BRPI0506581A - processo para preparar adipodinitrila e metilglutaronitrila - Google Patents

processo para preparar adipodinitrila e metilglutaronitrila

Info

Publication number
BRPI0506581A
BRPI0506581A BRPI0506581-0A BRPI0506581A BRPI0506581A BR PI0506581 A BRPI0506581 A BR PI0506581A BR PI0506581 A BRPI0506581 A BR PI0506581A BR PI0506581 A BRPI0506581 A BR PI0506581A
Authority
BR
Brazil
Prior art keywords
stream
product stream
adipodinitrile
catalyst
promoter
Prior art date
Application number
BRPI0506581-0A
Other languages
English (en)
Inventor
Tim Jungkamp
Robert Baumann
Michael Bartsch
Gerd Haderlein
Hermann Luyken
Jens Scheidel
Original Assignee
Basf Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=34801260&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=BRPI0506581(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Basf Ag filed Critical Basf Ag
Publication of BRPI0506581A publication Critical patent/BRPI0506581A/pt
Publication of BRPI0506581B1 publication Critical patent/BRPI0506581B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/08—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds
    • C07C253/10—Preparation of carboxylic acid nitriles by addition of hydrogen cyanide or salts thereof to unsaturated compounds to compounds containing carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
    • C07C255/02—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms of an acyclic and saturated carbon skeleton
    • C07C255/04—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms of an acyclic and saturated carbon skeleton containing two cyano groups bound to the carbon skeleton

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Extraction Or Liquid Replacement (AREA)
  • Catalysts (AREA)

Abstract

"PROCESSO PARA PREPARAR ADIPODINITRILA E METILGLUTARONITRILA". A invenção diz respeito a um método para produzir adipodinitrila e metilglutar nitrila, o dito método sendo caracterizado pelas etapas seguintes: (a) um fluxo de extrato contendo pentenonitrilas é reagido com cianeto de hidrogênio na presença de pelo menos um catalisador e pelo menos um promotor para se obter um fluxo de reação contendo pentenonitrilas, o pelo menos um catalisador, produtos de decomposição de catalisador, o pelo menos um promotor, adipodinitrila e metilglutar nitrila; (b) o fluxo de reação é destilado para se obter um fluxo de produto de fundo (3) que é suprimido de pentenonitrilas e contém o pelo menos um catalisador, produtos de decomposição de catalisador, o pelo menos um promotor, adipodinitrila e metilglutar nitrila, e um fluxo de produto de topo (4) enriquecido em pentenonitrilas; (c) o fluxo (3) é extraído por um meio de extração contido no fluxo (5) para se obter um fluxo de produto de topo (6) que é enriquecido com meios de extração e contém o catalisador, e um fluxo de produto de fundo (7) que é suprimido de meios de extração e contém produtos de decomposição de catalisador, o pelo menos um promotor, pentenonitrilas, adipodinitrila e metilglutar nitrila; (d) o fluxo (6) é destilado para se obter um fluxo de produto de fundo (8) contendo o catalisador, e um fluxo de produto de topo (9) contendo os meios de extração; (e) o fluxo (7) é destilado para se obter um fluxo de produto de fundo (10) contendo produtos de decomposição de catalisador, o pelo menos um promotor, penteno nitrilas, adipodinitrila e metilglutamitrila, e um fluxo de produto de topo (11) contendo os meios de extração; (f) o fluxo (10) é destilado para se obter um fluxo de produto de fundo (12) contendo produtos de decomposição de catalisador, o pelo menos um promotor, pentenonitrilas, adipodinitrila e metilglutamitrila, e um fluxo de produto de topo (13) contendo pentenonitrilas; (g) o fluxo (12) é destilado para se obter um fluxo de produto de fundo (14) contendo produtos de decomposição de catalisador e o pelo menos um promotor, e um fluxo de produto de topo (15) contendo adipodinitrila e metilglutar nitrila; e (h) o fluxo (15) é destilado para se obter um fluxo de produto de fundo (16) contendo adipodinitrila, e um fluxo de produto de topo (17) contendo metilglutarnitrila.
BRPI0506581-0A 2004-01-29 2005-01-27 Processo para preparar adipodinitrila e metilglutaronitrila BRPI0506581B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102004004683A DE102004004683A1 (de) 2004-01-29 2004-01-29 Verfahren zur Herstellung von Dinitrilen
DE102004004683.2 2004-01-29
PCT/EP2005/000777 WO2005073172A1 (de) 2004-01-29 2005-01-27 Verfahren zur herstellung von dinitrilen

Publications (2)

Publication Number Publication Date
BRPI0506581A true BRPI0506581A (pt) 2007-04-10
BRPI0506581B1 BRPI0506581B1 (pt) 2014-10-29

Family

ID=34801260

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0506581-0A BRPI0506581B1 (pt) 2004-01-29 2005-01-27 Processo para preparar adipodinitrila e metilglutaronitrila

Country Status (15)

