BRPI0417926A - composições de polietileno tendo propriedades de rasgamento melhoradas - Google Patents

composições de polietileno tendo propriedades de rasgamento melhoradas

Info

Publication number
BRPI0417926A
BRPI0417926A BRPI0417926-9A BRPI0417926A BRPI0417926A BR PI0417926 A BRPI0417926 A BR PI0417926A BR PI0417926 A BRPI0417926 A BR PI0417926A BR PI0417926 A BRPI0417926 A BR PI0417926A
Authority
BR
Brazil
Prior art keywords
polyethylene
component
tear properties
improved tear
polyethylene compositions
Prior art date
Application number
BRPI0417926-9A
Other languages
English (en)
Inventor
Tae Hoon Kwalk
Original Assignee
Univation Tech Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univation Tech Llc filed Critical Univation Tech Llc
Publication of BRPI0417926A publication Critical patent/BRPI0417926A/pt
Publication of BRPI0417926B1 publication Critical patent/BRPI0417926B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethylene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/013—Fillers, pigments or reinforcing additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/06—Properties of polyethylene
    • C08L2207/062—HDPE
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/06—Metallocene or single site catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
    • C08L2666/06—Homopolymers or copolymers of unsaturated hydrocarbons; Derivatives thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

"COMPOSIçõES DE POLIETILENO TENDO PROPRIEDADES DE RASGAMENTO MELHORADAS". A presente invenção refere-se a uma composição de polietileno multimodal de alta densidade que tem uma densidade de 0,935 g/cm3 ou mais, e que inclui uma mistura de um primeiro componente de polietileno e um segundo componente de polietileno, em que o primeiro componente de polietileno inclui um polietileno bimodal; e o segundo componente de polietileno inclui um polietileno unimodal produzido com metaloceno, a composição caracterizada por ter um baixo nível de polietileno tendo um peso molecular inferior a 1 000 uma e um baixo nível de polietileno tendo um peso molecular superior a 500 000 uma.
BRPI0417926A 2003-12-22 2004-04-14 composições de polietileno tendo propriedades de rasgamento melhoradas BRPI0417926B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/745,461 US7288596B2 (en) 2003-12-22 2003-12-22 Polyethylene compositions having improved tear properties
PCT/US2004/011455 WO2005068076A1 (en) 2003-12-22 2004-04-14 Polyethylene compositions having improved tear properties

Publications (2)

Publication Number Publication Date
BRPI0417926A true BRPI0417926A (pt) 2007-04-17
BRPI0417926B1 BRPI0417926B1 (pt) 2016-09-20

Family

ID=34679163

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0417926A BRPI0417926B1 (pt) 2003-12-22 2004-04-14 composições de polietileno tendo propriedades de rasgamento melhoradas

Country Status (12)

Country Link
US (2) US7288596B2 (pt)
EP (1) EP1697044B1 (pt)
JP (1) JP2007515540A (pt)
KR (1) KR20060123360A (pt)
CN (1) CN100464854C (pt)
AR (1) AR045846A1 (pt)
AT (1) ATE528072T1 (pt)
BR (1) BRPI0417926B1 (pt)
CA (1) CA2546629A1 (pt)
RU (1) RU2349613C2 (pt)
TW (1) TW200521178A (pt)
WO (1) WO2005068076A1 (pt)

