BR9905721A - Processo de adsorção/dessorção para remoção seletiva de nitrilas de uma alimentação de hidrocarboneto. - Google Patents
Processo de adsorção/dessorção para remoção seletiva de nitrilas de uma alimentação de hidrocarboneto.Info
- Publication number
- BR9905721A BR9905721A BR9905721-2A BR9905721A BR9905721A BR 9905721 A BR9905721 A BR 9905721A BR 9905721 A BR9905721 A BR 9905721A BR 9905721 A BR9905721 A BR 9905721A
- Authority
- BR
- Brazil
- Prior art keywords
- adsorbent
- nitrile
- hydrocarbon feed
- adsorption
- selective removal
- Prior art date
Links
- 150000002825 nitriles Chemical class 0.000 title abstract 8
- 239000004215 Carbon black (E152) Substances 0.000 title abstract 5
- 229930195733 hydrocarbon Natural products 0.000 title abstract 5
- 150000002430 hydrocarbons Chemical class 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 3
- 238000002336 sorption--desorption measurement Methods 0.000 title abstract 3
- 239000003463 adsorbent Substances 0.000 abstract 7
- 229910021536 Zeolite Inorganic materials 0.000 abstract 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 2
- 239000010457 zeolite Substances 0.000 abstract 2
- 239000002253 acid Substances 0.000 abstract 1
- 125000002091 cationic group Chemical group 0.000 abstract 1
- 238000003795 desorption Methods 0.000 abstract 1
- 239000008240 homogeneous mixture Substances 0.000 abstract 1
- 229910052809 inorganic oxide Inorganic materials 0.000 abstract 1
- 239000011159 matrix material Substances 0.000 abstract 1
- 238000001179 sorption measurement Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/32—Separation; Purification; Stabilisation; Use of additives
- C07C253/34—Separation; Purification
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D15/00—Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
- B01J20/183—Physical conditioning without chemical treatment, e.g. drying, granulating, coating, irradiation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
- C10G25/02—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material
- C10G25/03—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with ion-exchange material with crystalline alumino-silicates, e.g. molecular sieves
- C10G25/05—Removal of non-hydrocarbon compounds, e.g. sulfur compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Crystallography & Structural Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Treatment Of Liquids With Adsorbents In General (AREA)
Abstract
"PROCESSO DE ADSORçãO/DESSORçãO PARA REMOçãO SELETIVA DE NITRILAS DE UMA ALIMENTAçãO DE HIDROCARBONETO". Um processo de adsorção/dessorção para remoção seletiva de nitrilas de uma alimentação de hidrocarboneto inclui as etapas de: (a) proporcionar uma alimentação de hidrocarboneto possuindo um conteúdo de nitrila menor do que ou igual a cerca de 400 ppm; (b) proporcionar um adsorvente para remoção seletiva de nitrila de uma alimentação de hidrocarboneto compreendendo uma mistura substancialmente homogênea de um zeólito não-ácido, catiónico, e uma matriz de óxido inorgânico, possuindo um zeólito um índice de acessibilidade entre cerca de 0,1 a cerca de 0,4; (c) contactar a alimentação e o adsorvente nas condições de adsorção de nitrila por meio das quais pelo menos cerca de 80% do conteúdo de nitrila é adsorvido pelo adsorvente durante o contacto com pelo menos cerca de 200 volumes de alimentação por volume de adsorvente de modo a proporcionar um adsorvente usado possuindo moléculas de nitrila adsorvidas sobre o mesmo; e (d) contactar o adsorvente usado com um dessorvente nas condições de dessorção de modo a remover as moléculas de nitrila e proporcionar um adsorvente renovado.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/195,856 US6019887A (en) | 1995-09-18 | 1998-11-19 | Nitrile selective removal process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR9905721A true BR9905721A (pt) | 2001-01-23 |
