BRPI0702604A - método de conversão de etanol em estoque de base para combustìvel diesel - Google Patents
método de conversão de etanol em estoque de base para combustìvel dieselInfo
- Publication number
- BRPI0702604A BRPI0702604A BRPI0702604-8A BRPI0702604A BRPI0702604A BR PI0702604 A BRPI0702604 A BR PI0702604A BR PI0702604 A BRPI0702604 A BR PI0702604A BR PI0702604 A BRPI0702604 A BR PI0702604A
- Authority
- BR
- Brazil
- Prior art keywords
- diesel fuel
- base stock
- liquid phase
- ethanol
- converting ethanol
- Prior art date
Links
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 title abstract 6
- 239000002283 diesel fuel Substances 0.000 title abstract 2
- 239000007791 liquid phase Substances 0.000 abstract 4
- 239000012071 phase Substances 0.000 abstract 2
- 239000003377 acid catalyst Substances 0.000 abstract 1
- 239000011148 porous material Substances 0.000 abstract 1
- 230000009466 transformation Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/50—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids in the presence of hydrogen, hydrogen donors or hydrogen generating compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/42—Catalytic treatment
- C10G3/44—Catalytic treatment characterised by the catalyst used
- C10G3/45—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/42—Catalytic treatment
- C10G3/44—Catalytic treatment characterised by the catalyst used
- C10G3/47—Catalytic treatment characterised by the catalyst used containing platinum group metals or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/62—Catalyst regeneration
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4081—Recycling aspects
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/04—Diesel oil
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Output Control And Ontrol Of Special Type Engine (AREA)
- Exhaust Gas After Treatment (AREA)
Abstract
MéTODO DE CONVERSãO DE ETANOL EM ESTOQUE DE BASE PARA COMBUSTìVEL DIESEL. A presente invenção refere-se a um método de conversão de etanol em estoque de base de combustível diesel que compreende: - um estágio de reação (a) de contato do etanol com um catalisador ácido, amorfo ou estruturado, predominantemente mesoporoso, por exemplo a uma temperatura de 300 C a 500 C a uma pressão de 2 a 10 MPa e a WHSV de 0,2 a 4 h-¹, produzindo uma fase gasosa, uma fase líquida orgânica e uma fase líquida aquosa, e - um estágio (b) de separação da fase gasosa, a fase líquida orgânica e a fase líquida aquosa em uma pressão próxima da pressão de reação. O método pode envolver reciclagem de pelo menos parte da fase gasosa separada no estágio (b) para o estágio (a) e hidrogenação de pelo menos parte da fase líquida orgânica separada no estágio (b).
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0604928A FR2901804B1 (fr) | 2006-05-30 | 2006-05-30 | Procede de transformation de l'ethanol en base pour carburant diesel |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0702604A true BRPI0702604A (pt) | 2008-03-04 |
| BRPI0702604B1 BRPI0702604B1 (pt) | 2017-03-21 |
Family
ID=37685338
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0702604A BRPI0702604B1 (pt) | 2006-05-30 | 2007-05-30 | método de conversão de etanol em estoque de base para combustível diesel |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US7994377B2 (pt) |
| EP (1) | EP1862528B1 (pt) |
| AT (1) | ATE530623T1 (pt) |
| BR (1) | BRPI0702604B1 (pt) |
| DK (1) | DK1862528T3 (pt) |
