2011-10-15 Anticipated expiration legal-status Critical

Status Ceased legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims description 99
239000003599 detergent Substances 0.000 title claims description 64
239000007844 bleaching agent Substances 0.000 claims description 77
239000012190 activator Substances 0.000 claims description 47
239000004615 ingredient Substances 0.000 claims description 31
VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical group [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 claims description 26
229940045872 sodium percarbonate Drugs 0.000 claims description 26
URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical group CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 claims description 24
150000001875 compounds Chemical class 0.000 claims description 19
238000004061 bleaching Methods 0.000 claims description 18
FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical group CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 claims description 16
239000002243 precursor Substances 0.000 claims description 15
KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 claims description 14
238000005406 washing Methods 0.000 claims description 13
235000013773 glyceryl triacetate Nutrition 0.000 claims description 12
229960002622 triacetin Drugs 0.000 claims description 12
229960001922 sodium perborate Drugs 0.000 claims description 7
YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical group [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 claims description 7
239000004744 fabric Substances 0.000 claims description 5
CKSYEJTXXXFCEV-UHFFFAOYSA-N C1(=CC=CC=C1)S(=O)(=O)OOC(C1=CC=CC=C1)=O.[Na] Chemical group C1(=CC=CC=C1)S(=O)(=O)OOC(C1=CC=CC=C1)=O.[Na] CKSYEJTXXXFCEV-UHFFFAOYSA-N 0.000 claims description 4
239000002253 acid Substances 0.000 claims description 4
229910052757 nitrogen Inorganic materials 0.000 claims description 4
238000005204 segregation Methods 0.000 claims description 4
YNJSNEKCXVFDKW-UHFFFAOYSA-N 3-(5-amino-1h-indol-3-yl)-2-azaniumylpropanoate Chemical group C1=C(N)C=C2C(CC(N)C(O)=O)=CNC2=C1 YNJSNEKCXVFDKW-UHFFFAOYSA-N 0.000 claims description 3
150000001412 amines Chemical class 0.000 claims description 3
125000004432 carbon atom Chemical group C* 0.000 claims description 2
230000001627 detrimental effect Effects 0.000 claims 1
239000003826 tablet Substances 0.000 description 114
239000000843 powder Substances 0.000 description 25
239000002585 base Substances 0.000 description 21
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical group [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 19
238000009472 formulation Methods 0.000 description 15
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 14
230000008901 benefit Effects 0.000 description 14
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 13
230000000052 comparative effect Effects 0.000 description 13
239000011734 sodium Substances 0.000 description 13
229910052708 sodium Inorganic materials 0.000 description 12
238000005056 compaction Methods 0.000 description 11
-1 monosaccharide esters Chemical class 0.000 description 11
150000004965 peroxy acids Chemical class 0.000 description 11
MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 11
PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 9
239000011230 binding agent Substances 0.000 description 9
239000008187 granular material Substances 0.000 description 9
239000000463 material Substances 0.000 description 9
108090000790 Enzymes Proteins 0.000 description 8
102000004190 Enzymes Human genes 0.000 description 8
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 8
229940088598 enzyme Drugs 0.000 description 8
229910000029 sodium carbonate Inorganic materials 0.000 description 8
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 7
229920000642 polymer Polymers 0.000 description 7
239000012418 sodium perborate tetrahydrate Substances 0.000 description 7
IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 7
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
