BRPI0505212A - aperfeiçoamentos em processo de hidrólise ácida rápida de material lignocelulósico e em reator de hidrólise - Google Patents

aperfeiçoamentos em processo de hidrólise ácida rápida de material lignocelulósico e em reator de hidrólise

Info

Publication number
BRPI0505212A
BRPI0505212A BRPI0505212-2A BRPI0505212A BRPI0505212A BR PI0505212 A BRPI0505212 A BR PI0505212A BR PI0505212 A BRPI0505212 A BR PI0505212A BR PI0505212 A BRPI0505212 A BR PI0505212A
Authority
BR
Brazil
Prior art keywords
reactor
hydrolysis
liquid phase
levels
lignocellulosic material
Prior art date
Application number
BRPI0505212-2A
Other languages
English (en)
Inventor
Antonio Geraldo Proenca Hilst
Original Assignee
Dedini Sa Ind De Base
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dedini Sa Ind De Base filed Critical Dedini Sa Ind De Base
Priority to BRPI0505212-2A priority Critical patent/BRPI0505212A/pt
Priority to ARP060104735A priority patent/AR057564A1/es
Priority to AU2006308733A priority patent/AU2006308733B2/en
Priority to US11/916,617 priority patent/US7988788B2/en
Priority to EP06804597A priority patent/EP1945823B1/en
Priority to RU2008117424/13A priority patent/RU2008117424A/ru
Priority to PCT/BR2006/000239 priority patent/WO2007051269A1/en
Priority to CA002613745A priority patent/CA2613745A1/en
Priority to ZA200711049A priority patent/ZA200711049B/xx
Priority to DE602006007374T priority patent/DE602006007374D1/de
Priority to CN2006800261306A priority patent/CN101223288B/zh
Priority to MX2008005647A priority patent/MX2008005647A/es
Publication of BRPI0505212A publication Critical patent/BRPI0505212A/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C13SUGAR INDUSTRY
    • C13KSACCHARIDES OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DISACCHARIDES, OLIGOSACCHARIDES OR POLYSACCHARIDES
    • C13K1/00Glucose; Glucose-containing syrups
    • C13K1/02Glucose; Glucose-containing syrups obtained by saccharification of cellulosic materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08HDERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
    • C08H8/00Macromolecular compounds derived from lignocellulosic materials
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C3/00Pulping cellulose-containing materials
    • D21C3/04Pulping cellulose-containing materials with acids, acid salts or acid anhydrides
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C11/00Regeneration of pulp liquors or effluent waste waters
    • D21C11/0007Recovery of by-products, i.e. compounds other than those necessary for pulping, for multiple uses or not otherwise provided for
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C3/00Pulping cellulose-containing materials
    • D21C3/20Pulping cellulose-containing materials with organic solvents or in solvent environment
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C7/00Digesters
    • D21C7/14Means for circulating the lye

Landscapes

  • Chemical & Material Sciences (AREA)
  • Biochemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • General Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Emergency Medicine (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
  • Compounds Of Unknown Constitution (AREA)
  • Processing Of Solid Wastes (AREA)
  • Furan Compounds (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

APERFEIçOAMENTOS EM PROCESSO DE HIDRóLISE áCIDA RáPIDA DE MATERIAL LIGNOCELULóSICO E EM REATOR DE HIDRóLISE, dito material lignocelulósico sendo alimentado em diferentes níveis de um reator (10) e contactado com fluxos de solvente orgânico de lignina, água e uma solução extremamente diluída de um ácido inogârnico forte, para obter uma fase líquida de extrato de hidrólise e uma fase sólida de material não reagido e não dissolvido. Um fluxo controlado de vapor é injetado nos diferentes níveis do reator, de modo a prover temperaturas adequadas de solvente orgânico e de ácido inorgânico forte e a formar os produtos (açúcares) desejados. Um fluxo da fase líquida é recirculado em diferentes níveis do reator. O remanescente da fase liquida é retirado do reator, resfriado bruscamente e submetido à evaporação do solvente para obter um concentrado dos produtos de reação, sendo a lignina transferida por decantação e sendo o concentrado transferido a etapas processuais subseqüentes.
BRPI0505212-2A 2005-11-01 2005-11-01 aperfeiçoamentos em processo de hidrólise ácida rápida de material lignocelulósico e em reator de hidrólise BRPI0505212A (pt)

Priority Applications (12)

