BRPI0705939A2 - processo para a produção de catalisadores hìbridos para a sìntese de fischer-tropsch e catalisador hìbrido produzido de acordo com o processo - Google Patents

processo para a produção de catalisadores hìbridos para a sìntese de fischer-tropsch e catalisador hìbrido produzido de acordo com o processo

Info

Publication number
BRPI0705939A2
BRPI0705939A2 BRPI0705939-6A BRPI0705939A BRPI0705939A2 BR PI0705939 A2 BRPI0705939 A2 BR PI0705939A2 BR PI0705939 A BRPI0705939 A BR PI0705939A BR PI0705939 A2 BRPI0705939 A2 BR PI0705939A2
Authority
BR
Brazil
Prior art keywords
hybrid
fischer
catalysts
tropsch synthesis
production
Prior art date
Application number
BRPI0705939-6A
Other languages
English (en)
Inventor
Figueiredo Costa Alexandre De
Original Assignee
Petroleo Brasileiro Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Petroleo Brasileiro Sa filed Critical Petroleo Brasileiro Sa
Priority to BRPI0705939-6A priority Critical patent/BRPI0705939A2/pt
Priority to ARP080103783A priority patent/AR068146A1/es
Priority to EP08253534A priority patent/EP2055380A1/en
Priority to US12/260,123 priority patent/US8097555B2/en
Publication of BRPI0705939A2 publication Critical patent/BRPI0705939A2/pt

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/19—Catalysts containing parts with different compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6527—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913—Cobalt and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • B01J29/068—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/12—Noble metals
    • B01J29/126—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B01J29/7415—Zeolite Beta
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/334—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing molecular sieve catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/03—Catalysts comprising molecular sieves not having base-exchange properties
    • B01J29/0308—Mesoporous materials not having base exchange properties, e.g. Si-MCM-41
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

PROCESSO PARA A PRODUçãO DE CATALISADORES HìBRIDOS PARA A SìNTESE DE FISCHER-TROPSCH E CATALISADOR HìBRIDO PRODUZIDO DE ACORDO COM O PROCESSO. Processo para a produção de catalisadores híbridos formados pela mistura de dois catalisadores; um ativo na síntese de Fischer-Tropsch, e outro bifuncional. O catalisador híbrido assim formado é ativo tanto em reações de hidrocraqueamento, quanto de hidroisomerização. A presente invenção proporciona ainda a obtenção de um catalisador híbrido e a sua aplicação em conjunto com os catalisadores de FT nas reações de síntese de Fischer-Tropsch. O catalisador híbrido da presente invenção é capaz de produzir, em condições tipicamente como as utilizadas na síntese de Fischer-Tropsch, hidrocarbonetos ramificados nas diversas faixas relativas aos produtos (por exemplo, nafta e diesel), e reduz ou mesmo ainda elimina a necessidade de uma etapa posterior de hidrotratamento nas reações de síntese. A utilização dos catalisadores híbridos da presente invenção prolonga a eficiência operacional e a vida útil dos catalisadores convencionais de síntese de Fischer-Tropsch, reduzindo substancialmente o encapsulamento de suas partículas com as ceras produzidas nas reações de hidroprocessamento.
BRPI0705939-6A 2007-10-29 2007-10-29 processo para a produção de catalisadores hìbridos para a sìntese de fischer-tropsch e catalisador hìbrido produzido de acordo com o processo BRPI0705939A2 (pt)

Priority Applications (4)

Application Number Priority Date Filing Date Title
BRPI0705939-6A BRPI0705939A2 (pt) 2007-10-29 2007-10-29 processo para a produção de catalisadores hìbridos para a sìntese de fischer-tropsch e catalisador hìbrido produzido de acordo com o processo
ARP080103783A AR068146A1 (es) 2007-10-29 2008-08-29 Procedimiento para la produccion de catalizadores hibridos para la sintesis de fischer-tropsch y catalizador hibrido producido de acuerdo con este procedimiento
EP08253534A EP2055380A1 (en) 2007-10-29 2008-10-29 Process for the production of hybrid catalysts for Fischer-Tropsch synthesis and hybrid catalysts produced according to said process
US12/260,123 US8097555B2 (en) 2007-10-29 2008-10-29 Process for the production of hybrid catalysts for fischer-tropsch synthesis and hybrid catalyst produced according to said process

