BRPI0404901A - Sistema de catalisador, leito catalìtico misto, e, processos para preparar um catalisador, para preparar alquenos a partir de alcanos correspondentes, para preparar ácidos carboxìlicos insaturados a partir de alcanos correspondentes, para converter alcanos a seus correspondentes ésteres de ácidos carboxìlicos insaturados, para a produção de ácido carboxìlicos insaturados superiores, para converter um alcano a seus correspondentes ácidos carboxìlicos insaturados, para converter um alcano a um correspondente éster análogo superior de ácidos carboxìlicos insaturados, e para converter um alcano a seus correspondentes produtos selecionados de ácido carboxìlico insaturado, ácido carboxìlico insaturado análogo superior e seu éster - Google Patents

Sistema de catalisador, leito catalìtico misto, e, processos para preparar um catalisador, para preparar alquenos a partir de alcanos correspondentes, para preparar ácidos carboxìlicos insaturados a partir de alcanos correspondentes, para converter alcanos a seus correspondentes ésteres de ácidos carboxìlicos insaturados, para a produção de ácido carboxìlicos insaturados superiores, para converter um alcano a seus correspondentes ácidos carboxìlicos insaturados, para converter um alcano a um correspondente éster análogo superior de ácidos carboxìlicos insaturados, e para converter um alcano a seus correspondentes produtos selecionados de ácido carboxìlico insaturado, ácido carboxìlico insaturado análogo superior e seu éster

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Publication number
BRPI0404901A
BRPI0404901A BR0404901-2A BRPI0404901A BRPI0404901A BR PI0404901 A BRPI0404901 A BR PI0404901A BR PI0404901 A BRPI0404901 A BR PI0404901A BR PI0404901 A BRPI0404901 A BR PI0404901A
Authority
BR
Brazil
Prior art keywords
unsaturated carboxylic
carboxylic acid
convert
alkane
carboxylic acids
Prior art date
Application number
BR0404901-2A
Other languages
English (en)
Inventor
Abraham Benderly
Nitin Chadda
Anne Mae Gaffney
Scott Han
Dominique Hung Nhu Le
Mark Anthony Silvano
Original Assignee
Rohm & Haas
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rohm & Haas filed Critical Rohm & Haas
Publication of BRPI0404901A publication Critical patent/BRPI0404901A/pt

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
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    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
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    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/648—Vanadium, niobium or tantalum or polonium
    • B01J23/6484—Niobium
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    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6525—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
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    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
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    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3335—Catalytic processes with metals
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    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3335—Catalytic processes with metals
    • C07C5/3337—Catalytic processes with metals of the platinum group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/39—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/56—Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional [3D] monoliths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0036—Grinding
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
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    • B01J37/0215—Coating
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    • C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
    • C07C2523/56—Platinum group metals
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    • C07C2523/56—Platinum group metals
    • C07C2523/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tatalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

"SISTEMA DE CATALISADOR, LEITO CATALìTICO MISTO, E, PROCESSOS PARA PREPARAR UM CATALISADOR, PARA PREPARAR ALQUENOS A PARTIR DE ALCANOS CORRESPONDENTES, PARA PREPARAR áCIDOS CARBOXìLICOS INSATURADOS A PARTIR DE ALCANOS CORRESPONDENTES, PARA CONVERTER ALCANOS A SEUS CORRESPONDENTES éSTERES DE áCIDOS CARBOXìLICOS INSATURADOS, PARA A PRODUçãO DE áCIDOS CARBOXìLICOS INSATURADOS SUPERIORES, PARA CONVERTER UM ALCANO A SEUS CORRESPONDENTES áCIDOS CARBOXìLICOS INSATURADOS, PARA CONVERTER UM ALCANO A UM CORRESPONDENTE éSTER ANáLOGO SUPERIOR DE áCIDOS CARBOXìLICOS INSATURADOS, E PARA CONVERTER UM ALCANO A SEUS CORRESPONDENTES PRODUTOS SELECIONADOS DE áCIDO CARBOXìLICO INSATURADO, áCIDO CARBOXìLICO INSATURADO ANáLOGO SUPERIOR E SEU éSTER". Alquenos, ácidos carboxílicos insaturados, ácidos carboxílicos saturados e seus análogos superiores são preparados diretamente a partir de seus correspondentes alcanos utilizando usando um catalisador de leito misto em temperaturas de chama em um reator de curto tempo de contato.
BR0404901-2A 2003-11-18 2004-11-09 Sistema de catalisador, leito catalìtico misto, e, processos para preparar um catalisador, para preparar alquenos a partir de alcanos correspondentes, para preparar ácidos carboxìlicos insaturados a partir de alcanos correspondentes, para converter alcanos a seus correspondentes ésteres de ácidos carboxìlicos insaturados, para a produção de ácido carboxìlicos insaturados superiores, para converter um alcano a seus correspondentes ácidos carboxìlicos insaturados, para converter um alcano a um correspondente éster análogo superior de ácidos carboxìlicos insaturados, e para converter um alcano a seus correspondentes produtos selecionados de ácido carboxìlico insaturado, ácido carboxìlico insaturado análogo superior e seu éster BRPI0404901A (pt)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US52329703P 2003-11-18 2003-11-18

Publications (1)

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BRPI0404901A true BRPI0404901A (pt) 2005-07-19

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Application Number Title Priority Date Filing Date
BR0404901-2A BRPI0404901A (pt) 2003-11-18 2004-11-09 Sistema de catalisador, leito catalìtico misto, e, processos para preparar um catalisador, para preparar alquenos a partir de alcanos correspondentes, para preparar ácidos carboxìlicos insaturados a partir de alcanos correspondentes, para converter alcanos a seus correspondentes ésteres de ácidos carboxìlicos insaturados, para a produção de ácido carboxìlicos insaturados superiores, para converter um alcano a seus correspondentes ácidos carboxìlicos insaturados, para converter um alcano a um correspondente éster análogo superior de ácidos carboxìlicos insaturados, e para converter um alcano a seus correspondentes produtos selecionados de ácido carboxìlico insaturado, ácido carboxìlico insaturado análogo superior e seu éster

Country Status (7)

Country Link
US (1) US20050131255A1 (pt)
EP (1) EP1533029A1 (pt)
JP (2) JP2005144432A (pt)
KR (1) KR100722491B1 (pt)
CN (1) CN1308075C (pt)
BR (1) BRPI0404901A (pt)
TW (1) TWI279253B (pt)

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KR20050048528A (ko) 2005-05-24
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TWI279253B (en) 2007-04-21
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