BR0012909A - Meio de reação de carbonilação em fase lìquida, e, processos para a carbonilação de um substrato e para a fabricação de um alquil éster - Google Patents
Meio de reação de carbonilação em fase lìquida, e, processos para a carbonilação de um substrato e para a fabricação de um alquil ésterInfo
- Publication number
- BR0012909A BR0012909A BR0012909-7A BR0012909A BR0012909A BR 0012909 A BR0012909 A BR 0012909A BR 0012909 A BR0012909 A BR 0012909A BR 0012909 A BR0012909 A BR 0012909A
- Authority
- BR
- Brazil
- Prior art keywords
- reaction medium
- metal
- polymeric dispersant
- carbonylation
- manufacture
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
- C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/20—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state
- B01J35/23—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state in a colloidal state
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
- B01J35/45—Nanoparticles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Chemically Coating (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Conductive Materials (AREA)
Abstract
"MEIO DE REAçãO DE CARBONILAçãO EM FASE LìQUIDA, E, PROCESSOS PARA A CARBONILAçãO DE UM SUBSTRATO E PARA A FABRICAçãO DE UM ALQUIL éSTER". Um meio de reação química em fase líquida compreende um ou mais reagentes, opcionalmente na presença de um produto da reação e um ou mais solventes, diluentes ou outra forma de transportador líquido, um sistema catalítico compreendendo pelo menos um metal ou composto metálico e opcionalmente outros compostos como ligandos ou agentes complexantes; caracterizado pelo fato de que o meio da reação compreende ainda um dispersante polimérico dissolvido no referido transportador líquido, o referido dispersante polimérico sendo capaz de estabilizar uma suspensão coloidal de partículas do referido metal ou do composto metálico dentro do transportador liquido. A presença do dispersante polimérico permite que o metal formado pela desativação do catalisador seja mais facilmente recuperado e reciclado. De preferência, o dispersante polimérico tem funcionalidade suficientemente ácida ou básica para estabilizar a suspensão coloidal do referido metal ou composto metálico.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB9918229.7A GB9918229D0 (en) | 1999-08-04 | 1999-08-04 | Improvements relating to metal-compound catalysed processes |
| GB9918229.7 | 1999-08-04 | ||
| PCT/GB2000/002981 WO2001010551A1 (en) | 1999-08-04 | 2000-08-02 | Improvements relating to metal-compound catalysed processes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR0012909A true BR0012909A (pt) | 2002-04-30 |
| BR0012909B1 BR0012909B1 (pt) | 2011-08-23 |
Family
ID=10858462
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0012909-7A BR0012909B1 (pt) | 1999-08-04 | 2000-08-02 | meio de reação de carbonilação em fase lìquida, e, processos para a carbonilação de um substrato e para a fabricação de um alquil-c1-c4-éster. |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US6984668B1 (pt) |
| EP (1) | EP1204476B2 (pt) |
| JP (1) | JP4921664B2 (pt) |
| KR (1) | KR100851423B1 (pt) |
| CN (1) | CN1153622C (pt) |
| AT (1) | ATE298268T1 (pt) |
| AU (1) | AU769991B2 (pt) |
| BR (1) | BR0012909B1 (pt) |
| CA (1) | CA2386505C (pt) |
| DE (1) | DE60020977T3 (pt) |
| ES (1) | ES2243285T5 (pt) |
| GB (1) | GB9918229D0 (pt) |
| PT (1) | PT1204476E (pt) |
| TW (1) | TW572785B (pt) |
| WO (1) | WO2001010551A1 (pt) |
| ZA (1) | ZA200200276B (pt) |
Families Citing this family (34)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10048874A1 (de) | 2000-09-29 | 2002-04-11 | Basf Ag | Katalysatorsystem und Verfahren zur Carbonylierung |
