BRPI0804461B1 - PRODUCT LIQUID FERTILIZER CONTAINING CALCIUM, BORON AND MOLYBDEN AND PRODUCTION PROCESS - Google Patents
PRODUCT LIQUID FERTILIZER CONTAINING CALCIUM, BORON AND MOLYBDEN AND PRODUCTION PROCESS Download PDFInfo
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- BRPI0804461B1 BRPI0804461B1 BRPI0804461-9A BRPI0804461A BRPI0804461B1 BR PI0804461 B1 BRPI0804461 B1 BR PI0804461B1 BR PI0804461 A BRPI0804461 A BR PI0804461A BR PI0804461 B1 BRPI0804461 B1 BR PI0804461B1
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- 229910052791 calcium Inorganic materials 0.000 title claims abstract description 45
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 39
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 24
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- 241000196324 Embryophyta Species 0.000 claims abstract description 45
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 42
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- 235000015097 nutrients Nutrition 0.000 claims abstract description 34
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims abstract description 32
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000011733 molybdenum Substances 0.000 claims abstract description 29
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- 239000011785 micronutrient Substances 0.000 claims abstract description 24
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Landscapes
- Fertilizers (AREA)
Abstract
produto fertilizante liquido contendo cálcio, boro e molibdénio e processo de produção. pertencente ao setor de fertilizantes, refere-se a um produto constituído de micronutrientes, macronutrientes e substâncias diversas para aplicação via foliar, hidroponia ou fertirrigação, em culturas anuais ou perenes, e a seu processo de produção. o produto consiste em um fertilizante líquido fornecedor de uma tripla combinação dos nutrientes ca , b e mo e outros micro e macronutrientes; agentes de complexação dos macro e micronutrientes; dispersante do cálcio e complexante do boro; agentes emuísificantes; agentes adesivos do produto à planta; dispersantes; nutrientes orgânicos para rápida absorção dos complexos de ca, b e mo; aditivos orgânicos naturais coadjuvantes para melhoria do sistema adesivo e ação de "repelente natural" contra insetos; agente modificador de reação e agente corretor de ph e de viscosidade. o produto é recomendado para aplicação em todas as culturas da área agrícola como, por exemplo: amendoim, girassol, soja, feijão, milho, sorgo, trigo, arroz, algodão, café, frutas tropicais ou temperadas, citros, hortaliças, batata, cebola, e outras.Liquid fertilizer product containing calcium, boron and molybdenum and production process. Fertilizer sector refers to a product made up of micronutrients, macronutrients and various substances for application via foliar, hydroponics or fertigation, in annual or perennial crops, and their production process. The product consists of a liquid fertilizer providing a triple combination of the nutrients ca, b and mo and other micro and macronutrients; macro and micronutrient complexing agents; calcium dispersant and boron complexant; emulsifying agents; plant product adhesive agents; dispersants; organic nutrients for rapid absorption of ca, b and mo complexes; Supporting natural organic additives to improve the adhesive system and "natural repellent" action against insects; reaction modifying agent and ph and viscosity correcting agent. The product is recommended for application in all crops in the agricultural area such as peanuts, sunflower, soybeans, beans, corn, sorghum, wheat, rice, coffee, tropical or temperate fruits, citrus, vegetables, potatoes, onions. , and others.
Description
-1 / 20“PRODUTO FERTILIZANTE LÍQUIDO CONTENDO CÁLCIO, BORO E MOLIBDÊNIO E PROCESSO DE PRODUÇÃO” [001] A presente invenção, pertencente ao setor de fertilizantes, refere-se a um produto constituído de micronutrientes, macronutrientes e substâncias diversas para aplicação via foliar, hidroponia ou fertirrigação, em culturas anuais ou perenes, e a seu processo de produção.-1 / 20 “LIQUID FERTILIZER PRODUCT CONTAINING CALCIUM, BORON AND MOLYBDENUM AND PRODUCTION PROCESS” [001] The present invention, belonging to the fertilizer sector, refers to a product consisting of micronutrients, macronutrients and various substances for application via leaf , hydroponics or fertigation, in annual or perennial crops, and their production process.
