BRPI0711452B8 - processo para a preparação de uma estrutura polimérica absorvente de água, estrutura polimérica absorvente de água, compósito, processo para a preparação de um compósito, uso da estrutura polimérica absorvente de água ou uso do compósito e uso de um sal - Google Patents
processo para a preparação de uma estrutura polimérica absorvente de água, estrutura polimérica absorvente de água, compósito, processo para a preparação de um compósito, uso da estrutura polimérica absorvente de água ou uso do compósito e uso de um salInfo
- Publication number
- BRPI0711452B8 BRPI0711452B8 BRPI0711452A BRPI0711452A BRPI0711452B8 BR PI0711452 B8 BRPI0711452 B8 BR PI0711452B8 BR PI0711452 A BRPI0711452 A BR PI0711452A BR PI0711452 A BRPI0711452 A BR PI0711452A BR PI0711452 B8 BRPI0711452 B8 BR PI0711452B8
- Authority
- BR
- Brazil
- Prior art keywords
- composite
- water
- absorbing polymeric
- polymeric structure
- preparing
- Prior art date
Links
- 239000002131 composite material Substances 0.000 title abstract 11
- 239000002250 absorbent Substances 0.000 title abstract 5
- 238000004519 manufacturing process Methods 0.000 title abstract 5
- 150000003839 salts Chemical class 0.000 title abstract 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 7
- 238000000034 method Methods 0.000 abstract 4
- 239000006260 foam Substances 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- 230000002745 absorbent Effects 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 239000004566 building material Substances 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 abstract 1
- 239000000835 fiber Substances 0.000 abstract 1
- 239000012530 fluid Substances 0.000 abstract 1
- 230000002538 fungal effect Effects 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 150000007530 organic bases Chemical class 0.000 abstract 1
- 239000005022 packaging material Substances 0.000 abstract 1
- 230000008635 plant growth Effects 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 239000003566 sealing material Substances 0.000 abstract 1
- 239000002689 soil Substances 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- 238000004381 surface treatment Methods 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
- C08J3/245—Differential crosslinking of one polymer with one crosslinking type, e.g. surface crosslinking
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/42—Use of materials characterised by their function or physical properties
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/42—Use of materials characterised by their function or physical properties
- A61L15/60—Liquid-swellable gel-forming materials, e.g. super-absorbents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/44—Preparation of metal salts or ammonium salts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
- C08L101/12—Compositions of unspecified macromolecular compounds characterised by physical features, e.g. anisotropy, viscosity or electrical conductivity
- C08L101/14—Compositions of unspecified macromolecular compounds characterised by physical features, e.g. anisotropy, viscosity or electrical conductivity the macromolecular compounds being water soluble or water swellable, e.g. aqueous gels
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
- C08F222/10—Esters
- C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
- C08F222/102—Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2300/00—Characterised by the use of unspecified polymers
- C08J2300/14—Water soluble or water swellable polymers, e.g. aqueous gels
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Materials Engineering (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Veterinary Medicine (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Hematology (AREA)
- Public Health (AREA)
- General Chemical & Material Sciences (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Absorbent Articles And Supports Therefor (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
processo para a preparação de uma estrutura polimérica absorvente de água, estrutura polimérica absorvente de água, compósito, processo para a preparação de um compósito, espumas, artigos moldados, folhas, filmes, cabos, materiais vedantes, artigos de higiene absorventes de fluido, veículos para composições reguladoras de crescimento de fungos e plantas, materiais de embalagem, aditivos de solo ou materiais de construção, uso da estrutura polimérica absorvente de água ou do compósito, e uso de um sal. a presente invenção se refere a um processo para a preparação de estruturas poliméricas absorventes de água, compreendendo as seguintes etapas de processo: i) proporcionar uma estrutura polimérica absorvente de água, não tratada; e ii) colocar a estrutura polimérica absorvente de água, não tratada em contato com um sal, compreendendo um cátion divalente ou de valência mais alta de um metal, e pelo menos uma base orgânica como um ániou. a invenção se refere também às estruturas poliméricas absorventes de água obteníveis por esse processo, a estruturas poliméricas absorventes de água, a um compósito compreendendo uma estrutura polimérica absorvente de água e um substrato, a um processo para a preparação de um compósito, ao compósito obtenível por esse processo, a produtos químicos, tais como espumas, artigos moldados e fibras, compreendendo estruturas políméricas absorventes de água ou um compósito, ao uso das estruturas poliméricas absorventes de água ou de um compósito em produtos químicos, e ao uso de um sal no tratamento superficial de estruturas poliméricas absorventes de água.
