BRPI0509507A - catalisador de conversão de hidrocarbonetos contendo zeólito, o processo de preparação dos mesmos, e um processo para converter óleos hidrocarbonados com o catalisador - Google Patents

catalisador de conversão de hidrocarbonetos contendo zeólito, o processo de preparação dos mesmos, e um processo para converter óleos hidrocarbonados com o catalisador

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Publication number
BRPI0509507A
BRPI0509507A BRPI0509507-7A BRPI0509507A BRPI0509507A BR PI0509507 A BRPI0509507 A BR PI0509507A BR PI0509507 A BRPI0509507 A BR PI0509507A BR PI0509507 A BRPI0509507 A BR PI0509507A
Authority
BR
Brazil
Prior art keywords
zeolite
catalyst
metals
weight
phosphorus
Prior art date
Application number
BRPI0509507-7A
Other languages
English (en)
Inventor
Jun Long
Zhijian Da
Huiping Tian
Zhenyu Chen
Weilin Zhang
Xingtian Shu
Jiushun Zhang
Yuxia Zhu
Yujian Liu
Original Assignee
China Petroleum & Chemical
Res Inst Petroleum Processing
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CN 200410029862 external-priority patent/CN1292052C/zh
Priority claimed from CN 200410029861 external-priority patent/CN1292051C/zh
Priority claimed from CNB2004100689364A external-priority patent/CN1332756C/zh
Priority claimed from CNB2004100689379A external-priority patent/CN1323136C/zh
Application filed by China Petroleum & Chemical, Res Inst Petroleum Processing filed Critical China Petroleum & Chemical
Publication of BRPI0509507A publication Critical patent/BRPI0509507A/pt
Publication of BRPI0509507B1 publication Critical patent/BRPI0509507B1/pt

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80—Mixtures of different zeolites
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/80—Additives
    • C10G2300/805—Water
    • C10G2300/807—Steam
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins

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  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

CATALISADOR DE CONVERSãO DE HIDROCARBONETOS CONTENDO ZEóLITO, O PROCESSO DE PREPARAçãO DOS MESMOS, E UM PROCESSO PARA CONVERTER óLEOS HIDROCARBONETOS COM O CATALISADOR A presente invenção refere-se a um catalisador para conversão de hidrocarbonetos, cujo catalisador contém, com base no peso do catalisador, 1-60% em peso de um zeólito, 0,1-10% em peso de um componente catalítico auxiliar, 5-98% em peso de um óxido inorgânico termotolerante, e 0-70% em peso de uma argila em termos do óxido. O referido zeólito é um zeólito estruturado MFI contendo fósforo e um ou mais metais de transição ou uma mistura do referido zeólito e um zeólito macroporoso, o qual compreende, com base no peso da mistura, 75-100% em peso do referido zeálito estruturado MFI contenda fósforo e um ou mais metais de transição e 0-25% em peso do zeólito macropomso. Em termos da massa do óxido, o referido zeólito estruturado MFI contendo fósforo e um au mais metais de transição têm a seguinte fórmula química anídrica: (0-0,3)Na2O. (0,3-5,5)AI2O3. (1,0-10)P2O5. (0,7-15)M1xOy (0,01-5)M2mOn.(0-10)RE2O3. (70-97)SiO2 ou (0-0,3)Na2O (0,3-5)AI2O3 (1,0-10)P2O5 (0,7-15)MpOq. (0-10)RE2O3 (70-98)SiO2 O referido componente catalítico auxiliar é um ou mais selecionados entre o grupo consistindo nos metais alcalino terrosos, metais do Grupo IVB, metais não nobres do Grupo VIII, e metais terrosos raros da Tabela Periódica das Elementos. Este catalisador tem uma capacidade maior de converter hidrocarbonetos de petróleo e maiores produções para propi- leno, etileno, e aromáticos leves.
BRPI0509507-7A 2004-03-31 2005-03-31 catalisador de conversão de hidrocarbonetos contendo zeólito, o processo de preparação dos mesmos, e um processo para converter óleos hidrocarbonados com o catalisador BRPI0509507B1 (pt)

Applications Claiming Priority (9)

Application Number Priority Date Filing Date Title
CN200410029862.3 2004-03-31
CN 200410029862 CN1292052C (zh) 2004-03-31 2004-03-31 一种含沸石的烃类转化催化剂及其制备方法
CN200410029861.9 2004-03-31
CN 200410029861 CN1292051C (zh) 2004-03-31 2004-03-31 一种烃油转化方法
CNB2004100689364A CN1332756C (zh) 2004-07-14 2004-07-14 一种含沸石的烃类转化催化剂
CN200410068937.9 2004-07-14
CN200410068936.4 2004-07-14
CNB2004100689379A CN1323136C (zh) 2004-07-14 2004-07-14 一种烃油转化方法
PCT/CN2005/000427 WO2005094992A1 (fr) 2004-03-31 2005-03-31 Catalyseur contenant un zeolite pour la conversion d'hydrocarbures et son elaboration, et procede de conversion d'huile d'hydrocarbure avec ce catalyseur

Publications (2)

Publication Number Publication Date
BRPI0509507A true BRPI0509507A (pt) 2007-09-11
BRPI0509507B1 BRPI0509507B1 (pt) 2021-02-23

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Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0509507-7A BRPI0509507B1 (pt) 2004-03-31 2005-03-31 catalisador de conversão de hidrocarbonetos contendo zeólito, o processo de preparação dos mesmos, e um processo para converter óleos hidrocarbonados com o catalisador

Country Status (6)

Country Link
US (1) US7923399B2 (pt)
EP (1) EP1762299B1 (pt)
JP (1) JP4987693B2 (pt)
BR (1) BRPI0509507B1 (pt)
CA (1) CA2563262C (pt)
WO (1) WO2005094992A1 (pt)

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