BRPI0407989A - processo, e planta, para processar gás natural - Google Patents

processo, e planta, para processar gás natural

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Publication number
BRPI0407989A
BRPI0407989A BRPI0407989-2A BRPI0407989A BRPI0407989A BR PI0407989 A BRPI0407989 A BR PI0407989A BR PI0407989 A BRPI0407989 A BR PI0407989A BR PI0407989 A BRPI0407989 A BR PI0407989A
Authority
BR
Brazil
Prior art keywords
hydrogen
natural gas
rich stream
steam
hydrocarbon
Prior art date
Application number
BRPI0407989-2A
Other languages
English (en)
Inventor
Michael Joseph Bowe
Original Assignee
Gtl Microsystems Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gtl Microsystems Ag filed Critical Gtl Microsystems Ag
Publication of BRPI0407989A publication Critical patent/BRPI0407989A/pt
Publication of BRPI0407989B1 publication Critical patent/BRPI0407989B1/pt

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
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    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
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    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/32Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air
    • C01B3/34Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide or air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382Processes with two or more reaction steps, of which at least one is catalytic, e.g. steam reforming and partial oxidation
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    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/50Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification
    • C01B3/501Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification by diffusion
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G31/00Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for
    • C10G31/11Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for by dialysis
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    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
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    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
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    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
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    • C01B2203/0405Purification by membrane separation
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    • C01B2203/0465Composition of the impurity
    • C01B2203/048Composition of the impurity the impurity being an organic compound
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    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/0495Composition of the impurity the impurity being water
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    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06Integration with other chemical processes
    • C01B2203/062Hydrocarbon production, e.g. Fischer-Tropsch process
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    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
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    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
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    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C01B2203/0827Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel at least part of the fuel being a recycle stream
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    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0838Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel
    • C01B2203/0844Methods of heating the process for making hydrogen or synthesis gas by heat exchange with exothermic reactions, other than by combustion of fuel the non-combustive exothermic reaction being another reforming reaction as defined in groups C01B2203/02 - C01B2203/0294
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    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
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    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0872Methods of cooling
    • C01B2203/0877Methods of cooling by direct injection of fluid
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    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
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    • C01B2203/0872Methods of cooling
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    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0872Methods of cooling
    • C01B2203/0888Methods of cooling by evaporation of a fluid
    • C01B2203/0894Generation of steam
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    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1047Group VIII metal catalysts
    • C01B2203/1052Nickel or cobalt catalysts
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    • C01B2203/1082Composition of support materials
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    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205Composition of the feed
    • C01B2203/1211Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235Hydrocarbons
    • C01B2203/1241Natural gas or methane
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    • C01B2203/1258Pre-treatment of the feed
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    • C01B2203/127Catalytic desulfurisation
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    • C01B2203/14Details of the flowsheet
    • C01B2203/142At least two reforming, decomposition or partial oxidation steps in series
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    • C01B2203/80Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/82Several process steps of C01B2203/02 - C01B2203/08 integrated into a single apparatus
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    • C01B2203/80Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/84Energy production
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/32Hydrogen storage
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Treating Waste Gases (AREA)
  • Insertion Pins And Rivets (AREA)
  • Heat Treatment Of Articles (AREA)

Abstract

"PROCESSO, E PLANTA, PARA PROCESSAR GáS NATURAL". Gás natural é reagido com vapor, de modo a gerar monóxido de carbono e hidrogênio em um primeiro reator catalítico; a mistura de gás resultante é usada para realizar a síntese de Fischer-Tropsch em um segundo reator catalítico. Após realizar a síntese de Fischer-Tropsch, o hidrogênio restante é separado de uma corrente rica em hidrocarboneto usando uma membrana permeável a hidrogênio, e a corrente rica em hidrocarboneto é retornada para ser submetida à reforma com vapor. Preferivelmente, a corrente rica em hidrogênio é suprida em um canal de combustão de modo a prover calor para a reação endotérmica de reforma com vapor. O processo global converte gás natural em hidrocarbonetos de cadeia mais longa e pode prover uma conversão de carbono acima de 80%.
BRPI0407989-2B1A 2003-03-05 2004-02-25 Processo para processar gás natural BRPI0407989B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB0304949.1A GB0304949D0 (en) 2003-03-05 2003-03-05 Catalytic reactor and process
PCT/GB2004/000737 WO2004078642A1 (en) 2003-03-05 2004-02-25 Method for producing long-chain hydrocarbons from natural gas

Publications (2)

Publication Number Publication Date
BRPI0407989A true BRPI0407989A (pt) 2006-03-07
BRPI0407989B1 BRPI0407989B1 (pt) 2013-11-19

