BE403029A - Process for improving the flexibility of leather - Google Patents
Process for improving the flexibility of leatherInfo
- Publication number
- BE403029A BE403029A BE403029A BE403029A BE403029A BE 403029 A BE403029 A BE 403029A BE 403029 A BE403029 A BE 403029A BE 403029 A BE403029 A BE 403029A BE 403029 A BE403029 A BE 403029A
- Authority
- BE
- Belgium
- Prior art keywords
- flexibility
- tanning
- leather
- improving
- skins
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 6
- 239000010985 leather Substances 0.000 title description 5
- 239000005018 casein Substances 0.000 claims description 4
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 claims description 4
- 235000021240 caseins Nutrition 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 235000011180 diphosphates Nutrition 0.000 claims description 3
- 102000009027 Albumins Human genes 0.000 claims description 2
- 108010088751 Albumins Proteins 0.000 claims description 2
- 108010010803 Gelatin Proteins 0.000 claims description 2
- 101100462438 Mus musculus Otulin gene Proteins 0.000 claims description 2
- 239000003995 emulsifying agent Substances 0.000 claims description 2
- 229920000159 gelatin Polymers 0.000 claims description 2
- 239000008273 gelatin Substances 0.000 claims description 2
- 235000019322 gelatine Nutrition 0.000 claims description 2
- 235000011852 gelatine desserts Nutrition 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 239000001397 quillaja saponaria molina bark Substances 0.000 claims description 2
- 229930182490 saponin Natural products 0.000 claims description 2
- 150000007949 saponins Chemical class 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- 230000001747 exhibiting effect Effects 0.000 claims 1
- 210000003491 skin Anatomy 0.000 description 8
- 238000002803 maceration Methods 0.000 description 5
- 238000001354 calcination Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 3
- 239000012535 impurity Substances 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- 235000011116 calcium hydroxide Nutrition 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 210000002615 epidermis Anatomy 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229940048084 pyrophosphate Drugs 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C1/00—Chemical treatment prior to tanning
- C14C1/08—Deliming; Bating; Pickling; Degreasing
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
- Detergent Compositions (AREA)
Description
<Desc/Clms Page number 1>
EMI1.1
océdé pour l'amélioration de la souplesse du cuir. -0
On sait qu'on doit soumettre les peaux animales avant le tannage $ un traitement préparatoire pour la séparation de l'épiderme et de la couche sous-jacente.
Après la calcination et après l'enlèvement de la couche supérieure à poils, la peau de cuir se trouve généralement dans un état fortement gonflé, plein et "ferme" et renferme à son intérieur des résidus de lait de chaux. Si la peau est tannée dans cet état de gonflement, elle donne un mauvais cuir. En employant des bains de macération, tels que des bains de son, d'excréments etc. ou aussi des enz,ymes pures, on diminue le gonflement de la peau, c'est-à-dire que la peau est amenée à un état ramolli et flasque, de sorte que les impuretés résiduelles, même celles retenues à son intérieur peuvent être enlevées mécaniquement sans difficultés. En même temps, la surface de la peau acquiert
<Desc/Clms Page number 2>
l'état favorable nécessaire pour le tannage, ce qu'on re- connaît à la rature glissante qu'elle prend.
La souplesse du cuir résultant après le tannage est, en dehors de l'action spécifique de l'agent de calcination, grandement dépendante du degré d'élimination ultérieure de l'agent de calcination et des impuretés.
Or, on a trouvé que les agents de lavage et d'emulsionnement préparés d'après le brevet français N 620. 120 au moyen de pyrophosphates et de gomme, gélatine, albumines, saponine, caséine etc. rendent aussi d'excellents services pour le traitement préparatoire des peaux avant le tannage en vue de la réalisation de cuirs extrêmement souples. Si la peau animale préparée comme d'usage en vue du tannage est traitée avec un bain contenant une prépara- tion établie d'après le dit brevet français, ce traitement pouvant précéder ou suivre l'opération de macération, on réalise, après le tannage, des cuirs qui sont beaucoup plus souples que ceux qu'on obtient suivant les procédés de macération usuels. Il est même possible de remplacer le procédé de macération usuel par le traitement particulier signalé suivant l'invention.
La durée de ce traitement perfectionné dépend de l'effet désiré ; il en est de même de la concentration des bains.
E x e m p l e .
Les peaux préparées de la manière ordinaire par calcination et macération sont mises sur les rames ou introduites dans le tambour conjointement avec la quantité d'eau nécessaire à une température de 35 à 40 C. et agitées ou mouvementées dans ce bain pendant 1 à 3/2 heures en y 2joutant 1 à 3/2 pour cent d'un mélange de
<Desc/Clms Page number 3>
2 parties de pyrophosphate de sodium neutralisé et d'une partie de caséine, puis elles sont rincées et soumises comme d'habitude l'opération de tannage. La quantité ajoutée du mélange de pyrophosphate et de caséine dépend de la nature des peaux ; pluscelles-ci renferment de graisse, plus devront être grandes les quantités de mélange employer.
