BE1000619A5 - Procede d'hydroformylation utilisant des ligands phosphiniques peu volatils. - Google Patents
Procede d'hydroformylation utilisant des ligands phosphiniques peu volatils. Download PDFInfo
- Publication number
- BE1000619A5 BE1000619A5 BE8701298A BE8701298A BE1000619A5 BE 1000619 A5 BE1000619 A5 BE 1000619A5 BE 8701298 A BE8701298 A BE 8701298A BE 8701298 A BE8701298 A BE 8701298A BE 1000619 A5 BE1000619 A5 BE 1000619A5
- Authority
- BE
- Belgium
- Prior art keywords
- ligands
- hydroformylation process
- low volatile
- phosphinic
- phosphinic ligands
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 3
- 238000007037 hydroformylation reaction Methods 0.000 title abstract 2
- 239000003446 ligand Substances 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 150000001299 aldehydes Chemical class 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 239000013110 organic ligand Substances 0.000 abstract 1
- 150000003003 phosphines Chemical group 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/52—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings
- C07C47/55—Compounds having —CHO groups bound to carbon atoms of six—membered aromatic rings containing halogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
L'invention concerne un procédé perfectionné d'hydroformylation consistant à faire réagir un composé organique à non-saturation oléfinique avec un oxyde de carbone et de l'hydrogène en présence d'un catalyseur. Le procédé consiste à utiliser comme ligands pour le catalyseur complexe des ligands organiques solubilisés peu volatils qui sont des sels métalliques de phosphines tertiaires monosulfonées. Application à la production d'aldéhydes
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/932,002 US4731486A (en) | 1986-11-18 | 1986-11-18 | Hydroformylation using low volatile phosphine ligands |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BE1000619A5 true BE1000619A5 (fr) | 1989-02-21 |
Family
ID=25461633
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BE8701298A BE1000619A5 (fr) | 1986-11-18 | 1987-11-17 | Procede d'hydroformylation utilisant des ligands phosphiniques peu volatils. |
Country Status (28)
| Country | Link |
|---|---|
| US (1) | US4731486A (fr) |
| EP (1) | EP0268268B1 (fr) |
| JP (1) | JPH0667868B2 (fr) |
| KR (1) | KR920003556B1 (fr) |
| CN (1) | CN1017145B (fr) |
| AR (1) | AR248390A1 (fr) |
| AT (1) | ATE77075T1 (fr) |
| AU (1) | AU611867B2 (fr) |
| BE (1) | BE1000619A5 (fr) |
| BR (1) | BR8706223A (fr) |
| CA (1) | CA1307296C (fr) |
| DE (2) | DE3739064A1 (fr) |
| DK (1) | DK605887A (fr) |
| ES (3) | ES2009221A6 (fr) |
| FI (1) | FI90858C (fr) |
| FR (1) | FR2606771B1 (fr) |
| GB (1) | GB2197867B (fr) |
| HU (1) | HU202177B (fr) |
| IN (1) | IN170369B (fr) |
| IT (1) | IT1223147B (fr) |
| MX (1) | MX166784B (fr) |
| NL (1) | NL8702752A (fr) |
| NO (1) | NO166440C (fr) |
| PL (1) | PL153062B1 (fr) |
| RU (1) | RU2002728C1 (fr) |
| SE (1) | SE8704533L (fr) |
| YU (1) | YU45074B (fr) |
| ZA (1) | ZA878638B (fr) |
Families Citing this family (85)
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| US5180854A (en) * | 1988-07-14 | 1993-01-19 | Union Carbide Chemicals & Plastics Technology Corporation | Process for catalyst aldehyde product separation |