235000014113 dietary fatty acids Nutrition 0.000 description 6
239000000194 fatty acid Substances 0.000 description 6
229930195729 fatty acid Natural products 0.000 description 6
150000003839 salts Chemical class 0.000 description 6
239000000344 soap Substances 0.000 description 6
238000012360 testing method Methods 0.000 description 6
239000010457 zeolite Substances 0.000 description 6
241000283891 Kobus Species 0.000 description 5
229910021536 Zeolite Inorganic materials 0.000 description 5
239000002518 antifoaming agent Substances 0.000 description 5
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 5
239000002245 particle Substances 0.000 description 5
229920005646 polycarboxylate Polymers 0.000 description 5
238000002360 preparation method Methods 0.000 description 5
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
239000003945 anionic surfactant Substances 0.000 description 4
238000006243 chemical reaction Methods 0.000 description 4
238000004090 dissolution Methods 0.000 description 4
230000000694 effects Effects 0.000 description 4
150000004665 fatty acids Chemical class 0.000 description 4
229910017053 inorganic salt Inorganic materials 0.000 description 4
239000007788 liquid Substances 0.000 description 4
238000011068 loading method Methods 0.000 description 4
239000002736 nonionic surfactant Substances 0.000 description 4
239000000047 product Substances 0.000 description 4
229910052938 sodium sulfate Inorganic materials 0.000 description 4
235000011152 sodium sulphate Nutrition 0.000 description 4
KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 3
229910000503 Na-aluminosilicate Inorganic materials 0.000 description 3
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 3
229910019142 PO4 Inorganic materials 0.000 description 3
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
244000269722 Thea sinensis Species 0.000 description 3
229920006243 acrylic copolymer Polymers 0.000 description 3
239000001768 carboxy methyl cellulose Substances 0.000 description 3
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
238000007580 dry-mixing Methods 0.000 description 3
230000006872 improvement Effects 0.000 description 3
239000011159 matrix material Substances 0.000 description 3
238000000034 method Methods 0.000 description 3
238000004806 packaging method and process Methods 0.000 description 3
239000010452 phosphate Substances 0.000 description 3
229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 description 3
230000009257 reactivity Effects 0.000 description 3
150000003333 secondary alcohols Chemical class 0.000 description 3
235000012217 sodium aluminium silicate Nutrition 0.000 description 3
235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 3
229920001027 sodium carboxymethylcellulose Polymers 0.000 description 3
XSVSPKKXQGNHMD-UHFFFAOYSA-N 5-bromo-3-methyl-1,2-thiazole Chemical compound CC=1C=C(Br)SN=1 XSVSPKKXQGNHMD-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 2
CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
108091005804 Peptidases Proteins 0.000 description 2
102000035195 Peptidases Human genes 0.000 description 2
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
239000004365 Protease Substances 0.000 description 2
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
229920002125 Sokalan® Polymers 0.000 description 2
108010056079 Subtilisins Proteins 0.000 description 2
102000005158 Subtilisins Human genes 0.000 description 2
239000011149 active material Substances 0.000 description 2
125000002252 acyl group Chemical group 0.000 description 2
229910052783 alkali metal Inorganic materials 0.000 description 2
229910052910 alkali metal silicate Inorganic materials 0.000 description 2
150000001340 alkali metals Chemical class 0.000 description 2
125000000217 alkyl group Chemical group 0.000 description 2
229910000323 aluminium silicate Inorganic materials 0.000 description 2
125000000129 anionic group Chemical group 0.000 description 2
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