Applications Claiming Priority (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/EP2006/003695 WO2006111403A1 (de) | 2005-04-22 | 2006-04-21 | Mit polykationen oberflächenbehandeltes wasserabsorbierende polymergebilde |
| DEEP2006/003696 | 2006-04-21 | ||
| DEEP2006/003695 | 2006-04-21 | ||
| DEEP2006/003694 | 2006-04-21 | ||
| PCT/EP2006/003694 WO2006111402A2 (de) | 2005-04-22 | 2006-04-21 | Oberflächennachvernetzte superabsorber behandelt mit metallsalz und metalloxid |
| DE102006019157A DE102006019157A1 (de) | 2006-04-21 | 2006-04-21 | Herstellung von hochpermeablen, superabsorbierenden Polymergebilden |
| PCT/EP2006/003696 WO2006111404A2 (de) | 2005-04-22 | 2006-04-21 | Oberflächennachvernetzte superabsorber behandelt mit metallsalz und metalloxid |
| DE102006019157.9 | 2006-04-21 | ||
| DE200610037983 DE102006037983A1 (de) | 2006-08-12 | 2006-08-12 | Wasserabsorbierendes Polymergebilde mit verbesserter Permeabilität und Absorption unter Druck |
| DE10200603783.7 | 2006-08-12 | ||
| PCT/EP2007/003475 WO2007121937A2 (de) | 2006-04-21 | 2007-04-20 | Oberflächennachvernetzte superabsorber behandelt mit aluminiumlactat und optional aluminiumsulfat |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| BRPI0711452A2 BRPI0711452A2 (pt) | 2011-11-08 |
| BRPI0711452B1 BRPI0711452B1 (pt) | 2018-03-20 |
| BRPI0711452B8 true BRPI0711452B8 (pt) | 2021-06-22 |
Family
ID=40684776
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0711452A BRPI0711452B8 (pt) | 2006-04-21 | 2007-04-20 | processo para a preparação de uma estrutura polimérica absorvente de água, estrutura polimérica absorvente de água, compósito, processo para a preparação de um compósito, uso da estrutura polimérica absorvente de água ou uso do compósito e uso de um sal |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US8907017B2 (pt) |
| JP (1) | JP5374793B2 (pt) |
| KR (1) | KR101407176B1 (pt) |
| CN (2) | CN101100526B (pt) |
| BR (1) | BRPI0711452B8 (pt) |
| TW (1) | TWI439297B (pt) |
| WO (1) | WO2007121937A2 (pt) |
Families Citing this family (51)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102004019264B4 (de) * | 2004-04-21 | 2008-04-10 | Stockhausen Gmbh | Verfahren zur Herstellung eines absorbierenden Polymers mittels Spreittrocknung |
| TWI529181B (zh) * | 2005-02-28 | 2016-04-11 | 贏創德固賽有限責任公司 | 以可更新原料為基之吸水聚合物結構及其生產的方法 |
| DE102005055497A1 (de) * | 2005-11-18 | 2007-05-31 | Stockhausen Gmbh | Geruchsbindende superabsorbierende Zusammensetzung |
| KR20140095569A (ko) * | 2006-02-28 | 2014-08-01 | 에보니크 데구사 게엠베하 | 우수한 흡수성과 보유성을 지니는 생분해성 초흡수성 중합체 조성물 |
| BRPI0711452B8 (pt) * | 2006-04-21 | 2021-06-22 | Evonik Degussa Gmbh | processo para a preparação de uma estrutura polimérica absorvente de água, estrutura polimérica absorvente de água, compósito, processo para a preparação de um compósito, uso da estrutura polimérica absorvente de água ou uso do compósito e uso de um sal |
| DE102006039205A1 (de) * | 2006-08-22 | 2008-03-20 | Stockhausen Gmbh | Auf nachwachsenden Rohstoffen basierende Acrylsäure und wasserabsorbierende Polymergebilde sowie Verfahren zu deren Herstellung mittels Dehydratisierung |
