BRPI0516973B1 - substrato revestido de (met)acrilato - Google Patents

substrato revestido de (met)acrilato

Info

Publication number
BRPI0516973B1
BRPI0516973B1 BRPI0516973A BRPI0516973A BRPI0516973B1 BR PI0516973 B1 BRPI0516973 B1 BR PI0516973B1 BR PI0516973 A BRPI0516973 A BR PI0516973A BR PI0516973 A BRPI0516973 A BR PI0516973A BR PI0516973 B1 BRPI0516973 B1 BR PI0516973B1
Authority
BR
Brazil
Prior art keywords
coating
meth
group
representing
compound
Prior art date
Application number
BRPI0516973A
Other languages
English (en)
Inventor
Hoa Thien Dang
Yannick Moysan
Original Assignee
Essilor Int
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Essilor Int filed Critical Essilor Int
Publication of BRPI0516973A publication Critical patent/BRPI0516973A/pt
Publication of BRPI0516973B1 publication Critical patent/BRPI0516973B1/pt

Links

Classifications

    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10—Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/18—Coatings for keeping optical surfaces clean, e.g. hydrophobic or photo-catalytic films
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/08—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/043—Improving the adhesiveness of the coatings per se, e.g. forming primers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/046—Forming abrasion-resistant coatings; Forming surface-hardening coatings
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/10—Homopolymers or copolymers of methacrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04—Homopolymers or copolymers of monomers containing silicon
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B27/00—Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00
    • G02B27/0006—Optical systems or apparatus not provided for by any of the groups G02B1/00 - G02B26/00, G02B30/00 with means to keep optical surfaces clean, e.g. by preventing or removing dirt, stains, contamination, condensation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/52—Two layers
    • B05D7/54—No clear coat specified
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2383/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
    • C08J2383/02—Polysilicates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2433/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2433/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C08J2433/10—Homopolymers or copolymers of methacrylic acid esters
    • C08J2433/12—Homopolymers or copolymers of methyl methacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/042—Coating with two or more layers, where at least one layer of a composition contains a polymer binder
    • C08J7/0423—Coating with two or more layers, where at least one layer of a composition contains a polymer binder with at least one layer of inorganic material and at least one layer of a composition containing a polymer binder
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
    • Y10T428/259—Silicic material
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers
    • Y10T428/31544—Addition polymer is perhalogenated
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31652—Of asbestos
    • Y10T428/31663—As siloxane, silicone or silane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31652—Of asbestos
    • Y10T428/31667—Next to addition polymer from unsaturated monomers, or aldehyde or ketone condensation product
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31935—Ester, halide or nitrile of addition polymer

Landscapes

  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Optics & Photonics (AREA)
  • General Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)
  • Surface Treatment Of Optical Elements (AREA)
  • Laminated Bodies (AREA)

Abstract

substrato, e, composição de revestimento. um substrato tendo pelo menos uma superficie principal, que compreende um primeiro revestimento depositado sobre a superficie principal e um segundo revestimento tendo propriedades contra a formação de sujeira, depositado e aderente sobre a superficie do primeiro revestimento - o primeiro revestimento sendo um revestimento à base de (met)acrilato e sendo obtido pela polimerização de uma composição polimerizável, que compreende: i) pelo menos um composto (met)acrilato e ii) pelo menos um composto 1 tendo pela menos uma ligação -m-z', com m representando si ou um átomo metálico, z' representando oh ou um grupo hidrolisável, e pelo menos um grupo etilênico insaturado ou um grupo epóxi, e! ou iii) pelo menos um colóide de sílica ou óxido metálico tendo grupos etilenicamente insaturados livres; e o segundo revestimento, tendo propriedades contra a formação de sujeira, sendo obtido pela deposição sobre o primeiro revestimento de uma compyiçáo contra a formação de sujeira, que compreende pelo menos um composto ii, ou um hidrolisado do mesmo, tendo pelo menos um grupo -si-z", com z" representando oh ou um grupo hidrolisável.
BRPI0516973A 2004-10-22 2005-10-21 substrato revestido de (met)acrilato BRPI0516973B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US62114204P 2004-10-22 2004-10-22
PCT/EP2005/011415 WO2006045582A1 (en) 2004-10-22 2005-10-21 Substrate with an anti-soiling coating

Publications (2)

Publication Number Publication Date
BRPI0516973A BRPI0516973A (pt) 2008-09-30
BRPI0516973B1 true BRPI0516973B1 (pt) 2016-11-16

Family

ID=35482245

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0516973A BRPI0516973B1 (pt) 2004-10-22 2005-10-21 substrato revestido de (met)acrilato

Country Status (7)

