BRPI0516272A - processo para a polimerização em fase gasosa de olefinas - Google Patents

processo para a polimerização em fase gasosa de olefinas

Info

Publication number
BRPI0516272A
BRPI0516272A BRPI0516272-6A BRPI0516272A BRPI0516272A BR PI0516272 A BRPI0516272 A BR PI0516272A BR PI0516272 A BRPI0516272 A BR PI0516272A BR PI0516272 A BRPI0516272 A BR PI0516272A
Authority
BR
Brazil
Prior art keywords
riser
olefins
polymerization
gas
downcomer
Prior art date
Application number
BRPI0516272-6A
Other languages
English (en)
Inventor
Gabriele Mei
Massimo Covezzi
Stefano Bertolini
Original Assignee
Basell Poliolefine Srl
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Poliolefine Srl filed Critical Basell Poliolefine Srl
Publication of BRPI0516272A publication Critical patent/BRPI0516272A/pt
Publication of BRPI0516272B1 publication Critical patent/BRPI0516272B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/34—Polymerisation in gaseous state
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/904—Monomer polymerized in presence of transition metal containing catalyst at least part of which is supported on a polymer, e.g. prepolymerized catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/919—Catalyst injection technique in addition polymerization processes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Processo para a polimerização em fase gasosa de olefinas. O presente invento descreve um processo para a polimerização em fase gasosa de uma ou mais <244>-olefinas na presença de um sistema catalítico, o processo compreendendo: a) contatar de forma contínua uma ou mais de ditas <244>-olefinas com dito sistema catalítico num reator de prepolimerização, em que a reação é executada em meio liquido a uma temperatura variando de 23 a 50°C; b) alimentar continuamente o prepolímero obtido a partir da etapa (a) em um reator de fase gasosa tendo zonas de polimerização interconectadas, em que as partículas poliméricas em crescimento fluem para cima através de uma primeira zona de polimerização (elevadora) sob condições de fluidização rápida ou de transporte, deixam dita zona elevadora e entram numa segunda zona de polimerização (abaixadora) através da qual elas fluem para baixo sob a ação da gravidade, deixam dita zona abaixadora e são reintroduzidas na zona elevadora, estabelecendo assim uma circulação de polímero entre as zonas elevadora e abaixadora, em que o polímero obtido a partir da etapa (a) é continuamente alimentado a uma seção de dita zona elevadora compreendendo uma velocidade de gás ascendente maior que 3,0 m/s.
BRPI0516272A 2004-10-14 2005-09-19 processo para a polimerização em fase gasosa de olefinas BRPI0516272B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP04105058 2004-10-14
US62014804P 2004-10-18 2004-10-18
PCT/EP2005/054645 WO2006040240A1 (en) 2004-10-14 2005-09-19 Process for the gas-phase polymerization of olefins

Publications (2)

Publication Number Publication Date
BRPI0516272A true BRPI0516272A (pt) 2008-09-02
BRPI0516272B1 BRPI0516272B1 (pt) 2016-05-17

Family

ID=35385646

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0516272A BRPI0516272B1 (pt) 2004-10-14 2005-09-19 processo para a polimerização em fase gasosa de olefinas

Country Status (11)

Country Link
US (1) US7652108B2 (pt)
EP (1) EP1799725B1 (pt)
JP (1) JP4987722B2 (pt)
KR (1) KR101228401B1 (pt)
CN (1) CN101035816B (pt)
AT (1) ATE461225T1 (pt)
BR (1) BRPI0516272B1 (pt)
CA (1) CA2583580A1 (pt)
DE (1) DE602005020040D1 (pt)
RU (1) RU2374265C2 (pt)
WO (1) WO2006040240A1 (pt)

Families Citing this family (24)