[002] O produto é recomendado para aplicação em todas as culturas da área agrícola como, por exemplo: amendoim, girassol, soja, feijão, milho, sorgo, trigo, arroz, algodão, café, frutas tropicais ou temperadas, citros, hortaliças, batata, cebola, e outras.[002] The product is recommended for application in all crops in the agricultural area, such as: peanuts, sunflowers, soybeans, corn, sorghum, wheat, rice, cotton, coffee, tropical or seasoned fruits, citrus, vegetables, potato, onion, and others.
[003] As aplicações podem ser feitas nas folhas, caules ou raízes da planta. O fertilizante visa facilitar o tratamento dessas culturas, por se tratar de um produto que contém alta concentração de cálcio, boro e molibdênio, e não causar corrosão ou queima das folhas após sua aplicação, como acontece com a maioria dos produtos usuais do comércio, quando empregada na quantidade necessária para a alimentação das plantas. Estes nutrientes são muito importantes no desenvolvimento de partes novas e reprodutivas da planta, como flores e frutos, em uma única formulação. Se aplicado nas dosagens recomendadas, proporciona uma rápida absorção suprindo as deficiências de cálcio, boro e molibdênio.[003] Applications can be made on the leaves, stems or roots of the plant. The fertilizer aims to facilitate the treatment of these crops, as it is a product that contains a high concentration of calcium, boron and molybdenum, and does not cause corrosion or burning of the leaves after application, as happens with most of the usual products of the trade, when used in the quantity necessary for plant feeding. These nutrients are very important in the development of new and reproductive parts of the plant, such as flowers and fruits, in a single formulation. If applied in the recommended dosages, it provides a fast absorption supplying the deficiencies of calcium, boron and molybdenum.
[004] O produto pode ser apresentado como uma emulsão ou uma mistura homogênea, chamada de solução, formulada com sais de Ca, B, Mo e outros aditivos, cuja função é fornecer macro e micro nutrientes na forma concentrada, totalmente solúvel e que não entupa os bicos dos pulverizadores ou aplicadores, liberando o nutriente boro na forma de complexo ionizável boro-sacarose e os nutrientes cálcio e molibdênio na forma de complexos aminoácidos/EDTA.[004] The product can be presented as an emulsion or a homogeneous mixture, called a solution, formulated with Ca, B, Mo salts and other additives, whose function is to provide macro and micro nutrients in concentrated form, totally soluble and that do not clogs the nozzles of sprayers or applicators, releasing the nutrient boron in the form of an ionizable boron-sucrose complex and the nutrients calcium and molybdenum in the form of amino acid / EDTA complexes.
[005] Atualmente, a alta produtividade das culturas necessita de grandes quantidades de nitrogênio (N), Fósforo (P2O5) e Potássio (K2O) e, não menos[005] Currently, the high productivity of crops requires large amounts of nitrogen (N), phosphorus (P2O5) and potassium (K 2 O) and, no less
Petição 870180065230, de 27/07/2018, pág. 8/35Petition 870180065230, of 27/07/2018, p. 8/35
-2 / 20importante, complementações por aplicações suplementares via foliar de alguns macro e micronutrientes e associados, sem as quais o cultivo seria economicamente inviável. Fatores físicos do solo e do meio ambiente, assim como fatores genéticos e nutricionais ligados à planta estão relacionados com a capacidade de se ter sucesso na colheita ou baixa produtividade ou, até mesmo, o fracasso da produção. Na agricultura moderna, esses fatores são minimizados através do uso do conhecimento das novas tecnologias aprendidas e desenvolvidas ao longo do tempo da nossa civilização.-2 / 20important, supplementation by supplementary applications via leaf of some macro and micronutrients and associates, without which cultivation would be economically unfeasible. Physical factors of the soil and the environment, as well as genetic and nutritional factors linked to the plant are related to the ability to succeed in harvesting or low productivity or even the failure of production. In modern agriculture, these factors are minimized through the use of knowledge of the new technologies learned and developed over the time of our civilization.
[006] A aplicação de macro e micronutrientes líquidos por via foliar, hidropônica ou fertirrigação, juntamente com outros aditivos como defensivos, hormônios de crescimento, etc. tem merecido atenção de estudos sob as mais diversas condições. Os efeitos benéficos desses elementos sobre a rápida absorção das plantas têm sido relatados em diversos estudos feitos em condições controladas em casa de vegetação e, principalmente, sob condições reais de manejo no campo.[006] The application of liquid macro and micronutrients via leaf, hydroponics or fertigation, together with other additives such as pesticides, growth hormones, etc. it has deserved attention from studies under the most diverse conditions. The beneficial effects of these elements on the rapid absorption of plants have been reported in several studies carried out under controlled conditions in a greenhouse and, mainly, under real management conditions in the field.
