BRPI0703617A2 - reator para a preparaÇço de cianeto de hidrogÊnio pelo processo de andrussow - Google Patents
reator para a preparaÇço de cianeto de hidrogÊnio pelo processo de andrussowInfo
- Publication number
- BRPI0703617A2 BRPI0703617A2 BRPI0703617-5A BRPI0703617A BRPI0703617A2 BR PI0703617 A2 BRPI0703617 A2 BR PI0703617A2 BR PI0703617 A BRPI0703617 A BR PI0703617A BR PI0703617 A2 BRPI0703617 A2 BR PI0703617A2
- Authority
- BR
- Brazil
- Prior art keywords
- reactor
- preparation
- hydrogen cyanide
- andrussow process
- gas inlet
- Prior art date
Links
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 title abstract 7
- 238000002360 preparation method Methods 0.000 title abstract 4
- 238000006189 Andrussov oxidation reaction Methods 0.000 title abstract 3
- 239000007789 gas Substances 0.000 abstract 6
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000007795 chemical reaction product Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J12/00—Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor
- B01J12/007—Chemical processes in general for reacting gaseous media with gaseous media; Apparatus specially adapted therefor in the presence of catalytically active bodies, e.g. porous plates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/008—Details of the reactor or of the particulate material; Processes to increase or to retard the rate of reaction
- B01J8/009—Membranes, e.g. feeding or removing reactants or products to or from the catalyst bed through a membrane
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0242—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
- B01J8/025—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical in a cylindrical shaped bed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/0285—Heating or cooling the reactor
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C3/00—Cyanogen; Compounds thereof
- C01C3/02—Preparation, separation or purification of hydrogen cyanide
- C01C3/0208—Preparation in gaseous phase
- C01C3/0212—Preparation in gaseous phase from hydrocarbons and ammonia in the presence of oxygen, e.g. the Andrussow-process
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C3/00—Cyanogen; Compounds thereof
- C01C3/02—Preparation, separation or purification of hydrogen cyanide
- C01C3/0208—Preparation in gaseous phase
- C01C3/0212—Preparation in gaseous phase from hydrocarbons and ammonia in the presence of oxygen, e.g. the Andrussow-process
- C01C3/022—Apparatus therefor
- C01C3/0225—Apparatus therefor characterised by the synthesis reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00194—Tubes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/0053—Controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00796—Details of the reactor or of the particulate material
- B01J2208/00823—Mixing elements
- B01J2208/00831—Stationary elements
- B01J2208/00849—Stationary elements outside the bed, e.g. baffles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00796—Details of the reactor or of the particulate material
- B01J2208/00884—Means for supporting the bed of particles, e.g. grids, bars, perforated plates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
- B01J2219/00076—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
- B01J2219/00081—Tubes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
- B01J2219/00159—Controlling the temperature controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Fluid Mechanics (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Catalysts (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