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
BRPI0705939-6A BRPI0705939A2 (pt) 2007-10-29 2007-10-29 processo para a produção de catalisadores hìbridos para a sìntese de fischer-tropsch e catalisador hìbrido produzido de acordo com o processo

Publications (1)

Publication Number Publication Date
BRPI0705939A2 true BRPI0705939A2 (pt) 2009-06-23

Family

ID=40328923

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0705939-6A BRPI0705939A2 (pt) 2007-10-29 2007-10-29 processo para a produção de catalisadores hìbridos para a sìntese de fischer-tropsch e catalisador hìbrido produzido de acordo com o processo

Country Status (4)

Country Link
US (1) US8097555B2 (pt)
EP (1) EP2055380A1 (pt)
AR (1) AR068146A1 (pt)
BR (1) BRPI0705939A2 (pt)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20100312030A1 (en) * 2009-06-04 2010-12-09 Chevron U.S.A., Inc. Process of synthesis gas conversion to liquid fuels using synthesis gas conversion catalyst and noble metal-promoted acidic zeolite hydrocracking-hydroisomerization catalyst
US7825164B1 (en) * 2009-11-18 2010-11-02 Chevron U.S.A. Inc. Process of synthesis gas conversion to liquid fuels using mixture of synthesis gas conversion catalyst and dual functionality catalyst
US8481601B2 (en) 2010-11-23 2013-07-09 Chevron U.S.A. Inc. Process of synthesis gas conversion to liquid hydrocarbon mixtures using a catalyst system containing ruthenium and an acidic component
EP2893977B1 (en) * 2012-09-04 2019-07-03 University of Yamanashi Co-selective methanation catalyst
US20160160128A1 (en) * 2013-07-24 2016-06-09 Shell Oil Company Method for starting up a fischer tropsch process
CN103920496B (zh) * 2014-04-22 2015-11-18 武汉凯迪工程技术研究总院有限公司 介孔材料包覆式钴基费托合成催化剂及其制备方法
PT3166912T (pt) 2014-07-11 2021-02-16 Dow Global Technologies Llc Conversão de monóxido de carbono, dióxido de carbono ou uma combinação dos mesmos sobre um catalisador híbrido
US10066169B2 (en) * 2015-07-14 2018-09-04 Research & Business Foundation Sungkyunkwan University Mesoporous cobalt-metal oxide catalyst for Fischer-Tropsch synthesis reactions and a preparing method thereof
US10010870B2 (en) 2015-11-12 2018-07-03 Saudi Arabian Oil Company Synthesis of catalytic materials for metathesis and isomerization reactions and other catalytic applications via well controlled aerosol processing
US9969621B2 (en) * 2016-05-04 2018-05-15 Saudi Arabian Oil Company Methods for processing fumed metallic oxides
SG11202001238YA (en) 2017-08-17 2020-03-30 Saudi Arabian Oil Co Aerosol processing method for controlled coating of surface species to generate catalysts
CN109939728B (zh) * 2018-01-26 2020-08-14 中国科学院大连化学物理研究所 一种负载催化剂及合成气直接转化制低碳烯烃的方法
US11369950B2 (en) 2018-02-21 2022-06-28 Saudi Arabian Oil Company Multi-functional composite catalyst materials and methods of synthesizing the catalyst materials
EP3830219A1 (en) * 2018-07-27 2021-06-09 Gas Technology Institute Fluidized bed processes and catalyst systems for fischer-tropsch conversion
CN109225292B (zh) * 2018-10-10 2021-06-15 上海兖矿能源科技研发有限公司 高抗耐磨性浆态床费托合成铁基催化剂及制备方法和应用
US11033892B2 (en) 2019-01-24 2021-06-15 Saudi Arabian Oil Company Methods for reacting chemical streams with catalysts comprising silica, alumina, and tungsten
EP4168512A4 (en) * 2020-06-18 2024-07-03 University of Delaware HYDROCRACKING CATALYSTS AND USES THEREOF