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Application Number Title Priority Date Filing Date
BRPI0407989-2B1A BRPI0407989B1 (pt) 2003-03-05 2004-02-25 Processo para processar gás natural

Country Status (10)

Country Link
US (1) US7351750B2 (pt)
EP (1) EP1599414B1 (pt)
AT (1) ATE396144T1 (pt)
AU (1) AU2004218207B2 (pt)
BR (1) BRPI0407989B1 (pt)
DE (1) DE602004013931D1 (pt)
DK (1) DK1599414T3 (pt)
GB (1) GB0304949D0 (pt)
NO (1) NO20054084L (pt)
WO (1) WO2004078642A1 (pt)

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GB2399516B (en) * 2001-12-05 2005-03-16 Gtl Microsystems Ag Process and apparatus for steam-methane reforming
GB0405796D0 (en) 2004-03-16 2004-04-21 Accentus Plc Converting natural gas to longer-chain hydrocarbons
GB0501731D0 (en) * 2005-01-31 2005-03-02 Accentus Plc Catalytic reactor
AU2007246840B2 (en) 2006-05-08 2011-10-13 Compactgtl Plc Catalyst structure for a rapid reaction
CA2675816C (en) * 2007-01-19 2015-09-01 Velocys, Inc. Process and apparatus for converting natural gas to higher molecular weight hydrocarbons using microchannel process technology
US8100996B2 (en) * 2008-04-09 2012-01-24 Velocys, Inc. Process for upgrading a carbonaceous material using microchannel process technology
WO2009126765A2 (en) * 2008-04-09 2009-10-15 Velocys Inc. Process for converting a carbonaceous material to methane, methanol and/or dimethyl ether using microchannel process technology
US8747656B2 (en) 2008-10-10 2014-06-10 Velocys, Inc. Process and apparatus employing microchannel process technology
WO2011044549A1 (en) * 2009-10-09 2011-04-14 Velocys Inc. Process for treating heavy oil
US9050588B2 (en) * 2011-05-27 2015-06-09 Gi—Gasification International, S.A. Fischer-tropsch catalyst activation procedure
US8857185B2 (en) * 2012-01-06 2014-10-14 United Technologies Corporation High gliding fluid power generation system with fluid component separation and multiple condensers
GB201216271D0 (en) * 2012-09-12 2012-10-24 Compactgtl Plc Operation of catalytic process plant
EP2727979B1 (de) * 2012-11-02 2015-01-07 Helmholtz-Zentrum Geesthacht Zentrum für Material- und Küstenforschung GmbH Fischer-Tropsch-Verfahren zur Herstellung von Kohlenwasserstoffen aus Biogas
US9676623B2 (en) 2013-03-14 2017-06-13 Velocys, Inc. Process and apparatus for conducting simultaneous endothermic and exothermic reactions
EP3328965B1 (en) * 2015-07-28 2019-04-24 Shell International Research Maatschappij B.V. Process for preparing a paraffin product
DE102020128868A1 (de) 2020-11-03 2022-05-05 Karlsruher Institut für Technologie Umwandlung von CO2 in chemische Energieträger und Produkte

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FR2788051B1 (fr) * 1999-01-05 2001-02-09 Air Liquide Procede et installation de production de monoxyde de carbone ou d'un melange co/h2
WO2000058242A2 (en) * 1999-03-30 2000-10-05 Syntroleum Corporation System and method for converting light hydrocarbons into heavier hydrocarbons with a plurality of synthesis gas subsystems
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US6497856B1 (en) * 2000-08-21 2002-12-24 H2Gen Innovations, Inc. System for hydrogen generation through steam reforming of hydrocarbons and integrated chemical reactor for hydrogen production from hydrocarbons
GB0116894D0 (en) 2001-07-11 2001-09-05 Accentus Plc Catalytic reactor

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AU2004218207B2 (en) 2009-07-23
US7351750B2 (en) 2008-04-01
NO20054084L (no) 2005-10-05
EP1599414B1 (en) 2008-05-21
GB0304949D0 (en) 2003-04-09
US20060142400A1 (en) 2006-06-29
WO2004078642A1 (en) 2004-09-16
DK1599414T3 (da) 2008-08-11
AU2004218207A1 (en) 2004-09-16
BRPI0407989B1 (pt) 2013-11-19
DE602004013931D1 (de) 2008-07-03
EP1599414A1 (en) 2005-11-30
ATE396144T1 (de) 2008-06-15
NO20054084D0 (no) 2005-09-02
AU2004218207A2 (en) 2004-09-16

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