BRPI0700207A - processo para a co-produção de olefinas e diésteres ou diácidos partindo de gorduras insaturadas - Google Patents

processo para a co-produção de olefinas e diésteres ou diácidos partindo de gorduras insaturadas

Info

Publication number
BRPI0700207A
BRPI0700207A BRPI0700207-6A BRPI0700207A BRPI0700207A BR PI0700207 A BRPI0700207 A BR PI0700207A BR PI0700207 A BRPI0700207 A BR PI0700207A BR PI0700207 A BRPI0700207 A BR PI0700207A
Authority
BR
Brazil
Prior art keywords
introduction
separation
zone
catalyst
ethylene
Prior art date
Application number
BRPI0700207-6A
Other languages
English (en)
Inventor
Helene Olivier-Bourbigou
Christophe Vallee
Gerard Hillion
Original Assignee
Inst Francais Du Petrole
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Inst Francais Du Petrole filed Critical Inst Francais Du Petrole
Publication of BRPI0700207A publication Critical patent/BRPI0700207A/pt
Publication of BRPI0700207B1 publication Critical patent/BRPI0700207B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/207—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms from carbonyl compounds
    • C07C1/213—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms from carbonyl compounds by splitting of esters
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02—Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04—Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/30—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group
    • C07C67/333—Preparation of carboxylic acid esters by modifying the acid moiety of the ester, such modification not being an introduction of an ester group by isomerisation; by change of size of the carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/475—Preparation of carboxylic acid esters by splitting of carbon-to-carbon bonds and redistribution, e.g. disproportionation or migration of groups between different molecules
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PROCESSO PARA A CO-PRODUçãO DE OLEFINAS E DIéSTERES OU DIáCIDOS PARTINDO DE GORDURAS INSATURADAS. A presente invenção refere-se a produzir tanto uma fração olefínica e uma composição de diácidos ou diésteres de gorduras, onde um processo é realizado incluindo, em sucessão: a) metátese de uma gordura insaturada com etileno na presença de pelo menos um líquido iónico não-aquoso; b) separação e reciclagem do líquido iónico usado na primeira etapa; c) separação por destilação, da fração olefínica (fração A) da fração de ácido monobásico ou monoáster da gordura insaturada (fração B) formado na etapa a); d) homometátese do éster de gordura monoinsaturada ou parte ácida (fração B) que permita a co-produção de diésteres ou diácidos de gordura insaturada (fração C) e etileno que é reciclado na primeira etapa de metátese do processo; e) opcionalmente, reciclagem do líquido iónico contendo o catalisador usado na etapa d). De aplicação particular a um óleo de semente de girassol oléico, um óleo de semente de colza olélco ou a uma mistura de ésteres de mono-álcool de tais óleos, onde o processo pode produzir tanto uma fração olefínica (composta principalmente de 1-deceno) e uma composição de diásteres ou diácidos onde, em geral, mais da metade das cadeias é constituída de cadeias C~ 18~ insaturadas (principalmente compostas de 9-octadeceno-1,18-diácido ou diáster) e a reciclagem do etileno empregado.
BRPI0700207A 2006-01-24 2007-01-24 processo para a produção de tanto uma fração olefínica como uma composição de diésteres ou diácidos de gorduras insaturadas e construção para executar o referido processo BRPI0700207B1 (pt)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0600646A FR2896498B1 (fr) 2006-01-24 2006-01-24 Procede de co-production d'olefines et de diesters ou de diacides a partir de corps gras insatures.

Publications (2)

Publication Number Publication Date
BRPI0700207A true BRPI0700207A (pt) 2007-11-06
BRPI0700207B1 BRPI0700207B1 (pt) 2016-03-29

Family

ID=37057152

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0700207A BRPI0700207B1 (pt) 2006-01-24 2007-01-24 processo para a produção de tanto uma fração olefínica como uma composição de diésteres ou diácidos de gorduras insaturadas e construção para executar o referido processo

Country Status (11)