Application Number Priority Date Filing Date Title
BRPI0505212-2A BRPI0505212A (pt) 2005-11-01 2005-11-01 aperfeiçoamentos em processo de hidrólise ácida rápida de material lignocelulósico e em reator de hidrólise
ARP060104735A AR057564A1 (es) 2005-11-01 2006-10-30 Proceso de hidrolisis acida rapida de material lignocelulosico y un reactor de hidrolisis
AU2006308733A AU2006308733B2 (en) 2005-11-01 2006-10-31 Improvements in a process for rapid acid hydrolysis of lignocellulosic material and in a hydrolysis reactor
US11/916,617 US7988788B2 (en) 2005-11-01 2006-10-31 Process for rapid acid hydrolysis of lignocellulosic material and in a hydrolysis reactor
EP06804597A EP1945823B1 (en) 2005-11-01 2006-10-31 Improvements in a process for rapid acid hydrolysis of lignocellulosic material and in a hydrolysis reactor
RU2008117424/13A RU2008117424A (ru) 2005-11-01 2006-10-31 Усовершенствования способа быстрого кислотного гидролиза лигноцеллюлозного материала и реактора гидролиза
PCT/BR2006/000239 WO2007051269A1 (en) 2005-11-01 2006-10-31 Improvements in a process for rapid acid hydrolysis of lignocellulosic material and in a hydrolysis reactor
CA002613745A CA2613745A1 (en) 2005-11-01 2006-10-31 Improvements in a process for rapid acid hydrolysis of lignocellulosic material and in a hydrolysis reactor
ZA200711049A ZA200711049B (en) 2005-11-01 2006-10-31 Improvements in a process for rapid acid hydrolysis of lignocellulosic material and in a hydrolysis reactor
DE602006007374T DE602006007374D1 (de) 2005-11-01 2006-10-31 Verbesserung bei einem verfahren zur schnellen sauren hydrolyse von lignocellulosematerial und bei einem hydrolysereaktor
CN2006800261306A CN101223288B (zh) 2005-11-01 2006-10-31 改进的对木质纤维素材料快速酸水解的方法和水解反应器
MX2008005647A MX2008005647A (es) 2005-11-01 2006-10-31 Mejoras en un procedimiento para hidrolisis acida rapida de material lignocelulosico y en un reactor de hidrolisis.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
BRPI0505212-2A BRPI0505212A (pt) 2005-11-01 2005-11-01 aperfeiçoamentos em processo de hidrólise ácida rápida de material lignocelulósico e em reator de hidrólise

Publications (1)

Publication Number Publication Date
BRPI0505212A true BRPI0505212A (pt) 2007-08-07

Family

ID=37696763

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0505212-2A BRPI0505212A (pt) 2005-11-01 2005-11-01 aperfeiçoamentos em processo de hidrólise ácida rápida de material lignocelulósico e em reator de hidrólise

Country Status (12)

Country Link
US (1) US7988788B2 (pt)
EP (1) EP1945823B1 (pt)
CN (1) CN101223288B (pt)
AR (1) AR057564A1 (pt)
AU (1) AU2006308733B2 (pt)
BR (1) BRPI0505212A (pt)
CA (1) CA2613745A1 (pt)
DE (1) DE602006007374D1 (pt)
MX (1) MX2008005647A (pt)
RU (1) RU2008117424A (pt)
WO (1) WO2007051269A1 (pt)
ZA (1) ZA200711049B (pt)