239000000872 buffer Substances 0.000 description 2
239000000969 carrier Substances 0.000 description 2
239000007795 chemical reaction product Substances 0.000 description 2
239000003085 diluting agent Substances 0.000 description 2
239000007884 disintegrant Substances 0.000 description 2
PMPJQLCPEQFEJW-GNTLFSRWSA-L disodium;2-[(z)-2-[4-[4-[(z)-2-(2-sulfonatophenyl)ethenyl]phenyl]phenyl]ethenyl]benzenesulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC=CC=C1\C=C/C1=CC=C(C=2C=CC(\C=C/C=3C(=CC=CC=3)S([O-])(=O)=O)=CC=2)C=C1 PMPJQLCPEQFEJW-GNTLFSRWSA-L 0.000 description 2
238000002474 experimental method Methods 0.000 description 2
229910001385 heavy metal Inorganic materials 0.000 description 2
230000003993 interaction Effects 0.000 description 2
238000005342 ion exchange Methods 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
238000002156 mixing Methods 0.000 description 2
150000004682 monohydrates Chemical class 0.000 description 2
125000002801 octanoyl group Chemical group C(CCCCCCC)(=O)* 0.000 description 2
239000001301 oxygen Substances 0.000 description 2
229910052760 oxygen Inorganic materials 0.000 description 2
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
229920000058 polyacrylate Polymers 0.000 description 2
150000003138 primary alcohols Chemical class 0.000 description 2
239000003352 sequestering agent Substances 0.000 description 2
239000002002 slurry Substances 0.000 description 2
239000002689 soil Substances 0.000 description 2
238000001694 spray drying Methods 0.000 description 2
239000003381 stabilizer Substances 0.000 description 2
238000003860 storage Methods 0.000 description 2
238000004448 titration Methods 0.000 description 2
CIOXZGOUEYHNBF-UHFFFAOYSA-N (carboxymethoxy)succinic acid Chemical class OC(=O)COC(C(O)=O)CC(O)=O CIOXZGOUEYHNBF-UHFFFAOYSA-N 0.000 description 1
CFPOJWPDQWJEMO-UHFFFAOYSA-N 2-(1,2-dicarboxyethoxy)butanedioic acid Chemical class OC(=O)CC(C(O)=O)OC(C(O)=O)CC(O)=O CFPOJWPDQWJEMO-UHFFFAOYSA-N 0.000 description 1
LVVZBNKWTVZSIU-UHFFFAOYSA-N 2-(carboxymethoxy)propanedioic acid Chemical class OC(=O)COC(C(O)=O)C(O)=O LVVZBNKWTVZSIU-UHFFFAOYSA-N 0.000 description 1
ZTGKHKPZSMMHNM-UHFFFAOYSA-N 3-(2-phenylethenyl)benzene-1,2-disulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC(C=CC=2C=CC=CC=2)=C1S(O)(=O)=O ZTGKHKPZSMMHNM-UHFFFAOYSA-N 0.000 description 1
YGUMVDWOQQJBGA-VAWYXSNFSA-N 5-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-[(e)-2-[4-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound C=1C=C(\C=C\C=2C(=CC(NC=3N=C(N=C(NC=4C=CC=CC=4)N=3)N3CCOCC3)=CC=2)S(O)(=O)=O)C(S(=O)(=O)O)=CC=1NC(N=C(N=1)N2CCOCC2)=NC=1NC1=CC=CC=C1 YGUMVDWOQQJBGA-VAWYXSNFSA-N 0.000 description 1
ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
102000013142 Amylases Human genes 0.000 description 1
108010065511 Amylases Proteins 0.000 description 1
BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical group [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
102000005575 Cellulases Human genes 0.000 description 1
108010084185 Cellulases Proteins 0.000 description 1
OCUCCJIRFHNWBP-IYEMJOQQSA-L Copper gluconate Chemical class [Cu+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O OCUCCJIRFHNWBP-IYEMJOQQSA-L 0.000 description 1
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
229920000896 Ethulose Polymers 0.000 description 1
239000001859 Ethyl hydroxyethyl cellulose Substances 0.000 description 1
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
244000020551 Helianthus annuus Species 0.000 description 1
235000003222 Helianthus annuus Nutrition 0.000 description 1
108090001060 Lipase Proteins 0.000 description 1
239000004367 Lipase Substances 0.000 description 1
102000004882 Lipase Human genes 0.000 description 1
JYXGIOKAKDAARW-UHFFFAOYSA-N N-(2-hydroxyethyl)iminodiacetic acid Chemical class OCCN(CC(O)=O)CC(O)=O JYXGIOKAKDAARW-UHFFFAOYSA-N 0.000 description 1
AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
MQNVHUZWFZKETG-UHFFFAOYSA-N P1(OCCCCCO1)=O.NCCNCCN Chemical compound P1(OCCCCCO1)=O.NCCNCCN MQNVHUZWFZKETG-UHFFFAOYSA-N 0.000 description 1