| ES (1) | ES2373923T3 (pt) |
| FR (1) | FR2901804B1 (pt) |
| MY (1) | MY145212A (pt) |
| PL (1) | PL1862528T3 (pt) |
| ZA (1) | ZA200703781B (pt) |
Families Citing this family (49)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8143469B2 (en) | 2007-06-11 | 2012-03-27 | Neste Oil Oyj | Process for producing branched hydrocarbons |
| US7982078B2 (en) | 2007-09-20 | 2011-07-19 | Uop Llc | Production of diesel fuel from biorenewable feedstocks with selective separation of converted oxygen |
| US7915460B2 (en) * | 2007-09-20 | 2011-03-29 | Uop Llc | Production of diesel fuel from biorenewable feedstocks with heat integration |
| US7982075B2 (en) * | 2007-09-20 | 2011-07-19 | Uop Llc | Production of diesel fuel from biorenewable feedstocks with lower hydrogen consumption |
| US7999142B2 (en) | 2007-09-20 | 2011-08-16 | Uop Llc | Production of diesel fuel from biorenewable feedstocks |
| US7982077B2 (en) | 2007-09-20 | 2011-07-19 | Uop Llc | Production of diesel fuel from biorenewable feedstocks with selective separation of converted oxygen |
| US7999143B2 (en) * | 2007-09-20 | 2011-08-16 | Uop Llc | Production of diesel fuel from renewable feedstocks with reduced hydrogen consumption |
| US8003834B2 (en) * | 2007-09-20 | 2011-08-23 | Uop Llc | Integrated process for oil extraction and production of diesel fuel from biorenewable feedstocks |
| US7982076B2 (en) | 2007-09-20 | 2011-07-19 | Uop Llc | Production of diesel fuel from biorenewable feedstocks |
| US20090077864A1 (en) * | 2007-09-20 | 2009-03-26 | Marker Terry L | Integrated Process of Algae Cultivation and Production of Diesel Fuel from Biorenewable Feedstocks |
| US20090162264A1 (en) * | 2007-12-21 | 2009-06-25 | Mccall Michael J | Production of Aviation Fuel from Biorenewable Feedstocks |
| US8742183B2 (en) * | 2007-12-21 | 2014-06-03 | Uop Llc | Production of aviation fuel from biorenewable feedstocks |
| US8193400B2 (en) * | 2008-03-17 | 2012-06-05 | Uop Llc | Production of diesel fuel from renewable feedstocks |
| US8198492B2 (en) | 2008-03-17 | 2012-06-12 | Uop Llc | Production of transportation fuel from renewable feedstocks |
| US8039682B2 (en) | 2008-03-17 | 2011-10-18 | Uop Llc | Production of aviation fuel from renewable feedstocks |
| US8058492B2 (en) | 2008-03-17 | 2011-11-15 | Uop Llc | Controlling production of transportation fuels from renewable feedstocks |
| US8193399B2 (en) * | 2008-03-17 | 2012-06-05 | Uop Llc | Production of diesel fuel and aviation fuel from renewable feedstocks |
| US8329968B2 (en) * | 2008-04-06 | 2012-12-11 | Uop Llc | Production of blended gasoline aviation and diesel fuels from renewable feedstocks |
| JP2011517470A (ja) * | 2008-04-06 | 2011-06-09 | ユーオーピー エルエルシー | バイオマス由来熱分解油からの燃料および燃料ブレンド成分 |
| US8324438B2 (en) * | 2008-04-06 | 2012-12-04 | Uop Llc | Production of blended gasoline and blended aviation fuel from renewable feedstocks |
| US8329967B2 (en) * | 2008-04-06 | 2012-12-11 | Uop Llc | Production of blended fuel from renewable feedstocks |
| EP2123736A1 (de) * | 2008-05-19 | 2009-11-25 | C.E.-Technology Limited | Verfahren zur Herstellung von Dieselkraftstoffen und Flugzeugtreibstoffen aus C1-C5-Alkoholen |
| US8766025B2 (en) | 2008-06-24 | 2014-07-01 | Uop Llc | Production of paraffinic fuel from renewable feedstocks |
| US8304592B2 (en) * | 2008-06-24 | 2012-11-06 | Uop Llc | Production of paraffinic fuel from renewable feedstocks |