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4468303B2 (ja) * 2003-09-19 2010-05-26 株式会社プライムポリマー 延伸フィルム
US7288596B2 (en) * 2003-12-22 2007-10-30 Univation Technologies, Llc Polyethylene compositions having improved tear properties
US7193017B2 (en) * 2004-08-13 2007-03-20 Univation Technologies, Llc High strength biomodal polyethylene compositions
US7473745B2 (en) 2005-09-02 2009-01-06 Equistar Chemicals, Lp Preparation of multimodal polyethylene
US20090099315A1 (en) * 2005-11-28 2009-04-16 Basell Polyolefine Gmbh Polyethylene Composition Suitable for the Preparation of Films and Process for Preparing the Same
AU2007319883B2 (en) * 2006-11-14 2012-12-13 Univation Technologies, Llc. Catalyst systems and polymerization processes
WO2008132054A1 (en) * 2007-04-26 2008-11-06 Norfolier As Polyethylene compositions
US8318872B2 (en) * 2007-12-18 2012-11-27 Univation Technologies, Llc Method for controlling bimodal catalyst activity during polymerization
RU2372360C1 (ru) * 2008-06-06 2009-11-10 Открытое акционерное общество "НИИ шинной промышленности" Способ производства термоусадочных пленок
US8957158B2 (en) * 2008-09-25 2015-02-17 Basell Polyolefine Gmbh Impact resistant LLDPE composition and films made thereof
US8022154B2 (en) * 2008-11-06 2011-09-20 Exxonmobil Chemical Patents Inc. Ethylene polymers, their production and use
RU2436815C2 (ru) * 2009-09-07 2011-12-20 Общество с ограниченной ответственностью "ОСБИО" Полимерный композиционный материал для изготовления электролизных ванн
US9084444B2 (en) * 2010-05-25 2015-07-21 Inteplast Group, Ltd. Disposable gloves and glove material compositions
US9084445B2 (en) 2011-09-15 2015-07-21 Inteplast Group, Ltd. Disposable gloves and glove material compositions
US9131737B2 (en) 2011-09-15 2015-09-15 Inteplast Group, Ltd. Disposable gloves and glove material compositions including a coloring agent
US9387957B2 (en) * 2012-01-25 2016-07-12 The Glad Products Company Trash bag with inner bag
ES2657137T5 (en) 2012-03-28 2025-02-12 Borealis Ag Multimodal polymer
KR101331556B1 (ko) * 2012-03-30 2013-11-20 대림산업 주식회사 멀티모달 폴리올레핀 수지 및 이로부터 제조되는 성형체
JP6574326B2 (ja) 2014-08-26 2019-09-11 クレイトン・ポリマーズ・ユー・エス・エル・エル・シー ネオジム触媒イソプレン成分を含んだ、透明かつ強靭かつ耐熱性のあるゴム組成物およびその製造方法
CN104817752B (zh) * 2015-05-06 2017-05-10 无锡耀汇科技有限公司 一种聚乙烯薄膜及其制备方法
KR20170049272A (ko) * 2015-10-28 2017-05-10 대림산업 주식회사 멀티모달 폴리올레핀 수지 및 이로부터 제조되는 성형체
EP3580244B1 (en) 2017-02-07 2025-02-12 ExxonMobil Chemical Patents Inc. Processes for reducing the loss of catalyst activity of a ziegler-natta catalyst
US9963529B1 (en) 2017-04-19 2018-05-08 Nova Chemicals (International) S.A. Multi reactor solution polymerization
US10538654B2 (en) 2017-04-19 2020-01-21 Nova Chemicals (International) S.A. Multi reactor solution polymerization, polyethylene and polyethylene film
EP3749707A1 (en) 2018-02-05 2020-12-16 ExxonMobil Chemical Patents Inc. Enhanced processability of lldpe by addition of ultra-high molecular weight high density polyethylene
SG11202113216TA (en) * 2019-06-10 2021-12-30 Univation Tech Llc Polyethylene blend
BR112022004186A2 (pt) * 2019-09-26 2022-05-31 Univation Tech Llc Composição de homopolímero de polietileno bimodal, métodos para fazer a composição de homopolímero de polietileno bimodal, para fabricar um artigo fabricado, para fazer um filme extrudado e para proteger um material sensível à umidade e/ou sensível ao oxigênio, formulação, artigo fabricado, filme extrudado, e, embalagem vedada
KR102547229B1 (ko) * 2019-10-16 2023-06-26 한화솔루션 주식회사 올레핀 중합용 혼성 촉매의 제조방법, 올레핀 중합용 혼성 촉매 및 올레핀계 중합체
PL4172114T3 (pl) * 2020-08-31 2024-09-02 Veolia Water Solutions & Technologies Support Wykorzystanie nośnika biofilmu do reaktorów z ruchomym złożem biofilmowym
BR112023004722A2 (pt) 2020-10-09 2023-05-09 Dow Global Technologies Llc Composição polimérica, e, condutor revestido
BR112023018908A2 (pt) 2021-04-15 2023-10-24 Dow Global Technologies Llc Composição polimérica, e, condutor revestido

