BE363764A - - Google Patents

Info

Publication number
BE363764A
BE363764A BE363764A BE363764A BE363764A BE 363764 A BE363764 A BE 363764A BE 363764 A BE363764 A BE 363764A BE 363764 A BE363764 A BE 363764A BE 363764 A BE363764 A BE 363764A
Authority
BE
Belgium
Prior art keywords
magnesium
dolomite
carbonate
lime
wind
Prior art date
Application number
BE363764A
Other languages
French (fr)
Original Assignee
Rwk Rhein Westfael Kalkwerke
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rwk Rhein Westfael Kalkwerke filed Critical Rwk Rhein Westfael Kalkwerke
Publication of BE363764A publication Critical patent/BE363764A/fr

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01FCOMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
    • C01F5/00Compounds of magnesium
    • C01F5/02Magnesia
    • C01F5/06Magnesia by thermal decomposition of magnesium compounds
    • C01F5/08Magnesia by thermal decomposition of magnesium compounds by calcining magnesium hydroxide
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2/00Lime, magnesia or dolomite
    • C04B2/10Preheating, burning calcining or cooling
    • C04B2/102Preheating, burning calcining or cooling of magnesia, e.g. dead burning

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)

Description

       

   <Desc/Clms Page number 1> 
 



  Procédé pour   11 obtention   de magnésie, à partir de dolomie. 



   Pour l'obtention de magnégi , partir de la dolomie on connait déjà depuis plusieurs dizaines d'années des procédés servant à séparer les deux constituants de la dolomie, la chaux et la magnésie. La plupart de ces procédés consistent à mettre en solution l'un des deux constituants. 



   C'est ainsi qu'on obtient suivant le procédé pattinson uns magnésie très pure en transformant l'oxyde de magnésium en bicarbonate de magnésium soluble et en séparant ce dernier par filtration du carbonate de chaux in oluble.   'Dans   d'autres pro- 

 <Desc/Clms Page number 2> 

 cédés on utilise pour la séparation la solubilité différente des sulfates et des saccharates.Par l'audition d'une   s olu-   tion de chlorure de magnésium à de la dolomie cuite, on peut aussi atteindre une séparation car il se produit une transfor- mation suivant l'équation. 
 EMI2.1 
 



  MgC12 + CaO = bRgO + Caca 2 
De la chaux passe donc en solution comme chlorure de cal- cium tandis qu'il se sépare en même temps de l'hydrate de magnésium du chlorure de magnésium. On a finalement proposé 
 EMI2.2 
 aussi d'éliminer la chaux par lixivistion -:1 moyen d'eau de la, dolomie fortement cuite ou de tirer la magnésie de la dolomie à moitié cuite* Tous ces procédés nécessitent toutefois des dispositifs encombrants qui ont été abandonnés peurdes raisons économiques. 



   En opposition avec les procédés purement chimiques men- tionnés plus haut, il a en outre été proposé   de   cuire la dolo- mie à une température à laquelle seul le carbonate de magné- sium cède son acide carbonique. Ce produit à moitié cuit est broyé et soumis à un blutage au moyen de vent. On produit donc ici la séparation de l'oxyde de   magnésium   du carbonate 
 EMI2.3 
 de chaux à l'aide de la différence des poids spécifique s'Comme la différence des poids spécifiqu-s i1' f!St toute-: f01s ).'"\S suf- fisamment grande, la séparation ne ;:'1(: ut e t  'Lu,:' tri,s s 1mpé'r- faite. 



   La présente invention se rapporte à, un   perfectionneront   notable de ce procédé. Suivant catte invention, la dolomie à moitié cuite et broyée est traitée, avant le blutage au moyen de vent, par une quantité d'eau telle   que     l' oxyde   de ma- gnésium se transforme en hydrate- On peut en même temps faire agir de l'acide carbonique de façon qu'il se forme du carbona- te de magnésium basique. De cette   manière,   la différence des poids spécifiques des parties à séprer est tellement grande 

 <Desc/Clms Page number 3> 

 que la séparation réussit parfaitement car les composés de magnésium ainsi obtenus ont un poids spécifique relativement minime par rapport au carbonate de chaux.



   <Desc / Clms Page number 1>
 



  Process for obtaining magnesia from dolomite.