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EP1926755A1 (en) * 2005-09-19 2008-06-04 Basell Poliolefine Italia S.R.L. Gas-phase process for the polymerization of olefins
CN100443155C (zh) 2006-05-31 2008-12-17 中国石油化工股份有限公司 一种浆态床环流反应器及其应用
CN100464832C (zh) * 2006-12-30 2009-03-04 中国石油大学(北京) 双喷嘴气提式外环流反应器
BRPI0807128B1 (pt) * 2007-02-05 2018-05-29 Basell Poliolefine Italia S.R.L. Aparelho para a polimerização de olefinas em fase líquida
JP2009221323A (ja) * 2008-03-14 2009-10-01 Sumitomo Chemical Co Ltd プロピレン系ブロック共重合体粒子群
CN102015090B (zh) * 2008-04-22 2014-03-12 尤尼威蒂恩技术有限公司 反应器系统和使用该反应器系统的方法
US8318102B2 (en) * 2008-12-15 2012-11-27 Syntroleum Corporation Process for increasing the efficiency of heat removal from a Fischer-Tropsch slurry reactor
US9068028B2 (en) 2009-06-19 2015-06-30 Basell Poliolefine Italia S.R.L. Process for the preparation of impact resistant propylene polymer compositions
BR112012005542B1 (pt) * 2009-09-11 2019-08-20 Basell Poliolefine Italia S.R.L Processo para polimerização em fase gasosa de olefinas
EP2516489B1 (en) * 2009-12-21 2014-07-02 W.R. Grace & CO. - CONN. Gas-phase polymerization process having multiple flow regimes
EP2428524A4 (en) 2010-04-30 2018-01-03 Daelim Industrial Co., Ltd. Gas-phase polymerization of alpha-olefins
EP2803676A1 (en) * 2013-05-16 2014-11-19 Basell Polyolefine GmbH Process for the gas-phase polymerization of ethylene or ethylene mixtures
EP2816062A1 (en) * 2013-06-18 2014-12-24 Basell Poliolefine Italia S.r.l. Pre-polymerized catalyst components for the polymerization of olefins
CN104292370B (zh) * 2013-07-17 2016-05-18 中国石油化工股份有限公司 一种丙烯连续变温预聚合装置及丙烯预聚合工艺
ES2866947T3 (es) * 2014-09-02 2021-10-20 Univation Tech Llc Producción de poliolefinas con catalizadores a base de cromo
US9289748B1 (en) 2015-06-11 2016-03-22 Chevron Phillips Chemical Company Lp Treater regeneration
US9861955B2 (en) 2015-06-11 2018-01-09 Chevron Phillips Chemical Company, Lp Treater regeneration
CA3047847C (en) * 2016-12-22 2020-03-24 Basell Polyolefine Gmbh Process for start-up of a multizone circulating reactor
ES2986055T3 (es) 2017-05-03 2024-11-08 Chevron Phillips Chemical Co Lp Regeneración de un desecante en un dispositivo de tratamiento fuera de línea de un proceso de producción de poliolefina
US10792609B2 (en) 2018-05-07 2020-10-06 Chevron Phillips Chemical Company Lp Nitrogen conservation in polymerization processes
KR20210033017A (ko) 2018-07-19 2021-03-25 보레알리스 아게 초고분자량 폴리에틸렌 동종중합체의 제조 방법
US10781273B2 (en) 2018-12-27 2020-09-22 Chevron Phillips Chemical Company Lp Multiple reactor and multiple zone polyolefin polymerization
US11254761B1 (en) 2020-10-15 2022-02-22 Chevron Phillips Chemical Company Lp Catalyst pretreatment and feeding system for polypropylene production
CN115703055B (zh) * 2021-08-17 2024-10-29 中国石油天然气股份有限公司 丙烯聚合催化剂的进料方法及进料系统、聚丙烯及其制备方法

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DE3600611A1 (de) 1986-01-11 1987-07-16 Basf Ag Einsatz von antistatika zur vermeidung von belagbildung bei der herstellung von ultrahochmolekularem polyethylen in gasphasenreaktoren
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Also Published As

Publication number Publication date
US20080312388A1 (en) 2008-12-18
BRPI0516272B1 (pt) 2016-05-17
JP2008517083A (ja) 2008-05-22
KR20070085255A (ko) 2007-08-27
CN101035816A (zh) 2007-09-12
WO2006040240A1 (en) 2006-04-20
ATE461225T1 (de) 2010-04-15
RU2007117724A (ru) 2008-11-20
EP1799725A1 (en) 2007-06-27
US7652108B2 (en) 2010-01-26
CN101035816B (zh) 2010-11-03
EP1799725B1 (en) 2010-03-17
DE602005020040D1 (de) 2010-04-29
RU2374265C2 (ru) 2009-11-27
CA2583580A1 (en) 2006-04-20
JP4987722B2 (ja) 2012-07-25
KR101228401B1 (ko) 2013-02-01

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Legal Events

Date Code Title Description
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 17/05/2016, OBSERVADAS AS CONDICOES LEGAIS.