WFRXSOIFNFJAFL-UHFFFAOYSA-N P1(OCCCCO1)=O.C(CN)N Chemical compound P1(OCCCCO1)=O.C(CN)N WFRXSOIFNFJAFL-UHFFFAOYSA-N 0.000 description 1
LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
235000019484 Rapeseed oil Nutrition 0.000 description 1
229910004298 SiO 2 Inorganic materials 0.000 description 1
239000004115 Sodium Silicate Substances 0.000 description 1
239000004133 Sodium thiosulphate Substances 0.000 description 1
239000004902 Softening Agent Substances 0.000 description 1
229910000831 Steel Inorganic materials 0.000 description 1
ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
239000001083 [(2R,3R,4S,5R)-1,2,4,5-tetraacetyloxy-6-oxohexan-3-yl] acetate Substances 0.000 description 1
UAOKXEHOENRFMP-ZJIFWQFVSA-N [(2r,3r,4s,5r)-2,3,4,5-tetraacetyloxy-6-oxohexyl] acetate Chemical compound CC(=O)OC[C@@H](OC(C)=O)[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](OC(C)=O)C=O UAOKXEHOENRFMP-ZJIFWQFVSA-N 0.000 description 1
ZYPMNZKYVVSXOJ-YNEHKIRRSA-N [(2r,3s,4r)-2,3,4-triacetyloxy-5-oxopentyl] acetate Chemical compound CC(=O)OC[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](OC(C)=O)C=O ZYPMNZKYVVSXOJ-YNEHKIRRSA-N 0.000 description 1
239000002250 absorbent Substances 0.000 description 1
230000002745 absorbent Effects 0.000 description 1
230000009102 absorption Effects 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
230000009471 action Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
239000003513 alkali Substances 0.000 description 1
150000004996 alkyl benzenes Chemical class 0.000 description 1
125000002947 alkylene group Chemical group 0.000 description 1
ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
235000019418 amylase Nutrition 0.000 description 1
229940025131 amylases Drugs 0.000 description 1
235000015278 beef Nutrition 0.000 description 1
JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
229910001424 calcium ion Inorganic materials 0.000 description 1
239000012876 carrier material Substances 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
229920003086 cellulose ether Polymers 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
150000001860 citric acid derivatives Chemical class 0.000 description 1
235000019864 coconut oil Nutrition 0.000 description 1
239000003240 coconut oil Substances 0.000 description 1
239000003086 colorant Substances 0.000 description 1
239000007891 compressed tablet Substances 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
239000007859 condensation product Substances 0.000 description 1
229920001577 copolymer Polymers 0.000 description 1
238000005260 corrosion Methods 0.000 description 1
230000007797 corrosion Effects 0.000 description 1
239000002178 crystalline material Substances 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
125000003074 decanoyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C(*)=O 0.000 description 1
VUJGKADZTYCLIL-YHPRVSEPSA-L disodium;5-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-[(e)-2-[4-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-sulfonatophenyl]ethenyl]benzenesulfonate Chemical compound [Na+].[Na+].C=1C=C(\C=C\C=2C(=CC(NC=3N=C(N=C(NC=4C=CC=CC=4)N=3)N3CCOCC3)=CC=2)S([O-])(=O)=O)C(S(=O)(=O)[O-])=CC=1NC(N=C(N=1)N2CCOCC2)=NC=1NC1=CC=CC=C1 VUJGKADZTYCLIL-YHPRVSEPSA-L 0.000 description 1
239000006185 dispersion Substances 0.000 description 1
239000002552 dosage form Substances 0.000 description 1
238000004453 electron probe microanalysis Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
UFZOPKFMKMAWLU-UHFFFAOYSA-N ethoxy(methyl)phosphinic acid Chemical compound CCOP(C)(O)=O UFZOPKFMKMAWLU-UHFFFAOYSA-N 0.000 description 1
235000019326 ethyl hydroxyethyl cellulose Nutrition 0.000 description 1
229940071106 ethylenediaminetetraacetate Drugs 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
239000000945 filler Substances 0.000 description 1
229910021505 gold(III) hydroxide Inorganic materials 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
230000007062 hydrolysis Effects 0.000 description 1
