BR9610651A - Processo catalisado para preparar carboxilato de cátion de metal polivalente seco,em partìculas - Google Patents
Processo catalisado para preparar carboxilato de cátion de metal polivalente seco,em partìculasInfo
- Publication number
- BR9610651A BR9610651A BR9610651-4A BR9610651A BR9610651A BR 9610651 A BR9610651 A BR 9610651A BR 9610651 A BR9610651 A BR 9610651A BR 9610651 A BR9610651 A BR 9610651A
- Authority
- BR
- Brazil
- Prior art keywords
- polyvalent metal
- carboxylate
- carboxylic acid
- metal cation
- particles
- Prior art date
Links
- 229910052751 metal Inorganic materials 0.000 title abstract 6
- 239000002184 metal Substances 0.000 title abstract 6
- 238000000034 method Methods 0.000 title abstract 3
- -1 cation carboxylate Chemical class 0.000 title abstract 2
- 239000002245 particle Substances 0.000 title abstract 2
- 150000007942 carboxylates Chemical class 0.000 abstract 3
- 150000001735 carboxylic acids Chemical class 0.000 abstract 3
- 239000011572 manganese Substances 0.000 abstract 3
- 239000011651 chromium Substances 0.000 abstract 2
- 239000011541 reaction mixture Substances 0.000 abstract 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 abstract 1
- 239000006053 animal diet Substances 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 125000002091 cationic group Chemical group 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 1
- 229910052748 manganese Inorganic materials 0.000 abstract 1
- 150000002736 metal compounds Chemical class 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 230000009469 supplementation Effects 0.000 abstract 1
- 229910021655 trace metal ion Inorganic materials 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/41—Preparation of salts of carboxylic acids
- C07C51/412—Preparation of salts of carboxylic acids by conversion of the acids, their salts, esters or anhydrides with the same carboxylic acid part
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F11/00—Compounds containing elements of Groups 6 or 16 of the Periodic Table
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23K—FODDER
- A23K20/00—Accessory food factors for animal feeding-stuffs
- A23K20/20—Inorganic substances, e.g. oligoelements
- A23K20/30—Oligoelements
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Animal Husbandry (AREA)
- Zoology (AREA)
- Inorganic Chemistry (AREA)
- Food Science & Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Fodder In General (AREA)
- Catalysts (AREA)
Abstract
"PROCESSO CATALISADO PARA PREPARAR CARBOXILATO DE CáTION DE METAL POLIVALENTE SECO, EM PARTìCULAS". O processo catalisado é descrito para produzir um carboxilato C~ 2~-C~ 3~ de metal polivalente tendo fórmula M(CH~ 3~(CH~ 2~)~ x~COO~ -~)~ y~, em que M é cátion de metal polivalente que é manganês (Mn^ +2^), ou cobalto (Co^ +2^), ou cromo (Cr^ +3^), x é zero ou 1 e y é um número inteiro igual para carga catiónica M. O carboxilato C~ 2~-C~ 3~ de metal polivalente é preparado por misturação de (i) composto de metal polivalente seco que é um óxido, hidróxido ou carbonato de Mn^ +2^, Co^ +3^, (ii) um ácido carboxílico C~ 2~-C~ 3~anidro, e (iii) um agente catalítico em uma relação molar reativa de cerca de 1:2-10:0.01-3 em ausência de um adicionado solvente ou outro diluente para formar a mistura de reação. A mistura de reação é aquecida até completar a reação, remover a água produzida e cerca de 80 por cento de ácido carboxílico não reagido. O produto em ácido carboxílico residual é solidificado, triturado e produto é recuperado. Os carboxilatos de metal podem ser usados como biologicamente disponíveis e fontes económicas de íons de metal em traço para suplementação em dietas para animais.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/531,193 US5591878A (en) | 1995-09-19 | 1995-09-19 | Catalyzed process for producing metal carboxylates for use as animal feed supplements |
| PCT/US1996/014467 WO1997011082A1 (en) | 1995-09-19 | 1996-09-10 | A catalyzed process for producing metal carboxylates for use as animal feed supplements |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR9610651A true BR9610651A (pt) | 1999-12-21 |
Family
ID=24116633
