BR9813687A - Processo de epoxidação usando catalisadores de prata suportados tratados com dióxido de carbono - Google Patents
Processo de epoxidação usando catalisadores de prata suportados tratados com dióxido de carbonoInfo
- Publication number
- BR9813687A BR9813687A BR9813687-9A BR9813687A BR9813687A BR 9813687 A BR9813687 A BR 9813687A BR 9813687 A BR9813687 A BR 9813687A BR 9813687 A BR9813687 A BR 9813687A
- Authority
- BR
- Brazil
- Prior art keywords
- carbon dioxide
- epoxidation process
- supported silver
- silver catalysts
- catalyst
- Prior art date
Links
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title abstract 10
- 229910002092 carbon dioxide Inorganic materials 0.000 title abstract 5
- 239000001569 carbon dioxide Substances 0.000 title abstract 5
- 239000003054 catalyst Substances 0.000 title abstract 5
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 title abstract 3
- 238000006735 epoxidation reaction Methods 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 229910052709 silver Inorganic materials 0.000 title abstract 3
- 239000004332 silver Substances 0.000 title abstract 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 abstract 1
- 230000003197 catalytic effect Effects 0.000 abstract 1
- 229910001882 dioxygen Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/48—Silver or gold
- B01J23/50—Silver
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
- B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Epoxy Compounds (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Patente de Invenção <B>"PROCESSO DE EPOXIDAçãO USANDO CATALISADORES DE PRATA SUPORTADOS TRATADOS COM DIóXIDO DE CARBONO"<D> O desempenho catalítico de um catalisador de prata suportado, em um processo de epoxidação de propileno, é aperfeiçoado, primeiro, por colocação em contato do catalisador, em uma temperatura elevada, com uma corrente de tratamento, que compreende dióxido de carbono. O catalisador tratado com dióxido de carbono é, depois disso, colocado em contato com uma corrente de alimentação contendo propileno, oxigênio molecular, mas essencialmente, nenhum dióxido de carbono, sob condições eficazes para formar óxido de propileno.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/993,466 US5856534A (en) | 1997-12-18 | 1997-12-18 | Epoxidation process using supported silver catalysts treated with carbon dioxide |
| PCT/EP1998/005515 WO1999032471A1 (en) | 1997-12-18 | 1998-08-31 | Epoxidation process using supported silver catalysts treated with carbon dioxide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR9813687A true BR9813687A (pt) | 2000-10-10 |
Family
ID=25539579
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR9813687-9A BR9813687A (pt) | 1997-12-18 | 1998-08-31 | Processo de epoxidação usando catalisadores de prata suportados tratados com dióxido de carbono |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US5856534A (pt) |
| EP (1) | EP1040104B1 (pt) |
| JP (1) | JP2001526279A (pt) |
| KR (1) | KR20010024732A (pt) |
| CN (1) | CN1282327A (pt) |
| AU (1) | AU1022799A (pt) |
| BR (1) | BR9813687A (pt) |
| CA (1) | CA2310429A1 (pt) |
| DE (1) | DE69809592T2 (pt) |
| ES (1) | ES2184328T3 (pt) |
| WO (1) | WO1999032471A1 (pt) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5780657A (en) * | 1997-06-23 | 1998-07-14 | Arco Chemical Technology, L.P. | Propylene epoxidation using chloride-containing silver catalysts |
| US6509485B2 (en) | 2001-02-22 | 2003-01-21 | Sri International | Preparation of epoxides from alkanes using lanthanide-promoted silver catalysts |
| US6392066B1 (en) | 2001-02-22 | 2002-05-21 | Sri International | Epoxidation of olefins using lanthanide-promoted silver catalysts |
| KR100433010B1 (ko) * | 2002-01-26 | 2004-05-27 | 주식회사 토비이앤지 | 정제형 펠릿비료의 제조시스템 |
| WO2004002954A2 (en) * | 2002-06-28 | 2004-01-08 | Shell Internationale Research Maatschappij B.V. | A method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin |
| US7319156B2 (en) * | 2003-03-25 | 2008-01-15 | Sumitomo Chemical Company, Limited | Process for producing olefin oxide |
| US8148555B2 (en) * | 2003-06-26 | 2012-04-03 | Shell Oil Company | Method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin |
| CN101160298B (zh) * | 2005-02-25 | 2011-06-22 | 住友化学株式会社 | 环氧烷烃的制备方法 |
| US7615654B2 (en) * | 2005-10-20 | 2009-11-10 | Lyondell Chemical Technology, L.P. | Direct epoxidation process |
| US7432384B2 (en) * | 2005-10-25 | 2008-10-07 | Lyondell Chemical Technology, L.P. | Direct epoxidation process |
| US7365217B2 (en) * | 2006-01-25 | 2008-04-29 | Lyondell Chemical Technology, L.P. | Oxidation process |
| JP2009525848A (ja) * | 2006-02-03 | 2009-07-16 | シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー | 触媒の処理方法、触媒、および触媒の使用 |
| US7238817B1 (en) | 2006-02-22 | 2007-07-03 | Lyondell Chemical Technology, L.P. | Direct epoxidation process |
| US8097557B2 (en) * | 2006-08-08 | 2012-01-17 | Sd Lizenverwertungsgesellschaft Mbh & Co. Kg | Two-stage calcination for catalyst production |