| BR9905721B1 BR9905721B1 (pt) | 2009-01-13 |
Family
ID=22723106
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI9905721-2A BR9905721B1 (pt) | 1998-11-19 | 1999-11-19 | processo de adsorção/dessorção para remoção seletiva de nitrilas de uma alimentação de hidrocarboneto. |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6019887A (pt) |
| EP (1) | EP1002852B1 (pt) |
| JP (1) | JP3453333B2 (pt) |
| CN (1) | CN1312091C (pt) |
| BR (1) | BR9905721B1 (pt) |
| DE (1) | DE69916400T2 (pt) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6362122B1 (en) * | 1999-11-08 | 2002-03-26 | Uop Llc | Regeneration of spent zeolite compositions |
| GB0106269D0 (en) * | 2001-03-14 | 2001-05-02 | Auntiegravity Ltd | Improvements in noise cancellation |
| AU2003222610B2 (en) * | 2002-04-17 | 2008-10-23 | IFP Energies Nouvelles | Purification process |
| US7205448B2 (en) * | 2003-12-19 | 2007-04-17 | Uop Llc | Process for the removal of nitrogen compounds from a fluid stream |
| US6894201B1 (en) | 2003-12-19 | 2005-05-17 | Uop Llc | Process and apparatus for the removal of nitrogen compounds from a fluid stream |
| WO2005075608A1 (en) * | 2004-01-09 | 2005-08-18 | The Regents Of The University Of Michigan | Denitrogenation of liquid fuels |
| US7446077B2 (en) * | 2004-03-17 | 2008-11-04 | Intevep, S.A. | Selective sulfur removal from hydrocarbon streams by absorption |
| US7452459B2 (en) * | 2004-03-30 | 2008-11-18 | Uop Llc | Process for the removal of sulfur-oxidated compounds from a hydrocarbonaceous stream |
| US7473349B2 (en) * | 2004-12-30 | 2009-01-06 | Bp Corporation North America Inc. | Process for removal of sulfur from components for blending of transportation fuels |
| US9169169B2 (en) | 2006-03-10 | 2015-10-27 | Exxonmobil Chemical Patents Inc. | Lowering nitrogen-containing Lewis bases in molecular sieve oligomerisation |
| JP5590698B2 (ja) | 2006-03-10 | 2014-09-17 | エクソンモービル・ケミカル・パテンツ・インク | モレキュラーシーブを用いたオリゴマー化における窒素含有ルイス塩基の低減 |
| FR2918297B1 (fr) * | 2007-07-06 | 2011-03-25 | Inst Francais Du Petrole | Purification d'une coupe olefinique par adsorption sur des cogranules alumine-faujasite. |
| US7553995B2 (en) * | 2007-09-11 | 2009-06-30 | Catalytic Distillation Technologies | Method of producing tertiary amyl ethyl ether |
| US8193111B2 (en) * | 2009-07-24 | 2012-06-05 | Uop Llc | Process or system for desorbing an adsorbent bed |
| US20110073527A1 (en) * | 2009-09-30 | 2011-03-31 | Uop Llc | Process for Removing Nitrogen Compounds from a Hydrocarbon Stream |
| EP2649160B1 (en) | 2010-12-07 | 2022-03-16 | ExxonMobil Chemical Patents Inc. | Processes utilizing solvent extraction |
| ES2507240T3 (es) | 2010-12-23 | 2014-10-14 | Clariant Produkte (Deutschland) Gmbh | Procedimiento para la preparación de compuestos orgánicos a través de fermentación de biomasa y catálisis zeolítica |
| EP2736632B1 (en) | 2011-07-25 | 2017-02-01 | ExxonMobil Chemical Patents Inc. | Integrated nitrile poison adsorption and desorption system |
