BR0003343A - Processo para produção de acroleìna e ácido acrìlico - Google Patents

Processo para produção de acroleìna e ácido acrìlico

Info

Publication number
BR0003343A
BR0003343A BR0003343-0A BR0003343A BR0003343A BR 0003343 A BR0003343 A BR 0003343A BR 0003343 A BR0003343 A BR 0003343A BR 0003343 A BR0003343 A BR 0003343A
Authority
BR
Brazil
Prior art keywords
acrolein
acrylic acid
production
content
packaged
Prior art date
Application number
BR0003343-0A
Other languages
English (en)
Inventor
Michio Tanimoto
Hiromi Yunoki
Hideyuki Hironaka
Naomasa Kimura
Original Assignee
Nippon Catalytic Chem Ind
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Catalytic Chem Ind filed Critical Nippon Catalytic Chem Ind
Publication of BR0003343A publication Critical patent/BR0003343A/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/20—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms
    • C07C47/21—Unsaturated compounds having —CHO groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C47/22—Acryaldehyde; Methacryaldehyde
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B01J23/8885—Tungsten containing also molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

"PROCESSO PARA PRODUçãO DE ACROLEìNA E áCIDO ACRìLICO". A presente invenção proporciona um processo para produção de acroleína e ácido acrílico pela oxidação em fase de vapor de propileno na presença de catalisadores de óxido de composto de base Mo-Bi-Fe embalado em um reator multitubular de leito fixo em que acroleína e ácido acrílico podem ser estavelmente produzidos em alto rendimento por um longo período de tempo. Este processo é caracterizado em que cada tubo de reação tendo duas ou mais zonas de reação dispostas no sentido do eixo do tubo é embalado com catalisador tendo diferentes proporções do teor de Bi e/ou Fe para o teor de Mo de tal maneira que a proporção diminui do lado de entrada de gás na direção do lado de saída de gás.
BR0003343-0A 1999-08-04 2000-08-02 Processo para produção de acroleìna e ácido acrìlico BR0003343A (pt)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP22142899A JP3943291B2 (ja) 1999-08-04 1999-08-04 アクロレインおよびアクリル酸の製造方法

Publications (1)

Publication Number Publication Date
BR0003343A true BR0003343A (pt) 2001-03-13

Family

ID=16766597

Family Applications (1)

Application Number Title Priority Date Filing Date
BR0003343-0A BR0003343A (pt) 1999-08-04 2000-08-02 Processo para produção de acroleìna e ácido acrìlico

Country Status (13)

Country Link
US (1) US6632965B1 (pt)
EP (1) EP1074538B1 (pt)
JP (1) JP3943291B2 (pt)
KR (1) KR100587182B1 (pt)
CN (1) CN1162382C (pt)
BR (1) BR0003343A (pt)
CZ (1) CZ299169B6 (pt)
DE (1) DE60002793T2 (pt)
ID (1) ID26738A (pt)
MY (1) MY118110A (pt)
SG (1) SG87148A1 (pt)
TW (1) TW572884B (pt)
ZA (1) ZA200003948B (pt)

