BRPI0516675A - composto de ferrocênio substituìdo, processo para a polimerização por adição de um ou mais monÈmeros olefìnicos e processo para a sìntese de um composto organometálico de grupo 3-10 - Google Patents
composto de ferrocênio substituìdo, processo para a polimerização por adição de um ou mais monÈmeros olefìnicos e processo para a sìntese de um composto organometálico de grupo 3-10Info
- Publication number
- BRPI0516675A BRPI0516675A BRPI0516675-6A BRPI0516675A BRPI0516675A BR PI0516675 A BRPI0516675 A BR PI0516675A BR PI0516675 A BRPI0516675 A BR PI0516675A BR PI0516675 A BRPI0516675 A BR PI0516675A
- Authority
- BR
- Brazil
- Prior art keywords
- synthesis
- compound
- polymerization
- group
- addition
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 5
- 230000015572 biosynthetic process Effects 0.000 title abstract 3
- 238000003786 synthesis reaction Methods 0.000 title abstract 3
- 238000006116 polymerization reaction Methods 0.000 title abstract 2
- -1 ferrocene compound Chemical class 0.000 title 1
- 239000000178 monomer Substances 0.000 title 1
- 150000002902 organometallic compounds Chemical class 0.000 title 1
- 150000001875 compounds Chemical class 0.000 abstract 2
- 239000012190 activator Substances 0.000 abstract 1
- 238000012644 addition polymerization Methods 0.000 abstract 1
- 150000001450 anions Chemical class 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 abstract 1
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical class [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/02—Iron compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
- C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic Table
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
- B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
COMPOSTO DE FERROCêNIO SUBSTITUìDO, PROCESSO PARA A POLIMERIZAçãO POR ADIçãO DE UM OU MAIS MONÈMEROS OLEFìNICOS, E PROCESSO PARA A SìNTESE DE UM COMPOSTO ORGANOMETáLICO DE GRUPO 3-10. Compostos de ferrocênio substituídos compreendendo pelo menos um substituinte oleofílico pendente em pelo menos um dos grupos ciclopentadienila do mesmo, e um ânion não coordenador, compatível, inerte e processos para uso dos mesmos como ativadores de catalisadores para polimerizações por adição ou como agentes oxidantes para sínteses de complexo metálico.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US62569304P | 2004-11-05 | 2004-11-05 | |
| PCT/US2005/038070 WO2006052427A1 (en) | 2004-11-05 | 2005-10-25 | Highly soluble ferrocenyl compounds |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BRPI0516675A true BRPI0516675A (pt) | 2008-09-16 |
Family
ID=35697090
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0516675-6A BRPI0516675A (pt) | 2004-11-05 | 2005-10-25 | composto de ferrocênio substituìdo, processo para a polimerização por adição de um ou mais monÈmeros olefìnicos e processo para a sìntese de um composto organometálico de grupo 3-10 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US7645893B2 (pt) |
| EP (1) | EP1809643A1 (pt) |
| KR (1) | KR20070085713A (pt) |
| CN (1) | CN101072785A (pt) |
| BR (1) | BRPI0516675A (pt) |
| WO (1) | WO2006052427A1 (pt) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2534469T3 (es) * | 2006-05-17 | 2015-04-23 | Dow Global Technologies Llc | Procedimiento de polimerización de polietileno en disolución a alta temperatura |
| US9402394B2 (en) * | 2013-04-04 | 2016-08-02 | University Of South Carolina | Anion-paired cationic metallocene-containing compounds and polymers as antimicrobial agents |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4575544A (en) * | 1984-04-16 | 1986-03-11 | Loctite (Ireland) Ltd. | Ferricenium salt catalysts for vinyl ethers |
| US5384299A (en) * | 1987-01-30 | 1995-01-24 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
| US5198401A (en) * | 1987-01-30 | 1993-03-30 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
| US5153157A (en) * | 1987-01-30 | 1992-10-06 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
| US5064802A (en) * | 1989-09-14 | 1991-11-12 | The Dow Chemical Company | Metal complex compounds |
| JP2545006B2 (ja) * | 1990-07-03 | 1996-10-16 | ザ ダウ ケミカル カンパニー | 付加重合触媒 |
| US5189192A (en) * | 1991-01-16 | 1993-02-23 | The Dow Chemical Company | Process for preparing addition polymerization catalysts via metal center oxidation |
| DE69222700T2 (de) | 1991-07-11 | 1998-03-26 | Idemitsu Kosan Co | Verfahren zur Herstellung von Polymeren auf Olefinbasis und Olefin-Polymerisationskatalysatoren |
| RU2178422C2 (ru) * | 1996-03-27 | 2002-01-20 | Дзе Дау Кемикал Компани | Активатор катализаторов полимеризации олефинов, каталитическая система и способ полимеризации |
| ATE243700T1 (de) * | 1998-02-20 | 2003-07-15 | Dow Global Technologies Inc | Expandierte anionen enthaltende katalysatoraktivatoren |
| JP3572570B2 (ja) * | 1999-02-01 | 2004-10-06 | オーテックス株式会社 | カチオン重合性有機物質用の重合開始剤 |
-
2005
- 2005-10-25 WO PCT/US2005/038070 patent/WO2006052427A1/en not_active Ceased
- 2005-10-25 CN CNA2005800418986A patent/CN101072785A/zh active Pending
- 2005-10-25 KR KR1020077012566A patent/KR20070085713A/ko not_active Ceased
- 2005-10-25 EP EP05815022A patent/EP1809643A1/en not_active Withdrawn
- 2005-10-25 BR BRPI0516675-6A patent/BRPI0516675A/pt not_active Application Discontinuation
- 2005-10-25 US US11/666,941 patent/US7645893B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| KR20070085713A (ko) | 2007-08-27 |
| CN101072785A (zh) | 2007-11-14 |
| US20080097056A1 (en) | 2008-04-24 |
| US7645893B2 (en) | 2010-01-12 |
| EP1809643A1 (en) | 2007-07-25 |
| WO2006052427A1 (en) | 2006-05-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
Free format text: REFERENTE A 6A ANUIDADE. |
|
| B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |
Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 2160 DE 29/05/2012. |
|
| B08H | Application fees: decision cancelled [chapter 8.8 patent gazette] |
Free format text: REFERENTE AO DESPACHO 8.6 NA RPI 2160 DE 29/05/2012, E O DESPACHO 8.11 NA RPI 2181 DE 23/10/2012 |
|
| B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
Free format text: REFERENTE A 3A E 4A ANUIDADES |
|
| B08G | Application fees: restoration [chapter 8.7 patent gazette] | ||
| B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
| B09B | Patent application refused [chapter 9.2 patent gazette] | ||
| B09B | Patent application refused [chapter 9.2 patent gazette] |