BRPI0417462A - uso de compostos de complexo de metal como catalisadores de oxidação - Google Patents
uso de compostos de complexo de metal como catalisadores de oxidaçãoInfo
- Publication number
- BRPI0417462A BRPI0417462A BRPI0417462-3A BRPI0417462A BRPI0417462A BR PI0417462 A BRPI0417462 A BR PI0417462A BR PI0417462 A BRPI0417462 A BR PI0417462A BR PI0417462 A BRPI0417462 A BR PI0417462A
- Authority
- BR
- Brazil
- Prior art keywords
- alkylene
- sym
- unsubstituted
- substituted
- hydrogen
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 3
- -1 metal complex compounds Chemical class 0.000 title abstract 3
- 230000003647 oxidation Effects 0.000 title abstract 3
- 238000007254 oxidation reaction Methods 0.000 title abstract 3
- 229910052739 hydrogen Inorganic materials 0.000 abstract 5
- 239000001257 hydrogen Substances 0.000 abstract 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 4
- 125000000217 alkyl group Chemical group 0.000 abstract 4
- 125000003118 aryl group Chemical group 0.000 abstract 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- 229910052757 nitrogen Inorganic materials 0.000 abstract 2
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 2
- 125000003161 (C1-C6) alkylene group Chemical group 0.000 abstract 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical group C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 239000011230 binding agent Substances 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 150000004696 coordination complex Chemical class 0.000 abstract 1
- 229910052802 copper Inorganic materials 0.000 abstract 1
- 239000010949 copper Substances 0.000 abstract 1
- 239000003599 detergent Substances 0.000 abstract 1
- 238000009472 formulation Methods 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical class 0.000 abstract 1
- 125000005842 heteroatom Chemical group 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 239000011572 manganese Substances 0.000 abstract 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical group [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910052759 nickel Inorganic materials 0.000 abstract 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3723—Polyamines or polyalkyleneimines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Catalysts (AREA)
Abstract
"USO DE COMPOSTOS DE COMPLEXO DE METAL COMO CATALISADORES DE OXIDAçãO". Formulação detergente para lavadora automática de louças compreendendo: (a) um composto de complexo de metal da fórmula (I): ¢L~ n~Me~ m~X~ p~!¬ 2¬ Yq em que Me é manganês, titânio, ferro, cobalto, níquel ou cobre, X é um radical de coordenação ou ligação em ponte, n e m são, independentemente um do outro, um número inteiro tendo um valor de 1 a 8, p é um número inteiro tendo um valor de 0 a 32, z é a carga do complexo de metal, Y é um contra-íon, q = z/ (carga Y), e L é um ligante da fórmula (II): em que R~ 1~, R~ 2~, R~ 3~, R~ 4~, R~ 5~, R~ 6~, R~ 7~, R~ 8~, R~ 9~, R~ 10~ e R~ 11~, são cada um independentemente dos outros hidrogênio; C~ 1~-C~ 18~ alquila ou arila não substituída ou substituída; ciano; halogênio; nitro; -COOR~ 12~ ou -SO~ 3~R~ 12~, em que R~ 12~ é em cada caso hidrogênio, um cátion ou C~ 1~-C~ 18~ alquila ou arila não substituída ou substituída; -SR~ 13~, -SO~ 2~R~ 13~ ou -OR~ 13~ em que R~ 13~ é em cada caso hidrogênio ou C~ 1~-C~ 18~ alquila ou arila não substituída ou substituida; -NR~ 14~R~ 15~; - (C~ 1~-C~ 8~alquileno) -NR~ 14~R~ 15~; -N¬ <sym>¬R~ 14~R~ 15~R~ 16~; -(C~ 1~-C~ 6~alquileno)- -N¬ <sym¬R~ 14~R~ 15~R~ 16~; -N(R~ 13~)-(C~ 1~-C~ 6~alquileno) -NR~ 14~R~ 15~; -N ¢ (C~ 1~-C~ 6~alquileno) -NR~ 14~ R~ 15~!