Family Cites Families (56)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4304871A (en) * 1976-10-15 1981-12-08 Mobil Oil Corporation Conversion of synthesis gas to hydrocarbon mixtures utilizing a dual catalyst bed
US4192777A (en) * 1978-03-01 1980-03-11 Exxon Research & Engineering Co. Preparation and use of supported potassium (or rubidium)-Group VIII-metal cluster catalysts in CO/H2 Fischer-Tropsch synthesis reactions
US4154751A (en) * 1978-03-01 1979-05-15 Exxon Research & Engineering Co. Preparation and use of supported potassium (or rubidium)-Group VIII-metal cluster catalysts in CO/H2 Fischer-Tropsch synthesis reactions
NL8003313A (nl) * 1980-06-06 1982-01-04 Shell Int Research Werkwijze voor de bereiding van middeldestillaten.
US4463101A (en) * 1980-12-29 1984-07-31 Mobil Oil Corporation Catalyst for converting synthesis gas to high octane predominantly olefinic naphtha
CA1176228A (en) * 1981-05-18 1984-10-16 Minoru Koikeda Catalyst for the production of hydrocarbons from the synthesis gas
US4396539A (en) * 1981-08-14 1983-08-02 Sapienza Richard S Hydrocarbon synthesis catalyst and method of preparation
FR2513626A1 (fr) 1981-09-30 1983-04-01 Shell Int Research Procede pour la production d'hydrocarbures
US4605680A (en) * 1981-10-13 1986-08-12 Chevron Research Company Conversion of synthesis gas to diesel fuel and gasoline
US4471145A (en) * 1982-12-01 1984-09-11 Mobil Oil Corporation Process for syngas conversions to liquid hydrocarbon products utilizing zeolite Beta
US4523047A (en) * 1982-12-01 1985-06-11 Mobil Oil Corporation Process for syngas conversions to liquid hydrocarbon products utilizing ZSM-45 zeolite
US4522939A (en) 1983-05-31 1985-06-11 Shell Oil Company Preparation of catalyst for producing middle distillates from syngas
IN161735B (pt) * 1983-09-12 1988-01-30 Shell Int Research
US4652538A (en) * 1983-11-01 1987-03-24 Union Carbide Corporation Catalysts for conversion of syngas to liquid motor fuels
CA1240708A (en) * 1983-11-15 1988-08-16 Johannes K. Minderhoud Process for the preparation of hydrocarbons
NL8400608A (nl) 1984-02-28 1985-09-16 Shell Int Research Werkwijze voor de bereiding van koolwaterstoffen.
US4617283A (en) * 1984-06-27 1986-10-14 Union Carbide Corporation Catalyst for converting synthesis gas to liquid motor fuels
US4556645A (en) * 1984-06-27 1985-12-03 Union Carbide Corporation Enhanced catalyst for conversion of syngas to liquid motor fuels
US4568663A (en) * 1984-06-29 1986-02-04 Exxon Research And Engineering Co. Cobalt catalysts for the conversion of methanol to hydrocarbons and for Fischer-Tropsch synthesis
WO1986001743A1 (en) * 1984-09-12 1986-03-27 Commonwealth Scientific And Industrial Research Or Composite catalyst of ruthenium on zeolite and a group vi and/or group viii metal on refractory
EP0180269B1 (en) 1984-11-02 1990-06-27 Shell Internationale Researchmaatschappij B.V. Catalyst preparation
US4906671A (en) * 1985-08-29 1990-03-06 Mobil Oil Corporation Fischer-tropsch process
US4624967A (en) * 1985-12-06 1986-11-25 Exxon Research & Engineering Company Fe-Co catalyst slurry system for use in alpha olefin production
US4874733A (en) * 1987-07-13 1989-10-17 Uop Cobalt Fischer-Tropsch catalysts having improved selectivity
US4874732A (en) * 1987-07-13 1989-10-17 Uop Cobalt Fischer-Tropsch catalysts having improved selectivity
AU615698B2 (en) 1987-12-17 1991-10-10 Broken Hill Proprietary Company Limited, The Hydrocarbon processing
US5344849A (en) * 1990-10-31 1994-09-06 Canada Chemical Corporation Catalytic process for the production of hydrocarbons
GB9109747D0 (en) * 1991-05-07 1991-06-26 Shell Int Research A process for the production of isoparaffins
