BR0010512A - Uso de materiais mesoporosos tipo mcm-41 como catalisadores na oxidação de "alfa"-pineno e processo para a oxidação de "alfa"-pineno - Google Patents

Uso de materiais mesoporosos tipo mcm-41 como catalisadores na oxidação de "alfa"-pineno e processo para a oxidação de "alfa"-pineno

Info

Publication number
BR0010512A
BR0010512A BR0010512-0A BR0010512A BR0010512A BR 0010512 A BR0010512 A BR 0010512A BR 0010512 A BR0010512 A BR 0010512A BR 0010512 A BR0010512 A BR 0010512A
Authority
BR
Brazil
Prior art keywords
pinene
oxidation
alpha
catalysts
mcm
Prior art date
Application number
BR0010512-0A
Other languages
English (en)
Inventor
Avelino Corma Canos
Marcelo Eduardo Domine
Manuel Susarte Rogel
Fernando Rey Garcia
Original Assignee
Consejo Superior Investigacion
Univ Valencia Politecnica
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Consejo Superior Investigacion, Univ Valencia Politecnica filed Critical Consejo Superior Investigacion
Publication of BR0010512A publication Critical patent/BR0010512A/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D301/00Preparation of oxiranes
    • C07D301/02Synthesis of the oxirane ring
    • C07D301/03Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/19Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with organic hydroperoxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/03Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/0308Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/89Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/065Galloaluminosilicates; Group IVB- metalloaluminosilicates; Ferroaluminosilicates
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/28Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation of CHx-moieties
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D303/00Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02Compounds containing oxirane rings
    • C07D303/04Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Geology (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Epoxy Compounds (AREA)

Abstract

"USO DE MATERIAIS MESOPOROSOS TIPO MCM-41 COMO CATALISADORES NA OXIDAçãO DE <244>-PINENO E PROCESSO PARA A OXIDAçãO DE <244>-PINENO". A invenção relaciona-se com a utilização de catalisadores sólidos microporosos tipo MCM-41 baseados em sílica contendo adicionalmente Ti em sua composição para obter produtos de oxidação de <244>-pineno usando hidroperóxidos orgânicos como agentes oxidantes.
BR0010512-0A 1999-03-16 2000-03-13 Uso de materiais mesoporosos tipo mcm-41 como catalisadores na oxidação de "alfa"-pineno e processo para a oxidação de "alfa"-pineno BR0010512A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ES9900565A ES2160044B1 (es) 1999-03-16 1999-03-16 Oxidacion de *-pineno.
PCT/ES2000/000087 WO2000054880A1 (es) 1999-03-16 2000-03-13 MATERIALES MESOPOROSOS TIPO MCM-41 CONTENIENDO TITANIO Y SU USO COMO CATALIZADORES EN LA OXIDACIÓN DE α PINENO

Publications (1)

Publication Number Publication Date
BR0010512A true BR0010512A (pt) 2002-04-02

Family

ID=8307719

Family Applications (1)

Application Number Title Priority Date Filing Date
BR0010512-0A BR0010512A (pt) 1999-03-16 2000-03-13 Uso de materiais mesoporosos tipo mcm-41 como catalisadores na oxidação de "alfa"-pineno e processo para a oxidação de "alfa"-pineno

Country Status (6)

Country Link
EP (1) EP1172142A1 (pt)
JP (1) JP2002538952A (pt)
CN (1) CN1351519A (pt)
BR (1) BR0010512A (pt)
ES (1) ES2160044B1 (pt)
WO (1) WO2000054880A1 (pt)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100415427B1 (ko) * 2001-08-07 2004-01-16 인천정유 주식회사 금속/Al-MCM-41 이원촉매 및 이의 제조방법과금속/Al-MCM-41 이원촉매를 이용한 불포화탄화수소의 수소화반응
KR20060032136A (ko) * 2003-05-08 2006-04-14 플렉시트랄, 인코포레이티드 신규한 방향 유도체
RU2425040C1 (ru) * 2010-02-24 2011-07-27 Новосибирский институт органической химии им. Н.Н. Ворожцова Сибирского отделения Российской академии наук (НИОХ СО РАН) Способ получения 2,3-эпоксипинана из скипидара
CN101885671A (zh) * 2010-07-01 2010-11-17 杭州格林香料化学有限公司 一种连续合成龙脑烯醛的生产方法
CN104190392B (zh) * 2014-07-25 2017-04-12 广西梧州松脂股份有限公司 钛基催化剂的制备方法
PL237108B1 (pl) * 2018-02-27 2021-03-22 Univ West Pomeranian Szczecin Tech Sposób utleniania alfa-pinenu
CN113905987B (zh) * 2019-05-29 2024-10-18 住友化学株式会社 含钛的硅氧化物的制造方法、环氧化物的制造方法和含钛的硅氧化物
CN113181967B (zh) * 2021-04-28 2023-07-14 昆明理工大学 磺酸化钛改性的kit-6固体酸催化剂在合成龙脑中的应用

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2092428B1 (es) * 1993-06-15 1997-08-01 Univ Valencia Politecnica Material de estructura tipo zeolita de poros ultragrandes con un red constituida por oxidos de silicio y titanio; su sintesis y utilizacion para la oxidacion selectiva de productos organicos.

Also Published As

Publication number Publication date
EP1172142A1 (en) 2002-01-16
JP2002538952A (ja) 2002-11-19
ES2160044A1 (es) 2001-10-16
ES2160044B1 (es) 2002-06-16
WO2000054880A1 (es) 2000-09-21
CN1351519A (zh) 2002-05-29

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Legal Events

Date Code Title Description
B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]

Free format text: REFERENTE A 4A, 5A, 6A E 7A ANUIDADES.

B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 1927 DE 11/12/2007.