BRPI0508539A - processo de oxidação com geração in-situ de h2o2 e catalisadores encapsulados em polìmero para o mesmo - Google Patents

processo de oxidação com geração in-situ de h2o2 e catalisadores encapsulados em polìmero para o mesmo

Info

Publication number
BRPI0508539A
BRPI0508539A BRPI0508539-0A BRPI0508539A BRPI0508539A BR PI0508539 A BRPI0508539 A BR PI0508539A BR PI0508539 A BRPI0508539 A BR PI0508539A BR PI0508539 A BRPI0508539 A BR PI0508539A
Authority
BR
Brazil
Prior art keywords
catalysts
transition metal
oxidation process
situ generation
polymer
Prior art date
Application number
BRPI0508539-0A
Other languages
English (en)
Inventor
Roger A Grey
Bi Le-Khac
Original Assignee
Lyondell Chemical Tech Lp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lyondell Chemical Tech Lp filed Critical Lyondell Chemical Tech Lp
Publication of BRPI0508539A publication Critical patent/BRPI0508539A/pt

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
    • B01J13/02—Making microcapsules or microballoons
    • B01J13/06—Making microcapsules or microballoons by phase separation
    • B01J13/08—Simple coacervation, i.e. addition of highly hydrophilic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1691—Coordination polymers, e.g. metal-organic frameworks [MOF]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0219—Coating the coating containing organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/06—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the liquid phase
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/70—Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
    • B01J2231/72—Epoxidation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/52—Gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/165—Polymer immobilised coordination complexes, e.g. organometallic complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/4038—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J33/00—Protection of catalysts, e.g. by coating
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Epoxy Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

PROCESSO DE OXIDAçãO COM GERAçãO IN SITU DE H~2~O~2~ E CATALISADORES ENCAPSULADOS EM POLìMERO PARA O MESMO. A presente invenção refere-se a catalisadores úteis para reações de titânio, um metal de transição e um polímero, em que pelo menos um entre zeólita de titânio ou metal de transição é encapsulado em uma fina camada do polímero. Os catalisadores são fáceis de preparar e usar, são fáceis de recuperar e reutilizar, e proporcionam boas conversões em uma gama de importantes processos de oxidação, incluindo epoxidação de propileno. A invenção inclui um processo que compreende oxidar um composto orgânico na presença de hidrogênio e do catalisador, onde o metal de transição catalisa a formação de peróxido de hidrogênio in situ.
BRPI0508539-0A 2004-03-09 2005-02-03 processo de oxidação com geração in-situ de h2o2 e catalisadores encapsulados em polìmero para o mesmo BRPI0508539A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/796,680 US7030255B2 (en) 2004-03-09 2004-03-09 Oxidation process with in-situ H202 generation and polymer-encapsulated catalysts therefor
PCT/US2005/003205 WO2005092502A1 (en) 2004-03-09 2005-02-03 Oxidation process with in-situ h2o2 generation and polymer-encapsulated catalysts therefor

Publications (1)

Publication Number Publication Date
BRPI0508539A true BRPI0508539A (pt) 2007-08-14

Family

ID=34919911

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0508539-0A BRPI0508539A (pt) 2004-03-09 2005-02-03 processo de oxidação com geração in-situ de h2o2 e catalisadores encapsulados em polìmero para o mesmo

Country Status (8)

Country Link
US (1) US7030255B2 (pt)
EP (1) EP1722891A1 (pt)
JP (1) JP2007528296A (pt)
KR (1) KR20070014128A (pt)
CN (1) CN100411737C (pt)
BR (1) BRPI0508539A (pt)
CA (1) CA2553802A1 (pt)
WO (1) WO2005092502A1 (pt)

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US7432384B2 (en) * 2005-10-25 2008-10-07 Lyondell Chemical Technology, L.P. Direct epoxidation process
US7528269B2 (en) * 2005-12-20 2009-05-05 Lyondell Chemical Technology, L.P. Process for oxidizing organic compounds
CN101397240B (zh) * 2007-09-28 2012-12-12 中国石油化工股份有限公司 一种苯酚羟基化制备对苯二酚和邻苯二酚的方法
CN101544582B (zh) * 2008-03-27 2012-06-27 中国石油化工股份有限公司 一种丁酮肟的合成方法
US20100317880A1 (en) * 2009-06-11 2010-12-16 Grey Roger A Direct epoxidation process using modifiers
US8124797B2 (en) * 2009-06-26 2012-02-28 Lyondell Chemical Technology, Lp Epoxidation process
US20110098491A1 (en) * 2009-10-28 2011-04-28 Bernard Cooker Direct epoxidation process using alkanoic acid modifier
US8124798B2 (en) 2009-12-17 2012-02-28 Lyondell Chemical Technology, Lp Direct epoxidation catalyst and process
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TWI510291B (zh) * 2011-04-27 2015-12-01 China Petrochemical Technology Co Ltd A titanium silicon molecular sieve and resin composite catalyst, preparation method and use thereof
WO2016153969A1 (en) 2015-03-20 2016-09-29 Northwestern University Catalysts and related methods for photocatalytc production of h2o2 and thermocatalytic reactant oxidation
KR101949074B1 (ko) 2015-04-09 2019-02-15 라이온델 케미칼 테크놀로지, 엘.피. 프로필렌 에폭사이드화에서의 촉매 성능 개선
CN105921171B (zh) * 2016-04-29 2018-07-24 山西大学 一种提高环己酮氨肟化催化剂ts-1分子筛稳定性的方法
US10947330B2 (en) * 2017-08-18 2021-03-16 Rohm And Haas Company Encapsulated catalyst and methods of olefin polymerization
JP7455116B2 (ja) 2018-10-03 2024-03-25 ザ ボード オブ トラスティーズ オブ ザ ユニバーシティ オブ イリノイ 可溶化触媒錯体の調製方法、可溶化触媒配合、および触媒オレフィン重合方法
CN113058643B (zh) * 2021-03-29 2021-12-21 北京化工大学 一种改性ts-1分子筛复合催化剂及其制备方法和应用

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Also Published As

Publication number Publication date
CN1921939A (zh) 2007-02-28
CA2553802A1 (en) 2005-10-06
US7030255B2 (en) 2006-04-18
KR20070014128A (ko) 2007-01-31
US20050202957A1 (en) 2005-09-15
WO2005092502A1 (en) 2005-10-06
EP1722891A1 (en) 2006-11-22
JP2007528296A (ja) 2007-10-11
CN100411737C (zh) 2008-08-20

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B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

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