Résumé.
**ATTENTION** fin du champ DESC peut contenir debut de CLMS **.
<Desc / Clms Page number 1>
EMI1.1
oced for improving the suppleness of the leather. -0
It is known that animal skins must be subjected before tanning to a preparatory treatment for the separation of the epidermis and the underlying layer.
After calcination and after removal of the top pile layer, the leather hide is generally in a highly swollen, full and "firm" state and has milk of lime residue inside. If the skin is tanned in this swelling state, it results in bad leather. By using maceration baths, such as bran baths, excrement baths etc. or also pure enz, ymes, the swelling of the skin is reduced, that is to say that the skin is brought to a softened and flabby state, so that the residual impurities, even those retained inside it can be mechanically removed without difficulty. At the same time, the surface of the skin acquires
<Desc / Clms Page number 2>
the favorable condition necessary for tanning, which is recognized by the slippery erasure which it takes.
The flexibility of the resulting leather after tanning is, apart from the specific action of the calcining agent, greatly dependent on the degree of subsequent removal of the calcining agent and impurities.
Now, it has been found that the washing and emulsifying agents prepared according to French patent No. 620.120 by means of pyrophosphates and gum, gelatin, albumins, saponin, casein, etc. also render excellent services for the preparatory treatment of hides before tanning for the production of extremely flexible leathers. If the animal skin prepared as usual for tanning is treated with a bath containing a preparation established according to the said French patent, this treatment being able to precede or follow the maceration operation, after tanning is carried out , leathers which are much softer than those obtained by the usual maceration processes. It is even possible to replace the usual maceration process by the particular treatment indicated according to the invention.
The duration of this advanced treatment depends on the desired effect; the same is true of the concentration of the baths.
E x e m p l e.
The skins prepared in the ordinary way by calcination and maceration are put on the oars or introduced into the drum together with the quantity of water required at a temperature of 35 to 40 C. and stirred or stirred in this bath for 1 to 3 / 2 hours adding 1 to 3/2 percent of a mixture of
<Desc / Clms Page number 3>
2 parts of neutralized sodium pyrophosphate and 1 part of casein, then they are rinsed and subjected as usual to the tanning operation. The quantity added of the mixture of pyrophosphate and casein depends on the nature of the skins; the more fat they contain, the greater the amount of mixture to use.
Summary.
** ATTENTION ** end of DESC field can contain start of CLMS **.
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEG85519A DE622213C (en) | 1933-05-11 | 1933-05-11 | Process for improving the softness and suppleness of leather |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BE403029A true BE403029A (en) | 1934-06-30 |
Family
ID=89942814
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BE403029A BE403029A (en) | 1933-05-11 | 1934-05-08 | Process for improving the flexibility of leather |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US1974861A (en) |
| BE (1) | BE403029A (en) |
| DE (1) | DE622213C (en) |
| FR (1) | FR772976A (en) |
| GB (1) | GB433815A (en) |
| NL (1) | NL38797C (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1213950B (en) * | 1957-07-17 | 1966-04-07 | Benckiser Gmbh Joh A | Process for tanning hides and skins with chrome tanning agents |
| DE1221394B (en) * | 1960-03-11 | 1966-07-21 | Benckiser Gmbh Joh A | Process for tanning hides and skins with chrome tanning agents |
| DE2911401A1 (en) | 1979-03-23 | 1980-10-02 | Roehm Gmbh | METHOD FOR ASHING BLEES FROM ANIMAL SKIN AND SKIN |
| DE2930342A1 (en) | 1979-07-26 | 1981-02-19 | Roehm Gmbh | IMPROVED METHOD FOR PRODUCING LEATHER |
-
1933
- 1933-05-11 DE DEG85519A patent/DE622213C/en not_active Expired
-
1934
- 1934-04-27 US US722815A patent/US1974861A/en not_active Expired - Lifetime
- 1934-05-07 NL NL69365A patent/NL38797C/en active
- 1934-05-08 BE BE403029A patent/BE403029A/en unknown
- 1934-05-08 FR FR772976D patent/FR772976A/en not_active Expired
- 1934-05-11 GB GB14280/34A patent/GB433815A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE622213C (en) | 1935-11-22 |
| FR772976A (en) | 1934-11-09 |
| US1974861A (en) | 1934-09-25 |
| NL38797C (en) | 1936-08-15 |
| GB433815A (en) | 1935-08-21 |
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