[007] Atualmente, existe no mercado nacional um grande número de produtos contendo somente cálcio e boro, entretanto são fabricados somente pela simples mistura de sais e, quando misturados em altas concentrações, a solução fica totalmente saturada, isto é, grande parte dos sais presentes não fica dissociada, precipitando-se no fundo do frasco, sendo chamada de corpo de fundo ou precipitado. Mesmo quando diluídos em tanques de preparo, estes sais permanecem “insolúveis” durante um longo período de tempo. Por outro lado, esses produtos são limitados a 1% de Boro quando estão associados com 10% de Ca e assim mesmo, ficam parcialmente precipitados. No mercado, existem formulações até 11 % de Boro (15,4 % p/v ou 11 % p/p), em formulação onde apenas é feita uma reação de complexação entre o ácido ortobórico com etanolamina (monoetanolamina), sem Cálcio e sem Molibdênio. Não existe no mercado nenhum fertilizante líquido que contenha numa só formulação os três nutrientes Ca10% B2% Mo 0,01% e aditivos especiais totalmente solúveis que não precipitem.[007] Currently, there is a large number of products on the national market containing only calcium and boron, however they are manufactured only by simply mixing salts and, when mixed in high concentrations, the solution is completely saturated, that is, a large part of the salts present is not dissociated, precipitating at the bottom of the bottle, being called the bottom or precipitated body. Even when diluted in preparation tanks, these salts remain "insoluble" for a long period of time. On the other hand, these products are limited to 1% Boron when they are associated with 10% Ca and even so, they are partially precipitated. On the market, there are formulations of up to 11% Boron (15.4% w / v or 11% w / w), in a formulation where only a complexation reaction is carried out between ortho-boric acid with ethanolamine (monoethanolamine), without calcium and without Molybdenum. There is no liquid fertilizer on the market that contains in one formulation the three nutrients Ca10% B2% Mo 0.01% and special soluble additives that do not precipitate.
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-3/20[008] O agricultor, na maioria das vezes, determina a tarefa de solubilização a um funcionário que, sem ter o conhecimento detalhado para fazer o trabalho de aplicação imediatamente após a diluição, transfere o fertilizante diretamente para os equipamentos pulverizadores ou gotejadores. Com isso, os bicos destes equipamentos, que são muito finos, ficam entupidos, parando a produção, além do fato mais importante de o agricultor perder sua garantia da concentração do macro ou micro elemento contido no fertilizante para suprir a necessidade da planta. Consequentemente, haverá perdas irreparáveis da produtividade. Para poder reparar isso, a fertilização deve ser repetida várias vezes, o que representa um aumento do custo de produção e sem contar que as substâncias nutrientes, antes de serem absorvidas pela planta, são retiradas pela ação do vento ou da chuva por não conterem agentes fixadores ou espalhantes.-3/20 [008] The farmer, in most cases, determines the solubilization task to an employee who, without having the detailed knowledge to do the application work immediately after dilution, transfers the fertilizer directly to the spray equipment or drippers. As a result, the nozzles of this equipment, which are very thin, become clogged, stopping production, in addition to the most important fact that the farmer loses his guarantee of the concentration of the macro or micro element contained in the fertilizer to supply the plant's need. Consequently, there will be irreparable losses in productivity. In order to repair this, fertilization must be repeated several times, which represents an increase in the cost of production and not to mention that the nutrient substances, before being absorbed by the plant, are removed by the action of wind or rain because they do not contain agents fasteners or spreaders.
[009] O objetivo da presente invenção foi desenvolver um produto que contivesse nutrientes Ca, B e Mo (na proporção Ca 10%, B 2%, Mo 0,01%) de forma a melhorar a eficiência na absorção das folhas com uma rápida penetração, sem ocasionar queimas e de modo que não sejam perdidos por ação do vento ou da chuva, o que aumenta os riscos de expor a cultura às deficiências destas substâncias nutrientes.[009] The objective of the present invention was to develop a product that contained nutrients Ca, B and Mo (in the proportion Ca 10%, B 2%, Mo 0.01%) in order to improve the efficiency in the absorption of the leaves with a fast penetration, without causing burns and so that they are not lost due to the action of wind or rain, which increases the risks of exposing the crop to the deficiencies of these nutrient substances.