| EP2115019B2 (de) † | 2007-01-29 | 2019-07-10 | Basf Se | VERFAHREN ZUR HERSTELLUNG WEIßER UND FARBSTABILER WASSERABSORBIERENDER POLYMERPARTIKEL MIT HOHEM ABSORPTIONSVERMÖGEN UND HOHER FLÜSSIGKEITSLEITFÄHIGKEIT |
| CN101594889A (zh) * | 2007-01-29 | 2009-12-02 | 巴斯夫欧洲公司 | 生产具有高吸收率和高盐水导流率的白色且颜色稳定的吸水性聚合物颗粒的方法 |
| DE102007007203A1 (de) * | 2007-02-09 | 2008-08-14 | Evonik Stockhausen Gmbh | Wasserabsorbierendes Polymergebilde mit hoher Ammoniak-Bindekapazität |
| US7816426B2 (en) | 2007-07-16 | 2010-10-19 | Evonik Stockhausen, Llc | Superabsorbent polymer compositions having color stability |
| DE102007045724B4 (de) | 2007-09-24 | 2012-01-26 | Evonik Stockhausen Gmbh | Superabsorbierende Zusammensetzung mit Tanninen zur Geruchskontrolle, Verfahren zu deren Herstellung und Verwendung |
| DE102007053619A1 (de) * | 2007-11-08 | 2009-05-20 | Evonik Stockhausen Gmbh | Wasserabsorbierende Polymergebilde mit verbesserter Farbstabilität |
| JP2011517703A (ja) * | 2007-12-19 | 2011-06-16 | ビーエーエスエフ ソシエタス・ヨーロピア | 表面架橋超吸収性物質の製造方法 |
| TWI455973B (zh) * | 2008-03-05 | 2014-10-11 | 贏創德固賽有限責任公司 | 用於氣味控制的具有水楊酸鋅的超吸收性組合物 |
| EP2250222B1 (en) * | 2008-03-07 | 2015-12-23 | Nippon Shokubai Co., Ltd. | Water absorbing agent and production method thereof |
| JP5730013B2 (ja) * | 2008-04-25 | 2015-06-03 | 株式会社日本触媒 | ポリアクリル酸(塩)系吸水性樹脂およびその製造方法 |
| US7910688B2 (en) * | 2008-10-22 | 2011-03-22 | Evonik Stockhausen Inc. | Recycling superabsorbent polymer fines |
| JP5780763B2 (ja) | 2009-02-06 | 2015-09-16 | 株式会社日本触媒 | ポリアクリル酸(塩)系吸水性樹脂およびその製造方法 |
| US20100247916A1 (en) * | 2009-03-24 | 2010-09-30 | Basf Se | Process for Producing Surface Postcrosslinked Water-Absorbing Polymer Particles |
| WO2010149735A1 (de) † | 2009-06-26 | 2010-12-29 | Basf Se | Verfahren zur herstellung wasserabsorbierender polymerpartikel mit geringer verbackungsneigung und hoher absorption unter druck |
| JP5732396B2 (ja) | 2009-08-27 | 2015-06-10 | 株式会社日本触媒 | ポリアクリル酸(塩)系吸水性樹脂およびその製造方法 |
| EP2484702B2 (en) | 2009-09-30 | 2021-11-10 | Nippon Shokubai Co., Ltd. | Polyacrylic acid salt-based water absorbent resin and method for producing same |
| JP5587348B2 (ja) | 2010-01-20 | 2014-09-10 | 株式会社日本触媒 | 吸水性樹脂の製造方法 |
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| WO2011111857A1 (ja) | 2010-03-12 | 2011-09-15 | 株式会社日本触媒 | 吸水性樹脂の製造方法 |
| EP2550316B2 (de) * | 2010-03-25 | 2018-11-14 | Basf Se | Verfahren zur herstellung wasserabsorbierender polymerpartikel |
| EP2371869A1 (en) | 2010-03-30 | 2011-10-05 | Evonik Stockhausen GmbH | A process for the production of a superabsorbent polymer |
| BR112012027406B1 (pt) | 2010-04-26 | 2021-02-09 | Nippon Shokubai Co., Ltd. | resina absorvedora de água tipo ácido poliacrílico (sal), material sanitário e método para produzir a referida resina |
| JP5806209B2 (ja) | 2010-04-26 | 2015-11-10 | 株式会社日本触媒 | ポリアクリル酸(塩)系吸水性樹脂及びその製造方法 |
| US9962459B2 (en) * | 2010-07-02 | 2018-05-08 | Basf Se | Ultrathin fluid-absorbent cores |