| EP1236512A1 (en) * | 2001-02-28 | 2002-09-04 | Council Of Scientific And Industrial Research | Nanosized noble metal catalyst and process for selective preparation of 1,4 butenediol |
| RU2337754C2 (ru) * | 2002-08-10 | 2008-11-10 | ЛУСАЙТ ИНТЕРНЭШНЛ ЮКей ЛИМИТЕД | Адамантилсодержащая каталитическая система, способ получения интермедиатов для бидентатных лигандов такой системы и способ карбонилирования этиленовых соединений в ее присутствии |
| TWI301481B (en) * | 2002-08-10 | 2008-10-01 | Lucite Int Uk Ltd | A catalyst system |
| US7767864B2 (en) | 2003-07-03 | 2010-08-03 | Lucite International Uk Limited | Process for the hydroformylation of ethylenically unsaturated compounds |
| GB0403592D0 (en) | 2004-02-18 | 2004-03-24 | Lucite Int Uk Ltd | A catalyst system |
| GB0411951D0 (en) * | 2004-05-28 | 2004-06-30 | Lucite Int Uk Ltd | Carbonylation of ester |
| US20080269425A1 (en) * | 2004-12-02 | 2008-10-30 | Wako Pure Chemical Industries, Ltd. | Novel Catalyst |
| US7910022B2 (en) | 2006-09-15 | 2011-03-22 | Performance Indicator, Llc | Phosphorescent compositions for identification |
| AU2005319365B2 (en) | 2004-12-20 | 2011-02-03 | Performance Indicator L.L.C. | High-intensity, persistent photoluminescent formulations and objects, and methods for creating the same |
| GB0516556D0 (en) | 2005-08-12 | 2005-09-21 | Lucite Int Uk Ltd | Improved catalyst system |
| CA2626107C (en) | 2005-11-17 | 2016-06-21 | Lucite International Uk Limited | Carbonylation of ethylenically unsaturated compounds |
| US20070173866A1 (en) * | 2006-01-23 | 2007-07-26 | Tyco Healthcare Group, Lp | Surgical hemostatic clip |
| GB0607494D0 (en) | 2006-04-13 | 2006-05-24 | Lucite Int Uk Ltd | Metal complexes |
| GB2437930A (en) | 2006-05-10 | 2007-11-14 | Lucite Int Uk Ltd | Mixing apparatus |
| US7547894B2 (en) | 2006-09-15 | 2009-06-16 | Performance Indicator, L.L.C. | Phosphorescent compositions and methods for identification using the same |
| JP2010511600A (ja) * | 2006-12-02 | 2010-04-15 | ルーサイト インターナショナル ユーケー リミテッド | 新規のカルボニル化配位子及びエチレン性不飽和化合物のカルボニル化におけるその使用 |
| GB0625518D0 (en) * | 2006-12-21 | 2007-01-31 | Lucite Int Uk Ltd | Carbonylation of conjugated dienes |
| US7842128B2 (en) | 2007-09-13 | 2010-11-30 | Performance Indicatior LLC | Tissue marking compositions |
| US8039193B2 (en) | 2007-09-13 | 2011-10-18 | Performance Indicator Llc | Tissue markings and methods for reversibly marking tissue employing the same |
| GB0812297D0 (en) * | 2008-07-04 | 2008-08-13 | Lucite Int Uk Ltd | Novel carbonylation ligand sand thier use of in the carbonylation of ethylenically unsaturated compounds |
| GB201000078D0 (en) | 2010-01-05 | 2010-02-17 | Lucite Int Uk Ltd | Process for the carbonylation of ethylenically unsaturated compounds, novel carbonylation ligands and catalyst systems incorporatng such ligands |
| US8962512B1 (en) * | 2011-01-05 | 2015-02-24 | Stc.Unm | Synthesis of PD particles by alcohols-assisted photoreduction for use in supported catalysts |
| CN103764284B (zh) * | 2011-09-01 | 2016-08-17 | 帝斯曼知识产权资产管理有限公司 | 官能化的烯烃的烷氧基羰基化方法 |
| CN102516430B (zh) * | 2011-12-06 | 2014-08-06 | 广东慧信环保有限公司 | 一种利用活性/可控自由基聚合制备聚丙烯酰胺的方法 |
| WO2013107902A1 (en) | 2012-01-20 | 2013-07-25 | Dsm Ip Assets B.V. | Process for the separation of a dissolved catalyst system from an alkoxycarbonylation reaction mixture |
| CN103227335A (zh) * | 2013-04-07 | 2013-07-31 | 南京大学 | 一种二氧化钛改性钯金属纳米催化材料、其制备方法及应用 |
| WO2017170585A1 (ja) | 2016-03-31 | 2017-10-05 | 日本ゼオン株式会社 | 金属担持型触媒および水素化共役ジエン系重合体の製造方法 |
