BRPI0703617A2 - reator para a preparaÇço de cianeto de hidrogÊnio pelo processo de andrussow - Google Patents

reator para a preparaÇço de cianeto de hidrogÊnio pelo processo de andrussow

Info

Publication number
BRPI0703617A2
BRPI0703617A2 BRPI0703617-5A BRPI0703617A BRPI0703617A2 BR PI0703617 A2 BRPI0703617 A2 BR PI0703617A2 BR PI0703617 A BRPI0703617 A BR PI0703617A BR PI0703617 A2 BRPI0703617 A2 BR PI0703617A2
Authority
BR
Brazil
Prior art keywords
reactor
preparation
hydrogen cyanide
andrussow process
gas inlet
Prior art date
Application number
BRPI0703617-5A
Other languages
English (en)
Inventor
Thomas Schaefer
Robert Weber
Udo Gropp
Thomas Mertz
Original Assignee
Roehm Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Roehm Gmbh filed Critical Roehm Gmbh
Publication of BRPI0703617A2 publication Critical patent/BRPI0703617A2/pt
Publication of BRPI0703617B1 publication Critical patent/BRPI0703617B1/pt

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J12/00Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor
    • B01J12/007Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor in the presence of catalytically active bodies, e.g. porous plates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/008Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
    • B01J8/009Membranes, e.g. feeding or removing reactants or products to or from the catalyst bed through a membrane
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0242Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
    • B01J8/025Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical in a cylindrical shaped bed
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0285Heating or cooling the reactor
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01CAMMONIA; CYANOGEN; COMPOUNDS THEREOF
    • C01C3/00Cyanogen; Compounds thereof
    • C01C3/02Preparation, separation or purification of hydrogen cyanide
    • C01C3/0208Preparation in gaseous phase
    • C01C3/0212Preparation in gaseous phase from hydrocarbons and ammonia in the presence of oxygen, e.g. the Andrussow-process
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01CAMMONIA; CYANOGEN; COMPOUNDS THEREOF
    • C01C3/00Cyanogen; Compounds thereof
    • C01C3/02Preparation, separation or purification of hydrogen cyanide
    • C01C3/0208Preparation in gaseous phase
    • C01C3/0212Preparation in gaseous phase from hydrocarbons and ammonia in the presence of oxygen, e.g. the Andrussow-process
    • C01C3/022Apparatus therefor
    • C01C3/0225Apparatus therefor characterised by the synthesis reactor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/00106Controlling the temperature by indirect heat exchange
    • B01J2208/00168Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
    • B01J2208/00194Tubes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008Controlling the process
    • B01J2208/00017Controlling the temperature
    • B01J2208/0053Controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796Details of the reactor or of the particulate material
    • B01J2208/00823Mixing elements
    • B01J2208/00831Stationary elements
    • B01J2208/00849Stationary elements outside the bed, e.g. baffles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00796Details of the reactor or of the particulate material
    • B01J2208/00884Means for supporting the bed of particles, e.g. grids, bars, perforated plates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/00074Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00076Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
    • B01J2219/00081Tubes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00051Controlling the temperature
    • B01J2219/00159Controlling the temperature controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Catalysts (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

REATOR PARA A PREPARAÇçO DE CIANETO DE HIDROGÊNIO PELO PROCESSO DE ANDRUSSOW. A presente invenção refere-se a um reator (1) para a preparação de cianeto de hidrogênio pelo processo de Andrussow, que compreende um recipiente do reator (2), pelo menos uma entrada de gás (3) que se abre para uma região de entrada de gás (4), uma saída para os produtos da reação (5) e um catalisador (6), em que são fornecidos pelo menos um elemento de misturação (7) e pelo menos uma camada intermediária permeável a gás (8) dentro do recipiente do reator (2) entre a região de entrada de gás (4) e o catalisador (6), o elemento de misturação (7) estando disposto entre a região de entrada de gás (4) e a camada intermediária permeável a gás (8). A presente invenção também se refere a um processo para a preparação de HCN, em que é usado um reator da invenção.
BRPI0703617-5A 2007-07-23 2007-10-04 Reactor and process for the preparation of hydrogen cyanide by the andrussow process BRPI0703617B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102007034715A DE102007034715A1 (de) 2007-07-23 2007-07-23 Reaktor zur Herstellung von Cyanwasserstoff nach dem Andrussow-Verfahren
DE102007034715.6 2007-07-23