REATOR PARA A PREPARAÇçO DE CIANETO DE HIDROGÊNIO PELO PROCESSO DE ANDRUSSOW. A presente invenção refere-se a um reator (1) para a preparação de cianeto de hidrogênio pelo processo de Andrussow, que compreende um recipiente do reator (2), pelo menos uma entrada de gás (3) que se abre para uma região de entrada de gás (4), uma saída para os produtos da reação (5) e um catalisador (6), em que são fornecidos pelo menos um elemento de misturação (7) e pelo menos uma camada intermediária permeável a gás (8) dentro do recipiente do reator (2) entre a região de entrada de gás (4) e o catalisador (6), o elemento de misturação (7) estando disposto entre a região de entrada de gás (4) e a camada intermediária permeável a gás (8). A presente invenção também se refere a um processo para a preparação de HCN, em que é usado um reator da invenção.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102007034715A DE102007034715A1 (de) | 2007-07-23 | 2007-07-23 | Reaktor zur Herstellung von Cyanwasserstoff nach dem Andrussow-Verfahren |
| DE102007034715.6 | 2007-07-23 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0703617A2 true BRPI0703617A2 (pt) | 2009-03-10 |
| BRPI0703617B1 BRPI0703617B1 (pt) | 2017-06-13 |
Family
ID=39596817
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0703617-5A BRPI0703617B1 (pt) | 2007-07-23 | 2007-10-04 | Reactor and process for the preparation of hydrogen cyanide by the andrussow process |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US8802020B2 (pt) |
| EP (1) | EP2170499B1 (pt) |
| JP (1) | JP5656631B2 (pt) |
| KR (1) | KR101527240B1 (pt) |
| CN (1) | CN101353173B (pt) |
| AU (1) | AU2008280378B2 (pt) |
| BR (1) | BRPI0703617B1 (pt) |
| CA (1) | CA2694236C (pt) |
| DE (1) | DE102007034715A1 (pt) |
| EG (1) | EG25565A (pt) |
| ES (1) | ES2614277T3 (pt) |
| MY (1) | MY154793A (pt) |
| RU (1) | RU2470860C2 (pt) |
| TW (1) | TWI505991B (pt) |
| WO (1) | WO2009013035A1 (pt) |
| ZA (1) | ZA201000527B (pt) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2389241B1 (de) * | 2009-01-21 | 2018-06-06 | Basf Se | Rohrbündelreaktor und verfahren für unkatalysierte oder homogenkatalysierte reaktionen |
| SG192908A1 (en) | 2011-02-23 | 2013-09-30 | Evonik Degussa Gmbh | Storage-stable 2-hydroxy-4-(methylthio) butyric acid nitrile |
| EP2678312B1 (de) | 2011-02-23 | 2017-10-11 | Evonik Degussa GmbH | Verfahren zur herstellung von 2-hydroxy-4-(methylthio)buttersäurenitril aus 3-(methylthio)propanal und cyanwasserstoff |
| EP2644264A1 (de) | 2012-03-28 | 2013-10-02 | Aurotec GmbH | Druckreguliertes Mehrreaktorsystem |
| EP2644263A1 (de) | 2012-03-28 | 2013-10-02 | Aurotec GmbH | Druckgeregelter Reaktor |
| EP2703076B1 (de) * | 2012-08-29 | 2016-04-27 | Wolfgang Gerlinger | Reaktor mit einer oder mehreren zuführleitungen und einer gleichverteilungseinrichtung für einen oder mehrere fluidströme |
| CN103864113B (zh) * | 2012-12-18 | 2018-01-19 | 英威达纺织(英国)有限公司 | 使用转化器生产氰化氢的方法 |
| EP2935094A1 (en) * | 2012-12-18 | 2015-10-28 | Invista Technologies S.à.r.l. | Apparatus and method for hydrogen recovery in an andrussow process |
| WO2014099567A1 (en) | 2012-12-18 | 2014-06-26 | Invista Technologies S.A R. L. | Processes for producing hydrogen cyanide using static mixer |
| WO2014099568A1 (en) * | 2012-12-18 | 2014-06-26 | Invista Technologies S.A.R.L. | Enhanced methane control for andrussow process |
| WO2014099605A1 (en) * | 2012-12-18 | 2014-06-26 | Invista Technologies S.A R.L. | Process for producing hydrogen cyanide using flow straightener |
| JP2016508112A (ja) * | 2012-12-18 | 2016-03-17 | インヴィスタ テクノロジーズ エスアエルエル | アンドリュッソープロセスにおける反応器のスキーム |
| CN113816398B (zh) * | 2012-12-18 | 2023-11-10 | 英威达纺织(英国)有限公司 | 安德卢梭法中氨比例的变化 |
| WO2014099601A1 (en) * | 2012-12-18 | 2014-06-26 | Invista Technologies S.A.R.L. | Process for stabilizing heat exchanger tubes in andrussow process |
| WO2014099592A1 (en) * | 2012-12-18 | 2014-06-26 | Invista Technologies S.A.R.L. | Processes for producing hydrogen cyanide using catalyst bed |
| CN103864109A (zh) * | 2012-12-18 | 2014-06-18 | 因温斯特技术公司 | 用于安德卢梭法中的再循环的系统和方法 |
