BRPI0608128A2 - processo para fabricação de ácido acrìlico - Google Patents

processo para fabricação de ácido acrìlico

Info

Publication number
BRPI0608128A2
BRPI0608128A2 BRPI0608128-2A BRPI0608128A BRPI0608128A2 BR PI0608128 A2 BRPI0608128 A2 BR PI0608128A2 BR PI0608128 A BRPI0608128 A BR PI0608128A BR PI0608128 A2 BRPI0608128 A2 BR PI0608128A2
Authority
BR
Brazil
Prior art keywords
acrylic acid
manufacturing acrylic
reaction
manufacturing
oxidehydration
Prior art date
Application number
BRPI0608128-2A
Other languages
English (en)
Inventor
Jean-Luc Dubois
Christophe M Duquenne
Wolfgang Hilderich
Original Assignee
Arkema France
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR0504111A external-priority patent/FR2884817B1/fr
Application filed by Arkema France filed Critical Arkema France
Publication of BRPI0608128A2 publication Critical patent/BRPI0608128A2/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/053—Sulfates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/187—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/188—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/52—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition by dehydration and rearrangement involving two hydroxy groups in the same molecule
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03—Monocarboxylic acids
    • C07C57/04—Acrylic acid; Methacrylic acid
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/14—Phosphorus; Compounds thereof
    • C07C2527/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/14—Phosphorus; Compounds thereof
    • C07C2527/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PROCESSO PARA FABRICAçãO DE áCIDO ACRìLICO A invenção se refere a um método para produção de ácido acrílico em uma etapa através de uma reação de oxidesidratação de glicerol na presença de oxigênio molecular. A reação é, de preferência, realizada em fase gasosa na presença de um catalisador adequado.
BRPI0608128-2A 2005-04-25 2006-04-24 processo para fabricação de ácido acrìlico BRPI0608128A2 (pt)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
FR0504111A FR2884817B1 (fr) 2005-04-25 2005-04-25 Procede de preparation d'acide acrylique a partir de glycerol
US68942305P 2005-06-10 2005-06-10
FR0600183A FR2884818B1 (fr) 2005-04-25 2006-01-10 Procede de preparation d'acide acrylique a partir de glycerol
PCT/FR2006/000907 WO2006114506A1 (fr) 2005-04-25 2006-04-24 Procede de preparation d’acide acrylique a partir de glycerol

Publications (1)

Publication Number Publication Date
BRPI0608128A2 true BRPI0608128A2 (pt) 2009-11-17

Family

ID=37672391

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0608128-2A BRPI0608128A2 (pt) 2005-04-25 2006-04-24 processo para fabricação de ácido acrìlico

Country Status (7)

Country Link
US (1) US7910771B2 (pt)
EP (1) EP1874720B1 (pt)
JP (1) JP4885947B2 (pt)
KR (1) KR100947196B1 (pt)
BR (1) BRPI0608128A2 (pt)
FR (1) FR2884818B1 (pt)
WO (1) WO2006114506A1 (pt)

Families Citing this family (75)