238000006460 hydrolysis reaction Methods 0.000 description 1
230000002209 hydrophobic effect Effects 0.000 description 1
125000001165 hydrophobic group Chemical group 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
238000007373 indentation Methods 0.000 description 1
230000010354 integration Effects 0.000 description 1
229910052740 iodine Inorganic materials 0.000 description 1
239000011630 iodine Substances 0.000 description 1
125000000400 lauroyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
238000002386 leaching Methods 0.000 description 1
235000019421 lipase Nutrition 0.000 description 1
239000000314 lubricant Substances 0.000 description 1
229910052943 magnesium sulfate Inorganic materials 0.000 description 1
235000019341 magnesium sulphate Nutrition 0.000 description 1
238000005259 measurement Methods 0.000 description 1
108010003855 mesentericopeptidase Proteins 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
229920000609 methyl cellulose Polymers 0.000 description 1
239000001923 methylcellulose Substances 0.000 description 1
235000010981 methylcellulose Nutrition 0.000 description 1
108010020132 microbial serine proteinases Proteins 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
125000001402 nonanoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical group [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
238000011056 performance test Methods 0.000 description 1
239000002304 perfume Substances 0.000 description 1
235000019271 petrolatum Nutrition 0.000 description 1
239000000049 pigment Substances 0.000 description 1
239000001267 polyvinylpyrrolidone Substances 0.000 description 1
229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
239000011148 porous material Substances 0.000 description 1
230000008569 process Effects 0.000 description 1
238000012545 processing Methods 0.000 description 1
239000011253 protective coating Substances 0.000 description 1
230000009103 reabsorption Effects 0.000 description 1
238000011160 research Methods 0.000 description 1
239000000377 silicon dioxide Substances 0.000 description 1
229920002545 silicone oil Polymers 0.000 description 1
229910001388 sodium aluminate Inorganic materials 0.000 description 1
239000000429 sodium aluminium silicate Substances 0.000 description 1
URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
235000017557 sodium bicarbonate Nutrition 0.000 description 1
NVIFVTYDZMXWGX-UHFFFAOYSA-N sodium metaborate Chemical compound [Na+].[O-]B=O NVIFVTYDZMXWGX-UHFFFAOYSA-N 0.000 description 1
159000000000 sodium salts Chemical group 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
229910052911 sodium silicate Inorganic materials 0.000 description 1
AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
235000019345 sodium thiosulphate Nutrition 0.000 description 1
RPQSWSMNPBZEHT-UHFFFAOYSA-M sodium;2-acetyloxybenzenesulfonate Chemical compound [Na+].CC(=O)OC1=CC=CC=C1S([O-])(=O)=O RPQSWSMNPBZEHT-UHFFFAOYSA-M 0.000 description 1
MIKSWWHQLZYKGU-UHFFFAOYSA-M sodium;2-benzoyloxybenzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1OC(=O)C1=CC=CC=C1 MIKSWWHQLZYKGU-UHFFFAOYSA-M 0.000 description 1
239000008234 soft water Substances 0.000 description 1
239000007858 starting material Substances 0.000 description 1
239000010959 steel Substances 0.000 description 1
150000003890 succinate salts Chemical class 0.000 description 1
125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
239000007916 tablet composition Substances 0.000 description 1
239000003760 tallow Substances 0.000 description 1
150000003512 tertiary amines Chemical class 0.000 description 1
DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
125000000297 undecanoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
238000009736 wetting Methods 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
- C11D17/0078—Multilayered tablets
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3907—Organic compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Detergent Compositions (AREA)

