BR0315802A - Processo para oxidação eletroquìmica de ferrocianeto em ferricianeto - Google Patents
Processo para oxidação eletroquìmica de ferrocianeto em ferricianetoInfo
- Publication number
- BR0315802A BR0315802A BR0315802-0A BR0315802A BR0315802A BR 0315802 A BR0315802 A BR 0315802A BR 0315802 A BR0315802 A BR 0315802A BR 0315802 A BR0315802 A BR 0315802A
- Authority
- BR
- Brazil
- Prior art keywords
- ferricyanide
- ferrocyanide
- aqueous phase
- electrochemical cell
- anolyte
- Prior art date
Links
- YAGKRVSRTSUGEY-UHFFFAOYSA-N ferricyanide Chemical compound [Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] YAGKRVSRTSUGEY-UHFFFAOYSA-N 0.000 title abstract 6
- 238000000034 method Methods 0.000 title abstract 4
- 238000006056 electrooxidation reaction Methods 0.000 title abstract 2
- 239000008346 aqueous phase Substances 0.000 abstract 4
- 238000005859 coupling reaction Methods 0.000 abstract 3
- 230000001590 oxidative effect Effects 0.000 abstract 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 3
- 238000010908 decantation Methods 0.000 abstract 1
- 238000000605 extraction Methods 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
- C02F1/467—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D491/00—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00
- C07D491/02—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00 in which the condensed system contains two hetero rings
- C07D491/10—Spiro-condensed systems
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- General Chemical & Material Sciences (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Physical Water Treatments (AREA)
Abstract
"PROCESSO PARA OXIDAçãO ELETROQUìMICA DE FERROCIANETO EM FERRICIANETO". A presente invenção refere-se a um processo para oxidação de uma fase aquosa compreendendo ferrocianeto (V), o qual é recuperado a partir de uma reação de acoplamento fenólico oxidativa, para uma fase aquosa compreendendo ferricianeto (IV), em uma célula eletroquímica dividida, compreendendo preparar um anólito compreendendo o pré-tratamento da fase aquosa, compreendendo ferrocianeto (V) recuperado a partir de uma reação de acoplamento fenólico oxidativa por decantação ou extração; colocar o anólito em contato com o eletrodo anólito da célula eletroquímica dividida; colocar um católito em contato com um eletrodo catódico da célula eletroquímica dividida; e aplicar energia elétrica para a célula eletroquímica dividida, em que a energia elétrica tem uma amperagem ou voltagem e em que a aplicação é durante um período de tempo suficiente para oxidar o ferrocianeto (V) em ferricianeto (IV). Também se reivindica o uso de uma fase aquosa compreendendo ferricianeto (IV) obtenível portal processo para uma reação de acoplamento fenólico oxidativa.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/EP2002/012325 WO2004042116A1 (en) | 2002-11-04 | 2002-11-04 | Process for electrochemical oxidation of ferrocyanide to ferricyanide |
| PCT/EP2003/050641 WO2004042117A1 (en) | 2002-11-04 | 2003-09-19 | Process for electrochemical oxidation of ferrocyanide to ferricyanide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR0315802A true BR0315802A (pt) | 2005-09-20 |
Family
ID=32309276
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR0315802-0A BR0315802A (pt) | 2002-11-04 | 2003-09-19 | Processo para oxidação eletroquìmica de ferrocianeto em ferricianeto |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US20060049064A1 (pt) |
| EP (1) | EP1560947A1 (pt) |
| JP (1) | JP2006505390A (pt) |
| KR (1) | KR20050072092A (pt) |
| CN (1) | CN1694979A (pt) |
| AU (2) | AU2002351836A1 (pt) |
| BR (1) | BR0315802A (pt) |
| CA (1) | CA2503118A1 (pt) |
| NO (1) | NO20052533L (pt) |
| NZ (1) | NZ540003A (pt) |
| PL (1) | PL375606A1 (pt) |
| RU (1) | RU2005117353A (pt) |
| WO (2) | WO2004042116A1 (pt) |
| ZA (1) | ZA200503519B (pt) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7713401B2 (en) * | 2007-08-08 | 2010-05-11 | Battelle Energy Alliance, Llc | Methods for performing electrochemical nitration reactions |
| JP2011506967A (ja) * | 2007-12-10 | 2011-03-03 | バイエル・ヘルスケア・エルエルシー | バックグラウンド電流が低下した試薬を生成する方法およびシステム |