Country Link
US (1) US7816551B2 (pt)
EP (1) EP1713760B2 (pt)
JP (1) JP4386922B2 (pt)
KR (1) KR101143755B1 (pt)
CN (1) CN100475779C (pt)
AR (1) AR048150A1 (pt)
AT (1) ATE399761T1 (pt)
BR (1) BRPI0506581B1 (pt)
CA (1) CA2553028A1 (pt)
DE (2) DE102004004683A1 (pt)
ES (1) ES2308428T3 (pt)
MY (1) MY138391A (pt)
PL (1) PL1713760T3 (pt)
TW (1) TW200604146A (pt)
WO (1) WO2005073172A1 (pt)

Families Citing this family (44)

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FR2850966B1 (fr) 2003-02-10 2005-03-18 Rhodia Polyamide Intermediates Procede de fabrication de composes dinitriles
FR2854891B1 (fr) 2003-05-12 2006-07-07 Rhodia Polyamide Intermediates Procede de preparation de dinitriles
DE102004004682A1 (de) 2004-01-29 2005-08-18 Basf Ag Verfahren zur Herstellung von Adipodinitril durch Hydrocyanierung von 1,3-Butadien
DE102004050935A1 (de) 2004-10-18 2006-04-20 Basf Ag Extraktion von Nickel(0)-Komplexen aus Nitrilgemischen mit verminderter Mulmbildung
FR2878848B1 (fr) * 2004-12-07 2007-01-05 Rhodia Chimie Sa Procede de fabrication de composes dinitriles
US7973174B2 (en) 2005-10-18 2011-07-05 Invista North America S.A.R.L. Process of making 3-aminopentanenitrile
FR2898356B1 (fr) * 2006-03-07 2008-12-05 Rhodia Recherches & Tech Diesters d'acides carboxylique ramifies
WO2007109005A2 (en) * 2006-03-17 2007-09-27 Invista Technologies S.A R.L. Method for the purification of triorganophosphites by treatment with a basic additive
US7709674B2 (en) * 2006-07-14 2010-05-04 Invista North America S.A R.L Hydrocyanation process with reduced yield losses
US7919646B2 (en) 2006-07-14 2011-04-05 Invista North America S.A R.L. Hydrocyanation of 2-pentenenitrile
US7880028B2 (en) 2006-07-14 2011-02-01 Invista North America S.A R.L. Process for making 3-pentenenitrile by hydrocyanation of butadiene
WO2008028843A1 (de) * 2006-09-04 2008-03-13 Basf Aktiengesellschaft Verfahren zur herstellung von dinitrilen
FR2909088B1 (fr) * 2006-11-24 2009-02-13 Rhodia Recherches & Tech Procede de transformation de composes nitriles en acides carboxyliques et esters correspondants
WO2008074645A1 (de) * 2006-12-20 2008-06-26 Basf Se Verfahren zur herstellung von 2-methylpentan-1,5-diisocyanat aus methylglutarsäuredinitril
CN101687658B (zh) 2007-05-14 2013-07-24 因温斯特技术公司 高效反应器和方法
WO2008157218A1 (en) 2007-06-13 2008-12-24 Invista Technologies S.A.R.L. Process for improving adiponitrile quality
JP2011505490A (ja) 2007-12-03 2011-02-24 ジーヴォ，インコーポレイテッド 再生可能組成物
US7977502B2 (en) 2008-01-15 2011-07-12 Invista North America S.A R.L. Process for making and refining 3-pentenenitrile, and for refining 2-methyl-3-butenenitrile
WO2009091790A1 (en) * 2008-01-15 2009-07-23 Invista Technologies S.A.R.L. Hydrocyanation of pentenenitriles
EP2257516A4 (en) * 2008-03-19 2012-12-12 Invista Tech Sarl METHODS FOR PREPARING CYCLODODECATRIENE AND METHODS FOR PREPARING LAUROLACTONE
EP2334624B1 (en) 2008-10-14 2014-10-01 Invista Technologies S.à.r.l. Process for making 2-secondary-alkyl-4,5-di-(normal-alkyl)phenols
CN102471218B (zh) 2009-08-07 2014-11-05 因温斯特技术公司 用于形成二酯的氢化并酯化
CN102770397A (zh) 2010-01-08 2012-11-07 格沃股份有限公司 制备可再生的化学品的整合方法
US8530690B2 (en) 2010-04-07 2013-09-10 Basf Se Process for isomerizing CIS-2-pentenenitrile to 3-pentenenitriles
WO2011124610A1 (de) 2010-04-07 2011-10-13 Basf Se Verfahren zur isomerisierung von cis-2-pentennitril zu 3-pentennitrilen
US8373012B2 (en) 2010-05-07 2013-02-12 Gevo, Inc. Renewable jet fuel blendstock from isobutanol
WO2012005918A1 (en) * 2010-07-07 2012-01-12 Invista Technologies S.A.R.L. Process for making nitriles
WO2012145495A2 (en) 2011-04-19 2012-10-26 Gevo, Inc. Variations on prins-like chemistry to produce 2,5-dimethylhexadiene from isobutanol
JP2014530221A (ja) * 2011-10-07 2014-11-17 インヴィスタテクノロジーズ エスアエルエル ニトリルの作製方法
EP2794048B1 (en) 2011-12-21 2022-01-05 INVISTA Textiles (U.K.) Limited Extraction solvent control for reducing stable emulsions
CN104039412B (zh) 2011-12-21 2016-08-24 因温斯特技术公司 用于减少稳定乳液的萃取溶剂控制
KR20140127218A (ko) 2011-12-21 2014-11-03 인비스타 테크놀러지스 에스.에이 알.엘. 안정한 에멀젼을 감소시키기 위한 추출 용매 제어
US8772527B2 (en) 2012-04-27 2014-07-08 Basf Se Process for isomerization of cis-2-pentenenitrile to 3-pentenenitriles
EP2657224A1 (de) 2012-04-27 2013-10-30 Basf Se Verfahren zur Isomerisierung von cis-2-Pentennitril zu 3-Pentennitril
US9896397B2 (en) * 2012-06-29 2018-02-20 Mitsubishi Gas Chemical Company, Inc. Method and apparatus for separating alkyl aromatic hydrocarbon
WO2014210191A1 (en) * 2013-06-26 2014-12-31 Invista Technologies S.A R.L. Improved process for refining nitriles
WO2015009847A1 (en) 2013-07-17 2015-01-22 Invista Technologies S.À R.L. Separating a solvent from a nickel catalyst by distillation
CN103521158B (zh) * 2013-10-29 2015-12-02 万华化学集团股份有限公司 一种连续化制备丁二腈的方法
EP2998290A1 (de) * 2014-09-16 2016-03-23 Basf Se Verfahren zur kontinuierlichen Herstellung von Adipodinitril
CN105481720A (zh) * 2015-12-04 2016-04-13 中国天辰工程有限公司 一种戊烯腈氢氰化制己二腈工艺萃取剂回收工艺及系统
CN109071421B (zh) 2016-05-02 2022-02-25 英威达纺织（英国）有限公司 减少二腈流中的cpi的方法
CN111995547B (zh) 2020-01-19 2021-07-09 浙江新和成股份有限公司 己二腈的制备方法和装置
EP4097077A1 (en) * 2020-01-31 2022-12-07 INVISTA Textiles (U.K.) Limited Impurity formation reduction during product refining
KR102803733B1 (ko) * 2020-10-28 2025-05-02 주식회사 엘지화학 아크릴로니트릴 이량체의 제조 방법