~ 2~; -N(R~ 13~) - (C~ 1~-C~ 6~-alquileno) -N¬ <sym>¬R~ 14~R~ 15~R~ 16~, --N ¢ (C~ 1~-C~ 6~alquileno)-N¬ <sym>¬R~ 14~R~ 15~R~ 16~!~ 2~; -N(R~ 13~)-N-R~ 14~ R~ 15~ ou -N(R~ 13~)-N¬ <sym>R~ 14~R~ 15~R~ 16~, em que R~ 13~ é conforme definido acima e R~ 14~, R~ 16~ e R~ 16~ são cada um independentemente dos outros hidrogênio ou C~ 1~-C~ 18~ alquila ou arila não substituída ou substituída ou R~ 14~ e R~ 18~, junto com o átomo de nitrogênio preso aos mesmos, formam um anel não substituído ou substituído de 5-, 6- ou 7- elementos o qual pode opcionalmente conter outros heteroátomos; contanto que: (I) pelo menos um dos substituintes R~ 1~-R~ 11~, contenha um átomo de nitrogênio quaternizado o qual não é diretamente preso a um dos três anéis de piridina A, B ou C e que (II) Y não é I nem Cl no caso que Me é Mn (II) R~ 1~-R~ 5~ e R~ 7~-R~ 11~, são hidrogênio e R~ 8~ é: como catalisadores para as reações de oxidação; e (b) um polímero sulfonado.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0329561A GB2409207B (en) | 2003-12-20 | 2003-12-20 | Use of metal complex compounds as oxidation catalysts |
| PCT/GB2004/005297 WO2005061688A1 (en) | 2003-12-20 | 2004-12-17 | Use of metal complex compounds as oxidation catalysts |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BRPI0417462A true BRPI0417462A (pt) | 2007-03-13 |
Family
ID=30776188
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0417462-3A BRPI0417462A (pt) | 2003-12-20 | 2004-12-17 | uso de compostos de complexo de metal como catalisadores de oxidação |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20060247144A1 (pt) |
| EP (1) | EP1694807A1 (pt) |
| CN (1) | CN1898372A (pt) |
| AU (1) | AU2004303582A1 (pt) |
| BR (1) | BRPI0417462A (pt) |
| CA (1) | CA2548373A1 (pt) |
| GB (1) | GB2409207B (pt) |
| WO (1) | WO2005061688A1 (pt) |
| ZA (1) | ZA200604394B (pt) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102005063059A1 (de) * | 2005-12-29 | 2007-07-12 | Henkel Kgaa | Reinigungsmittel mit bleichkatalytisch aktiven Komplexen |
| US8338352B2 (en) * | 2007-05-07 | 2012-12-25 | Ecolab Usa Inc. | Solidification matrix |
| US8759269B2 (en) * | 2007-07-02 | 2014-06-24 | Ecolab Usa Inc. | Solidification matrix including a salt of a straight chain saturated mono-, di-, and tri- carboxylic acid |
| US8889048B2 (en) | 2007-10-18 | 2014-11-18 | Ecolab Inc. | Pressed, self-solidifying, solid cleaning compositions and methods of making them |
| US8138138B2 (en) | 2008-01-04 | 2012-03-20 | Ecolab Usa Inc. | Solidification matrix using a polycarboxylic acid polymer |
| US8198228B2 (en) * | 2008-01-04 | 2012-06-12 | Ecolab Usa Inc. | Solidification matrix using an aminocarboxylate |
| US8772221B2 (en) | 2008-01-04 | 2014-07-08 | Ecolab Usa Inc. | Solidification matrices using phosphonocarboxylic acid copolymers and phosphonopolyacrylic acid homopolymers |
| WO2009141258A1 (de) * | 2008-05-23 | 2009-11-26 | Henkel Ag & Co. Kgaa | Textilschonendes waschmittel |
| DE102009029636A1 (de) * | 2009-09-21 | 2011-03-24 | Henkel Ag & Co. Kgaa | Maschine Geschirrspülmittel |
| US8530403B2 (en) * | 2009-11-20 | 2013-09-10 | Ecolab Usa Inc. | Solidification matrix using a maleic-containing terpolymer binding agent |
| US20110124547A1 (en) * | 2009-11-23 | 2011-05-26 | Ecolab Inc. | Solidification matrix using a sulfonated/carboxylated polymer binding agent |