Families Citing this family (62)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2479341A1 (en) 2006-05-08 2012-07-25 Vertichem Corporation Process for the production of biofuel from plant material
US9260818B2 (en) 2007-05-23 2016-02-16 Andritz Inc. Single vessel reactor system for hydrolysis and digestion of wood chips with chemical enhanced wash method
US8734610B2 (en) * 2007-05-23 2014-05-27 Andritz Inc. Two vessel reactor system and method for hydrolysis and digestion of wood chips with chemical enhanced wash method
CN101121735B (zh) * 2007-07-06 2011-04-06 陈培豪 植物纤维原料水解液及利用该水解液预处理植物纤维原料的方法
ATE503027T1 (de) * 2007-07-25 2011-04-15 Haarslev As Verfahren und system zur vorbehandlung von lignocellulosischem material
AU2008293139A1 (en) 2007-08-31 2009-03-05 Vertichem Corporation Lignin and other products isolated from plant material, and methods and compositions therefor
US8057639B2 (en) * 2008-02-28 2011-11-15 Andritz Inc. System and method for preextraction of hemicellulose through using a continuous prehydrolysis and steam explosion pretreatment process
WO2009124240A1 (en) * 2008-04-03 2009-10-08 Cellulose Sciences International, Inc. Highly disordered cellulose
US20090308383A1 (en) 2008-06-10 2009-12-17 Andritz Inc. Apparatus and method for hydrolysis of cellulosic material in a multi-step process to produce c5 and c6 sugars using a single vessel
US8192549B2 (en) 2008-06-10 2012-06-05 Andritz Inc. Apparatus and method for hydrolysis of cellulosic material in a two-step process
GB0819406D0 (en) 2008-10-22 2008-11-26 Weyland As Process
US8353989B2 (en) 2008-11-10 2013-01-15 Andritz Inc. Apparatus and method for treating, pressing and washing biomass
US8216809B2 (en) 2008-12-19 2012-07-10 E I Du Pont De Nemours And Company Organic solvent pretreatment of biomass to enhance enzymatic saccharification
CA2742681A1 (en) * 2008-12-19 2010-07-15 E. I. Du Pont De Nemours And Company Organic solvent pretreatment of biomass to enhance enzymatic saccharification
US8278070B2 (en) 2008-12-19 2012-10-02 E I Du Pont De Nemours And Company Organic solvent pretreatment of biomass to enhance enzymatic saccharification
US8241873B2 (en) * 2008-12-19 2012-08-14 E I Du Pont De Nemours And Company Organic solvent pretreatment of biomass to enhance enzymatic saccharification
US8304213B2 (en) 2008-12-19 2012-11-06 E I Du Pont De Nemours And Company Organic solvent pretreatment of biomass to enhance enzymatic saccharification
US20120329116A1 (en) * 2009-04-20 2012-12-27 Greenfield Ethanol Inc. Pretreatment of lignocellulosic biomass through removal of inhibitory compounds
ES2499490T3 (es) * 2009-04-20 2014-09-29 Greenfield Ethanol Inc. Pretratamiento de biomasa lignocelulósica para eliminación de compuestos inhibidores
GB0907879D0 (en) 2009-05-07 2009-06-24 Weyland As Process
US8636402B2 (en) * 2009-05-20 2014-01-28 Xyleco, Inc. Processing biomass
WO2010135377A1 (en) 2009-05-20 2010-11-25 Xyleco, Inc. Bioprocessing
SI2432865T1 (en) * 2009-05-20 2018-07-31 Xyleco, Inc. Treatment of biomass
BRPI1012286A2 (pt) * 2009-05-28 2015-09-22 Lignol Innovations Ltd derivados de lignina nativa de matérias-primas de fibras de plantas anuais
US8597431B2 (en) 2009-10-05 2013-12-03 Andritz (Usa) Inc. Biomass pretreatment
EP2513080B1 (en) 2009-12-16 2015-07-29 Shell Internationale Research Maatschappij B.V. Method for producing furfural from lignocellulosic biomass material
MY181812A (en) 2010-01-20 2021-01-07 Xyleco Inc Dispersing feedstocks and processing materials
US8691526B2 (en) * 2010-01-20 2014-04-08 Xyleco, Inc. Processing materials
WO2011151823A1 (en) * 2010-06-03 2011-12-08 Hcl Cleantech Ltd. Lignin compositions, systems and methods for processing lignin and/or hcl
BR112012032999B1 (pt) 2010-06-26 2022-11-29 Virdia, Llc Hidrolisado lignocelulósico e métodos de hidrólise ácida e desacidificação para gerar misturas de açúcar a partir de lignocelulose
IL206678A0 (en) 2010-06-28 2010-12-30 Hcl Cleantech Ltd A method for the production of fermentable sugars
IL207329A0 (en) 2010-08-01 2010-12-30 Robert Jansen A method for refining a recycle extractant and for processing a lignocellulosic material and for the production of a carbohydrate composition
IL207945A0 (en) 2010-09-02 2010-12-30 Robert Jansen Method for the production of carbohydrates
WO2012027822A1 (en) * 2010-09-03 2012-03-08 Greg Naterer Thermochemical reactors and processes for hydrolysis of cupric chloride
RU2013117010A (ru) 2010-09-14 2014-10-20 Сельюлоуз Сайенсиз Интернэшнл, Инк. Нано-дезагрегированная целлюлоза
PT106039A (pt) 2010-12-09 2012-10-26 Hcl Cleantech Ltd Processos e sistemas para o processamento de materiais lenhocelulósicos e composições relacionadas
DK2675907T3 (en) 2011-02-14 2018-01-08 Xyleco Inc PAPER RAW MATERIALS PROCESSING
GB2524906B8 (en) 2011-04-07 2016-12-07 Virdia Ltd Lignocellulose conversion processes and products
ES2606611T3 (es) * 2011-07-15 2017-03-24 Greenfield Specialty Alcohols Inc. Acondicionamiento de biomasa para la liberación mejorada de azúcares C5/C6 antes de la fermentación
US9228243B2 (en) * 2011-08-24 2016-01-05 Red Shield Acquistion, LLC System and method for conditioning a hardwood pulp liquid hydrolysate
US9617608B2 (en) 2011-10-10 2017-04-11 Virdia, Inc. Sugar compositions
GB2496001A (en) * 2011-10-24 2013-05-01 Virdia Ltd Hydrolysis systems and methods
EP2862890A1 (en) 2012-05-03 2015-04-22 Virdia Ltd. Method for the extraction of lignin from biomass
US9493851B2 (en) 2012-05-03 2016-11-15 Virdia, Inc. Methods for treating lignocellulosic materials
CN102816877A (zh) * 2012-08-29 2012-12-12 上海交通大学 一种纤维素类生物质水热糖化方法及装置
US9657146B2 (en) 2013-03-14 2017-05-23 Virdia, Inc. Methods for treating lignocellulosic materials
US9255187B2 (en) * 2013-03-15 2016-02-09 Synergy Horizon Limited Method for production of dry hydrolytic lignin
KR20160007537A (ko) 2013-05-03 2016-01-20 버디아, 인크. 열안정성 리그닌 분획물의 제조 방법
BR112015027744B1 (pt) 2013-05-03 2022-05-24 Virdia, Llc Composição de lignina e produto compreendendo a dita composição
FI3137553T3 (fi) 2014-05-01 2025-02-11 Renmatix Inc Ligniinin jalostaminen ligniinipitoisista jäännöksistä reaktiivisen uuton avulla
CN109851814B (zh) 2014-07-09 2022-03-11 威尔迪亚有限责任公司 用于从黑液中分离和精制木质素的方法及其组合物
US11078548B2 (en) 2015-01-07 2021-08-03 Virdia, Llc Method for producing xylitol by fermentation
CN107849620B (zh) 2015-05-27 2022-01-11 威尔迪亚有限责任公司 用于处理木质纤维素材料的综合方法
WO2019067526A1 (en) 2017-09-26 2019-04-04 Poet Research, Inc. SYSTEMS AND METHODS FOR TREATING LIGNOCELLULOSIC BIOMASS
WO2020112701A1 (en) 2018-11-26 2020-06-04 Board Of Trustees Of Michigan State University Methods for cellulose hydrolysis using sulfonated polyaromatic catalysts
SE1950386A1 (en) * 2019-03-29 2020-09-22 Valmet Oy A method and a system for extracting hydrolyzate in a continuous cooking process for producing pulp
CN110541320B (zh) * 2019-09-12 2021-12-17 武汉轻工大学 从木质纤维素原料中分离木质素和纤维素的方法
CN113304671B (zh) * 2021-05-28 2022-02-01 江西海尔思药业股份有限公司 一种含乳果糖的口服溶液制备用装置及其使用方法
LU102852B1 (en) * 2021-08-02 2023-02-02 Technische Univ Hamburg Process for continuous extraction of lignocellulosic material
JP2024528940A (ja) * 2021-08-02 2024-08-01 ムシュラブス ゲゼルシャフト ミット ベシュレンクテル ハフツング リグノセルロース系材料の連続抽出方法
CN114029022B (zh) * 2021-12-01 2023-05-16 合肥智慧环境研究院 一种木质素分离系统及其方法
CA3243740A1 (en) 2022-02-24 2023-08-31 Mushlabs Gmbh PRODUCTION OF A COLORED MYCELIUM