| CN1024186C (zh) * | 1988-07-14 | 1994-04-13 | 联合碳化化学品及塑料有限公司 | 催化剂醛产物的分离方法 |
| AU617836B2 (en) * | 1988-07-14 | 1991-12-05 | Union Carbide Chemicals And Plastics Company Inc. | Process for producing alcohols and aldehydes |
| US5113022A (en) * | 1988-08-05 | 1992-05-12 | Union Carbide Chemicals & Plastics Technology Corporation | Ionic phosphites used in homogeneous transition metal catalyzed processes |
| US5059710A (en) * | 1988-08-05 | 1991-10-22 | Union Carbide Chemicals And Plastics Technology Corporation | Ionic phosphites and their use in homogeneous transition metal catalyzed processes |
| US4965404A (en) * | 1989-03-09 | 1990-10-23 | Kuraray Company, Ltd. | Process for the preparation of lithium diphenylphosphinobenzene-m-monosulfonate |
| DE3942954A1 (de) * | 1989-12-23 | 1991-06-27 | Hoechst Ag | Verfahren zur herstellung von aldehyden |
| JPH06503808A (ja) * | 1990-08-31 | 1994-04-28 | ザ ガヴァナーズ オヴ ザ ユニヴァーシティ オヴ アルバータ | 新規の遷移金属触媒先駆物質を用いるメタノールのカルボニル化 |
| US5087763A (en) * | 1990-11-09 | 1992-02-11 | Union Carbide Chemicals & Plastics Technology Corporation | Hydroformylation process |
| US5215667A (en) * | 1991-08-20 | 1993-06-01 | Exxon Chemical Patents Inc. | Method for separating water soluble noble metal catalyst from a noble metal catalyzed hydroformylation reaction |
| US5288818A (en) * | 1991-08-20 | 1994-02-22 | Exxon Chemical Patents Inc. | Method for separating a water soluble noble metal catalyst from a noble metal catalyzed hydroformylation reaction |
| US5196596A (en) * | 1991-12-26 | 1993-03-23 | Union Carbide Chemicals & Plastics Technology Corporation | Higher aldehyde separation process |
| US5300617A (en) * | 1993-01-21 | 1994-04-05 | Exxon Chemical Patents Inc. | Potassium para-diphenyl phosphino benzene sulfonate ligand |
| DE4400837A1 (de) * | 1994-01-14 | 1995-07-20 | Basf Ag | Verfahren zur Herstellung von n-Butyraldehyd und/oder n-Butanol |
| US6143211A (en) * | 1995-07-21 | 2000-11-07 | Brown University Foundation | Process for preparing microparticles through phase inversion phenomena |
| DE19532393A1 (de) * | 1995-09-02 | 1997-03-06 | Hoechst Ag | Verfahren zur Hydroformylierung olefinisch ungesättigter Verbindungen |
| ATE192133T1 (de) * | 1995-09-26 | 2000-05-15 | Kuraray Co | Hydroformylierungsverfahren |
| DE19700805C1 (de) * | 1997-01-13 | 1998-08-06 | Hoechst Ag | Verfahren zur Herstellung von Aldehyden durch Hydroformylierung olefinischer Verbindungen mit 3 bis 5 Kohlenstoffatomen in Anwesenheit einer Rhodium und sulfonierte Triarylphosphine als Katalysator enthhaltenden wäßrigen Phase |
| DE19700804C1 (de) * | 1997-01-13 | 1998-08-06 | Hoechst Ag | Verfahren zur Herstellung von Aldehyden durch Hydroformylierung olefinischer Verbindungen mit 6 bis 16 Kohlenstoffatomen in Anwesenheit einer Rhodium und sulfonierte Triarylphosphine als Katalysator enthaltenden wäßrigen Phase |
| DE19742305A1 (de) * | 1997-09-25 | 1999-04-01 | Hoechst Ag | Verfahren zur Herstellung von Aldehyden durch Hydroformylierung in Gegenwart von Kronenether |
| DE10034360A1 (de) * | 2000-07-14 | 2002-01-24 | Oxeno Olefinchemie Gmbh | Mehrstufiges Verfahren zur Herstellung von Oxo-Aldehyden und/oder Alkoholen |
| FI20002807A0 (fi) * | 2000-09-05 | 2000-12-20 | Neste Chemicals Oy | Menetelmä alkeenien hydroformyloimiseksi |