FR2676749B1 (fr) * 1991-05-21 1993-08-20 Inst Francais Du Petrole Procede d'hydroisomerisation de paraffines issues du procede fischer-tropsch a l'aide de catalyseurs a base de zeolithe h-y.
FR2676750B1 (fr) * 1991-05-21 1993-08-13 Inst Francais Du Petrole Procede d'hydrocraquage de paraffines issue du procede fischer-tropsch a l'aide de catalyseurs a base de zeolithe h-y.
US5187138A (en) * 1991-09-16 1993-02-16 Exxon Research And Engineering Company Silica modified hydroisomerization catalyst
US5780381A (en) * 1994-12-15 1998-07-14 Syncrude Technology Inc. Cobalt/molybdenum/zirconium catalyst for Fischer-Tropsch synthesis
US6117814A (en) 1998-02-10 2000-09-12 Exxon Research And Engineering Co. Titania catalysts their preparation and use in fischer-tropsch synthesis
US6365544B2 (en) * 1998-05-22 2002-04-02 Conoco Inc. Fischer-Tropsch processes and catalysts using fluorided alumina supports
BR9912641B1 (pt) 1998-08-04 2010-07-13 sólido microporoso deslaminado.
US6235677B1 (en) * 1998-08-20 2001-05-22 Conoco Inc. Fischer-Tropsch processes using xerogel and aerogel catalysts by destabilizing aqueous colloids
US6451864B1 (en) * 1999-08-17 2002-09-17 Battelle Memorial Institute Catalyst structure and method of Fischer-Tropsch synthesis
AU7756400A (en) 1999-10-12 2001-04-23 Exxon Research And Engineering Company Preparation of catalysts and use thereof for fischer-tropsch hydrocarbon synthesis
CN1436097A (zh) 2000-06-12 2003-08-13 萨索尔技术(控股)有限公司 钴催化剂
AU2002216754B2 (en) * 2000-07-03 2005-11-03 Conocophillips Company Fischer-tropsch processes and catalysts using aluminum borate supports
US6359018B1 (en) * 2000-10-27 2002-03-19 Chevron U.S.A. Inc Process for upflow fixed-bed hydroprocessing of fischer-tropsch wax
US7452844B2 (en) * 2001-05-08 2008-11-18 Süd-Chemie Inc High surface area, small crystallite size catalyst for Fischer-Tropsch synthesis
US6555725B1 (en) 2001-11-06 2003-04-29 Exxonmobil Research And Engineering Company In-situ hydroisomerization of synthesized hydrocarbon liquid in a slurry fischer-tropsch reactor
US6720283B2 (en) * 2002-01-03 2004-04-13 Dalian Institute Of Chemical Physics Activated carbon supported cobalt based catalyst for direct conversion of synthesis gas to diesel fuels
DE10256404B4 (de) * 2002-05-31 2009-02-05 Kataleuna Gmbh Catalysts Katalysator zur Isomerisierung von festen Fischer-Tropsch-Paraffinen und Verfahren zu seiner Herstellung
GB0222240D0 (en) * 2002-09-25 2002-10-30 Ici Plc Cobalt catalysts
US6768037B2 (en) 2002-10-30 2004-07-27 Chevron U.S.A. Inc. Process to upgrade fischer-tropsch products and form light olefins
US7157501B2 (en) 2002-11-05 2007-01-02 Albemarle Netherlands B.V. Fischer-tropsch process using a fischer-tropsch catalyst and a zeolite-containing catalyst
US7541310B2 (en) * 2003-10-16 2009-06-02 Conocophillips Company Silica-alumina catalyst support, catalysts made therefrom and methods of making and using same
GB0409901D0 (en) * 2004-05-04 2004-06-09 Johnson Matthey Plc Catalysts
US7323100B2 (en) * 2004-07-16 2008-01-29 Conocophillips Company Combination of amorphous materials for hydrocracking catalysts
GB0418934D0 (en) * 2004-08-25 2004-09-29 Johnson Matthey Plc Catalysts
EP1827690A1 (en) * 2004-12-23 2007-09-05 Shell Internationale Research Maatschappij B.V. Process for preparing a catalyst
US7462338B2 (en) * 2004-12-28 2008-12-09 Umicore Ag & Co. Kg Boron-alumina catalyst support
GB0506976D0 (en) * 2005-04-06 2005-05-11 Johnson Matthey Plc Catalyst supports
FR2888584B1 (fr) * 2005-07-18 2010-12-10 Inst Francais Du Petrole Procede de production de distillats moyens par hydroisomerisation et hydrocraquage de charges issues du procede fischer-tropsch utilisant un lit de garde multifonctionnel