| US11266978B2 (en) * | 2016-03-31 | 2022-03-08 | Zeon Corporation | Method for preparing dispersion of metal-containing particles and method for producing hydrogenated conjugated diene polymer |
| CN114409541A (zh) * | 2020-10-28 | 2022-04-29 | 上海浦景化工技术股份有限公司 | 一种乙烯羰基化制丙酸酯类的系统 |
| CN114539058A (zh) * | 2020-11-24 | 2022-05-27 | 中国科学院大连化学物理研究所 | 一种甲醇和低碳烯烃多相催化制甲酯类化合物的方法 |
| CN114685276B (zh) * | 2020-12-30 | 2024-04-16 | 上海浦景化工技术股份有限公司 | 一种乙烯羰基化制备丙酸酯类产品的方法 |
| CN119488952B (zh) * | 2023-08-14 | 2025-10-10 | 中国石油化工股份有限公司 | Pd负载PAN催化剂及其制备方法、采用其制备羧酸酯的方法 |
| CN120054473A (zh) * | 2023-11-29 | 2025-05-30 | 中国石油化工股份有限公司 | Pd催化剂及其制备方法与应用 |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2542767A (en) * | 1949-02-11 | 1951-02-20 | Du Pont | Organic ester synthesis |
| DE2326489A1 (de) † | 1973-05-24 | 1974-12-12 | Ernst Prof Dr Bayer | Verfahren zur katalyse unter verwendung von loeslichen metallverbindungen synthetischer polymerer |
| US4235744A (en) † | 1978-10-30 | 1980-11-25 | Standard Oil Company (Ohio) | Carbonylation of olefinically unsaturated compounds |
| US4252677A (en) * | 1979-12-04 | 1981-02-24 | Xerox Corporation | Preparation of colloidal dispersion of nickel, palladium and platinum by the polymer-catalyzed decomposition of carbonyl compounds thereof |
| US4447639A (en) | 1982-08-06 | 1984-05-08 | Atlantic Richfield Company | Oxidative carbonylation of alcohols to dialkyl oxalates using a heterogeneous iron promoted Pd-V-P catalyst |
| US4743358A (en) | 1985-06-11 | 1988-05-10 | Exxon Research And Engineering Company | Method for suppressing the harmful effects of metal contaminants on hydrocarbon conversion catalysts using a strontium colloid system |
| DE3669446D1 (de) * | 1985-06-11 | 1990-04-19 | Exxon Research Engineering Co | Eine wasserunloesliche strontiumverbindung enthaltender krackkatalysator und verfahren zu seiner verwendung. |
| US4774361A (en) † | 1986-05-20 | 1988-09-27 | Union Carbide Corporation | Transition metal complex catalyzed reactions |
| KR880007426A (ko) * | 1986-12-24 | 1988-08-27 | 오노 알버어스 | 팔라듐 촉매를 사용한 올레핀형 불포화 화합물의 카르보닐화 방법 |
| US5166411A (en) | 1990-02-05 | 1992-11-24 | Shell Oil Company | Carbonylation catalyst system |
| GB9002521D0 (en) * | 1990-02-05 | 1990-04-04 | Shell Int Research | Carbonylation catalyst system |
| JPH06192175A (ja) * | 1992-12-28 | 1994-07-12 | Agency Of Ind Science & Technol | カルボン酸エステルの製造法 |
| DE4443701C1 (de) | 1994-12-08 | 1996-08-29 | Degussa | Schalenkatalysator, Verfahren zu seiner Herstellung und seine Verwendung |
| DE4443705A1 (de) * | 1994-12-08 | 1996-06-13 | Studiengesellschaft Kohle Mbh | Verfahren zur Herstellung von tensidstabilisierten Mono- und Bimetallkolloiden der Gruppe VIII und Ib des Periodensystems als isolierbare und in hoher Konzentration wasserlösliche Precursor für Katalysatoren |
| GB9425911D0 (en) * | 1994-12-22 | 1995-02-22 | Ici Plc | Process for the carbonylation of olefins and catalyst system for use therein |
| JPH0975744A (ja) * | 1995-09-07 | 1997-03-25 | Daicel Chem Ind Ltd | カルボニル化触媒系およびそれを用いたカルボニル化方法 |
| GB9705699D0 (en) * | 1997-03-19 | 1997-05-07 | Ici Plc | Process for the carbonylation of ethylene |
| JP3103322B2 (ja) * | 1997-05-23 | 2000-10-30 | コナミ株式会社 | シューティングゲーム装置、シューティングゲームの画像表示方法及び可読記録媒体 |
| DE19721601A1 (de) * | 1997-05-23 | 1998-11-26 | Hoechst Ag | Polybetain-stabilisierte, Palladium-haltige Nanopartikel, ein Verfahren zu ihrer Herstellung sowie daraus hergestellte Katalysatoren zur Gewinnung von Vinylacetat |
| GB9712601D0 (en) | 1997-06-16 | 1997-08-20 | Bp Chem Int Ltd | Chemical process |
| DE19745904A1 (de) * | 1997-10-17 | 1999-04-22 | Hoechst Ag | Polymerstabilisierte Metallkolloid-Lösungen, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren für Brennstoffzellen |