AU85843/91A 1990-10-19 1991-10-15 Detergent compositions Ceased AU643077B2 (en)

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
GB9022723		1990-10-19
GB909022723A GB9022723D0 (en)	1990-10-19	1990-10-19	Detergent compositions
GB9117862		1991-08-19
GB919117862A GB9117862D0 (en)	1990-10-19	1991-08-19	Detergent compositions

Publications (2)

Publication Number	Publication Date
AU8584391A AU8584391A (en)	1992-06-11
AU643077B2 true AU643077B2 (en)	1993-11-04

Family

ID=26297822

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
AU85843/91A Ceased AU643077B2 (en)	1990-10-19	1991-10-15	Detergent compositions

Country Status (7)

Country	Link
EP (1)	EP0481792B1 (fr)
JP (1)	JP2611071B2 (fr)
AU (1)	AU643077B2 (fr)
BR (1)	BR9104511A (fr)
CA (1)	CA2053433C (fr)
DE (1)	DE69124334T2 (fr)
ES (1)	ES2097193T3 (fr)

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* Cited by examiner, † Cited by third party
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GB9022724D0 (en) *	1990-10-19	1990-12-05	Unilever Plc	Detergent compositions
US6656466B1 (en)	1995-06-06	2003-12-02	Genetech, Inc.	Human tumor necrosis factor—immunoglobulin(TNFR1-IgG1) chimera composition
US6475725B1 (en)	1997-06-20	2002-11-05	Baxter Aktiengesellschaft	Recombinant cell clones having increased stability and methods of making and using the same
BR9812955A (pt)	1997-10-22	2000-08-08	Unilever Nv	Tablete de detergente de composição particulada comprimida, e, processo para obtenção do mesmo
DE69914582T2 (de)	1998-02-10	2004-08-05	Unilever N.V.	Waschmittel in tablettenform
DE19806220A1 (de) *	1998-02-16	1999-08-19	Henkel Kgaa	Mehrphasen-Formkörper mit optimiertem Phasensplit
KR20010043055A (ko)	1998-04-27	2001-05-25	데이비드 엠 모이어	표백 활성제를 포함하는 비입상 세제 제품
DE19856214C1 (de)	1998-12-05	2000-03-09	Henkel Kgaa	Punkttablette
GB9911949D0 (en) *	1999-05-21	1999-07-21	Unilever Plc	Detergent compositions
FI107544B (fi) *	1999-06-15	2001-08-31	Kemira Chemicals Oy	Valkaisuaktivaattori ja menetelmä aktivaattorin käyttämiseksi
WO2001034759A1 (fr) *	1999-11-11	2001-05-17	The Procter & Gamble Company	Pastilles detergentes contenant un agent de blanchiment
US20060094104A1 (en)	2004-10-29	2006-05-04	Leopold Grillberger	Animal protein-free media for cultivation of cells
ES2474573T3 (es)	2006-01-04	2014-07-09	Baxter International Inc	Medio de cultivo celular sin oligop�ptidos
JP2017131488A (ja) *	2016-01-29	2017-08-03	パナソニックＩｐマネジメント株式会社	洗濯機
GB201701356D0 (en) *	2017-01-27	2017-03-15	Cares Laboratory Ltd	Hair removal from textiles
GB2581441B (en) *	2018-01-18	2020-10-07	Cares Laboratory Ltd	Hair removal from textiles
AU2020304637B2 (en) *	2019-06-28	2023-01-12	Ecolab Usa Inc.	Surfactant stabilization of hygroscopic species

Citations (3)

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Publication number	Priority date	Publication date	Assignee	Title
AU7538387A (en) *	1986-07-15	1988-01-21	Warner-Lambert Company	Bleach activator compositions
EP0331229A2 (fr) *	1988-03-01	1989-09-06	Unilever N.V.	Composés à ammonium quaternaire pour utilisation dans des systèmes de blanchiment
EP0337535A2 (fr) *	1988-04-14	1989-10-18	Unilever N.V.	Composition de blanchiment

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GB911204A (en) *	1960-07-28	1962-11-21	Unilever Ltd	Bleaching compositions
DE2263939C2 (de) *	1972-07-03	1983-01-13	Henkel KGaA, 4000 Düsseldorf	Zur Verwendung in perhydrathaltigen Textilwaschmitteln geeignete Bleichaktivator-Tablette
LU72575A1 (fr) *	1975-05-23	1977-02-10
JPS52103405A (en) *	1976-02-27	1977-08-30	Kao Corp	Detergent compositions for use in drainage pipes
JPS5851999B2 (ja) *	1978-08-30	1983-11-19	花王株式会社	漂白剤組成物
JPS577081A (en) *	1980-06-16	1982-01-14	Matsushita Electric Industrial Co Ltd	Method of manufacturing heater
US4678594A (en) *	1985-07-19	1987-07-07	Colgate-Palmolive Company	Method of encapsulating a bleach and activator therefor in a binder
ZA874540B (en) *	1986-07-15	1987-12-28	Warner-Lambert Company	Denture cleansing and/or washing compositions containing a bleach activator
JPH0813993B2 (ja) *	1987-06-29	1996-02-14	ライオン株式会社	高嵩密度粒状漂白洗剤組成物
EP0312278A3 (fr) *	1987-10-12	1990-07-11	Unilever Plc	Composition détergente
GB2213159B (en) *	1987-12-03	1992-07-29	Richardson Vicks Ltd	Cleansing compositions
US4800038A (en) *	1988-01-21	1989-01-24	Colgate-Palmolive Company	Acetylated sugar ethers as bleach activators detergency boosters and fabric softeners
GB8810954D0 (en) *	1988-05-09	1988-06-15	Unilever Plc	Enzymatic detergent & bleaching composition
DE3827895A1 (de) *	1988-08-17	1990-02-22	Henkel Kgaa	Verfahren zur herstellung phosphatreduzierter waschmitteltabletten
AU647736B2 (en) *	1989-04-24	1994-03-31	Unilever Plc	Detergent compositions
US5030380A (en) *	1989-06-27	1991-07-09	Lever Brothers Company, Division Of Conopco, Inc.	Polymeric electrolyte-hydrogen peroxide adducts
DE59006160D1 (de) *	1989-08-09	1994-07-21	Henkel Kgaa	Herstellung verdichteter granulate für waschmittel.
DE4010533A1 (de) *	1990-04-02	1991-10-10	Henkel Kgaa	Tablettierte wasch- und/oder reinigungsmittel fuer haushalt und gewerbe und verfahren zu ihrer herstellung