Family Cites Families (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5910724B2 (ja) * 1979-08-24 1984-03-10 旭化成株式会社 エチレンの連続重合法
US4461873A (en) * 1982-06-22 1984-07-24 Phillips Petroleum Company Ethylene polymer blends
KR960007297B1 (ko) 1987-07-13 1996-05-30 미쓰비시 가가꾸 가부시끼가이샤 폴리에틸렌 필름으로 제조된 포대
US5110685A (en) 1990-05-18 1992-05-05 Exxon Chemical Patents, Inc. Low friction, abrasion resistant polymer coating
US5338589A (en) * 1991-06-05 1994-08-16 Hoechst Aktiengesellschaft Polyethylene molding composition
US5274056A (en) 1992-01-31 1993-12-28 Phillips Petroleum Company Linear, very low density polyethylene polymerization process and products thereof
US5208309A (en) 1992-01-31 1993-05-04 Phillips Petroleum Company Linear, very low density polyethylene polymerization process and products thereof
US5284613A (en) * 1992-09-04 1994-02-08 Mobil Oil Corporation Producing blown film and blends from bimodal high density high molecular weight film resin using magnesium oxide-supported Ziegler catalyst
US5344884A (en) 1992-10-08 1994-09-06 Phillips Petroleum Company Polyethylene blends
US5378764A (en) 1992-10-08 1995-01-03 Phillips Petroleum Company Polyethylene blends
BE1006439A3 (fr) * 1992-12-21 1994-08-30 Solvay Societe Annonyme Procede de preparation d'une composition de polymeres d'ethylene, composition de polymeres d'ethylene et son utilisation.
FI98819C (fi) 1993-03-26 1997-08-25 Borealis Polymers Oy Prosessi olefiinipolymeerien valmistamiseksi ja prosessilla valmistetut tuotteet
EP0696300B1 (en) * 1993-04-28 1998-12-23 The Dow Chemical Company Fabricated articles made from ethylene polymer blends
EP0737694B1 (en) 1993-12-28 2001-06-06 Idemitsu Kosan Company Limited Process for producing olefin polymer and ethylene polymer
US5635262A (en) * 1994-12-12 1997-06-03 Exxon Chemical Patents Inc. High molecular weight high density polyethylene with improved tear resistance
FI101546B (fi) * 1994-12-16 1998-07-15 Borealis Polymers Oy Polyeteenikompositio
FI108452B (fi) 1996-06-07 2002-01-31 Borealis Polymers Oy Etyleenipolymeerituote, jolla on leveõ moolimassajakauma, sen valmistus ja kõytt÷
US5795941A (en) 1995-10-03 1998-08-18 The Dow Chemical Company Crosslinkable bimodal polyolefin compositions
GB9806407D0 (en) * 1998-03-25 1998-05-20 Bp Chem Int Ltd Novel polymer compositions
IL138733A0 (en) * 1998-04-06 2001-10-31 Borealis Tech Oy High density polyethylene compositions, a process for the production thereof and films prepared thereof
DE69935332T2 (de) 1998-07-16 2007-10-31 Univation Technologies, LLC, Houston Lewis-säure cokatalysatoren auf aluminium-basis für die olefinpolymerisation
EP0989141A1 (en) * 1998-09-25 2000-03-29 Fina Research S.A. Production of multimodal polyethelene
SE9803501D0 (sv) * 1998-10-14 1998-10-14 Borealis Polymers Oy Polymer composition for pipes
JP2000129044A (ja) * 1998-10-27 2000-05-09 Asahi Chem Ind Co Ltd 高純度薬品用ポリエチレン容器
CA2350451A1 (en) 1998-12-18 2000-06-29 Clark C. Williams Olefin polymerization catalyst system, polymerization process and polymer therefrom
SE9804407D0 (sv) * 1998-12-18 1998-12-18 Borealis Polymers Oy A multimodal polymer composition
WO2000039170A1 (en) * 1998-12-30 2000-07-06 Union Carbide Chemicals & Plastics Technology Corporation Compositions of preactivated unsupported catalyst having a given concentration and methods of using them
EP1041113A1 (en) * 1999-03-30 2000-10-04 Fina Research S.A. Polyolefins and uses thereof
US6339134B1 (en) 1999-05-06 2002-01-15 Univation Technologies, Llc Polymerization process for producing easier processing polymers
US6218472B1 (en) * 1999-09-24 2001-04-17 Fina Research, S.A. Production of multimodal polyethylene
DE19945980A1 (de) * 1999-09-24 2001-03-29 Elenac Gmbh Polyethylen Formmasse mit verbesserter ESCR-Steifigkeitsrelation und Schwellrate, Verfahren zu ihrer Herstellung und daraus hergestellte Hohlkörper
US6274684B1 (en) 1999-10-22 2001-08-14 Univation Technologies, Llc Catalyst composition, method of polymerization, and polymer therefrom
US6420580B1 (en) 1999-11-05 2002-07-16 Univation Technologies, Llc Catalyst compositions and method of polymerization therewith
US6340730B1 (en) 1999-12-06 2002-01-22 Univation Technologies, Llc Multiple catalyst system
US6281306B1 (en) * 1999-12-16 2001-08-28 Univation Technologies, Llc Method of polymerization
US6359072B1 (en) 2000-02-16 2002-03-19 Univation Technologies, Llc Polyethylene films having improved optical properties
US6388017B1 (en) 2000-05-24 2002-05-14 Phillips Petroleum Company Process for producing a polymer composition
US6403717B1 (en) 2000-07-12 2002-06-11 Univation Technologies, Llc Ethylene inter-polymer blends
US6525148B1 (en) * 2000-08-18 2003-02-25 Phillips Petroleum Company Polymerization catalyst systems and processes therefor and therewith
US6605675B2 (en) * 2000-12-04 2003-08-12 Univation Technologies, Llc Polymerization process
US6608149B2 (en) * 2000-12-04 2003-08-19 Univation Technologies, Llc Polymerization process
AU1790702A (en) * 2000-12-04 2002-06-18 Univaton Technologies Llc Polimerization process
US6613841B2 (en) * 2002-01-28 2003-09-02 Equistar Chemicals, Lp Preparation of machine direction oriented polyethylene films
EP1405866A1 (en) * 2002-09-27 2004-04-07 ATOFINA Research Polyolefin production
US7288596B2 (en) * 2003-12-22 2007-10-30 Univation Technologies, Llc Polyethylene compositions having improved tear properties