Country Link
US (1) US7678464B2 (pt)
EP (1) EP1809706B1 (pt)
CN (1) CN101061190B (pt)
AT (1) ATE556122T1 (pt)
BR (1) BRPI0516973B1 (pt)
CA (1) CA2584901C (pt)
WO (1) WO2006045582A1 (pt)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008024475A2 (en) * 2006-08-24 2008-02-28 Aculon, Inc. Optical articles with thin hydrophobic layers
US7732068B2 (en) * 2007-08-28 2010-06-08 Alcoa Inc. Corrosion resistant aluminum alloy substrates and methods of producing the same
US8309237B2 (en) * 2007-08-28 2012-11-13 Alcoa Inc. Corrosion resistant aluminum alloy substrates and methods of producing the same
US20090162544A1 (en) * 2007-12-20 2009-06-25 Garesche Carl E Method of surface coating to enhance durability of aesthetics and substrate component fatigue
CN101864240B (zh) * 2010-06-13 2012-08-08 徐友志 适用于海洋环境的自释型船舶防污漆及其制备与用法
FR2965820B1 (fr) * 2010-10-12 2012-11-16 Essilor Int Article comprenant une couche mesoporeuse protegee par un revetement faisant barriere au sebum et procede de fabrication
US20120237777A1 (en) * 2011-02-02 2012-09-20 Ppg Industries Ohio, Inc. Process for forming an anti-fouling coating system
CN102608265B (zh) * 2012-02-29 2014-11-19 东莞市升微机电设备科技有限公司 释放舱与被测试物接触的表面的处理方法
CA2873596C (fr) 2012-05-16 2021-05-04 Essilor International(Compagnie Generale D'optique) Lentille ophtalmique reduisant les effets de la lumiere bleue
EP2698212B1 (en) * 2012-08-17 2017-10-11 Rohm and Haas Company Substrate marking system
FR2996930B1 (fr) 2012-10-11 2017-11-24 Essilor Int Lentille ophtalmique photochromique
CN104936771B (zh) * 2013-01-22 2017-09-22 埃西勒国际通用光学公司 用于使用预定涂覆组合物涂覆光学制品的机器和用于使用该机器的方法
FR3007024A1 (fr) * 2013-06-14 2014-12-19 Essilor Int Article revetu d'une couche de nature silico-organique ameliorant les performances d'un revetement externe
US20170107381A1 (en) * 2014-03-27 2017-04-20 Lintec Corporation Antifouling sheet
CN105985670A (zh) * 2015-02-11 2016-10-05 国家电网公司 一种抑制覆冰的绝缘子
JP6483595B2 (ja) * 2015-12-04 2019-03-13 日立アプライアンス株式会社 塗料組成物及び塗装部品の製造方法
JP2018177951A (ja) * 2017-04-12 2018-11-15 株式会社ダイセル 硬化性組成物、硬化物及びハードコートフィルム
EP3880371A1 (en) * 2018-11-13 2021-09-22 Basf Se Easy to clean coating
CN110272645B (zh) * 2019-06-25 2021-06-01 东南大学 一种可重涂增透的超疏水涂料及其制备方法和应用
WO2023198748A1 (en) * 2022-04-14 2023-10-19 Optitune Oy Process for preparing an abrasion resistant coating

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4410563A (en) 1982-02-22 1983-10-18 The United States Of America As Represented By The Secretary Of The Navy Repellent coatings for optical surfaces
EP0203730B1 (en) 1985-04-30 1993-06-23 Toray Industries, Inc. Anti-reflection optical article and process for preparation thereof
US5096626A (en) * 1988-06-10 1992-03-17 Asahi Kogaku Kogyo Kabushiki Kaisha Process of molding a coated plastic lens
US5258225A (en) * 1990-02-16 1993-11-02 General Electric Company Acrylic coated thermoplastic substrate
US5614321A (en) * 1995-04-14 1997-03-25 General Electric Company Abrasion resistant, curable hardcoating compositions and tinted articles made therefrom
US5763061A (en) 1995-06-15 1998-06-09 Sumitomo Chemical Company, Limited Antireflection filter
EP0844265B1 (en) 1995-08-11 2002-11-20 Daikin Industries, Limited Silicon-containing organic fluoropolymers and use of the same
US6277485B1 (en) 1998-01-27 2001-08-21 3M Innovative Properties Company Antisoiling coatings for antireflective surfaces and methods of preparation
JP4733798B2 (ja) 1998-01-31 2011-07-27 凸版印刷株式会社 防汚剤、防汚層の形成方法、光学部材、反射防止光学部材、光学機能性部材及び表示装置
US6322860B1 (en) * 1998-11-02 2001-11-27 Rohm And Haas Company Plastic substrates for electronic display applications
FR2805901B1 (fr) * 2000-03-06 2002-05-31 Essilor Int Finissage d'une lentille optalmique
US7217440B2 (en) * 2003-06-13 2007-05-15 Essilor International Compagnie Generale D'optique Process for replacing an initial outermost coating layer of a coated optical lens with a different coating layer or by depositing thereon a different coating layer

Also Published As

Publication number Publication date
EP1809706A1 (en) 2007-07-25
CN101061190B (zh) 2012-04-11
ATE556122T1 (de) 2012-05-15
CN101061190A (zh) 2007-10-24
US20070026237A1 (en) 2007-02-01
WO2006045582A1 (en) 2006-05-04
CA2584901C (en) 2014-01-21
EP1809706B1 (en) 2012-05-02
BRPI0516973A (pt) 2008-09-30
CA2584901A1 (en) 2006-05-04
US7678464B2 (en) 2010-03-16

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Legal Events

Date Code Title Description
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 16/11/2016, OBSERVADAS AS CONDICOES LEGAIS.

B25A Requested transfer of rights approved
B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE A 17A ANUIDADE.

B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2693 DE 16-08-2022 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.