| DE19754304A1 (de) * | 1997-12-08 | 1999-06-10 | Hoechst Ag | Polybetain-stabilisierte Platin-Nanopartikel, Verfahren zu ihrer Herstellung und Verwendung für Elektrokatalysatoren in Brennstoffzellen |
| DE19801437A1 (de) † | 1998-01-16 | 1999-07-22 | Basf Ag | Verfahren zur Herstellung von Aldehyden |
| DE19908462A1 (de) † | 1999-02-26 | 2000-08-31 | Basf Ag | Verfahren zur Hydroformylierung von Olefinen |
| DE10048874A1 (de) | 2000-09-29 | 2002-04-11 | Basf Ag | Katalysatorsystem und Verfahren zur Carbonylierung |
| DE10228293A1 (de) * | 2001-07-28 | 2003-02-13 | Basf Ag | Verfahren zur Herstellung von Dialkylketonen |
-
1999
- 1999-08-04 GB GBGB9918229.7A patent/GB9918229D0/en not_active Ceased
-
2000
- 2000-08-01 TW TW89115432A patent/TW572785B/zh not_active IP Right Cessation
- 2000-08-02 DE DE60020977T patent/DE60020977T3/de not_active Expired - Lifetime
- 2000-08-02 PT PT00949774T patent/PT1204476E/pt unknown
- 2000-08-02 AT AT00949774T patent/ATE298268T1/de not_active IP Right Cessation
- 2000-08-02 CA CA2386505A patent/CA2386505C/en not_active Expired - Lifetime
- 2000-08-02 JP JP2001515056A patent/JP4921664B2/ja not_active Expired - Fee Related
- 2000-08-02 ES ES00949774T patent/ES2243285T5/es not_active Expired - Lifetime
- 2000-08-02 WO PCT/GB2000/002981 patent/WO2001010551A1/en not_active Ceased
- 2000-08-02 US US10/048,595 patent/US6984668B1/en not_active Expired - Fee Related
- 2000-08-02 CN CNB008110816A patent/CN1153622C/zh not_active Expired - Lifetime
- 2000-08-02 KR KR1020027001546A patent/KR100851423B1/ko not_active Expired - Fee Related
- 2000-08-02 BR BRPI0012909-7A patent/BR0012909B1/pt not_active IP Right Cessation
- 2000-08-02 EP EP00949774A patent/EP1204476B2/en not_active Expired - Lifetime
- 2000-08-02 AU AU63045/00A patent/AU769991B2/en not_active Ceased
-
2002
- 2002-01-11 ZA ZA200200276A patent/ZA200200276B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ATE298268T1 (de) | 2005-07-15 |
| DE60020977T2 (de) | 2006-05-04 |
| CA2386505C (en) | 2010-11-09 |
| ZA200200276B (en) | 2003-06-25 |
| US6984668B1 (en) | 2006-01-10 |
| JP2003506418A (ja) | 2003-02-18 |
| JP4921664B2 (ja) | 2012-04-25 |
| EP1204476A1 (en) | 2002-05-15 |
| GB9918229D0 (en) | 1999-10-06 |
| CA2386505A1 (en) | 2001-02-15 |
| BR0012909B1 (pt) | 2011-08-23 |
| DE60020977D1 (de) | 2005-07-28 |
| PT1204476E (pt) | 2005-09-30 |
| DE60020977T3 (de) | 2010-07-29 |
| CN1367715A (zh) | 2002-09-04 |
| CN1153622C (zh) | 2004-06-16 |
| AU769991B2 (en) | 2004-02-12 |
| EP1204476B2 (en) | 2010-03-17 |
| ES2243285T3 (es) | 2005-12-01 |
| EP1204476B1 (en) | 2005-06-22 |
| AU6304500A (en) | 2001-03-05 |
| KR20020072274A (ko) | 2002-09-14 |
| TW572785B (en) | 2004-01-21 |
| WO2001010551A1 (en) | 2001-02-15 |
| ES2243285T5 (es) | 2010-07-21 |
| KR100851423B1 (ko) | 2008-08-08 |
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Legal Events
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| B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
| B06A | Patent application procedure suspended [chapter 6.1 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 23/08/2011, OBSERVADAS AS CONDICOES LEGAIS. |
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| B21F | Lapse acc. art. 78, item iv - on non-payment of the annual fees in time |
Free format text: REFERENTE A 18A ANUIDADE. |
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| B24J | Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12) |
Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2473 DE 29-05-2018 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013. |