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR9610651-4A BR9610651A (pt) | 1995-09-19 | 1996-09-10 | Processo catalisado para preparar carboxilato de cátion de metal polivalente seco,em partìculas |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US5591878A (pt) |
| EP (1) | EP0902787B1 (pt) |
| KR (1) | KR100282109B1 (pt) |
| AT (1) | ATE217876T1 (pt) |
| AU (1) | AU707201B2 (pt) |
| BR (1) | BR9610651A (pt) |
| CA (1) | CA2232393C (pt) |
| DE (1) | DE69621354T2 (pt) |
| WO (1) | WO1997011082A1 (pt) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5795615A (en) * | 1994-09-30 | 1998-08-18 | Kemin Industries, Inc. | Process for producing metal carboxylates for use as animal feed supplements |
| US5846581A (en) * | 1997-01-31 | 1998-12-08 | Catron; Douglas Howard | Chromium (III) salts of short chain fatty acids composition for use in animal feeds |
| US6352714B1 (en) | 2000-07-11 | 2002-03-05 | Der, Inc. | Method of producing a metal nutrient for an animal feed |
| US6673964B1 (en) | 2002-06-27 | 2004-01-06 | Solutia Inc. | Process for producing a calcium carboxylate |
| ES2222106B1 (es) * | 2003-07-11 | 2006-04-01 | Norel, S.A. | Procedimiento de produccion de carboxilatos metalicos y su uso como promotores de crecimiento en alimentacion animal. |
| US7495117B2 (en) * | 2006-08-04 | 2009-02-24 | Kemin Industries, Inc. | Metal carboxylate salts |
| US8471085B2 (en) | 2008-10-31 | 2013-06-25 | Chevron Phillips Chemical Company Lp | Oligomerization catalyst system and process for oligomerizing olefins |
| CA2741568C (en) | 2008-10-31 | 2016-06-28 | Chevron Phillips Chemical Company Lp | Compositions and catalyst systems of metal precursors and olefinic diluents |
| CN104829272A (zh) * | 2009-12-22 | 2015-08-12 | 拉尔科营养品有限公司 | 有机螯合的矿物组合物及其制备方法 |
| US8741375B2 (en) | 2011-06-07 | 2014-06-03 | Zinpro Corporation | Mixed amino acid metal salt complexes |
| US8957235B2 (en) * | 2011-12-12 | 2015-02-17 | Chevron Phillips Chemical Company Lp | Preparation of transition metal carboxylates |
| US9956548B2 (en) | 2011-12-12 | 2018-05-01 | Chevron Phillips Chemical Company Lp | Preparation of an olefin oligomerization catalyst |
| US8968807B1 (en) | 2013-09-24 | 2015-03-03 | Zinpro Corporation | Use of ethylene diamine metal complexes to deliver highly absorbable metals for animal nutrition |
| MX366759B (es) | 2014-04-17 | 2019-07-23 | Ralco Nutrition Inc | Composiciones agrícolas y aplicaciones que utilizan compuestos minerales. |
| US9867809B2 (en) | 2015-06-30 | 2018-01-16 | Kemin Industries, Inc. | Encapsulated active ingredients for controlled enteric release |
| WO2020198716A1 (en) * | 2019-03-27 | 2020-10-01 | Kemin Industries, Inc. | Methods for preparing metal carboxylates in one-pot reaction |
| US11753430B2 (en) | 2020-06-03 | 2023-09-12 | Vitalix, Inc. | Method of making cobalt compounds for feed supplements |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE371186B (pt) * | 1971-01-04 | 1974-11-11 | Labofina Sa | |
| US3932285A (en) * | 1973-10-03 | 1976-01-13 | Tenneco Chemicals, Inc. | Chromium salt compositions and a process for their production |
| GB1533061A (en) * | 1976-02-13 | 1978-11-22 | Graesser Salicylates Ltd | Preparation of chromium alkanoates |
| US4060535A (en) * | 1976-08-31 | 1977-11-29 | Tenneco Chemicals, Inc. | Process for the production of metal salts of organic acids |
| US4278610A (en) * | 1978-08-11 | 1981-07-14 | National Research Laboratories | Method of making an organic metal salt or complex |
| US4315927A (en) * | 1980-08-08 | 1982-02-16 | The United States Of America As Represented By The Secretary Of Agriculture | Dietary supplementation with essential metal picolinates |
| DE3215752A1 (de) * | 1982-04-28 | 1983-11-03 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von calciumpropionat |
| US4636572A (en) * | 1985-03-11 | 1987-01-13 | Phillips Petroleum Company | Permeability contrast correction employing propionate-sequestered chromium(III) prepared by nitrite/dichromate redox |
| US5461172A (en) * | 1993-08-09 | 1995-10-24 | Mooney Chemicals, Inc. | Light-colored manganese carboxylates |
| US5795615A (en) * | 1994-09-30 | 1998-08-18 | Kemin Industries, Inc. | Process for producing metal carboxylates for use as animal feed supplements |
-
1995
- 1995-09-19 US US08/531,193 patent/US5591878A/en not_active Expired - Lifetime
-
1996