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AR227462A1 (es) * 1981-03-26 1982-10-29 Thermoform Bau Forschung Procedimiento mejorado para la produccion de hidrolizados de carbohidratos a partir de material celulosico triturado
CA1225636A (en) * 1984-07-13 1987-08-18 Robert P. Chang Method for continuous countercurrent organosolv saccharification of wood and other lignocellulosic materials
BR9600672A (pt) * 1996-03-08 1997-12-30 Dedini S A Administracao E Par Processo de hidrólise ácido de material lignocelulósico e reator de hidrólise

Also Published As

Publication number Publication date
EP1945823B1 (en) 2009-06-17
MX2008005647A (es) 2008-10-03
CN101223288A (zh) 2008-07-16
EP1945823A1 (en) 2008-07-23
CA2613745A1 (en) 2007-05-10
CN101223288B (zh) 2011-12-14
WO2007051269A1 (en) 2007-05-10
AR057564A1 (es) 2007-12-05
US20080202504A1 (en) 2008-08-28
US7988788B2 (en) 2011-08-02
ZA200711049B (en) 2009-04-29
RU2008117424A (ru) 2009-11-20
DE602006007374D1 (de) 2009-07-30
AU2006308733A1 (en) 2007-05-10
AU2006308733B2 (en) 2011-02-03

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B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]

Free format text: REFERENTE A 10A ANUIDADE.

B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: EM VIRTUDE DO ARQUIVAMENTO PUBLICADO NA RPI 2331 DE 08-09-2015 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDO O ARQUIVAMENTO DO PEDIDO DE PATENTE, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.