   To obtain maggi, starting from dolomite, processes have already been known for several decades for separating the two constituents of dolomite, lime and magnesia. Most of these processes consist of putting one of the two constituents in solution.



   It is thus that one obtains according to the Pattinson process a very pure magnesia by converting the magnesium oxide into soluble magnesium bicarbonate and by separating the latter by filtration from the inoluble lime carbonate. 'In other pro-

 <Desc / Clms Page number 2>

 The different solubility of sulphates and saccharates is used for the separation. By hearing a solution of magnesium chloride to cooked dolomite, a separation can also be achieved because a transformation takes place. according to the equation.
 EMI2.1
 



  MgC12 + CaO = bRgO + Poop 2
Lime therefore goes into solution as calcium chloride while at the same time it separates from the magnesium hydrate from the magnesium chloride. We finally proposed
 EMI2.2
 also to remove lime by leaching -: 1 means of water from the strongly cooked dolomite or to draw the magnesia from the half-cooked dolomite * All these processes however require bulky devices which have been abandoned for economic reasons.



   In opposition to the purely chemical processes mentioned above, it has also been proposed to cook the dolomite at a temperature at which only the magnesium carbonate gives up its carbonic acid. This half-cooked product is crushed and subjected to blasting by means of wind. The separation of the magnesium oxide from the carbonate is therefore produced here.
 EMI2.3
 of lime using the difference in specific weights sAs the difference in specific weights i1 'f! St all-: f01s).' "\ S sufficiently large, the separation ne;: '1 ( : ut and 'Lu ,:' sort, ss 1mpé'r- done.



   The present invention relates to a significant improvement of this process. According to this invention, the half-cooked and crushed dolomite is treated, before the blasting by means of wind, with a quantity of water such that the oxide of magnesium is transformed into a hydrate. carbonic acid so that basic magnesium carbonate is formed. In this way, the difference in the specific weights of the parts to be separated is so great.

 <Desc / Clms Page number 3>

 that the separation is perfectly successful because the magnesium compounds thus obtained have a relatively low specific gravity relative to lime carbonate.


    

Claims (1)

R e v e n d i c a t i o n. R e v e n d i c a t i o n. =+=+=+=+=+=+=+ Procédé pour extraire la magnésie de la dolomie, dans le- quel la dolomie est cuite à une tempérauture à laque lle seul l'acide carbonique du carbonate de magnésium s'échappe et l'o- xyde de magnésium ou l'hydrate de magnésium est séparé du car- bonate de chaux par blutage au moyen de vent et est ensuite calciné, caractérisé en ce que l'oxyde de magnésium est trans- formé, avant le blutage au moyen de vent, en hydrate de ma- gnésium ou en carbonate basique de magnésium. = + = + = + = + = + = + = + A process for extracting magnesia from dolomite, in which the dolomite is fired at a temperature where only the carbonic acid of the magnesium carbonate escapes and the magnesium oxide or magnesium hydrate is separated from the lime carbonate by blasting by means of wind and is then calcined, characterized in that the magnesium oxide is transformed, before the sifting by means of wind, into magnesium hydrate or basic carbonate magnesium.
BE363764A 1928-09-27 1929-09-14 BE363764A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DER75831D DE519420C (en) 1928-09-27 1928-09-27 Process for the extraction of magnesia from dolomite

Publications (1)

Publication Number Publication Date
BE363764A true BE363764A (en) 1929-10-31

Family

ID=7415186

Family Applications (1)

Application Number Title Priority Date Filing Date
BE363764A BE363764A (en) 1928-09-27 1929-09-14

Country Status (2)

Country Link
BE (1) BE363764A (en)
DE (1) DE519420C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2459209A1 (en) * 1979-06-14 1981-01-09 Ustav Pro Vyzkum Rud Purificn. of magnesite - by roasting to controlled degree and treating product with water and steam, for magnesium oxide prodn.

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2459209A1 (en) * 1979-06-14 1981-01-09 Ustav Pro Vyzkum Rud Purificn. of magnesite - by roasting to controlled degree and treating product with water and steam, for magnesium oxide prodn.

Also Published As

Publication number Publication date
DE519420C (en) 1931-02-27

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