1991
- 1991-10-15 CA CA 2053433 patent/CA2053433C/fr not_active Expired - Fee Related
- 1991-10-15 AU AU85843/91A patent/AU643077B2/en not_active Ceased
- 1991-10-17 BR BR9104511A patent/BR9104511A/pt not_active IP Right Cessation
- 1991-10-17 ES ES91309597T patent/ES2097193T3/es not_active Expired - Lifetime
- 1991-10-17 EP EP19910309597 patent/EP0481792B1/fr not_active Revoked
- 1991-10-17 DE DE1991624334 patent/DE69124334T2/de not_active Expired - Fee Related
- 1991-10-18 JP JP3271424A patent/JP2611071B2/ja not_active Expired - Lifetime

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
AU7538387A (en) *	1986-07-15	1988-01-21	Warner-Lambert Company	Bleach activator compositions
EP0331229A2 (fr) *	1988-03-01	1989-09-06	Unilever N.V.	Composés à ammonium quaternaire pour utilisation dans des systèmes de blanchiment
EP0337535A2 (fr) *	1988-04-14	1989-10-18	Unilever N.V.	Composition de blanchiment

Also Published As

Publication number	Publication date
EP0481792B1 (fr)	1997-01-22
EP0481792A1 (fr)	1992-04-22
JPH04285699A (ja)	1992-10-09
DE69124334T2 (de)	1997-05-15
DE69124334D1 (de)	1997-03-06
BR9104511A (pt)	1992-06-09
ES2097193T3 (es)	1997-04-01
CA2053433A1 (fr)	1992-04-20
JP2611071B2 (ja)	1997-05-21
AU8584391A (en)	1992-06-11
CA2053433C (fr)	1997-03-25

Legal Events

Date	Code	Title	Description
2004-05-27	MK14	Patent ceased section 143(a) (annual fees not paid) or expired

Publication	Publication Date	Title
AU632713B2 (en)	1993-01-07	Detergent compositions
AU643077B2 (en)	1993-11-04	Detergent compositions
AU636776B2 (en)	1993-05-06	Detergent compositions in the form of tablets
AU635141B2 (en)	1993-03-11	Detergent compositions in the form of tablets
US5407594A (en)	1995-04-18	Detergent tablets having specific particle size distribution
US5900399A (en)	1999-05-04	Tablet containing builders
AU625911B2 (en)	1992-07-16	Particulate bleaching detergent composition in a sachet
ZA200108763B (en)	2002-10-24	Cleaning compositions.
EP0395333A2 (fr)	1990-10-31	Compositions détergentes
AU757238B2 (en)	2003-02-06	Water-softening and detergent compositions
GB2318800A (en)	1998-05-06	Detergent composition
WO2001038479A1 (fr)	2001-05-31	Compositions de detergent
US20040058843A1 (en)	2004-03-25	Detergent compositions
KR960001017B1 (ko)	1996-01-17	세제 조성물
EP1337615A2 (fr)	2003-08-27	Compositions detergentes
GB2270690A (en)	1994-03-23	Percarboxylic acid precursors
EP0777715A1 (fr)	1997-06-11	Compositions detergentes
GB2240110A (en)	1991-07-24	Detergent tablets