[0010] Por meio de testes em campo e do conhecimento sobre nutrição das plantas, desenvolveu-se uma formulação combinando os três nutrientes Cálcio, Boro e Molibdênio e outros aditivos em uma só mistura homogênea ou em forma de emulsão e com a máxima concentração possível, visando a prevenção de doenças ocasionadas pela falta destes nutrientes e principalmente para o aumento da qualidade e produtividade.[0010] Through field tests and knowledge about plant nutrition, a formulation was developed combining the three nutrients Calcium, Boron and Molybdenum and other additives in a single homogeneous mixture or in emulsion form and with the maximum concentration possible , aiming at preventing diseases caused by the lack of these nutrients and mainly to increase quality and productivity.
[0011] A presente invenção, diferentemente das demais, apresenta uma alternativa simples e de fácil aplicação no campo, com a vantagem das pessoas que manejam uma fórmula não necessitarem do acompanhamento de um técnico durante o preparo no campo, envolvendo uma só mistura homogênea, totalmente solúvel e contendo os macro e micronutrientes Ca, B, Mo e aditivos especialmente adicionados como complexantes, dispersantes, nutrientes[0011] The present invention, differently from the others, presents a simple and easy application in the field, with the advantage that people who handle a formula do not need the assistance of a technician during preparation in the field, involving a single homogeneous mixture, totally soluble and containing macro and micronutrients Ca, B, Mo and additives specially added as complexing, dispersing, nutrients
Petição 870180065230, de 27/07/2018, pág. 10/35Petition 870180065230, of 27/07/2018, p. 10/35
-4/20orgânícos e fixadores naturais. O novo fertilizante líquido, quando aplicado sobre as plantas, forma uma fina camada de “filme” onde retém as substâncias nutrientes, ocorrendo uma rápida absorção. Com isso, ocorre uma eficaz utilização dos nutrientes pela planta, além de diminuir as perdas pela chuva ou vento e, também, a possibilidade de queima ou corrosão não ocorrer devido a rápida metabolização.-4 / 20organic and natural fixatives. The new liquid fertilizer, when applied to plants, forms a thin layer of “film” where it retains nutrient substances, with rapid absorption. As a result, there is an efficient use of nutrients by the plant, in addition to reducing losses due to rain or wind and, also, the possibility of burning or corrosion does not occur due to rapid metabolization.
[0012] Fertilizantes ou adubos são compostos químicos ou orgânicos que visam suprir as deficiências em substâncias vitais à sobrevivência dos vegetais, sendo aplicados na agricultura com o intuito de aumentar a produção. Produzidos nas formas fluida e sólida, podem ser aplicados através das folhas mediante pulverização manual ou mecanizada, chamada de adubaçâo foliar, via irrigação ou diretamente no solo.[0012] Fertilizers or fertilizers are chemical or organic compounds that aim to fill deficiencies in substances vital to the survival of vegetables, being applied in agriculture in order to increase production. Produced in fluid and solid forms, they can be applied through the leaves by means of manual or mechanized spraying, called foliar fertilization, via irrigation or directly on the soil.
[0013] Os nutrientes essenciais são requeridos pelas plantas em determinadas quantidades, variáveis conforme a espécie e o estado de desenvolvimento. Esses elementos encontram-se nos solos em diferentes combinações químicas, sendo só algumas destas passíveis de serem absorvidas pelas plantas. Além do Hidrogênio, Oxigênio e Carbono, as plantas também necessitam de elevadas quantidades de Nitrogênio, Fósforo, Potássio, chamados macronutrientes primários; e Enxofre, Cálcio e Magnésio, chamados macronutrientes secundários. No entanto, também necessitam de pequenas quantidades de Boro, Manganês, Zinco, Cobre, Molibdênio, Ferro e Cloro, chamados de micronutrientes ou oligoelementos.[0013] Essential nutrients are required by plants in certain quantities, varying according to the species and the state of development. These elements are found in soils in different chemical combinations, only a few of which can be absorbed by plants. In addition to Hydrogen, Oxygen and Carbon, plants also require high amounts of Nitrogen, Phosphorus, Potassium, called primary macronutrients; and Sulfur, Calcium and Magnesium, called secondary macronutrients. However, they also need small amounts of Boron, Manganese, Zinc, Copper, Molybdenum, Iron and Chlorine, called micronutrients or trace elements.
