BR0101552A - Processo para hidrogenação catalìtica de aminasaromáticas - Google Patents
Processo para hidrogenação catalìtica de aminasaromáticasInfo
- Publication number
- BR0101552A BR0101552A BR0101552-4A BR0101552A BR0101552A BR 0101552 A BR0101552 A BR 0101552A BR 0101552 A BR0101552 A BR 0101552A BR 0101552 A BR0101552 A BR 0101552A
- Authority
- BR
- Brazil
- Prior art keywords
- aromatic amines
- catalytic hydrogenation
- improvement
- hydrogenation
- rhodium catalyst
- Prior art date
Links
- 150000004982 aromatic amines Chemical class 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 3
- 238000009903 catalytic hydrogenation reaction Methods 0.000 title abstract 2
- 239000003054 catalyst Substances 0.000 abstract 3
- 238000005984 hydrogenation reaction Methods 0.000 abstract 2
- 229910052703 rhodium Inorganic materials 0.000 abstract 2
- 239000010948 rhodium Substances 0.000 abstract 2
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- YQNQTEBHHUSESQ-UHFFFAOYSA-N lithium aluminate Chemical compound [Li+].[O-][Al]=O YQNQTEBHHUSESQ-UHFFFAOYSA-N 0.000 abstract 1
- 229910052707 ruthenium Inorganic materials 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/58—Platinum group metals with alkali- or alkaline earth metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
- B01J23/46—Ruthenium, rhodium, osmium or iridium
- B01J23/464—Rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
- B01J37/031—Precipitation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
- C07C209/68—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton
- C07C209/70—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton by reduction of unsaturated amines
- C07C209/72—Preparation of compounds containing amino groups bound to a carbon skeleton from amines, by reactions not involving amino groups, e.g. reduction of unsaturated amines, aromatisation, or substitution of the carbon skeleton by reduction of unsaturated amines by reduction of six-membered aromatic rings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
"PROCESSO PARA HIDROGENAçãO CATALìTICA DE AMINASAROMáTICAS". Esta invenção refere-se a um aperfeiçoamentoem um processo para a hidrogenação catalítica de aminasaromáticas e ao catalisador resultante. O processo básico para ahidrogenação, tanto de aminas aromáticas mononucleares quantopolinucleares, compreende o contato de uma amina aromática comhidrogênio, na presença de catalisador de ródio, sob condiçõesapropriadas para efetuar a hidrogenação do anel. Oaperfeiçoamento no processo de hidrogenação do anel reside nouso de um catalisador de ródio depositado sobre um suporte dealuminato de lítio. Freq³entemente, rutênio é incluído.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/561,071 US6184416B1 (en) | 2000-04-28 | 2000-04-28 | Lithium aluminate as a catalyst support for hydrogenation of aromatic amines |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR0101552A true BR0101552A (pt) | 2001-12-04 |
| BR0101552B1 BR0101552B1 (pt) | 2014-04-08 |
Family
ID=24240510
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0101552-4A BR0101552B1 (pt) | 2000-04-28 | 2001-04-23 | Processo para hidrogenação catalítica de aminas aromáticas |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US6184416B1 (pt) |
| EP (1) | EP1149629B1 (pt) |
| JP (1) | JP3954810B2 (pt) |
| CN (1) | CN1152852C (pt) |
| AT (1) | ATE268640T1 (pt) |
| BR (1) | BR0101552B1 (pt) |
| CA (1) | CA2344875C (pt) |
| DE (1) | DE60103695T2 (pt) |
| ES (1) | ES2222289T3 (pt) |
| PT (1) | PT1149629E (pt) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6429338B1 (en) * | 2002-01-17 | 2002-08-06 | Air Products And Chemicals, Inc. | Hydrogenation of single ring aromatic diamines |
| US6858769B2 (en) | 2002-10-18 | 2005-02-22 | Uop Llc | Lithium aluminate layered catalyst and a selective oxidation process using the catalyst |
| US7211180B2 (en) * | 2003-02-10 | 2007-05-01 | Robert Bosch Corporation | Contamination-resistant gas sensor element |
| US20090101502A1 (en) * | 2003-02-10 | 2009-04-23 | Robert Bosch Gmbh | Thermal Shock Resistant Gas Sensor Element |
| US8906214B2 (en) * | 2003-02-10 | 2014-12-09 | Robert Bosch Gmbh | Contamination-resistant gas sensor element |
| US7038088B2 (en) * | 2004-05-19 | 2006-05-02 | Air Products And Chemicals, Inc. | Hydrogenation of highly contaminated methylenedianiline |
| US6998507B1 (en) * | 2004-08-24 | 2006-02-14 | Air Products And Chemicals, Inc. | Hydrogenation of methylenedianiline |
| US7304183B2 (en) * | 2004-12-16 | 2007-12-04 | Huntsman Petrochemical Corporation | Co-production of cyclohexylamine and bis(para-aminocyclohexyl) methane |