| FR3008626B1 (fr) | 2013-07-19 | 2015-08-07 | Arkema France | Reacteur pour preparer du cyanure d'hydrogene par le procede d'andrussow, equipement comprenant ledit reacteur et procede utilisant un tel equipement |
| FR3008692B1 (fr) * | 2013-07-19 | 2016-12-23 | Arkema France | Installation et procede pour la preparation de cyanure d'hydrogene |
| EP3475248B1 (de) | 2016-06-27 | 2020-08-05 | Evonik Operations GmbH | Dipeptidhaltige granulate |
| EP3339289A1 (de) | 2016-12-21 | 2018-06-27 | Evonik Degussa GmbH | Verfahren zur herstellung von methionin |
| WO2019020705A1 (en) * | 2017-07-27 | 2019-01-31 | Haldor Topsøe A/S | CATALYTIC REACTOR COMPRISING A FIBROUS CATALYST PARTICLE CARRIER |
| EP3461803A1 (de) | 2017-10-02 | 2019-04-03 | Evonik Degussa GmbH | Herstellverfahren für dipeptidhaltige granulate |
| SG11202106150XA (en) | 2018-12-14 | 2021-07-29 | Evonik Operations Gmbh | Method for producing methionine |
| CN111533136A (zh) * | 2020-07-03 | 2020-08-14 | 重庆奕翔化工有限公司 | 一种氢氰酸的生产系统及工艺 |
| CN115371047A (zh) * | 2021-05-19 | 2022-11-22 | 武汉氢阳能源有限公司 | 一种新型防回火氢气催化燃烧反应器 |
| CN113267076B (zh) * | 2021-06-04 | 2022-08-23 | 四川能投建工集团设计研究院有限公司 | 一种氢氰酸氧化反应器及其管板冷却结构 |
| CN117205848B (zh) * | 2023-11-07 | 2024-12-06 | 上海氢田新材料科技有限公司 | 一种基于气相分解法制备纳米硅的系统及方法 |
| CN120268332A (zh) * | 2024-01-05 | 2025-07-08 | 中国天辰工程有限公司 | 一种制备氰化氢的反应器 |
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| US4015A (en) * | 1845-04-26 | Hand-loom for weaving figured fabrics | ||
| US2011A (en) * | 1841-03-18 | Appabatxts for piling saws | ||
| US1934838A (en) * | 1930-04-14 | 1933-11-14 | Ig Farbenindustrie Ag | Production of hydrocyanic acid |
| DE549055C (de) | 1930-04-15 | 1932-04-22 | I G Farbenindustrie Akt Ges | Verfahren zur Herstellung von Cyanwasserstoff |
| US2387577A (en) * | 1943-09-20 | 1945-10-23 | Du Pont | Production of hydrocyanic acid |
| US2404574A (en) * | 1943-11-30 | 1946-07-23 | Us Ind Chemicals Inc | Apparatus for catalytic operations |
| US2782107A (en) * | 1953-01-14 | 1957-02-19 | Du Pont | Reactor for making hydrogen cyanide |
| US2750266A (en) * | 1954-06-25 | 1956-06-12 | Chemical Construction Corp | Catalytic reactor for hydrocyanic acid production |
| US2906604A (en) * | 1955-08-01 | 1959-09-29 | Sueddeutsche Kalkstickstoff | Method of producing hydrogen cyanide |
| US2893852A (en) * | 1956-04-16 | 1959-07-07 | American Oil Co | Fixed bed reformer vapor distributor |
| US3073685A (en) * | 1960-06-15 | 1963-01-15 | Monsanto Chemicals | Gauze catalyst support |
| US3215495A (en) * | 1962-01-23 | 1965-11-02 | Du Pont | Apparatus and process for preparing hydrogen cyanide |
| US3505030A (en) * | 1965-11-16 | 1970-04-07 | Du Pont | Composite articles of manufacture and apparatus for their use |
| US3545939A (en) * | 1968-11-08 | 1970-12-08 | Union Carbide Corp | Catalyst system for making hydrogen cyanide |
| US4128622A (en) * | 1976-08-27 | 1978-12-05 | E. I. Du Pont De Nemours And Company | Process for producing hydrogen cyanide |
| DE2913925C2 (de) * | 1979-04-06 | 1982-06-03 | Degussa Ag, 6000 Frankfurt | Verfahren zur Herstellung von Cyanwasserstoff |
| US5431984A (en) | 1990-12-11 | 1995-07-11 | Avco Corporation | Composite preforms with groves for fibers and groves for off-gassing |
| US5242882A (en) * | 1992-05-11 | 1993-09-07 | Scientific Design Company, Inc. | Catalyst for the production of nitric acid by oxidation of ammonia |
| US6073467A (en) * | 1994-04-06 | 2000-06-13 | Degussa Aktiengesellschaft | Catalyst gauzes for gaseous reactions |
| DE4411774C1 (de) | 1994-04-06 | 1995-08-17 | Degussa | Katalysatornetze für Gasreaktionen |
| EP0680767A1 (en) | 1994-05-06 | 1995-11-08 | Nardino Righi | Non-reusable safety syringe |
| DE69613581T2 (de) | 1995-09-01 | 2002-04-25 | Ineos Acrylics Uk Ltd., Southampton | Verfahren und vorrichtung zur herstellung von cyanwasserstoff |