| EP1405854A4 (fr) * | 2001-06-07 | 2004-11-03 | Kuraray Co | P-diarylphosphinobenzenesulfonates de lithium, procede de preparation et utilisation de ces composes |
| EP1423175B1 (fr) * | 2001-08-08 | 2013-10-02 | Brown University Research Foundation | Procedes de micronisation de medicaments hydrophobes |
| CA2469718A1 (fr) * | 2001-12-10 | 2003-06-19 | Spherics, Inc. | Procedes et produits utiles dans la formation et l'isolation de microparticules |
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| DE3046355A1 (de) * | 1980-12-09 | 1982-07-15 | Basf Ag, 6700 Ludwigshafen | Verfahren zur hydroformylierung von olefinisch ungesaettigten verbindungen |
| US4400548A (en) * | 1981-08-17 | 1983-08-23 | Union Carbide Corporation | Hydroformylation process using bisphosphine monooxide ligands |
| JPS58157739A (ja) * | 1982-03-12 | 1983-09-19 | Kuraray Co Ltd | 1,9−ノナンジア−ルの製造方法 |
| US4453022A (en) * | 1982-04-21 | 1984-06-05 | Union Carbide Corporation | Process for preparing nonionic surfactants-oxyalkylation with calcium and/or strontium catalysts |
| FR2532318B1 (fr) * | 1982-08-31 | 1985-06-14 | Rhone Poulenc Chim Base | Procede de preparation de triarylphosphines sulfonees |
| DE3234701A1 (de) * | 1982-09-18 | 1984-04-05 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur herstellung von aldehyden |
| DE3235030A1 (de) * | 1982-09-22 | 1984-03-22 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur herstellung von sulfonierten arylphosphinen |
| DE3235029A1 (de) * | 1982-09-22 | 1984-03-22 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur rueckgewinnung von wasserloeslichen, rhodium enthaltenden hydroformylierungskatalysatoren |
| US4480138A (en) * | 1982-10-12 | 1984-10-30 | Celanese Corporation | Hydroformylation process |
| DE3245883A1 (de) * | 1982-12-11 | 1984-06-14 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur hydroformylierung von olefinen |
| FR2550202B1 (fr) * | 1983-08-03 | 1986-03-21 | Rhone Poulenc Rech | Procede de preparation de tri(m-sulfophenyl) phosphine |
| DE3341035A1 (de) * | 1983-11-12 | 1985-05-23 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur herstellung von aldehyden |
| DE3347406A1 (de) * | 1983-12-29 | 1985-07-11 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur abtrennung und wiedergewinnung von rhodium aus den produkten der oxosynthese |
| FR2561650B1 (fr) * | 1984-03-26 | 1987-10-23 | Rhone Poulenc Rech | Perfectionnement au procede de preparation de tri(m-sulfophenyl)phosphine par hydrolyse et dilution controlees du sulfonat |
| DE3411034A1 (de) * | 1984-03-26 | 1985-09-26 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur rueckgewinnung von rhodium aus reaktionsprodukten der oxosynthese |
| DE3412335A1 (de) * | 1984-04-03 | 1985-10-10 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur herstellung von aldehyden |
| DE3413427A1 (de) * | 1984-04-10 | 1985-10-17 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur herstellung von aldehyden |
| DE3415968A1 (de) * | 1984-04-28 | 1985-10-31 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur herstellung von aldehyden |
| DE3420491A1 (de) * | 1984-06-01 | 1985-12-05 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur herstellung von aldehyden |