[0014] Os nutrientes são necessários para a planta levar a cabo determinadas funções, pelo que a carência e o excesso estão relacionados com sintomas visíveis que, por sua vez, estão relacionados com a sua mobilidade e função. Os sintomas mais comuns ocorrem na formação dos nós, na inserção foliar, no crescimento vegetal, no desenvolvimento do sistema radicular (cor, grau de desenvolvimento) e nas folhas, que se apresentarem manchas amarelas têm clorose e se apresentarem manchas negras têm necrose.[0014] Nutrients are necessary for the plant to carry out certain functions, so the deficiency and excess are related to visible symptoms that, in turn, are related to its mobility and function. The most common symptoms occur in the formation of nodes, in leaf insertion, in plant growth, in the development of the root system (color, degree of development) and in leaves, which present yellow spots have chlorosis and if they present black spots have necrosis.
Petição 870180065230, de 27/07/2018, pág. 11/35Petition 870180065230, of 27/07/2018, p. 11/35
-5 / 20[0015] A zona da planta que apresenta maior sintoma de deficiência também se relaciona com a mobilidade do nutriente no corpo da planta. Plantas com deficiências em nutrientes móveis são afetadas primeiramente nas zonas mais antigas, como as folhas. Plantas com deficiências em nutrientes imóveis são afetada primeiramente nas zonas mais jovens.-5 / 20 [0015] The area of the plant that presents the greatest deficiency symptom is also related to the mobility of the nutrient in the plant's body. Plants with deficiencies in mobile nutrients are affected primarily in older areas, such as leaves. Plants with deficiencies in immobile nutrients are primarily affected in younger areas.
[0016] O Cálcio (Ca) é um componente da parede celular vegetal, sendo necessário à manutenção da estrutura, à ativação da amilase e à vitalidade das zonas meristemáticas, sendo um nutriente imóvel. Influi no crescimento e desenvolvimento da planta por meio da integração das paredes celulares, estimulando o desenvolvimento radicular e reduzindo a senescência e abscisão de folhas, flores e frutos. Reduz as más-formações dos frutos e aumenta significativamente a sua firmeza, diminuindo o rachamento. Aumenta a conservação dos frutos, assim como sua resistência durante o transporte, teor de carboidratos nas plantas, protegendo-as nas épocas de stress, e contribui positivamente para o desenvolvimento das flores e sua fertilização, estimulando a formação de grãos.[0016] Calcium (Ca) is a component of the plant cell wall, being necessary for the maintenance of the structure, the activation of amylase and the vitality of the meristematic zones, being an immobile nutrient. It influences the growth and development of the plant through the integration of cell walls, stimulating root development and reducing senescence and abscission of leaves, flowers and fruits. Reduces fruit malformations and significantly increases their firmness, reducing cracking. It increases the conservation of fruits, as well as their resistance during transport, carbohydrate content in plants, protecting them in times of stress, and contributes positively to the development of flowers and their fertilization, stimulating the formation of grains.
[0017] A carência de Cálcio origina malformações nas folhas jovens, curvamento dos ápices, clorose marginal que progride para necrose, aumento da porcentagem de vagens chochas, abortamento de flores e frutos, redução do crescimento radicular e mudança da coloração das raízes para castanho. Inicialmente, os sintomas acentuam-se nas zonas mais jovens das plantas.[0017] Calcium deficiency causes malformations in young leaves, curvature of the apices, marginal chlorosis that progresses to necrosis, increase in the percentage of hatched pods, abortion of flowers and fruits, reduction of root growth and change of root color to brown. Initially, the symptoms are accentuated in the younger areas of the plants.