Also Published As

Publication number Publication date
US7288596B2 (en) 2007-10-30
AR045846A1 (es) 2005-11-16
CA2546629A1 (en) 2005-07-28
RU2349613C2 (ru) 2009-03-20
EP1697044B1 (en) 2011-10-12
CN1894038A (zh) 2007-01-10
JP2007515540A (ja) 2007-06-14
WO2005068076A1 (en) 2005-07-28
BRPI0417926B1 (pt) 2016-09-20
RU2006126543A (ru) 2008-01-27
TW200521178A (en) 2005-07-01
ATE528072T1 (de) 2011-10-15
US7560516B2 (en) 2009-07-14
US20050137337A1 (en) 2005-06-23
EP1697044A1 (en) 2006-09-06
CN100464854C (zh) 2009-03-04
US20080045647A1 (en) 2008-02-21
KR20060123360A (ko) 2006-12-01
EP1697044A4 (en) 2008-06-25

Similar Documents

Publication Publication Date Title
BRPI0417926A (pt) composições de polietileno tendo propriedades de rasgamento melhoradas
BR0109295A (pt) Pelìcula em múltiplas camadas
BR0114756A (pt) Composição elastomérica
BR0207073A (pt) Composições poliolefìnicas resistentes a impacto
BR0108450A (pt) Pelìculas de polietileno tendo propriedades óticas melhoradas
BR0316920A (pt) Composição de polietileno, e, processo para a produção e uso da mesma
BR0317322A (pt) Composição de moldagem de polietileno, e, processo para a produção e uso da mesma
BR0114560A (pt) Mesclas e filmes de polietileno
BR0115946A (pt) Composições de resina de polipropileno
BR0007075A (pt) Composições de poliolefina resistentes a impactos
BR9807528A (pt) Composições farmacêuticas isentas de óleo contendo ciclosporina a
BRPI0819573A8 (pt) Composição e artigo
BR0205962A (pt) Composição de resina de polietileno
BRPI0417169A (pt) composições de polietileno de alta resistência e baixa névoa
BR0317320A (pt) Composição de polietileno com distribuição de massa molecular multimodal, processo e uso para a produção da mesma
BR0111433A (pt) Composição de borracha e método para aumentar valor mooney scorch de composição de borracha
BRPI0417945A (pt) composições de resina de camada de selamento
BR9713799A (pt) Composição, artigo moldado, e, processo para preparar um polìmero de alta i.v.
BR9814729A (pt) Método e composição de uma preparação oral de itraconazol
BR0304880A (pt) Homopolìmeros ou copolìmeros de buteno-1 e processo para a sua preparação
BR9908805A (pt) Composições termoplásticas de misturas de materiais poliméricos com termoplásticos de engenharia
BR9908537A (pt) Copolìmeros biocompatìveis e utilização dos mesmos
BR9713707A (pt) Pelìcula estirável fundida e composição de interpolìmero
BRPI0511966A (pt) composições farmacêuticas contendo polietileno glicol tendo um peso molecular menor do que 600 daltons
BR0214577A (pt) Copolìmero de etileno/alfa-olefina feito com uma combinação de um catalisador de sìtio-único/sìtio-não-único, sua preparação e uso

Legal Events

Date Code Title Description
B25A Requested transfer of rights approved

Owner name: DOW GLOBAL TECHNOLOGIES LLC (US)

B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 20/09/2016, OBSERVADAS AS CONDICOES LEGAIS.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE A 15A ANUIDADE.

B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2510 DE 12-02-2019 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.