| JP2008184456A (ja) * | 2007-01-31 | 2008-08-14 | Sumitomo Chemical Co Ltd | 酸化プロピレンの製造法 |
| AR066468A1 (es) | 2007-05-09 | 2009-08-19 | Shell Int Research | Un catalizador de epoxidacion, un proceso para preparar el mismo, y un proceso para producir un oxido de olefina , un 1,2- diol, un 1,2 - diol eter, un 1,2- carbonato, o una alcanolamina |
| US7553980B2 (en) * | 2007-09-26 | 2009-06-30 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Process for initiating a highly selective ethylene oxide catalyst |
| WO2009137431A2 (en) * | 2008-05-07 | 2009-11-12 | Shell Oil Company | A process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine |
| CA2723517C (en) * | 2008-05-07 | 2017-03-07 | Shell Internationale Research Maatschappij B.V. | A process for the start-up of an epoxidation process, a process for the production of ethylene oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine |
| IN2012DN05178A (pt) * | 2009-12-17 | 2015-10-23 | Scient Design Co | |
| WO2012141942A1 (en) * | 2011-04-11 | 2012-10-18 | Dow Technology Investments Llc | Process for conditioning a high efficiency ethylene oxide catalyst |
| US10046311B2 (en) * | 2015-07-24 | 2018-08-14 | Lyondell Chemical Technology, L.P. | Post treated silver catalysts for epoxidation |
| CN113603658A (zh) | 2015-08-28 | 2021-11-05 | 利安德化学技术有限公司 | 环氧化工艺及其使用的催化剂 |
| BR112019011162B1 (pt) | 2016-12-02 | 2022-08-16 | Shell Internationale Research Maatschappij B.V. | Método para o condicionamento de um catalisador de epoxidação de etileno e método para melhorar a seletividade do referido catalisador em um processo de epoxidação de etileno |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1998878A (en) * | 1931-03-27 | 1935-04-23 | Fr De Catalyse Generalisee Sa | Process for the production of ethylene oxide |
| US2615900A (en) * | 1949-06-23 | 1952-10-28 | Du Pont | Process and catalyst for producing ethylene oxide |
| GB1338901A (en) * | 1970-10-30 | 1973-11-28 | Bp Chem Int Ltd | Production of propylene oxide |
| IT971362B (it) * | 1972-11-30 | 1974-04-30 | Sir Soc Italiana Resine Spa | Procedimento per la produzione dell ossido di etilene mediante ossidazione dell etilene e cata lizzatore relativo |
| GB1491447A (en) * | 1973-12-05 | 1977-11-09 | Ici Ltd | Alkylene oxide production and catalysts therefor |
| US4212772A (en) * | 1976-05-19 | 1980-07-15 | Basf Aktiengesellschaft | Catalyst for the manufacture of ethylene oxide |
| US4066575A (en) * | 1976-07-26 | 1978-01-03 | Halcon International, Inc. | Process for the preparation of a supported silver catalyst |
| DE3014091A1 (de) * | 1980-04-12 | 1981-10-15 | EC Erdölchemie GmbH, 5000 Köln | Silberhaltige traegerkatalysatoren und katalysator-zwischenprodukte, verfahren zu ihrer herstellung und ihre verwendung |
| US5625084A (en) * | 1996-01-31 | 1997-04-29 | Arco Chemical Technology, L.P. | Vapor phase oxidation of propylene to propylene oxide |
| US5763630A (en) * | 1996-03-18 | 1998-06-09 | Arco Chemical Technology, L.P. | Propylene oxide process using alkaline earth metal compound-supported silver catalysts |
| US5698719A (en) * | 1996-09-12 | 1997-12-16 | Arco Chemical Tehnology, L.P. | Oxirane production |
| US5703254A (en) * | 1996-10-02 | 1997-12-30 | Arco Chemical Technology, L.P. | Propylene oxide process using mixed precious metal catalyst supported on alkaline earth metal carbonate |
| US5770746A (en) * | 1997-06-23 | 1998-06-23 | Arco Chemical Technology, L.P. | Epoxidation process using supported silver catalysts pretreated with organic chloride |
-
1997
- 1997-12-18 US US08/993,466 patent/US5856534A/en not_active Expired - Fee Related
-
1998
- 1998-08-31 DE DE69809592T patent/DE69809592T2/de not_active Expired - Fee Related
- 1998-08-31 JP JP2000525408A patent/JP2001526279A/ja active Pending
- 1998-08-31 KR KR1020007006619A patent/KR20010024732A/ko not_active Ceased
- 1998-08-31 WO PCT/EP1998/005515 patent/WO1999032471A1/en not_active Ceased
- 1998-08-31 ES ES98952582T patent/ES2184328T3/es not_active Expired - Lifetime
- 1998-08-31 EP EP98952582A patent/EP1040104B1/en not_active Expired - Lifetime
- 1998-08-31 AU AU10227/99A patent/AU1022799A/en not_active Abandoned
- 1998-08-31 CN CN98812226A patent/CN1282327A/zh active Pending
- 1998-08-31 BR BR9813687-9A patent/BR9813687A/pt not_active IP Right Cessation
- 1998-08-31 CA CA002310429A patent/CA2310429A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| EP1040104A1 (en) | 2000-10-04 |
| DE69809592T2 (de) | 2003-10-02 |
| WO1999032471A1 (en) | 1999-07-01 |
| CA2310429A1 (en) | 1999-07-01 |
| KR20010024732A (ko) | 2001-03-26 |
| ES2184328T3 (es) | 2003-04-01 |
| EP1040104B1 (en) | 2002-11-20 |
| AU1022799A (en) | 1999-07-12 |
| JP2001526279A (ja) | 2001-12-18 |
| DE69809592D1 (de) | 2003-01-02 |
| US5856534A (en) | 1999-01-05 |
| CN1282327A (zh) | 2001-01-31 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
Free format text: REFERENTE A 5A,6A,7A,8A E 9A ANUIDADES. |
|
| B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |
Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 1910 DE 14/08/2007. |