[0018] O Boro (B) é um regulador de metabolismo necessário à translocação de açúcares, sendo um nutriente imóvel dos mais importantes para a planta atingir alta produtividade sem perder a qualidade. É ativador enzimático da fosfolirase do amido, contribuindo para a translocação de açucares e carboidratos das folhas para outros órgãos. Participa do crescimento das partes mais novas da planta, atuando na divisão celular e formação de sua parede, sendo essencial na formação e desenvolvimento reprodutivo. Promove a síntese de proteínas, permite uma boa formação do tubo polínico e pegamento da florada.[0018] Boron (B) is a metabolism regulator necessary for the translocation of sugars, being an immobile nutrient of the most important for the plant to achieve high productivity without losing quality. It is an enzymatic activator of starch phospholirase, contributing to the translocation of sugars and carbohydrates from leaves to other organs. It participates in the growth of the youngest parts of the plant, acting in the cell division and formation of its wall, being essential in the formation and reproductive development. It promotes the synthesis of proteins, allows a good formation of the pollen tube and setting of the flower.
Petição 870180065230, de 27/07/2018, pág. 12/35Petition 870180065230, of 27/07/2018, p. 12/35
-6 / 20[0019] A carência de boro afeta os órgãos de reserva e desorganiza os meristemas, causando a morte das extremidades caulinares. Provoca, ainda, o aparecimento de malformações, pecíolos quebradiços, lento desenvolvimento das gemas terminais e superbrotamento, as folhas novas ficam deformadas e enrugadas, baixa fecundação e acentuada queda de vagens. A floração é completamente suprimida ou originam-se frutos e sementes anormais. Inicialmente, os sintomas acentuam-se nas zonas mais jovens das plantas.-6 / 20 [0019] The lack of boron affects the reserve organs and disorganizes the meristems, causing the death of the stem ends. It also causes the appearance of malformations, brittle petioles, slow development of terminal buds and overgrowth, new leaves are deformed and wrinkled, low fertilization and sharp drop in pods. Flowering is completely suppressed or abnormal fruits and seeds originate. Initially, the symptoms are accentuated in the younger areas of the plants.
[0020] O Molibdênio (Mo) é essencial para a fixação de Nitrogênio e assimilação de nitratos, sendo um nutriente imóvel. Atua como ativador de enzimas e participa de diversos processos do metabolismo das plantas, como a fotossíntese, respiração, formação de vitaminas, hormônios de crescimento (auxinas) e transporte de açucares.[0020] Molybdenum (Mo) is essential for the fixation of Nitrogen and assimilation of nitrates, being an immobile nutrient. It acts as an enzyme activator and participates in several processes of plant metabolism, such as photosynthesis, respiration, formation of vitamins, growth hormones (auxins) and sugar transport.
[0021] A carência de Molibdênio origina manchas cloróticas intervenais seguidas de necrose marginal e enrolamento foliar, interferindo com a frutificação. Diminui a produtividade e a planta fica mais vulnerável a doenças e ataque de pragas. Inicialmente, os sintomas acentuam-se nas zonas mais jovens das plantas.[0021] Molybdenum deficiency causes intervening chlorotic spots followed by marginal necrosis and leaf rolling, interfering with fruiting. Productivity decreases and the plant is more vulnerable to disease and pest attack. Initially, the symptoms are accentuated in the younger areas of the plants.
[0022] Diversos processos ou produtos foram desenvolvidos para produção de fertilizantes disponibilizadores desses elementos para as plantas, destacandose entre os nacionais:[0022] Several processes or products have been developed for the production of fertilizers that make these elements available to plants, standing out among the nationals:
[0023] PI0502365-3 - “Processo para obtenção de fertilizantes”, de 20/06/2005, que visa a obtenção de um fertilizante fluido e homogêneo produzido substancialmente à base de água de maceração de milho, enzimas, corretor de pH e conservante, que pode ser enriquecido com outros elementos, como Magnésio, Enxofre, Cálcio, Cloro, Zinco, Manganês, Cobre, Boro, Molibdênio, Ferro, Cobalto e Silício.[0023] PI0502365-3 - "Process for obtaining fertilizers", dated 06/20/2005, which aims to obtain a fluid and homogeneous fertilizer produced substantially based on corn maceration water, enzymes, pH corrector and preservative , which can be enriched with other elements, such as Magnesium, Sulfur, Calcium, Chlorine, Zinc, Manganese, Copper, Boron, Molybdenum, Iron, Cobalt and Silicon.
