BRPI0413457A - sistema catalìtico, processos de preparação de um sistema catalìtico e de um copolìmero, e, copolìmero - Google Patents

sistema catalìtico, processos de preparação de um sistema catalìtico e de um copolìmero, e, copolìmero

Info

Publication number
BRPI0413457A
BRPI0413457A BRPI0413457-5A BRPI0413457A BRPI0413457A BR PI0413457 A BRPI0413457 A BR PI0413457A BR PI0413457 A BRPI0413457 A BR PI0413457A BR PI0413457 A BRPI0413457 A BR PI0413457A
Authority
BR
Brazil
Prior art keywords
catalytic system
copolymer
preparing
monoolefin
processes
Prior art date
Application number
BRPI0413457-5A
Other languages
English (en)
Inventor
Christophe Boisson
Vincent Monteil
Roger Spitz
Original Assignee
Michelin Soc Tech
Michelin Rech Et Techinique S
Total Petrochemicals Res Feluy
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Michelin Soc Tech, Michelin Rech Et Techinique S, Total Petrochemicals Res Feluy filed Critical Michelin Soc Tech
Publication of BRPI0413457A publication Critical patent/BRPI0413457A/pt
Publication of BRPI0413457B1 publication Critical patent/BRPI0413457B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/58—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with silicon, germanium, tin, lead, antimony, bismuth or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

"SISTEMA CATALìTICO , PROCESSOS DE PREPARAçãO DE UM SISTEMA CATALìTICO E DE UM COPOLìMERO, E, COPOLìMERO". A presente invenção refere-se a um sistema catalítico utilizável para o copolímero de um dieno conjugado e de pelo menos uma monoolefina, um processo de preparação deste sistema catalítico, um processo de preparação de um copolímero de um dieno conjugado e de pelo menos uma monoolefina utilizando este sistema catalítico e este copolímero. Este sistema catalítico compreende: (i) um complexo organometálico representado pela fórmula genérica seguinte: (1) {¢P(C~ p~)(Fl)Ln(X)(L~ x~)}~ p~ onde Ln representa um átomo de lantanídeo, ao qual é ligada uma molécula de ligando compreendendo os grupos ciclopentadienila C~ p~ e fluorenila Fl, ligados, entre si, por uma ponte P de fórmula MR¬ 1¬R¬ 2¬, onde M é um elemento de coluna IVA e onde R¬ 1¬ e R¬ 2¬, idênticos ou diferentes, representam, cada um, grupos alquila tendo de 1 a 20 átomos de carbono ou então os grupos cicloalquila ou fenila tendo de 6 a 20 átomos de carbono, onde X representa um átomo de halogênio podendo ser o cloro, o flúor, o bromo ou o iodo, onde L compreende uma molécula complexante opcional, tal como um éter, e eventualmente uma molécula sensivelmente menos complexante, como o tolueno, onde p é um inteiro natural igual ou superior a 1 e x é igual ou superior a 0, e (ii) um co-catalisador pertencendo ao grupo constituído por alquil magnésios, alquil lítios, alquil alumínios, os reagentes de Grignard e as misturas destes constituintes.
BRPI0413457-5A 2003-08-13 2004-07-26 Sistema catalítico, processos de preparação de um sistema catalítico e de um copolímero, e, copolímero BRPI0413457B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR0309930A FR2858817B1 (fr) 2003-08-13 2003-08-13 Systeme catalytique pour l'obtention de copolymeres diene(s) conjugue(s)/ mono-olefine(s) et ces copolymeres
FR0309930 2003-08-13
PCT/EP2004/008336 WO2005028526A1 (fr) 2003-08-13 2004-07-26 Système catalytique pour l'obtention de copolymères diène(s) conjugué(s) / mono-oléfine(s) et ces copolymères

Publications (2)

Publication Number Publication Date
BRPI0413457A true BRPI0413457A (pt) 2006-10-17
BRPI0413457B1 BRPI0413457B1 (pt) 2014-09-09

Family

ID=34112767

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0413457-5A BRPI0413457B1 (pt) 2003-08-13 2004-07-26 Sistema catalítico, processos de preparação de um sistema catalítico e de um copolímero, e, copolímero

Country Status (10)

Country Link
US (2) US7547654B2 (pt)
EP (1) EP1656400B1 (pt)
JP (1) JP5329040B2 (pt)
KR (2) KR101196236B1 (pt)
CN (1) CN100567343C (pt)
BR (1) BRPI0413457B1 (pt)
FR (1) FR2858817B1 (pt)
MX (1) MXPA06001656A (pt)
RU (1) RU2400492C2 (pt)
WO (1) WO2005028526A1 (pt)