- 1996-09-10 KR KR1019980702034A patent/KR100282109B1/ko not_active Expired - Fee Related
- 1996-09-10 DE DE69621354T patent/DE69621354T2/de not_active Expired - Lifetime
- 1996-09-10 WO PCT/US1996/014467 patent/WO1997011082A1/en not_active Ceased
- 1996-09-10 AU AU73598/96A patent/AU707201B2/en not_active Expired
- 1996-09-10 BR BR9610651-4A patent/BR9610651A/pt not_active Application Discontinuation
- 1996-09-10 EP EP96935804A patent/EP0902787B1/en not_active Expired - Lifetime
- 1996-09-10 CA CA002232393A patent/CA2232393C/en not_active Expired - Lifetime
- 1996-09-10 AT AT96935804T patent/ATE217876T1/de active
Also Published As
| Publication number | Publication date |
|---|---|
| KR100282109B1 (ko) | 2001-04-02 |
| DE69621354D1 (de) | 2002-06-27 |
| AU707201B2 (en) | 1999-07-08 |
| US5591878A (en) | 1997-01-07 |
| CA2232393A1 (en) | 1997-03-27 |
| EP0902787A1 (en) | 1999-03-24 |
| EP0902787A4 (en) | 1999-06-16 |
| DE69621354T2 (de) | 2003-01-16 |
| EP0902787B1 (en) | 2002-05-22 |
| WO1997011082A1 (en) | 1997-03-27 |
| ATE217876T1 (de) | 2002-06-15 |
| CA2232393C (en) | 2002-01-01 |
| KR19990063591A (ko) | 1999-07-26 |
| AU7359896A (en) | 1997-04-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| BR9610651A (pt) | Processo catalisado para preparar carboxilato de cátion de metal polivalente seco,em partìculas | |
| DE69411931T2 (de) | Reduktion von säuren emissionen | |
| ES2152568T3 (es) | Acelerador de solidificacion y endurecimiento para ligantes hidraulicos. | |
| BR9806034A (pt) | Composto tipo hidrotálico, catalisador adequado para reformar um hidrocarboneto, e, processos de reformar um hidrocarboneto contendo oxigênio. | |
| BR9804893A (pt) | Método contínuo de preparação de composto intercalação de óxido de manganês, método para sintetizar óxido de lítio e manganês, óxido de manganês e lítio | |
| TW228504B (en) | Regeneration of sulfuric acid from sulfate by-products of 2-hydroxy-4-(methylthio) butyric acid manufacture | |
| GR3035182T3 (en) | Mesoporous crystalline acid composition of a diphosphonate-phosphite of a tetravalent metal which can be used as a catalyst | |
| ES2089493T3 (es) | Procedimiento para producir sal de acido aminocarboxilico. | |
| CN105348128A (zh) | 一种乙撑双硬脂酸酰胺的制备方法 | |
| EP0379111A3 (en) | Process for producing alpha-hydroxycarboxylic acid amide | |
| MXPA02003721A (es) | Quelatos de metales mezclados y proceso para la preparacion de los mismos. | |
| DE3162130D1 (en) | Process for preparing fertilisers containing trace-metals | |
| BR9601110B1 (pt) | processo de sìntese de um sal de um composto orgánico, que é ao mesmo tempo fluorado e oxissulfurado, reagente, uso de um reagente, e, meio reagente. | |
| ES382048A1 (es) | Procedimiento para obtener acido fenilacetico por carboni- lacion de cloruro de bencilo. | |
| AU2375784A (en) | Catalyst | |
| CN101979128A (zh) | 四甲基胍羟基酸盐复合脱硫剂及其制备方法 | |
| DK0390677T3 (da) | Fremgangsmåde til fremstilling af kobolt- substitueret nikkelhydroxid med alpha-struktur, som er stabilt i basisk miljø, samt dets anvendelse i en elektromekanisk generator | |
| ES2173309T3 (es) | Catalizador de cobalto mejorado. | |
| BR0004064A (pt) | Processos para a preparação de um éster carboxilato de arila, e para a preparação de uma mistura de ésteres carboxilato de arila | |
| MX165579B (es) | Proceso para la preparacion de acido 4,4'-dinitroestilben-2,2'-disulfonico y sus sales | |
| DE3370318D1 (en) | Granular metal soap product and process for producing metal soap | |
| EP0968981A3 (de) | Mikronährstoffhaltiger Blattdünger auf Basis von Magnesiumsulfat und Verfahren zur seiner Herstellung | |
| KR910009657A (ko) | 캡토프릴의 직접 단리 방법 | |
| GB2019826A (en) | Process of Removing Oxides of Sulfur from Gases; Sludge Resulting from Process: and Product Comprising Lime or Limestone | |
| PT885872E (pt) | Processo continuo de fabricacao de solucoes aquosas de sais alcalinos de acidos arilaceticos |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EG | Technical examination (opinion): publication of technical examination (opinion) | ||
| B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
| B09B | Patent application refused [chapter 9.2 patent gazette] |
Free format text: INDEFIRO O PRESENTE PEDIDO DE PATENTE COMO INVENCAO DE ACORDO COM O ART. 8O DA LPI. |