[0024] PI9604184-6 - “Complexo nutricional para adubação foliar, hidroponia e fertilização”, de 30/08/1996, que consiste em um produto denominado Niphokam 180, que contém os principais nutrientes minerais[0024] PI9604184-6 - “Nutritional complex for leaf fertilization, hydroponics and fertilization”, of 08/30/1996, which consists of a product called Niphokam 180, which contains the main mineral nutrients
Petição 870180156938, de 29/11/2018, pág. 13/21Petition 870180156938, of 11/29/2018, p. 13/21
-7 / 20quelatizados e diluídos em meio orgânico rico, e contendo Magnésio, Zinco, Boro, Ferro, Molibdênio, Cobre, Enxofre, Manganês e Cálcio.-7 / 20quelatized and diluted in rich organic medium, and containing Magnesium, Zinc, Boron, Iron, Molybdenum, Copper, Sulfur, Manganese and Calcium.
[0025] PI9604185-4 - “Complexo nutricional para adubação foliar, hidroponia e fertirrigação”, de 30/08/1996, que consiste em um produto denominado Niphokam 180, que contém os principais nutrientes minerais quelatizados e diluídos em meio orgânico rico, e contendo Magnésio, Zinco, Boro, Ferro, Molibdênio, Cobre, Enxofre, Manganês e Cálcio.[0025] PI9604185-4 - "Nutritional complex for foliar fertilization, hydroponics and fertigation", of 08/30/1996, which consists of a product called Niphokam 180, which contains the main chelated mineral nutrients and diluted in rich organic medium, and containing Magnesium, Zinc, Boron, Iron, Molybdenum, Copper, Sulfur, Manganese and Calcium.
[0026] Dentre a técnica internacional, podem ser citados os seguintes processos ou produtos:[0026] Among the international techniques, the following processes or products can be mentioned:
[0027] JP2006306683 Mineral material for growing plant and soil conditioner obtained by blending the same”, de 09/11/2006, que consiste em produto condicionador de solo granulado, composto de hidróxidos de cálcio e magnésio, incorporados com Ferro, Manganês, Cobre, Zinco, Boro e Molibdênio (todos no estado atômico), e pela sua mistura com uma mistura de “kieselgur”, argila ativada, zeólito e bentonita cálcica.[0027] JP2006306683 Mineral material for growing plant and soil conditioner obtained by blending the same ”, from 11/09/2006, which consists of granulated soil conditioner product, composed of calcium and magnesium hydroxides, incorporated with Iron, Manganese, Copper , Zinc, Boron and Molybdenum (all in the atomic state), and for their mixture with a mixture of "kieselgur", activated clay, zeolite and calcium bentonite.
[0028] US2004177664 - “Production of a high quality organic-based fertilizer”, de 16/09/2004, que consiste em produto baseado em lama de esgoto tratada, contendo por adição sais de Cálcio, Ferro, lodo, Magnésio, Zinco, Selênio, Cobre, Manganês, Cromo, Molibdênio, Potássio e Boro.[0028] US2004177664 - “Production of a high quality organic-based fertilizer”, of 16/09/2004, which consists of a product based on treated sewage sludge, containing in addition salts of calcium, iron, sludge, magnesium, zinc, Selenium, Copper, Manganese, Chromium, Molybdenum, Potassium and Boron.
[0029] LT2002115 - “Liquid compound fertilizer”, de 26/05/2003, que consiste em processo e produto fertilizante líquido contendo Nitrogênio, Fósforo e Potássio, macronutrientes secundários como Cálcio, Magnésio, Enxofre e suas misturas, e micronutrientes como Cobre, Zinco, Boro, Cobalto, Manganês, Molibdênio, Ferro e suas misturas, onde os macronutrientes secundários (Ca Mg - S) e micronutrientes estão nas faixas (em percentagem de massa) entre 0 e 4 e os micronutrientes entre 0 e 0,5.[0029] LT2002115 - “Liquid compound fertilizer”, dated 05/26/2003, which consists of a liquid fertilizer product and process containing Nitrogen, Phosphorus and Potassium, secondary macronutrients such as Calcium, Magnesium, Sulfur and their mixtures, and micronutrients such as Copper, Zinc, Boron, Cobalt, Manganese, Molybdenum, Iron and their mixtures, where the secondary macronutrients (Ca Mg - S) and micronutrients are in the ranges (in percentage of mass) between 0 and 4 and the micronutrients between 0 and 0.5.