| EP3058608B1 (en) | 2013-10-16 | 2019-12-25 | Lockheed Martin Energy, LLC | Method and apparatus for measuring transient state-of-charge using inlet/outlet potentials |
| WO2015066398A1 (en) | 2013-11-01 | 2015-05-07 | Lock Heed Martin Advanced Energy Storage, Llc | Apparatus and method for determining state of charge in a redox flow battery via limiting currents |
| CA2927993C (en) | 2013-11-15 | 2021-10-26 | Lockheed Martin Advanced Energy Storage, Llc | Methods for determining state of charge and calibrating reference electrodes in a redox flow battery |
| KR20170092633A (ko) * | 2014-12-08 | 2017-08-11 | 록히드 마틴 어드밴스드 에너지 스토리지, 엘엘씨 | 충전 상태의 인시츄 분광학적 결정 방법을 포함하는 전기화학 시스템 |
| US10903511B2 (en) | 2016-11-29 | 2021-01-26 | Lockheed Martin Energy, Llc | Flow batteries having adjustable circulation rate capabilities and methods associated therewith |
| CA3051456A1 (en) * | 2017-03-01 | 2018-09-07 | Axine Water Technologies Inc. | Stack of electrochemical cells for wastewater treatment with isolated electrodes |
| CN113060801A (zh) * | 2021-03-29 | 2021-07-02 | 山东理工大学 | 用于处理含氰废水的电化学装置及其制备方法和应用 |
| WO2024250134A1 (zh) * | 2023-06-05 | 2024-12-12 | 广东邦普循环科技有限公司 | 一种普鲁士蓝材料的制备方法、普鲁士蓝材料及应用 |
| WO2024250140A1 (zh) * | 2023-06-05 | 2024-12-12 | 广东邦普循环科技有限公司 | 亚铁氰酸锂的应用、阳极电解液和盐湖卤水电脱嵌提锂方法 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4032415A (en) * | 1974-08-16 | 1977-06-28 | The Mead Corporation | Method for promoting reduction oxidation of electrolytically produced gas |
| US4290862A (en) * | 1979-11-14 | 1981-09-22 | Edinen Centar P Chimia | Method for the preparation of narwedine-type enones |
| US5302257A (en) * | 1992-02-21 | 1994-04-12 | Sepracor, Inc. | Electrocatalytic asymmetric dihydroxylation of olefinic compounds |
| RU2051203C1 (ru) * | 1992-09-17 | 1995-12-27 | Научно-исследовательский и проектный институт мономеров с опытным заводом | Способ получения калия железосинеродистого |
| US6407229B1 (en) * | 1994-10-21 | 2002-06-18 | Sanochemia Pharmazeutika Ag | Processes for the preparation of derivatives of 4a,5,9,10,11,12-hexahydro-6H-benzofuro-[3a,3,2-ef][2] benzazapine |
-
2002
- 2002-11-04 AU AU2002351836A patent/AU2002351836A1/en not_active Abandoned
- 2002-11-04 WO PCT/EP2002/012325 patent/WO2004042116A1/en not_active Ceased
-
2003
- 2003-09-19 BR BR0315802-0A patent/BR0315802A/pt not_active IP Right Cessation
- 2003-09-19 NZ NZ540003A patent/NZ540003A/en unknown
- 2003-09-19 JP JP2004549167A patent/JP2006505390A/ja not_active Withdrawn
- 2003-09-19 KR KR1020057005060A patent/KR20050072092A/ko not_active Withdrawn
- 2003-09-19 US US10/533,098 patent/US20060049064A1/en not_active Abandoned
- 2003-09-19 CN CNA038248506A patent/CN1694979A/zh active Pending
- 2003-09-19 CA CA002503118A patent/CA2503118A1/en not_active Abandoned
- 2003-09-19 EP EP03758098A patent/EP1560947A1/en active Pending
- 2003-09-19 PL PL03375606A patent/PL375606A1/xx not_active Application Discontinuation
- 2003-09-19 RU RU2005117353/15A patent/RU2005117353A/ru not_active Application Discontinuation
- 2003-09-19 WO PCT/EP2003/050641 patent/WO2004042117A1/en not_active Ceased
- 2003-09-19 AU AU2003274116A patent/AU2003274116A1/en not_active Abandoned
-
2005
- 2005-05-03 ZA ZA200503519A patent/ZA200503519B/en unknown
- 2005-05-26 NO NO20052533A patent/NO20052533L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| CN1694979A (zh) | 2005-11-09 |
| US20060049064A1 (en) | 2006-03-09 |
| JP2006505390A (ja) | 2006-02-16 |
| PL375606A1 (en) | 2005-12-12 |
| NO20052533D0 (no) | 2005-05-26 |
| WO2004042117A1 (en) | 2004-05-21 |
| AU2003274116A1 (en) | 2004-06-07 |
| KR20050072092A (ko) | 2005-07-08 |
| NZ540003A (en) | 2006-06-30 |
| RU2005117353A (ru) | 2006-01-20 |
| ZA200503519B (en) | 2006-08-30 |
| EP1560947A1 (en) | 2005-08-10 |
| WO2004042116A1 (en) | 2004-05-21 |
| NO20052533L (no) | 2005-05-26 |
| CA2503118A1 (en) | 2004-05-21 |
| AU2002351836A1 (en) | 2004-06-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
Free format text: REFERENTE 5A., 6A. E 7A. |
|
| B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |
Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 2073 DE 28/09/2010. |