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FR2886937B1 (fr) * 2005-06-14 2007-08-10 Michelin Soc Tech Procede de preparation d'un elastomere dienique, tel qu'un polybutadiene
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JP5917809B2 (ja) * 2010-11-30 2016-05-18 株式会社ブリヂストン 共重合体及びその製造方法、並びに、ゴム組成物、架橋ゴム組成物、及びタイヤ
JP5557710B2 (ja) * 2010-11-30 2014-07-23 株式会社ブリヂストン 共重合体
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JP5917886B2 (ja) * 2011-11-04 2016-05-18 株式会社ブリヂストン 共役ジエン系重合体
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FR3001223B1 (fr) 2013-01-22 2015-03-06 Michelin & Cie Composition de caoutchouc comprenant un elastomere dienique fortement sature
EP3148937B1 (en) 2014-05-30 2019-09-18 Bridgestone Corporation Metallic complex catalyst and polymerization methods employing same
US10457765B2 (en) 2014-05-31 2019-10-29 Bridgestone Corporation Metallic complex catalyst, polymerization methods employing same and polymer products thereof
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EP3363824B1 (en) * 2015-10-16 2024-05-01 Bridgestone Corporation Multicomponent copolymer, rubber composition, cross-linked rubber composition, rubber product, and tire
JPWO2017065300A1 (ja) * 2015-10-16 2018-08-02 株式会社ブリヂストン 多元共重合体、樹脂組成物、架橋樹脂組成物、及び製品
FR3044007B1 (fr) 2015-11-19 2017-12-08 Michelin & Cie Bande de roulement pour pneumatique d'avion
FR3044010A1 (fr) 2015-11-19 2017-05-26 Michelin & Cie Bande de roulement pour pneumatique d'avion
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FR3044663B1 (fr) * 2015-12-08 2017-12-29 Michelin & Cie Copolymere monofonctionnel ou telechelique de 1,3-butadiene et d'ethylene.
FR3045613B1 (fr) 2015-12-17 2017-12-15 Michelin & Cie Copolymere d'ethylene et de butadiene de microstructure homogene
FR3045633B1 (fr) 2015-12-22 2017-12-15 Michelin & Cie Pneumatique comprenant une composition de caoutchouc comprenant un elastomere dienique substitue
FR3060007A1 (fr) * 2016-12-09 2018-06-15 Compagnie Generale Des Etablissements Michelin Terpolymeres d'ethylene, de 1,3-butadiene ou d'isoprene, et d'une alpha-monoolefine aromatique
FR3060576A1 (fr) 2016-12-15 2018-06-22 Compagnie Generale Des Etablissements Michelin Elastomere dienique portant des groupes pendants anthracenyles
FR3060592A1 (fr) 2016-12-15 2018-06-22 Compagnie Generale Des Etablissements Michelin Pneumatique comportant une composition de caoutchouc comprenant un polymere porteur d'un groupement diene conjugue reticule par un dienophile
FR3060571A1 (fr) 2016-12-19 2018-06-22 Compagnie Generale Des Etablissements Michelin Procede de preparation d'un elastomere dienique modifie par un compose 1,3-dipolaire
FR3060570A1 (fr) 2016-12-19 2018-06-22 Compagnie Generale Des Etablissements Michelin Procede de preparation d'un elastomere dienique modifie par un compose 1,3-dipolaire par extrusion reactive
FR3063731A1 (fr) 2017-03-08 2018-09-14 Compagnie Generale Des Etablissements Michelin Pneumatique muni d'une composition comprenant un elastomere riche en ethylene, un peroxyde et un acrylate de zinc
FR3063732A1 (fr) 2017-03-08 2018-09-14 Compagnie Generale Des Etablissements Michelin Pneumatique muni d'une composition comprenant un elastomere riche en ethylene, un peroxyde et un derive d'acrylate polyfonctionnel
WO2019002756A1 (fr) 2017-06-28 2019-01-03 Compagnie Generale Des Etablissements Michelin Elastomère diénique portant des groupes imidazole
FR3068703A1 (fr) 2017-07-04 2019-01-11 Compagnie Generale Des Etablissements Michelin Composition a base d'au moins un compose polyaromatique particulier