| TWI426090B (zh) * | 2011-05-31 | 2014-02-11 | Tsrc Corp | 製造環氧化聚合物的方法 |
| EP2700704B1 (en) * | 2012-08-24 | 2018-05-09 | The Procter and Gamble Company | Dishwashing method |
| US8871699B2 (en) | 2012-09-13 | 2014-10-28 | Ecolab Usa Inc. | Detergent composition comprising phosphinosuccinic acid adducts and methods of use |
| US20140308162A1 (en) | 2013-04-15 | 2014-10-16 | Ecolab Usa Inc. | Peroxycarboxylic acid based sanitizing rinse additives for use in ware washing |
| US9994799B2 (en) | 2012-09-13 | 2018-06-12 | Ecolab Usa Inc. | Hard surface cleaning compositions comprising phosphinosuccinic acid adducts and methods of use |
| US9752105B2 (en) | 2012-09-13 | 2017-09-05 | Ecolab Usa Inc. | Two step method of cleaning, sanitizing, and rinsing a surface |
| CN103044462B (zh) * | 2012-11-20 | 2015-12-02 | 复旦大学 | 钳型Cu（II）金属有机络合物小分子水凝胶及其应用 |
| DE102020214114A1 (de) * | 2020-11-10 | 2022-05-12 | Henkel Ag & Co. Kgaa | Metallkomplexe und Geschirrspülmittel, die sie enthalten |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19852972A1 (de) * | 1998-11-17 | 2000-05-18 | Henkel Kgaa | Färbemittel mit Übergangsmetallkomplexen |
| AU4109100A (en) * | 1999-04-01 | 2000-10-23 | Unilever Plc | Composition and method for bleaching a substrate |
| GB9930248D0 (en) * | 1999-12-22 | 2000-02-09 | Johnson Matthey Plc | Surface cleaner |
| BR0209292B1 (pt) * | 2001-04-30 | 2014-04-29 | Ciba Sc Holding Ag | Composto de complexo de metal, agente de lavagem, limpeza, desinfecção ou alvejamento, e preparação sólida |
| EP1521820B1 (en) * | 2002-07-11 | 2006-03-22 | Ciba SC Holding AG | Use of metal complex compounds as oxidation catalysts |
| KR20050059312A (ko) * | 2002-10-29 | 2005-06-17 | 시바 스폐셜티 케미칼스 홀딩 인코포레이티드 | 분자 산소 또는 공기를 사용한 산화반응에 대한 촉매로서금속 착물 화합물의 용도 |
| GB2394720A (en) * | 2002-10-30 | 2004-05-05 | Reckitt Benckiser Nv | Metal complex compounds in dishwasher formulations |
-
2003
- 2003-12-20 GB GB0329561A patent/GB2409207B/en not_active Expired - Fee Related
-
2004
- 2004-12-17 EP EP04806108A patent/EP1694807A1/en not_active Withdrawn
- 2004-12-17 CN CNA2004800382053A patent/CN1898372A/zh active Pending
- 2004-12-17 BR BRPI0417462-3A patent/BRPI0417462A/pt not_active IP Right Cessation
- 2004-12-17 CA CA002548373A patent/CA2548373A1/en not_active Abandoned
- 2004-12-17 WO PCT/GB2004/005297 patent/WO2005061688A1/en not_active Ceased
- 2004-12-17 AU AU2004303582A patent/AU2004303582A1/en not_active Abandoned
-
2006
- 2006-05-30 ZA ZA200604394A patent/ZA200604394B/xx unknown
- 2006-06-14 US US11/424,061 patent/US20060247144A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| US20060247144A1 (en) | 2006-11-02 |
| ZA200604394B (en) | 2008-12-31 |
| AU2004303582A1 (en) | 2005-07-07 |
| GB0329561D0 (en) | 2004-01-28 |
| WO2005061688A1 (en) | 2005-07-07 |
| GB2409207A (en) | 2005-06-22 |
| GB2409207B (en) | 2006-08-09 |
| CA2548373A1 (en) | 2005-07-07 |
| EP1694807A1 (en) | 2006-08-30 |
| CN1898372A (zh) | 2007-01-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B25G | Requested change of headquarter approved |
Owner name: RECKITT BENCKISER N.V. (NL) Free format text: SEDE ALTERADA CONFORME SOLICITADO NA PETICAO NO 020070148014/RJ DE 19/10/2007. |
|
| B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
Free format text: REFERENTE AS 4A, 5A, 6A E 7A ANUIDADES. |
|
| B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |
Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 2158 DE 15/05/2012. |