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NL6504268A (pt) * 1965-04-03 1966-10-04
US3496215A (en) * 1965-11-23 1970-02-17 Du Pont Hydrocyanation of olefins using selected nickel phosphite catalysts
US3564040A (en) 1968-06-14 1971-02-16 Du Pont Removal of trans-2-pentenenitrile from 3- and 4-pentenenitrile
US3752839A (en) * 1970-07-02 1973-08-14 Du Pont Hydrocyanation olefins
US3766241A (en) 1971-05-26 1973-10-16 Du Pont Removal of metal cations from solution in nitriles
US3773809A (en) * 1972-06-28 1973-11-20 Du Pont Separation of organic phosphorus compounds and their metal complexes from organic nitriles in the hydrocyanation of olefins
US3852327A (en) * 1973-08-29 1974-12-03 Du Pont Selective cis/trans isomerization of 2-pentenenitrile in a solution of pentenenitrile isomers
US3852325A (en) * 1973-08-29 1974-12-03 Du Pont Selective isomerization of pentenenitriles
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Also Published As

Publication number Publication date
EP1713760B1 (de) 2008-07-02
TW200604146A (en) 2006-02-01
WO2005073172A1 (de) 2005-08-11
ES2308428T3 (es) 2008-12-01
CA2553028A1 (en) 2005-08-11
CN1914162A (zh) 2007-02-14
CN100475779C (zh) 2009-04-08
PL1713760T3 (pl) 2008-12-31
ATE399761T1 (de) 2008-07-15
AR048150A1 (es) 2006-04-05
US20070155978A1 (en) 2007-07-05
KR20070011284A (ko) 2007-01-24
EP1713760B2 (de) 2019-03-20
DE502005004577D1 (de) 2008-08-14
DE102004004683A1 (de) 2005-08-18
JP2007519673A (ja) 2007-07-19
EP1713760A1 (de) 2006-10-25
KR101143755B1 (ko) 2012-05-11
BRPI0506581B1 (pt) 2014-10-29
JP4386922B2 (ja) 2009-12-16
MY138391A (en) 2009-05-29
US7816551B2 (en) 2010-10-19

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Legal Events

Date Code Title Description
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 27/01/2005, OBSERVADAS AS CONDICOES LEGAIS.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time
B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)