| US8802786B2 (en) * | 2011-04-21 | 2014-08-12 | Evonik Corporation | Particulate superabsorbent polymer composition having improved performance properties |
| DE102011086522A1 (de) | 2011-11-17 | 2013-05-23 | Evonik Degussa Gmbh | Superabsorbierende Polymere für hochgefüllte oder faserfreie Hygieneartikel |
| DE102011086516A1 (de) | 2011-11-17 | 2013-05-23 | Evonik Degussa Gmbh | Superabsorbierende Polymere mit schnellen Absorptionseigenschaften sowieVerfahren zu dessen Herstellung |
| US8420567B1 (en) | 2011-12-30 | 2013-04-16 | Evonik Stockhausen, Llc | Process for superabsorbent polymer and crosslinker composition |
| EP2797971B1 (en) | 2011-12-30 | 2018-12-05 | Evonik Corporation | Process to make superabsorbent polymers with specific internal crosslinkers |
| EP2615120B2 (en) | 2012-01-12 | 2022-12-21 | Evonik Superabsorber GmbH | Process for the continuous preparation of water-absorbent polymers |
| EP2838572A1 (en) | 2012-04-17 | 2015-02-25 | Basf Se | Process for producing surface postcrosslinked water-absorbing polymer particles |
| KR102226473B1 (ko) | 2012-08-27 | 2021-03-12 | 가부시키가이샤 닛폰 쇼쿠바이 | 입자상 흡수제 및 그의 제조 방법 |
| KR102236466B1 (ko) | 2013-01-29 | 2021-04-07 | 가부시키가이샤 닛폰 쇼쿠바이 | 흡수성 수지 재료 및 그의 제조 방법 |
| US9302248B2 (en) | 2013-04-10 | 2016-04-05 | Evonik Corporation | Particulate superabsorbent polymer composition having improved stability |
| DE102013208942A1 (de) | 2013-05-15 | 2014-11-20 | Evonik Industries Ag | Superabsorbierende Polymere mit schnellen Absorptionseigenschaften sowie Verfahren zu dessen Herstellung |
| WO2015169913A1 (de) * | 2014-05-08 | 2015-11-12 | Basf Se | Wasserabsorbierende polymerpartikel |
| KR101820051B1 (ko) | 2014-12-18 | 2018-01-18 | 주식회사 엘지화학 | 표면 가교 처리된 고흡수성 수지 및 그 제조방법 |
| KR101805088B1 (ko) | 2014-12-18 | 2017-12-05 | 주식회사 엘지화학 | 표면 개질 처리된 고흡수성 수지 및 그 제조방법 |
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- 2007-04-20 JP JP2009505786A patent/JP5374793B2/ja active Active
- 2007-04-20 KR KR1020087028471A patent/KR101407176B1/ko active Active
- 2007-04-20 US US12/297,822 patent/US8907017B2/en active Active
- 2007-04-20 TW TW096113915A patent/TWI439297B/zh active
- 2007-04-20 WO PCT/EP2007/003475 patent/WO2007121937A2/de not_active Ceased
- 2007-04-23 CN CN200710136296XA patent/CN101100526B/zh active Active
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| Publication number | Publication date |
|---|---|
| CN102746519A (zh) | 2012-10-24 |
| TWI439297B (zh) | 2014-06-01 |
| BRPI0711452B1 (pt) | 2018-03-20 |
| TW200806341A (en) | 2008-02-01 |
| US9534095B2 (en) | 2017-01-03 |
| JP5374793B2 (ja) | 2013-12-25 |
| CN101100526B (zh) | 2012-09-26 |
| CN102746519B (zh) | 2015-08-12 |
| CN101100526A (zh) | 2008-01-09 |
| JP2009534482A (ja) | 2009-09-24 |
| US20090227741A1 (en) | 2009-09-10 |
| KR101407176B1 (ko) | 2014-06-12 |
| BRPI0711452A2 (pt) | 2011-11-08 |
| US20140350191A1 (en) | 2014-11-27 |
| WO2007121937A3 (de) | 2009-02-26 |
| US8907017B2 (en) | 2014-12-09 |
| WO2007121937A2 (de) | 2007-11-01 |
| KR20090015070A (ko) | 2009-02-11 |
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