FR3068698A1 (fr) 2017-07-04 2019-01-11 Compagnie Generale Des Etablissements Michelin Polymere portant des groupes pendants fonctionnels particuliers imidazolidinone
FR3069550A1 (fr) 2017-07-28 2019-02-01 Compagnie Generale Des Etablissements Michelin Elastomere etendu a la resine
US20210171669A1 (en) 2017-11-21 2021-06-10 Compagnie Generale Des Etablissements Michelin Diene polymer modified by an epoxide group
WO2019102128A1 (fr) 2017-11-21 2019-05-31 Compagnie Generale Des Etablissements Michelin Composé 1,3-dipolaire comportant un groupe époxyde
US11492459B2 (en) 2017-11-21 2022-11-08 Compagnie Generale Des Etablissements Michelin Rubber composition
WO2019102132A1 (fr) 2017-11-21 2019-05-31 Compagnie Generale Des Etablissements Michelin Composition de caoutchouc
JP6983048B2 (ja) * 2017-12-05 2021-12-17 株式会社ブリヂストン 共重合体、ゴム組成物、樹脂組成物、タイヤ及び樹脂製品
JP7002310B2 (ja) 2017-12-05 2022-02-04 株式会社ブリヂストン 多元共重合体の製造方法
JP2019099719A (ja) 2017-12-05 2019-06-24 株式会社ブリヂストン 共重合体、ゴム組成物、樹脂組成物、タイヤ及び樹脂製品
WO2019110926A1 (fr) 2017-12-06 2019-06-13 Compagnie Generale Des Etablissements Michelin Stratifie elastomere
WO2019110924A1 (fr) 2017-12-06 2019-06-13 Compagnie Generale Des Etablissements Michelin Stratifié élastomère
FR3085166B1 (fr) 2018-08-23 2020-07-17 Compagnie Generale Des Etablissements Michelin Pneumatique muni d'une composition comprenant un elastomere riche en ethylene, un peroxyde et un derive d'acrylate specifique
FR3085165B1 (fr) 2018-08-23 2020-07-17 Compagnie Generale Des Etablissements Michelin Pneumatique muni d'une composition comprenant un elastomere riche en ethylene, un peroxyde et un derive d'acrylate specifique
FR3085167B1 (fr) 2018-08-23 2020-07-31 Michelin & Cie Pneumatique muni d'une composition comprenant un elastomere riche en ethylene, un peroxyde et un derive d'acrylate specifique
FR3088328B3 (fr) 2018-11-09 2020-12-04 Michelin & Cie Elastomere dienique fonctionnel et composition de caoutchouc
FR3104584B1 (fr) 2019-12-17 2021-12-03 Michelin & Cie Composé diorganomagnésien asymétrique
FR3104586B1 (fr) 2019-12-17 2021-12-03 Michelin & Cie Composé diorganomagnésien asymétrique pour système catalytique
FR3116276B1 (fr) 2020-11-19 2023-11-10 Michelin & Cie Diorganomagnésien ayant une chaîne diénique ou oléfinique et fonctionnelle amine
FR3116277A1 (fr) 2020-11-19 2022-05-20 Compagnie Generale Des Etablissements Michelin Copolymères fonctionnels amine à blocs éthyléniques et diéniques
FR3116538B1 (fr) 2020-11-24 2022-11-25 Michelin & Cie Co-catalyseur comprenant plusieurs liaisons carbone magnésium
CN120981495A (zh) 2023-02-08 2025-11-18 埃克森美孚技术与工程公司 用于共聚的催化剂
CN121620541A (zh) 2023-06-06 2026-03-06 埃克森美孚技术与工程公司 溶液催化剂体系及其用途

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Also Published As

Publication number Publication date
JP5329040B2 (ja) 2013-10-30
WO2005028526A1 (fr) 2005-03-31
US7547654B2 (en) 2009-06-16
RU2006107530A (ru) 2006-06-27
US8039565B2 (en) 2011-10-18
FR2858817B1 (fr) 2006-02-03
CN100567343C (zh) 2009-12-09
KR101196236B1 (ko) 2012-11-05
EP1656400B1 (fr) 2019-05-29
EP1656400A1 (fr) 2006-05-17
RU2400492C2 (ru) 2010-09-27
KR101263815B1 (ko) 2013-05-13
CN1835978A (zh) 2006-09-20
FR2858817A1 (fr) 2005-02-18
BRPI0413457B1 (pt) 2014-09-09
MXPA06001656A (es) 2006-08-11
KR20060088100A (ko) 2006-08-03
JP2007501881A (ja) 2007-02-01
US20060160969A1 (en) 2006-07-20
KR20120082478A (ko) 2012-07-23
US20090270578A1 (en) 2009-10-29

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