| CN1112961C (zh) * | 1997-07-03 | 2003-07-02 | 纳幕尔杜邦公司 | 感应加热的催化反应器 |
| ID24281A (id) * | 1997-07-03 | 2000-07-13 | Du Pont | Metoda pembakaran suatu reaksi kimia secara induksi |
| AU1842899A (en) * | 1998-02-25 | 1999-09-09 | African Oxygen Limited | Reactor for hydrogen cyanide gas production |
| US6221327B1 (en) * | 1998-05-15 | 2001-04-24 | Rohm And Haas Company | Catalyst system using flow-through radiation shielding and a process for producing hydrogen cyanide using the same |
| AU4090600A (en) * | 1999-06-30 | 2001-01-04 | Rohm And Haas Company | High performance heat exchangers |
| US6579510B2 (en) * | 1999-07-30 | 2003-06-17 | Alfred E. Keller | SPOX-enhanced process for production of synthesis gas |
| RU2191746C2 (ru) * | 2000-01-27 | 2002-10-27 | Открытое акционерное общество "Волжский Оргсинтез" | Способ получения цианистого водорода |
| WO2001080988A2 (en) | 2000-04-25 | 2001-11-01 | E.I. Dupont De Nemours And Company | Catalyst and process for gas phase reactions |
| FR2812221B1 (fr) | 2000-07-28 | 2003-04-04 | Butachimie | Nouveau dispositif catalytique pour la mise en oeuvre d'une reaction en milieu gazeux a haute temperature |
| JP3913469B2 (ja) | 2000-12-27 | 2007-05-09 | 株式会社コロナ | ふろ装置のリモコン装置 |
| ES2229130T5 (es) | 2001-02-08 | 2009-01-16 | UMICORE AG & CO. KG | Gasas de catalizador tridimensionales tricotadas en dos capas. |
| EA007052B1 (ru) * | 2002-11-08 | 2006-06-30 | МОРТЕН МЮЛЛЕР ЛТД., АпС | Смесительное устройство для двухфазного потока в каталитическом реакторе |
| FR2850372B1 (fr) | 2003-01-23 | 2006-06-09 | Inst Francais Du Petrole | Nouveau reacteur d'oxydation partielle |
| US8133458B2 (en) * | 2007-03-01 | 2012-03-13 | Eicproc As | Reactor and the use thereof for producing cyanides |
-
2007
- 2007-07-23 DE DE102007034715A patent/DE102007034715A1/de not_active Withdrawn
- 2007-09-25 CN CN200710153798.3A patent/CN101353173B/zh active Active
- 2007-10-04 BR BRPI0703617-5A patent/BRPI0703617B1/pt active IP Right Grant
-
2008
- 2008-05-09 AU AU2008280378A patent/AU2008280378B2/en active Active
- 2008-05-09 JP JP2010517331A patent/JP5656631B2/ja active Active
- 2008-05-09 EP EP08750221.7A patent/EP2170499B1/de active Active
- 2008-05-09 CA CA2694236A patent/CA2694236C/en active Active
- 2008-05-09 KR KR1020107001544A patent/KR101527240B1/ko active Active
- 2008-05-09 US US12/668,957 patent/US8802020B2/en active Active
- 2008-05-09 MY MYPI20094775A patent/MY154793A/en unknown
- 2008-05-09 ES ES08750221.7T patent/ES2614277T3/es active Active
- 2008-05-09 RU RU2010105920/02A patent/RU2470860C2/ru active
- 2008-05-09 WO PCT/EP2008/055730 patent/WO2009013035A1/de not_active Ceased
- 2008-07-21 TW TW097127645A patent/TWI505991B/zh active
-
2010
- 2010-01-21 EG EG2010010113A patent/EG25565A/xx active
- 2010-01-22 ZA ZA201000527A patent/ZA201000527B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| RU2470860C2 (ru) | 2012-12-27 |
| ZA201000527B (en) | 2010-10-27 |
| US20110171101A1 (en) | 2011-07-14 |
| AU2008280378B2 (en) | 2013-11-28 |
| CA2694236A1 (en) | 2009-01-29 |
| JP2010534182A (ja) | 2010-11-04 |
| CA2694236C (en) | 2015-11-10 |
| BRPI0703617B1 (pt) | 2017-06-13 |
| AU2008280378A1 (en) | 2009-01-29 |
| KR20100051622A (ko) | 2010-05-17 |
| CN101353173A (zh) | 2009-01-28 |
| RU2010105920A (ru) | 2011-08-27 |
| KR101527240B1 (ko) | 2015-06-09 |
| CN101353173B (zh) | 2014-08-13 |
| EG25565A (en) | 2012-02-27 |
| US8802020B2 (en) | 2014-08-12 |
| JP5656631B2 (ja) | 2015-01-21 |
| WO2009013035A1 (de) | 2009-01-29 |
| DE102007034715A1 (de) | 2009-01-29 |
| ES2614277T3 (es) | 2017-05-30 |
| EP2170499B1 (de) | 2016-11-16 |
| MY154793A (en) | 2015-07-31 |
| TWI505991B (zh) | 2015-11-01 |
| EP2170499A1 (de) | 2010-04-07 |
| TW200922874A (en) | 2009-06-01 |
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