| WO2013013884A2 (en) | 2011-07-25 | 2013-01-31 | Exxonmobil Chemical Patents Inc. | Process for nitrile removal from hydrocarbon feeds |
| FR2984310B1 (fr) | 2011-12-20 | 2016-04-01 | IFP Energies Nouvelles | Procede de purification de charges olefiniques a l'aide d'un adsorbant comprenant une zeolithe de type 12mr |
| US9150464B2 (en) | 2012-05-31 | 2015-10-06 | Uop Llc | Methods and apparatus for treating a hydrocarbon stream |
| US9150463B2 (en) | 2012-05-31 | 2015-10-06 | Uop Llc | Methods and apparatus for treating a hydrocarbon stream |
| CN102816044A (zh) * | 2012-08-30 | 2012-12-12 | 宁夏宝塔石化集团有限公司 | 一种烷基化反应原料苯或甲苯脱碱性氮的方法 |
| EP2925835A1 (en) | 2012-11-29 | 2015-10-07 | ExxonMobil Chemical Patents Inc. | Processes for treating olefin feedstreams and related oligomerization processes |
| FR3006608B1 (fr) | 2013-06-10 | 2021-01-01 | Ifp Energies Now | Adsorbant a base d'une zeolithe et d'une argile riche en silice et procede de purification de charges d'hydrocarbures contenant des molecules insaturees |
| CN104560125B (zh) * | 2013-10-24 | 2016-06-22 | 中国石油化工股份有限公司 | 一种脱除轻烃中氮化物的方法 |
| WO2017050454A1 (en) * | 2015-09-24 | 2017-03-30 | Exxonmobil Chemical Patents Inc. | A process for regenerating an adsorbent for nitrogen-containing compounds present in a hydrocarbon feed |
| WO2017105784A1 (en) * | 2015-12-15 | 2017-06-22 | Uop Llc | Processes for removing nitriles from a feed to an oligomerization zone |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4467126A (en) * | 1983-07-18 | 1984-08-21 | Uop Inc. | Process for the separation of di-substituted benzene |
| US5271835A (en) * | 1992-05-15 | 1993-12-21 | Uop | Process for removal of trace polar contaminants from light olefin streams |
| US5834392A (en) * | 1995-09-18 | 1998-11-10 | Intevep, S.A. | Nitrile selective adsorbent |
| US6118037A (en) * | 1997-04-22 | 2000-09-12 | Snamprogetti S.P.A. | Process for the removal of contaminant compounds containing one or more heteroatoms of sulfur, nitrogen and/or oxygen from hydrocarbon streams |
-
1998
- 1998-11-19 US US09/195,856 patent/US6019887A/en not_active Expired - Lifetime
-
1999
- 1999-11-19 JP JP33053199A patent/JP3453333B2/ja not_active Expired - Fee Related
- 1999-11-19 CN CNB99123961XA patent/CN1312091C/zh not_active Expired - Fee Related
- 1999-11-19 EP EP99122997A patent/EP1002852B1/en not_active Expired - Lifetime
- 1999-11-19 BR BRPI9905721-2A patent/BR9905721B1/pt not_active IP Right Cessation
- 1999-11-19 DE DE69916400T patent/DE69916400T2/de not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP1002852B1 (en) | 2004-04-14 |
| US6019887A (en) | 2000-02-01 |
| DE69916400D1 (de) | 2004-05-19 |
| JP3453333B2 (ja) | 2003-10-06 |
| CN1312091C (zh) | 2007-04-25 |
| JP2000297050A (ja) | 2000-10-24 |
| CN1256260A (zh) | 2000-06-14 |
| EP1002852A1 (en) | 2000-05-24 |
| DE69916400T2 (de) | 2005-05-19 |
| BR9905721B1 (pt) | 2009-01-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B06A | Patent application procedure suspended [chapter 6.1 patent gazette] | ||
| B06A | Patent application procedure suspended [chapter 6.1 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 19/11/1999, OBSERVADAS AS CONDICOES LEGAIS. |
|
| B21F | Lapse acc. art. 78, item iv - on non-payment of the annual fees in time | ||
| B24J | Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12) |