BE896443A - Transformation d'alcanes en aldehydes insatures - Google Patents

Transformation d'alcanes en aldehydes insatures

Info

Publication number
BE896443A
BE896443A BE0/210540A BE210540A BE896443A BE 896443 A BE896443 A BE 896443A BE 0/210540 A BE0/210540 A BE 0/210540A BE 210540 A BE210540 A BE 210540A BE 896443 A BE896443 A BE 896443A
Authority
BE
Belgium
Prior art keywords
alcanes
transformation
unsaturated aldehydes
aldehydes
unsaturated
Prior art date
Application number
BE0/210540A
Other languages
English (en)
Inventor
S Khoobiar
Original Assignee
Halcon Sd Group Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US06/368,196 external-priority patent/US4413147A/en
Application filed by Halcon Sd Group Inc filed Critical Halcon Sd Group Inc
Publication of BE896443A publication Critical patent/BE896443A/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B01J27/19—Molybdenum
    • B01J27/192—Molybdenum with bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/37—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of >C—O—functional groups to >C=O groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3332—Catalytic processes with metal oxides or metal sulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3335—Catalytic processes with metals
    • C07C5/3337—Catalytic processes with metals of the platinum group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
BE0/210540A 1982-04-14 1983-04-13 Transformation d'alcanes en aldehydes insatures BE896443A (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/368,196 US4413147A (en) 1982-04-14 1982-04-14 Conversion of isobutane to methacrolein
US06/420,077 US4535188A (en) 1982-04-14 1982-09-20 Conversion of isobutane to methacrolein

Publications (1)

Publication Number Publication Date
BE896443A true BE896443A (fr) 1983-10-13

Family

ID=27004081

Family Applications (1)

Application Number Title Priority Date Filing Date
BE0/210540A BE896443A (fr) 1982-04-14 1983-04-13 Transformation d'alcanes en aldehydes insatures

Country Status (2)

Country Link
US (1) US4535188A (fr)
BE (1) BE896443A (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006077316A1 (fr) * 2005-01-21 2006-07-27 Arkema France Procede de preparation de l’acide acrylique comprenant une oxydation partielle du propane en propylene

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
USRE32082E (en) * 1982-04-14 1986-02-11 The Halcon Sd Group, Inc. Conversion of isobutane to methacrolein
JP2969965B2 (ja) * 1991-01-17 1999-11-02 住友化学工業株式会社 イソブタンの接触酸化によるメタクリル酸の製造方法
DE19837519A1 (de) 1998-08-19 2000-02-24 Basf Ag Verfahren zur Herstellung von Acrolein und/oder Acrylsäure aus Propan
US6889383B1 (en) * 2000-10-23 2005-05-03 Clearplay, Inc. Delivery of navigation data for playback of audio and video content
EP1404632A1 (fr) 2001-06-29 2004-04-07 Basf Aktiengesellschaft Procede de production d'acide methacrylique a partir d'isobutane
MXPA04000708A (es) * 2001-07-26 2005-02-17 M & G Polimeri Italia Spa Composiciones de resina barredoras de oxigeno y recipientes que tienen turbidez baja, y metodos relacionados.
US8431743B2 (en) * 2004-07-01 2013-04-30 Basf Aktiengesellschaft Preparation of acrylic acid by heterogeneously catalyzed partial gas phase oxidation of propylene
US7601866B2 (en) 2005-03-01 2009-10-13 Basf Aktiengesellschaft Process for removing methacrolein from liquid phase comprising acrylic acid as a main constituent and target product, and methacrolein as a secondary component
EP1879846B1 (fr) * 2005-04-27 2009-07-15 Basf Se Procede de separation par rectification d'un liquide contenant de l'acide acrylique et/ou de l'acide methacrylique
US7851397B2 (en) 2005-07-25 2010-12-14 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
US7649112B2 (en) 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Integrated plant for producing 2-ethyl-hexanol and methacrylic acid and a method based thereon
US7649111B2 (en) 2005-07-25 2010-01-19 Saudi Basic Industries Corporation Catalyst for the oxidation of a mixed aldehyde feedstock to methacrylic acid and methods for making and using same
US7732367B2 (en) 2005-07-25 2010-06-08 Saudi Basic Industries Corporation Catalyst for methacrolein oxidation and method for making and using same
DE502006003491D1 (de) * 2005-11-03 2009-05-28 Basf Se Verfahren zum stabilen betreiben eines kontinuierlich ausgeübten herstellprozesses zur erzeugung von acrolein, oder acrylsäure oder deren gemisch aus propan
KR101370749B1 (ko) * 2005-11-24 2014-03-06 바스프 에스이 프로판으로부터 아크롤레인 또는 아크릴산, 또는 그의혼합물의 제조 방법
DE102005062026A1 (de) * 2005-12-22 2007-06-28 Basf Ag Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propylen zu Acrylsäure
DE102005062010A1 (de) * 2005-12-22 2007-06-28 Basf Ag Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propylen zu Acrylsäure
US7799946B2 (en) * 2007-02-14 2010-09-21 Saudi Basic Industries Corporation Process for separating methacrolein from methacrylic acid in a gas phase product from the partial oxidation of isobutene
DE102008044946B4 (de) * 2008-08-29 2022-06-15 Evonik Superabsorber Gmbh Einsatz von Schaumkörpern in Oxidations-Reaktoren zur Herstellung ungesättigter Carbonsäuren
US8921257B2 (en) 2011-12-02 2014-12-30 Saudi Basic Industries Corporation Dual function partial oxidation catalyst for propane to acrylic acid conversion
US8722940B2 (en) 2012-03-01 2014-05-13 Saudi Basic Industries Corporation High molybdenum mixed metal oxide catalysts for the production of unsaturated aldehydes from olefins
KR102319012B1 (ko) * 2018-11-13 2021-10-29 한화토탈 주식회사 포화탄화수소를 포함한 이소부텐을 이용한 메틸메타크릴레이트의 제조방법