Publications (2)

Publication Number Publication Date
BRPI0703617A2 true BRPI0703617A2 (pt) 2009-03-10
BRPI0703617B1 BRPI0703617B1 (pt) 2017-06-13

Family

ID=39596817

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0703617-5A BRPI0703617B1 (pt) 2007-07-23 2007-10-04 Reactor and process for the preparation of hydrogen cyanide by the andrussow process

Country Status (16)

Country Link
US (1) US8802020B2 (pt)
EP (1) EP2170499B1 (pt)
JP (1) JP5656631B2 (pt)
KR (1) KR101527240B1 (pt)
CN (1) CN101353173B (pt)
AU (1) AU2008280378B2 (pt)
BR (1) BRPI0703617B1 (pt)
CA (1) CA2694236C (pt)
DE (1) DE102007034715A1 (pt)
EG (1) EG25565A (pt)
ES (1) ES2614277T3 (pt)
MY (1) MY154793A (pt)
RU (1) RU2470860C2 (pt)
TW (1) TWI505991B (pt)
WO (1) WO2009013035A1 (pt)
ZA (1) ZA201000527B (pt)

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CN113816398B (zh) * 2012-12-18 2023-11-10 英威达纺织(英国)有限公司 安德卢梭法中氨比例的变化
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EP3339289A1 (de) 2016-12-21 2018-06-27 Evonik Degussa GmbH Verfahren zur herstellung von methionin
WO2019020705A1 (en) * 2017-07-27 2019-01-31 Haldor Topsøe A/S CATALYTIC REACTOR COMPRISING A FIBROUS CATALYST PARTICLE CARRIER
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CN111533136A (zh) * 2020-07-03 2020-08-14 重庆奕翔化工有限公司 一种氢氰酸的生产系统及工艺
CN115371047A (zh) * 2021-05-19 2022-11-22 武汉氢阳能源有限公司 一种新型防回火氢气催化燃烧反应器
CN113267076B (zh) * 2021-06-04 2022-08-23 四川能投建工集团设计研究院有限公司 一种氢氰酸氧化反应器及其管板冷却结构
CN117205848B (zh) * 2023-11-07 2024-12-06 上海氢田新材料科技有限公司 一种基于气相分解法制备纳米硅的系统及方法
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Also Published As

Publication number Publication date
RU2470860C2 (ru) 2012-12-27
ZA201000527B (en) 2010-10-27
US20110171101A1 (en) 2011-07-14
AU2008280378B2 (en) 2013-11-28
CA2694236A1 (en) 2009-01-29
JP2010534182A (ja) 2010-11-04
CA2694236C (en) 2015-11-10
BRPI0703617B1 (pt) 2017-06-13
AU2008280378A1 (en) 2009-01-29
KR20100051622A (ko) 2010-05-17
CN101353173A (zh) 2009-01-28
RU2010105920A (ru) 2011-08-27
KR101527240B1 (ko) 2015-06-09
CN101353173B (zh) 2014-08-13
EG25565A (en) 2012-02-27
US8802020B2 (en) 2014-08-12
JP5656631B2 (ja) 2015-01-21
WO2009013035A1 (de) 2009-01-29
DE102007034715A1 (de) 2009-01-29
ES2614277T3 (es) 2017-05-30
EP2170499B1 (de) 2016-11-16
MY154793A (en) 2015-07-31
TWI505991B (zh) 2015-11-01
EP2170499A1 (de) 2010-04-07
TW200922874A (en) 2009-06-01

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B03A Publication of a patent application or of a certificate of addition of invention [chapter 3.1 patent gazette]
B25D Requested change of name of applicant approved

Owner name: EVONIK ROEHM GMBH (DE)

Free format text: NOME ALTERADO DE: ROEHM GMBH

B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]
B25D Requested change of name of applicant approved
B25G Requested change of headquarter approved
B25A Requested transfer of rights approved
B25D Requested change of name of applicant approved