| DE102004061608A1 (de) * | 2004-12-17 | 2006-07-06 | Basf Ag | Verfahren zur Herstellung von 1,2-Diamino-3-methylcyclohexan und/oder 1,2-Diamino-4-methylcyclohexan |
| GB0512791D0 (en) * | 2005-06-23 | 2005-07-27 | Johnson Matthey Plc | Catalysts |
| US7465833B2 (en) | 2005-09-22 | 2008-12-16 | Air Products And Chemicals, Inc. | Hydrogenation of aromatic amines to alicyclic amines using a lithium aluminate-based catalyst |
| DE102008002002A1 (de) | 2008-05-27 | 2009-12-03 | Evonik Degussa Gmbh | Chlor armes mehrstufiges Verfahren zur Herstellung von cycloaliphatischen Diisocyanaten |
| US9297791B2 (en) | 2012-12-20 | 2016-03-29 | Robert Bosch Gmbh | Gas sensor with thermal shock protection |
| EP2905273B1 (en) * | 2014-02-05 | 2018-06-06 | Covestro Deutschland AG | Process for hydrogenating aromatic di- and polyamines |
| TWI534131B (zh) | 2014-11-27 | 2016-05-21 | 財團法人工業技術研究院 | 氫化4,4’-二胺基二苯甲烷的觸媒與方法 |
| CA3188070A1 (en) | 2020-08-24 | 2022-03-03 | Jens Hildebrand | New depolymerization method for polyurethanes |
| WO2023275038A1 (de) * | 2021-07-02 | 2023-01-05 | Evonik Operations Gmbh | Hydrierung von aromatischen aminen aus pu-zersetzungsprozessen |
| CN117398987A (zh) * | 2023-10-18 | 2024-01-16 | 高化学(江苏)化工新材料有限责任公司 | 一种尖晶石结构铝酸锂催化剂载体的制备方法 |
| EP4685129A1 (de) | 2024-07-26 | 2026-01-28 | Evonik Operations GmbH | Verfahren zur hydrierung von mda |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2606927A (en) | 1946-10-21 | 1952-08-12 | Du Pont | Catalytic reduction of dicarbo-cyclic diamines |
| US2606925A (en) | 1949-12-15 | 1952-08-12 | Du Pont | Ruthenium catalyzed hydrogenation process for obtaining aminocyclohexyl compounds |
| US3636108A (en) | 1965-12-23 | 1972-01-18 | Du Pont | Catalytic hydrogenation of aromatic nitrogen containing compounds over alkali moderated ruthenium |
| US3697449A (en) | 1970-12-14 | 1972-10-10 | Du Pont | Alkali moderation of supported ruthenium catalysts |
| US4754070A (en) | 1986-01-23 | 1988-06-28 | Air Products And Chemicals, Inc. | Hydrogenation of methylenedianiline to produce bis(para-aminocyclohexyl)methane |
| US4960941A (en) * | 1988-03-30 | 1990-10-02 | Air Products And Chemicals, Inc. | Hydrogenation of aromatic amines to produce their ring hydrogenated counterparts |
| BE1004608A3 (fr) * | 1990-11-16 | 1992-12-22 | Solvay | Procede pour la fabrication du chloroforme a partir de tetrachlorure de carbone, compositions catalytiques et procede pour leur obtention. |
| US5360934A (en) * | 1993-06-25 | 1994-11-01 | Air Products And Chemicals, Inc. | Hydrogenation of aromatic amines to produce their ring hydrogenated counterparts |
| US5545756A (en) | 1994-09-14 | 1996-08-13 | Air Products And Chemicals, Inc. | Hydrogenation of aromatic amines using mixed metal oxide support |
-
2000
- 2000-04-28 US US09/561,071 patent/US6184416B1/en not_active Expired - Lifetime
-
2001
- 2001-04-23 CA CA002344875A patent/CA2344875C/en not_active Expired - Fee Related
- 2001-04-23 BR BRPI0101552-4A patent/BR0101552B1/pt not_active IP Right Cessation
- 2001-04-24 PT PT01109469T patent/PT1149629E/pt unknown
- 2001-04-24 ES ES01109469T patent/ES2222289T3/es not_active Expired - Lifetime
- 2001-04-24 DE DE60103695T patent/DE60103695T2/de not_active Expired - Lifetime
- 2001-04-24 EP EP01109469A patent/EP1149629B1/en not_active Expired - Lifetime
- 2001-04-24 AT AT01109469T patent/ATE268640T1/de not_active IP Right Cessation
- 2001-04-27 JP JP2001131284A patent/JP3954810B2/ja not_active Expired - Fee Related
- 2001-04-28 CN CNB011176636A patent/CN1152852C/zh not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| ES2222289T3 (es) | 2005-02-01 |
| JP3954810B2 (ja) | 2007-08-08 |
| US6184416B1 (en) | 2001-02-06 |
| CA2344875C (en) | 2004-12-14 |
| ATE268640T1 (de) | 2004-06-15 |
| DE60103695T2 (de) | 2005-06-09 |
| CN1322709A (zh) | 2001-11-21 |
| DE60103695D1 (de) | 2004-07-15 |
| EP1149629A1 (en) | 2001-10-31 |
| BR0101552B1 (pt) | 2014-04-08 |
| CA2344875A1 (en) | 2001-10-28 |
| PT1149629E (pt) | 2004-08-31 |
| JP2001314767A (ja) | 2001-11-13 |
| CN1152852C (zh) | 2004-06-09 |
| EP1149629B1 (en) | 2004-06-09 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
| B09B | Patent application refused [chapter 9.2 patent gazette] | ||
| B12B | Appeal against refusal [chapter 12.2 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 08/04/2014, OBSERVADAS AS CONDICOES LEGAIS. |
|
| B21F | Lapse acc. art. 78, item iv - on non-payment of the annual fees in time |
Free format text: REFERENTE A 20A ANUIDADE. |
|
| B24J | Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12) |
Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2622 DE 06-04-2021 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013. |