Country Link
US (1) US7906663B2 (pt)
EP (1) EP1810960B1 (pt)
JP (1) JP5171045B2 (pt)
AT (1) ATE449058T1 (pt)
AU (1) AU2007200278B2 (pt)
BR (1) BRPI0700207B1 (pt)
CA (1) CA2573638C (pt)
DE (1) DE602007003236D1 (pt)
ES (1) ES2335707T3 (pt)
FR (1) FR2896498B1 (pt)
NO (1) NO338394B1 (pt)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1856208B1 (en) 2005-01-10 2016-12-28 Elevance Renewable Sciences, Inc. Wax composition containing metathesis products and method for making an article by extrusion thereof
FR2896500B1 (fr) * 2006-01-24 2010-08-13 Inst Francais Du Petrole Procede de co-production d'olefines et de diesters ou de diacides par homometathese de corps gras insatures dans des liquides ioniques non-aqueux.
BRPI0708675B1 (pt) 2006-03-07 2017-04-04 Elevance Renewable Sciences composições compreendendo poliol ésteres insaturados que sofreram metátese e artigos para cuidados pessoais compreendendo as referidas composições
WO2008008420A1 (en) 2006-07-12 2008-01-17 Elevance Renewable Sciences, Inc. Hot melt adhesive compositions comprising metathesized unsaturated polyol ester wax
WO2008010961A2 (en) 2006-07-13 2008-01-24 Elevance Renewable Sciences, Inc. Synthesis of terminal alkenes from internal alkenes and ethylene via olefin metathesis
EP2074079B1 (en) 2006-10-13 2011-08-10 Elevance Renewable Sciences, Inc. Metathesis methods involving hydrogenation and compositions relating to same
WO2008048520A2 (en) * 2006-10-13 2008-04-24 Elevance Renewable Sciences, Inc. Methods of making organic compounds by metathesis and hydrocyanation
CN101558027B (zh) 2006-10-13 2013-10-16 埃莱文斯可更新科学公司 通过复分解反应制备α，ω-二羧酸烯烃衍生物的方法
CN102123979A (zh) 2006-10-13 2011-07-13 埃莱文斯可更新科学公司 通过烯烃复分解由内烯烃合成末端烯烃的方法
FR2921362B1 (fr) * 2007-09-20 2012-09-21 Arkema France Procede de synthese d'acides gras omega-insatures
EP2157076A1 (de) * 2008-08-21 2010-02-24 Cognis IP Management GmbH Verfahren zur Herstellung von ungesättigten alpha, omega Dicarbonsäurediestern
FR2939331B1 (fr) * 2008-12-10 2012-08-10 Inst Francais Du Petrole Composition catalytique et procede de metathese de corps gras insature
US8389625B2 (en) * 2008-12-23 2013-03-05 Exxonmobil Research And Engineering Company Production of synthetic hydrocarbon fluids, plasticizers and synthetic lubricant base stocks from renewable feedstocks
PL2488474T3 (pl) * 2009-10-12 2017-07-31 Elevance Renewable Sciences, Inc. Sposoby rafinacji i wytwarzania paliw z surowców na bazie olejów naturalnych
US9051519B2 (en) 2009-10-12 2015-06-09 Elevance Renewable Sciences, Inc. Diene-selective hydrogenation of metathesis derived olefins and unsaturated esters
WO2012027139A2 (en) 2010-08-25 2012-03-01 Exxonmobil Chemical Patents Inc. Functionalizable synthetic hydrocarbon fluids and integrated method of for production thereof
JP2014516932A (ja) * 2011-04-20 2014-07-17 コグニス・アイピー・マネージメント・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング 不飽和化合物の製造方法
CN104508101A (zh) 2011-12-28 2015-04-08 艾勒旺斯可再生科学公司 可再生脂肪酸蜡及其制造方法
CN104583369A (zh) 2012-06-20 2015-04-29 埃莱万斯可再生能源科学股份有限公司 天然油易位组合物
FR2992642B1 (fr) * 2012-06-29 2015-06-19 Novance Procede de synthese d’acides insatures biosources

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2715328B1 (fr) * 1994-01-26 1996-04-12 Inst Francais Du Petrole Composition catalytique et procédé pour la disproportion des oléfines.
JP2000256218A (ja) * 1999-03-05 2000-09-19 Bayer Ag イオン性液体存在下でのメタセシス
KR100898876B1 (ko) * 2001-03-26 2009-05-25 다우 글로벌 테크놀로지스 인크. 불균질 촉매 조성물
FR2878246B1 (fr) 2004-11-23 2007-03-30 Inst Francais Du Petrole Procede de co-production d'olefines et d'esters par ethenolyse de corps gras insatures dans des liquides ioniques non-aqueux
FR2896500B1 (fr) * 2006-01-24 2010-08-13 Inst Francais Du Petrole Procede de co-production d'olefines et de diesters ou de diacides par homometathese de corps gras insatures dans des liquides ioniques non-aqueux.