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JP4318367B2 (ja) * 2000-02-16 2009-08-19 株式会社日本触媒 アクロレインおよびアクリル酸の製造方法
JP3892244B2 (ja) 2001-03-21 2007-03-14 株式会社日本触媒 不飽和アルデヒドおよび不飽和カルボン酸製造用触媒の製造方法
EP1460053A4 (en) * 2001-12-27 2006-03-22 Mitsubishi Chem Corp VAPOR CATALYST OXIDATION PROCESS AND PROCESS FOR PRODUCING (METH) ACROLEIN OR (METH) ACRYLIC ACID
US6960684B2 (en) * 2002-03-29 2005-11-01 Nippon Shokubai Co., Ltd. Production process for unsaturated aldehyde
KR100487845B1 (ko) * 2002-07-25 2005-05-06 주식회사 엘지화학 프로필렌 기상 부분산화반응용 촉매 조성물 및 그것의 제조방법
JP4813758B2 (ja) 2003-02-27 2011-11-09 株式会社日本触媒 複合酸化物触媒およびそれを用いたアクリル酸の製造方法
KR100497175B1 (ko) 2003-03-26 2005-06-23 주식회사 엘지화학 프로필렌 및 이소부틸렌 부분산화 반응용 촉매의 제조방법
WO2005035115A1 (en) * 2003-10-14 2005-04-21 Lg Chem, Ltd. A catalyst for gaseous partial oxidation of propylene and method for preparing the same
US7161044B2 (en) * 2003-10-22 2007-01-09 Nippon Shokubai Co., Ltd. Catalytic gas phase oxidation reaction
WO2005049536A1 (ja) * 2003-11-14 2005-06-02 Mitsubishi Chemical Corporation 不飽和アルデヒド及び不飽和カルボン酸の製造方法
KR100561073B1 (ko) * 2004-02-25 2006-03-17 주식회사 엘지화학 기상 부분 산화 반응용 촉매 및 그의 제조방법
TWI303584B (en) * 2004-04-08 2008-12-01 Rohm & Haas Improved catalytic (amm)oxidation process for conversion of lower alkanes
JP5045175B2 (ja) * 2007-03-22 2012-10-10 住友化学株式会社 不飽和アルデヒド及び／又は不飽和カルボン酸の製造方法
JP5163273B2 (ja) * 2008-05-16 2013-03-13 住友化学株式会社 不飽和アルデヒド及び／又は不飽和カルボン酸製造用触媒の製造方法、並びに不飽和アルデヒド及び／又は不飽和カルボン酸の製造方法
EP2179790A1 (en) 2008-10-21 2010-04-28 Sued-Chemie AG Bismuth-containing mixed oxide catalysts
EP2179793A1 (en) 2008-10-21 2010-04-28 Sued-Chemie AG Phosphorous-containing mixed oxide catalysts
CN102389806A (zh) * 2011-10-08 2012-03-28 连云港阳方催化科技有限公司 用于丙烯催化氧化合成丙烯醛的催化剂及其制法
WO2013147032A1 (ja) * 2012-03-29 2013-10-03 株式会社日本触媒 固定床多管式反応器を用いてのアクリル酸の製造方法
EP2832717B1 (en) * 2012-03-30 2017-10-18 Nippon Shokubai Co., Ltd. Method for producing acrylic acid and acrolein using fixed-bed multitubular reactor
CN103769131B (zh) * 2012-10-23 2015-09-23 中国石油天然气股份有限公司 一种丙烯选择性氧化催化剂及其制备方法
US8835666B2 (en) * 2012-11-26 2014-09-16 Ineos Usa Llc Pre calcination additives for mixed metal oxide ammoxidation catalysts
CN103071514B (zh) * 2013-01-29 2015-09-30 新兴能源科技有限公司 一种用于丙烯一步催化氧化制备丙烯酸催化剂的制备方法
DE102013006251A1 (de) 2013-04-11 2014-10-16 Clariant International Ltd. Verfahren zur Herstellung eines Katalysators zur partiellen Oxidation von Olefinen
CN105209168B (zh) * 2013-05-09 2017-12-19 日本化药株式会社 不饱和醛和/或不饱和羧酸制造用催化剂、其制造方法以及不饱和醛和/或不饱和羧酸的制造方法
WO2015008815A1 (ja) 2013-07-18 2015-01-22 日本化薬株式会社 不飽和アルデヒドおよび／または不飽和カルボン酸の製造方法
CN104646012B (zh) * 2013-11-19 2017-06-06 中国石油天然气股份有限公司 丙烯选择性氧化催化剂及制备方法
CN104646013B (zh) * 2013-11-19 2017-06-06 中国石油天然气股份有限公司 用于不饱和醛选择性氧化的催化剂及其制备方法
CN104646011B (zh) * 2013-11-19 2017-06-06 中国石油天然气股份有限公司 一种低碳烯烃氧化催化剂及制备方法
JP6694884B2 (ja) * 2015-07-10 2020-05-20 日本化薬株式会社 不飽和アルデヒドおよび／または不飽和カルボン酸の製造方法
CN113905818B (zh) 2020-01-10 2023-01-13 日本化药株式会社 催化剂、催化剂填充方法和使用催化剂的化合物制造方法
CN114425379B (zh) * 2020-10-15 2024-01-26 中国石油化工股份有限公司 一种丙烯氧化制备丙烯醛的催化剂及其制备方法和应用
DE102021108191A1 (de) 2021-03-31 2022-10-06 Clariant Produkte (Deutschland) Gmbh Molybdän-bismut-eisen-nickel-mischoxid-material und verfahren zu dessen herstellung
JP2025532019A (ja) * 2022-09-28 2025-09-29 ローム アンド ハース カンパニー 高沸点副生成物の量を低減した（メタ）アクロレイン及び／又は（メタ）アクリル酸生成
WO2025176520A1 (de) 2024-02-23 2025-08-28 Basf Se Verfahren zur herstellung eines ethylenisch ungesättigten aldehyds und/oder einer ethylenisch ungesättigten carbonsäure an einem katalysatorfestbett eines rohrbündelreaktors

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JPS55113730A (en) * 1979-02-26 1980-09-02 Mitsubishi Petrochem Co Ltd Preparation of acrolein and acrylic acid
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JPH0784400B2 (ja) * 1990-04-03 1995-09-13 株式会社日本触媒 不飽和アルデヒドおよび不飽和酸の製造方法
JP3775872B2 (ja) * 1996-12-03 2006-05-17 日本化薬株式会社 アクロレイン及びアクリル酸の製造方法

Also Published As

Publication number Publication date
TW572884B (en) 2004-01-21
EP1074538A3 (en) 2001-07-04
MY118110A (en) 2004-08-30
DE60002793D1 (de) 2003-06-26
EP1074538B1 (en) 2003-05-21
SG87148A1 (en) 2002-03-19
KR100587182B1 (ko) 2006-06-08
US6632965B1 (en) 2003-10-14
CZ299169B6 (cs) 2008-05-07
KR20010049998A (ko) 2001-06-15
JP2001048817A (ja) 2001-02-20
JP3943291B2 (ja) 2007-07-11
ID26738A (id) 2001-02-08
DE60002793T2 (de) 2004-05-27
CZ20002824A3 (cs) 2001-03-14
EP1074538A2 (en) 2001-02-07
CN1162382C (zh) 2004-08-18
ZA200003948B (en) 2001-04-25
CN1283604A (zh) 2001-02-14

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