Also Published As

Publication number Publication date
US8097555B2 (en) 2012-01-17
EP2055380A1 (en) 2009-05-06
AR068146A1 (es) 2009-11-04
US20090124712A1 (en) 2009-05-14

Similar Documents

Publication Publication Date Title
AR068146A1 (es) Procedimiento para la produccion de catalizadores hibridos para la sintesis de fischer-tropsch y catalizador hibrido producido de acuerdo con este procedimiento
BR112016006685B8 (pt) Peneira molecular, processo para produção, composição e uso desta
BR112013001890A2 (pt) hidroprocessamento em múltiplos estágios para a produção de nafta de alta octana
BRPI0704436A2 (pt) processo de produção de hidrocarbonetos
BR112013027149A2 (pt) processo para a conversão de um material de biomassa sólida
Riazi et al. Life cycle environmental and cost implications of isostearic acid production for pharmaceutical and personal care products
BRPI0513338A (pt) métodos de produção de etileno e propileno
WO2009059936A3 (en) An integrated process for producing diesel fuel from biological material and products, uses and equipment relating to said process
BRPI0601460A (pt) processo para hidroconversão de mistura de óleos orgánicos de diferentes origens
Zhou et al. Hierarchical FAU zeolites boosting the hydrocracking of polyolefin waste into liquid fuels
BR112012005379A2 (pt) sistemas e processos para pirólise catalítica de biomassa e materiais hidrocarboníferos para produção de aromáticos com reciclagem de olefina opcional e catalisadores tendo tamanho de partícula selecionado para pirólise catalítica.
MY162910A (en) CATALYTIC PROCESSES AND SYSTEMS FOR BASE OIL PRODUCTION USING ZEOLITE SSZ-32x
BR112015002402A2 (pt) hidrocraqueamento de resíduos
WO2005104749A3 (en) Hydroprocessing method and system for upgrading heavy oil using a colloidal or molecular catalyst
Liu et al. One-pot three-dimensional printing of a hierarchical NiMo/Al2O3 monolithic catalyst for 4, 6-dimethyldibenzothiophene hydrodesulfurization
BR112013016574A2 (pt) processo para o craqueamento de alimentação de hidrocarbonetos pesados
MX2009000941A (es) Proceso de hidrodesintegracion.
Basir et al. Conversion of jet biofuel range hydrocarbons from palm oil over zeolite hybrid catalyst
de Paz Carmona et al. Hydrotreating of atmospheric gas oil and co-processing with rapeseed oil using sulfur-free PMoCx/Al2O3 catalysts
BR112013027079A2 (pt) processo e sistema para reduzir o teor de olefina de um produto fischer-tropsch
Lee et al. Enhanced isoparaffin selectivity in CO2 hydrogenation by combining Na-promoted Fe3O4 and Pt/WO3-ZrO2 catalysts
BR112014015026A2 (pt) catalisador utilizável em hidroconversão compreendendo pelo menos uma zeólita e metais dos grupos viii e vib, e preparo do catalisador
BR112013027137A2 (pt) processos para a conversão de um material de biomassa sólida, para a preparação de um componente de biocombustível e/ou componente bioquímico, e para a produção de um biocombustível e/ou produto bioquímico
Liu et al. Selective production of iso-paraffins from syngas over Co/SiO2 and Pd/beta hybrid catalysts
CL2007002877A1 (es) Proceso para producir nafta desde aceite pesado o bitumen usando una unidad fcc que comprende suministrar la alimentacion a la zona de reacion de la unidad con un catalizador en razon de peso catalizador/aceite entre 4 y 10 y y operar a n° de conversion entre 40 y 60; y sistema para producir mezcla de aceite pesado y nafta.

Legal Events

Date Code Title Description
B03A Publication of a patent application or of a certificate of addition of invention [chapter 3.1 patent gazette]
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]

Free format text: INDEFIRO O PEDIDO DE ACORDO COM O(S) ARTIGO(S) 8O, 11, 13 E 25 DA LPI

B09B Patent application refused [chapter 9.2 patent gazette]