| DE3420493A1 (de) * | 1984-06-01 | 1985-12-05 | Ruhrchemie Ag, 4200 Oberhausen | Quartaere ammoniumsalze sulfonierter triarylphosphine |
| US4578523A (en) * | 1985-05-29 | 1986-03-25 | Ruhrchemie Aktiengesellschaft | Process for the preparation of aldehydes |
-
1986
- 1986-11-18 US US06/932,002 patent/US4731486A/en not_active Expired - Lifetime
-
1987
- 1987-11-17 RU SU874203758A patent/RU2002728C1/ru active
- 1987-11-17 BE BE8701298A patent/BE1000619A5/fr not_active IP Right Cessation
- 1987-11-17 MX MX009383A patent/MX166784B/es unknown
- 1987-11-17 DE DE19873739064 patent/DE3739064A1/de active Granted
- 1987-11-17 DE DE8787116971T patent/DE3779725D1/de not_active Expired - Lifetime
- 1987-11-17 EP EP87116971A patent/EP0268268B1/fr not_active Expired - Lifetime
- 1987-11-17 AU AU81280/87A patent/AU611867B2/en not_active Ceased
- 1987-11-17 AT AT87116971T patent/ATE77075T1/de active
- 1987-11-18 DK DK605887A patent/DK605887A/da not_active Application Discontinuation
- 1987-11-18 BR BR8706223A patent/BR8706223A/pt not_active Application Discontinuation
- 1987-11-18 PL PL1987268876A patent/PL153062B1/pl unknown
- 1987-11-18 YU YU2091/87A patent/YU45074B/xx unknown
- 1987-11-18 IT IT22675/87A patent/IT1223147B/it active
- 1987-11-18 ZA ZA878638A patent/ZA878638B/xx unknown
- 1987-11-18 GB GB8727013A patent/GB2197867B/en not_active Expired - Lifetime
- 1987-11-18 JP JP62289666A patent/JPH0667868B2/ja not_active Expired - Fee Related
- 1987-11-18 CA CA000552143A patent/CA1307296C/fr not_active Expired - Lifetime
- 1987-11-18 NL NL8702752A patent/NL8702752A/nl not_active Application Discontinuation
- 1987-11-18 HU HU875125A patent/HU202177B/hu not_active IP Right Cessation
- 1987-11-18 IN IN834/MAS/87A patent/IN170369B/en unknown
- 1987-11-18 ES ES8703288A patent/ES2009221A6/es not_active Expired
- 1987-11-18 FI FI875087A patent/FI90858C/fi not_active IP Right Cessation
- 1987-11-18 FR FR878715930A patent/FR2606771B1/fr not_active Expired
- 1987-11-18 KR KR1019870012952A patent/KR920003556B1/ko not_active Expired
- 1987-11-18 AR AR87309326A patent/AR248390A1/es active
- 1987-11-18 NO NO874810A patent/NO166440C/no unknown
- 1987-11-18 SE SE8704533A patent/SE8704533L/ not_active Application Discontinuation
- 1987-11-18 CN CN87101178A patent/CN1017145B/zh not_active Expired
-
1989
- 1989-04-24 ES ES8901417A patent/ES2012718A6/es not_active Expired - Lifetime
- 1989-04-24 ES ES8901418A patent/ES2012719A6/es not_active Expired - Lifetime
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2459217A1 (fr) * | 1979-06-18 | 1981-01-09 | Celanese Corp | Procede d'hydroformylation d'une olefine, ameliore par le choix du solvant de reaction et le controle des parametres d'extraction du produit |
| FR2489308A1 (fr) * | 1980-09-04 | 1982-03-05 | Johnson Matthey Plc | Procede catalytique |
| EP0216315A1 (fr) * | 1985-09-26 | 1987-04-01 | Hoechst Aktiengesellschaft | Procédé de préparation d'aldéhydes |
| US4633021A (en) * | 1985-11-29 | 1986-12-30 | National Distillers And Chemical Corporation | Olefin hydroformylation |
| EP0254937A2 (fr) * | 1986-07-10 | 1988-02-03 | Union Carbide Corporation | Hydroformylation à l'aide des ligands organiques solubles et peu volatiles de phosphine |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| RE | Patent lapsed |
Owner name: UNION CARBIDE CORP. Effective date: 19951130 |