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA623383A (en) * 1961-07-04 L. Barclay John Production of unsaturated aliphatic aldehydes
US3313856A (en) * 1967-04-11 Preparation of acrolein or methacrolein
CH430676A (de) * 1960-12-01 1967-02-28 Stamicarbon Verfahren zum Herstellen von Akrolein durch katalytische Oxydation von Propylen
US3161670A (en) * 1960-12-12 1964-12-15 Shell Oil Co Preparation of olefinic compounds
DE1165570B (de) * 1962-07-03 1964-03-19 Stamicarbon Verfahren zur Herstellung von Methacrolein durch katalytische Oxydation von Isobuten
US3479416A (en) * 1967-05-19 1969-11-18 Petro Tex Chem Corp Production of isobutylene from isobutane
US3470239A (en) * 1968-06-07 1969-09-30 Halcon International Inc Process for preparing methacrylic acid and its esters from isobutane
GB1340891A (en) * 1970-03-24 1973-12-19 Power Gas Ltd Catalytic oxidation of alkanes to aldehydes acids anhydrides and alkenes
US3692701A (en) * 1970-07-15 1972-09-19 Phillips Petroleum Co Group viii metals on tin-containing supports dehydrogenation catalysts
US4005985A (en) * 1972-01-07 1977-02-01 Phillips Petroleum Company Catalytic reactor
JPS4928725A (fr) * 1972-07-14 1974-03-14
JPS5320485B2 (fr) * 1972-11-22 1978-06-27
US4083883A (en) * 1976-03-16 1978-04-11 Uop Inc. Hydrocarbon dehydrogenation using a platinum or palladium, rhodium, nickel, alkaline or alkaline earth metal catalyst
US4144277A (en) * 1976-11-19 1979-03-13 Phillips Petroleum Company Dehydrogenation of hydrocarbons with zinc titanate catalyst
US4176140A (en) * 1976-11-19 1979-11-27 Phillips Petroleum Company Dehydrogenation of hydrocarbons with zinc titanate catalyst
US4041009A (en) * 1976-12-08 1977-08-09 Fujitsu Limited Process for producing anti-blocking and low pressure moldable diallyl phthalate resin molding materials
JPS5492908A (en) * 1977-12-28 1979-07-23 Nippon Zeon Co Ltd Catalysts for oxidation use of isobutylene
NL183170C (nl) * 1978-09-05 1988-08-16 Halcon Res & Dev Katalysator voor oxydatie van isobuteen en/of tertiaire butylalcohol.
JPS584694B2 (ja) * 1978-12-27 1983-01-27 宇部興産株式会社 アクロレインまたはメタクロレインの製造方法
JPS56166140A (en) * 1980-05-24 1981-12-21 Asahi Chem Ind Co Ltd Preparation of methacrolein
US4392003A (en) * 1980-06-12 1983-07-05 The British Petroleum Company Limited Isobutene by dehydroisomerization of normal butane
US4413147A (en) * 1982-04-14 1983-11-01 The Halcon Sd Group, Inc. Conversion of isobutane to methacrolein

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2006077316A1 (fr) * 2005-01-21 2006-07-27 Arkema France Procede de preparation de l’acide acrylique comprenant une oxydation partielle du propane en propylene
FR2881136A1 (fr) * 2005-01-21 2006-07-28 Arkema Sa Procede de preparation de l'acide acrylique comprenant une oxydation partielle du propane en propylene
US7732639B2 (en) 2005-01-21 2010-06-08 Arkema France Process for the preparation of acrylic acid comprising a partial oxidation of propane to propylene

Also Published As

Publication number Publication date
US4535188A (en) 1985-08-13

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Legal Events

Date Code Title Description
RE Patent lapsed

Owner name: THE HALCON SD GROUP INC.

Effective date: 19900430