| US20090321311A1 (en) * | 2008-06-27 | 2009-12-31 | Uop Llc | Production of diesel fuel from renewable feedstocks containing phosphorus |
| US7982079B2 (en) | 2008-09-11 | 2011-07-19 | Uop Llc | Integrated process for production of diesel fuel from renewable feedstocks and ethanol denaturizing |
| US8921627B2 (en) * | 2008-12-12 | 2014-12-30 | Uop Llc | Production of diesel fuel from biorenewable feedstocks using non-flashing quench liquid |
| US8471079B2 (en) * | 2008-12-16 | 2013-06-25 | Uop Llc | Production of fuel from co-processing multiple renewable feedstocks |
| US8314274B2 (en) * | 2008-12-17 | 2012-11-20 | Uop Llc | Controlling cold flow properties of transportation fuels from renewable feedstocks |
| US8283506B2 (en) * | 2008-12-17 | 2012-10-09 | Uop Llc | Production of fuel from renewable feedstocks using a finishing reactor |
| US8850995B2 (en) | 2009-02-02 | 2014-10-07 | Deere & Company | Seeding machine with seed delivery system |
| US8671856B2 (en) | 2009-02-02 | 2014-03-18 | Deere & Company | Planting unit for a seeding machine having blocking member to control hand-off of seed from a seed meter to a seed delivery system |
| IN2012DN02440A (pt) * | 2009-09-24 | 2015-08-21 | Signa Chemistry Inc | |
| US8471081B2 (en) | 2009-12-28 | 2013-06-25 | Uop Llc | Production of diesel fuel from crude tall oil |
| FR2959749B1 (fr) | 2010-05-06 | 2012-06-01 | Inst Francais Du Petrole | Procede flexible de transformation de l'ethanol en distillats moyens. |
| US8850998B2 (en) | 2011-03-25 | 2014-10-07 | Deere & Company | Planting unit for a seeding machine having a seed meter and seed delivery system |
| US8900443B2 (en) | 2011-04-07 | 2014-12-02 | Uop Llc | Method for multi-staged hydroprocessing using quench liquid |
| WO2013170280A1 (en) * | 2012-05-11 | 2013-11-14 | The Petroleum Oil And Gas Corporation Of South Africa (Pty) Ltd | Conversion of alcohols to distillates |
| RU2510389C1 (ru) * | 2012-10-19 | 2014-03-27 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Московский государственный университет тонких химических технологий имени М.В. Ломоносова" (МИТХТ им. М.В. Ломоносова) | Способ получения реактивного топлива из биоэтанола |
| WO2014154803A1 (en) | 2013-03-28 | 2014-10-02 | Bp P.L.C. | Production of middle distillate hydrocarbon composition |
| US9732283B2 (en) | 2014-12-26 | 2017-08-15 | Phillips 66 Company | System for integrated catalytic cracking with ethanol conversion to fuel |
| EP3307853B1 (en) * | 2015-06-12 | 2020-11-11 | Vertimass, LLC | Systems and methods for reducing resource consumption in production of alcohol fuel by conversion to hydrocarbon fuels |
| EP4038040A4 (en) | 2019-09-30 | 2024-01-10 | GEVO, Inc. | SIMULTANEOUS DEHYDRATION, DIMERIZATION AND METATHESIS OF C2-C5 ALCOHOLS |
| WO2024091452A1 (en) | 2022-10-27 | 2024-05-02 | Gevo, Inc. | Processes for catalytic conversion of c1-c5 alcohols to c2-c5 olefin mixtures |
| MX2023012412A (es) | 2021-04-23 | 2023-10-31 | Gevo Inc | Sistemas y procesos para conversión catalítica de alcoholes c1-c5 a mezclas olefínicas c2-c5. |
| AU2022340452A1 (en) | 2021-08-31 | 2024-03-07 | Swedish Biofuels Ab | Method for producing motor fuel from ethanol |
| PT4141090T (pt) * | 2021-08-31 | 2023-11-02 | Swedish Biofuels Ab | Método para produzir combustível para motores a partir de etanol |
| US11752476B1 (en) | 2023-03-28 | 2023-09-12 | Phillips 66 Company | Automated tank mixing |