* Cited by examiner, † Cited by third party
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JP5006507B2 (ja) 2004-01-30 2012-08-22 株式会社日本触媒 アクリル酸の製造方法
FR2903620B1 (fr) * 2006-07-13 2009-02-20 Arkema France Catalyseur membranaire pour la synthese d'acide acrylique a partir de glycerol
WO2008066079A1 (en) * 2006-12-01 2008-06-05 Nippon Shokubai Co., Ltd. Method for producing acrylic acid
FR2909999B1 (fr) * 2006-12-19 2009-04-03 Arkema France Procede de preparation d'acide acrylique a partir de glycerol
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BRPI0806767A2 (pt) * 2007-01-26 2011-09-13 Basf Se processo para preparar ácido acrìlico
DE102007055086A1 (de) 2007-11-16 2009-05-20 Basf Se Verfahren zur Herstellung von Acrylsäure
FR2912131B1 (fr) * 2007-02-05 2009-03-13 Rhodia Poliamida E Especialidades Ltda Procede pour l'obtention d'acide propionique
US8969644B2 (en) * 2007-02-06 2015-03-03 Basf Se Method for providing an oxygen-containing gas stream for the endothermic reaction of an initial stream comprising one or more hydrocarbons
FR2913974A1 (fr) * 2007-03-19 2008-09-26 Arkema France Procede de vaporisation de glycerol
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FR2920767B1 (fr) * 2007-09-06 2009-12-18 Arkema France Procede de vaporisation reactive de glycerol
FR2921361B1 (fr) * 2007-09-20 2012-10-12 Arkema France Procede de fabrication d'acroleine a partir de glycerol
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FR2934261B1 (fr) * 2008-07-25 2015-04-10 Arkema France Procede de synthese d'esters de l'acide acrylique
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DE102008040799A1 (de) 2008-07-28 2008-12-11 Basf Se Verfahren zur Auftrennung von in einem Produktgasgemisch einer partiellen heterogen katalysierten Gasphasenoxidation einer C3-Vorläuferverbindung der Acrylsäure als Hauptbestandteil enthaltener Acrylsäure und als Nebenprodukt enthaltenem Glyoxal
DE102008041573A1 (de) 2008-08-26 2010-03-04 Basf Se Verfahren zur Auftrennung von in einem Produktgasgemisch einer partiellen heterogen katalysierten Gasphasenoxidation einer C3-Vorläuferverbindung der Acrylsäure als Hauptbestandteil enhaltener Acrylsäure und als Nebenprodukt enthaltenem Glyoxal
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FR2935971B1 (fr) 2008-09-16 2010-11-19 Arkema France Acide bio-acrylique de grade polymere et son procede de fabrication a partir de glycerol.
JP2010099596A (ja) * 2008-10-24 2010-05-06 Arkema France グリセリンの脱水反応によるアクロレイン及びアクリル酸の製造用触媒と、その製造法
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FR2948366B1 (fr) 2009-07-22 2012-08-17 Arkema France Procede de fabrication d'acide acrylique bio-ressource a partir de glycerol
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FR2952056B1 (fr) 2009-11-04 2013-01-25 Arkema France Glutaraldehyde bioressource et ses procedes de fabrication
FR2952057B1 (fr) 2009-11-04 2011-11-18 Arkema France Procede de synthese de pyridine et picolines bioressourcees
FR2953829B1 (fr) 2009-12-14 2011-12-09 Arkema France Procede de fabrication d'acroleine et/ou d'acide acrylique a partir de glycerol
FR2953830B1 (fr) 2009-12-14 2012-01-20 Arkema France Procede de fabrication d'acroleine et/ou d'acide acrylique a partir de glycerol
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FR2954311B1 (fr) 2009-12-22 2012-02-03 Arkema France Procede de synthese perfectionne d'acroleine a partir de glycerol
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WO2013017904A1 (en) 2011-07-29 2013-02-07 Arkema France Improved process of dehydration reactions
FR2989684B1 (fr) 2012-04-18 2014-10-31 Arkema France Procede de fabrication d'acroleine et/ou d'acide acrylique a partir de glycerol
US9409847B2 (en) 2012-11-07 2016-08-09 Council Of Scientific & Industrial Research Catalyst for single step conversion of glycerol to acrylic acid and process for the preparation thereof
CN105705647B (zh) 2013-09-03 2020-03-27 Ptt全球化学公众有限公司 从1，3-丙二醇制造丙烯酸、丙烯腈和1，4-丁二醇的方法
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KR101964275B1 (ko) 2015-09-01 2019-04-01 주식회사 엘지화학 아크릴산 제조용 촉매 제조방법 및 이로부터 제조되는 촉매
KR102044428B1 (ko) * 2015-12-23 2019-12-02 주식회사 엘지화학 글리세린으로부터 아크릴산의 제조방법
ES2949972T3 (es) * 2017-11-22 2023-10-04 Novamont Spa Producción de ácidos carboxílicos a partir de dioles vecinales
KR102893876B1 (ko) 2018-07-26 2025-12-03 바스프 에스이 액상 p 중 존재하는 아크릴산의 원치않는 라디칼 중합의 억제 방법
US20230132285A1 (en) 2020-03-26 2023-04-27 Basf Se Process for inhibiting the undesired free-radical polymerization of acrylic acid present in a liquid phase p
US20230174452A1 (en) 2020-05-04 2023-06-08 Basf Se Method for breaking down michael adducts contained in a fluid f and formed during the preparation of acrylic acid
FR3125048B1 (fr) 2021-07-09 2024-04-19 Snf Sa Polymère biosourcé à biodégradabilité améliorée
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Also Published As

Publication number Publication date
FR2884818B1 (fr) 2007-07-13
US7910771B2 (en) 2011-03-22
JP2008538781A (ja) 2008-11-06
WO2006114506A1 (fr) 2006-11-02
EP1874720B1 (fr) 2013-03-06
KR20070116655A (ko) 2007-12-10
JP4885947B2 (ja) 2012-02-29
FR2884818A1 (fr) 2006-10-27
US20080183013A1 (en) 2008-07-31
EP1874720A1 (fr) 2008-01-09
KR100947196B1 (ko) 2010-03-11

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