Also Published As

Publication number Publication date
US7906663B2 (en) 2011-03-15
BRPI0700207B1 (pt) 2016-03-29
CA2573638C (fr) 2014-10-07
ATE449058T1 (de) 2009-12-15
FR2896498B1 (fr) 2008-08-29
CA2573638A1 (fr) 2007-07-24
JP2007197444A (ja) 2007-08-09
ES2335707T3 (es) 2010-03-31
AU2007200278A1 (en) 2007-08-09
EP1810960A1 (fr) 2007-07-25
AU2007200278B2 (en) 2012-04-05
DE602007003236D1 (de) 2009-12-31
JP5171045B2 (ja) 2013-03-27
EP1810960B1 (fr) 2009-11-18
NO20070436L (no) 2007-07-25
FR2896498A1 (fr) 2007-07-27
US20070179307A1 (en) 2007-08-02
NO338394B1 (no) 2016-08-15

Similar Documents

Publication Publication Date Title
DE602007003236D1 (de) Verfahren zur gleichzeitigen Produktion von Olefinen und Diestern oder Disäuren aus ungesättigten Fettkörpern
BRPI0700205A (pt) processo para co-produção de olefinas e diésteres ou diácidos pela homometátese de gorduras insaturadas em lìquidos iÈnicos não aquosos
KR102653600B1 (ko) 나트륨-염-함유 mma-메탄올 혼합물의 추출 후처리
ATE522492T1 (de) Verfahren zur herstellung von (meth)acrylaten von c10-alkoholgemischen
UA108871C2 (uk) Безперервний спосіб окислювального розщеплення рослинних олій
FR2878246B1 (fr) Procede de co-production d'olefines et d'esters par ethenolyse de corps gras insatures dans des liquides ioniques non-aqueux
BR9708392A (pt) Processo para oxidação de alcanos
CO6280548A2 (es) Procedimiento para la preparacion de esteres alquilicos de acidos grasos
DE50114747D1 (de) Verfahren zur herstellung von estern mehrbasiger säuren
ES2755389T3 (es) Procedimiento para producir ésteres de ácido carboxílico en presencia de un líquido iónico y un catalizador de esterificación ácido y su uso como plastificante
Villaverde et al. Hydroperoxide production from linoleic acid by heterologous Gaeumannomyces graminis tritici lipoxygenase: optimization and scale-up
AR046567A1 (es) Procesos de preparacion de esteres de acidos mono, di o policarboxilicos
MY164355A (en) Process for the semi-continuous transvinylation of carboxylic acids with vinyl acetate
RU2009127514A (ru) Усовершенствованный способ получения ангидридов ненасыщенных карбоновых кислот
JP6097771B2 (ja) エステル類の製造方法およびその用途
JP2015530418A (ja) Ｃ１０アルコール混合物から（メタ）アクリレートを製造するための連続的方法
MY115846A (en) Esterification of (meth) acrylic acid with an alkanol
Soulère et al. An expeditious synthesis of 4-hydroxy-2 (E)-nonenal (4-HNE), its dimethyl acetal and of related compounds
US20130303796A1 (en) Method for continuously preparing carboxylic acid ester
CN1800173A (zh) 维生素e亚麻酸酯与维生素e油酸酯的制备
JPWO2016035573A1 (ja) （メタ）アクリル酸エステル混合物の製造方法
CL2008003052A1 (es) Procedimiento continuo para la esterificacion heterogéneamente catalizada de acidos grasos
Vyshnavi et al. Metathesis of 9-octadecenoic acid methyl ester: diversity and mechanism of product formation at various Grubbs’ catalyst concentrations
CN101302155A (zh) 一种合成不饱和烯酸异丙酯的方法
PH12014502081A1 (en) Process for the production of fatty acid esters

Legal Events

Date Code Title Description
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B09X Republication of the decision to grant [chapter 9.1.3 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 24/01/2007, OBSERVADAS AS CONDICOES LEGAIS.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE A 16A ANUIDADE.

B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2706 DE 16-11-2022 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.