| US11845042B1 (en) | 2023-03-28 | 2023-12-19 | Phillips 66 Company | Automated tank mixing |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3441498A (en) * | 1967-03-15 | 1969-04-29 | Atlantic Richfield Co | Hydrogenation method and apparatus |
| US4016218A (en) * | 1975-05-29 | 1977-04-05 | Mobil Oil Corporation | Alkylation in presence of thermally modified crystalline aluminosilicate catalyst |
| WO1981000062A1 (en) * | 1979-07-09 | 1981-01-22 | Commw Scient Ind Res Org | Zeolite catalysts |
| US4467133A (en) * | 1982-06-21 | 1984-08-21 | Mobil Oil Corporation | Conversion of alcohols and ethers to distillate range hydrocarbons |
| US4579999A (en) * | 1985-01-17 | 1986-04-01 | Mobil Oil Corporation | Multistage process for converting oxygenates to liquid hydrocarbons with aliphatic recycle |
| DE3838710A1 (de) * | 1988-11-15 | 1990-05-17 | Sued Chemie Ag | Katalysator auf der basis von kristallinen alumosilikaten |
| US5051386A (en) * | 1990-05-23 | 1991-09-24 | Union Oil Company Of California | Silica-alumina catalyst containing phosphorus |
| IT1265320B1 (it) * | 1993-12-22 | 1996-10-31 | Eniricerche Spa | Procedimento per la preparazione di silico-allumine amorfe cataliticamente attive |
| US6110879A (en) * | 1998-10-15 | 2000-08-29 | Chevron U.S.A. Inc. | Automatic transmission fluid composition |
| US6372949B1 (en) * | 1999-10-15 | 2002-04-16 | Mobil Oil Corporation | Single stage process for converting oxygenates to gasoline and distillate in the presence of undimensional ten member ring zeolite |
| EP1410844A1 (en) * | 2002-10-15 | 2004-04-21 | Centre National De La Recherche Scientifique (Cnrs) | Silicon-based porous catalytic system for oligomerising light olefins |
| US6872685B2 (en) * | 2002-11-08 | 2005-03-29 | Chevron U.S.A. Inc. | Method for preparing a highly homogeneous amorphous silica-alumina composition |
| US7211238B2 (en) * | 2003-03-12 | 2007-05-01 | Abb Lummus Global Inc. | Mesoporous aluminum oxide, preparation and use thereof |
| US7452838B2 (en) * | 2004-12-22 | 2008-11-18 | Exxonmobil Chemical Patents Inc. | Controlling temperature in catalyst regenerators |
-
2006
- 2006-05-30 FR FR0604928A patent/FR2901804B1/fr active Active
-
2007
- 2007-05-07 PL PL07290583T patent/PL1862528T3/pl unknown
- 2007-05-07 EP EP07290583A patent/EP1862528B1/fr active Active
- 2007-05-07 AT AT07290583T patent/ATE530623T1/de active
- 2007-05-07 DK DK07290583.9T patent/DK1862528T3/da active
- 2007-05-07 ES ES07290583T patent/ES2373923T3/es active Active
- 2007-05-10 ZA ZA200703781A patent/ZA200703781B/xx unknown
- 2007-05-28 MY MYPI20070836A patent/MY145212A/en unknown
- 2007-05-29 US US11/754,596 patent/US7994377B2/en active Active
- 2007-05-30 BR BRPI0702604A patent/BRPI0702604B1/pt active IP Right Grant
-
2011
- 2011-08-08 US US13/205,501 patent/US8552241B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| MY145212A (en) | 2012-01-13 |
| US8552241B2 (en) | 2013-10-08 |
| FR2901804B1 (fr) | 2012-08-31 |
| US7994377B2 (en) | 2011-08-09 |
| ZA200703781B (en) | 2010-05-26 |
| PL1862528T3 (pl) | 2012-03-30 |
| EP1862528B1 (fr) | 2011-10-26 |
| BRPI0702604B1 (pt) | 2017-03-21 |
| ATE530623T1 (de) | 2011-11-15 |
| ES2373923T3 (es) | 2012-02-10 |
| US20070287873A1 (en) | 2007-12-13 |
| EP1862528A1 (fr) | 2007-12-05 |
| DK1862528T3 (da) | 2012-01-09 |
| FR2901804A1 (fr) | 2007-12-07 |
| US20110295046A1 (en) | 2011-12-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
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