[0030] US6733560 - “Water soluble complex fertilizers, method for their preparation and related use”, de 11/05/2004, que se refere a método de[0030] US6733560 - “Water soluble complex fertilizers, method for their preparation and related use”, dated 11/05/2004, which refers to method of
Petição 870180065230, de 27/07/2018, pág. 14/35Petition 870180065230, of 27/07/2018, p. 14/35
-8 / 20preparação, produto e uso de fertilizante granulado ou perolado, solúvel em água, contendo os macronutrientes N, P, K, macronutrientes secundários como Ca, Mg, S e micronutrientes como F, Mn, Zn, Cu, B e Mo.-8 / 20preparation, product and use of granulated or pearly fertilizer, soluble in water, containing macronutrients N, P, K, secondary macronutrients such as Ca, Mg, S and micronutrients such as F, Mn, Zn, Cu, B and Mo.
[0031] CN1110266 “Trace element compound fertilizer”, de 18/10/1995, que se refere a produto fertilizante contendo macro e micronutrientes suportados em escória de carvão pulverizada, talos vegetais, casca, folhelhos, farelo, cinzas, solo turfoso pulverizado e suas misturas.[0031] CN1110266 “Trace element compound fertilizer”, dated 10/18/1995, which refers to a fertilizer product containing macro and micronutrients supported on pulverized coal slag, vegetable stalks, bark, shales, bran, ash, pulverized peat soil and their mixtures.
[0032] JP5076251 - “Hydroponic water and hydroponics using the same”, de 30/03/1993, que se refere à água hidropônica contendo Nitrogênio, Ácido Fosfórico, Potássio, Magnésio, Enxofre, Ferro, Manganês, Zinco, solução diluída de sais de ferro bi e trivalentes e Ca de 1 a 5% (peso), B de 0 a 0,2%, e Mo de 0 a 0,005 %.[0032] JP5076251 - “Hydroponic water and hydroponics using the same”, from 03/30/1993, which refers to hydroponic water containing Nitrogen, Phosphoric Acid, Potassium, Magnesium, Sulfur, Iron, Manganese, Zinc, diluted salt solution of bi and trivalent iron and Ca of 1 to 5% (weight), B of 0 to 0.2%, and Mo of 0 to 0.005%.
[0033] GB1138318- “Method and compositions for fertilising plants”, de 01/01/1969, que se refere a fertilizante em pó ou solução aquosa contendo Nitrogênio, Fósforo, Potássio, Cálcio, Magnésio e Enxofre, onde o Cálcio está na forma de carbonato de cálcio.[0033] GB1138318- “Method and compositions for fertilising plants”, from 01/01/1969, which refers to powdered fertilizer or aqueous solution containing Nitrogen, Phosphorus, Potassium, Calcium, Magnesium and Sulfur, where Calcium is in the form of calcium carbonate.
[0034] O produto objeto desta invenção é constituído de micronutrientes, macronutrientes, substâncias formadoras de filmes, complexantes de Boro, Cálcio e Molibdênio, agentes adesivos, agentes emulsificantes, agentes orgânicos naturais e aditivos nutritivos.[0034] The product object of this invention consists of micronutrients, macronutrients, film-forming substances, complexes of Boron, Calcium and Molybdenum, adhesive agents, emulsifying agents, natural organic agents and nutritional additives.
[0035] O produto da presente invenção se apresenta na forma líquida e altamente concentrada, fornecendo uma tripla combinação dos nutrientes Ca , B e Mo, além de aditivos combinados que ajudam a melhorar a qualidade da mistura e, principalmente, equilibrar o ponto máximo de saturação. O produto também possui aditivo especial que aumenta a sua dispersibilidade e aderência sobre as folhas, em caso de aplicação foliar.[0035] The product of the present invention comes in liquid and highly concentrated form, providing a triple combination of nutrients Ca, B and Mo, in addition to combined additives that help to improve the quality of the mixture and, mainly, to balance the maximum point of saturation. The product also has a special additive that increases its dispersibility and adhesion on the leaves, in case of foliar application.
[0036] Os nutrientes Ca ,B e Mo são disponibilizados nas doses e relações corretas para todo tipo de cultura, mostrando-se um produto fácil de usar. Sendo[0036] The nutrients Ca, B and Mo are available in the correct doses and ratios for all types of culture, proving to be an easy to use product. Being
Petição 870180065230, de 27/07/2018, pág. 15/35Petition 870180065230, of 27/07/2018, p. 15/35
-9 / 20aplicado preferencialmente via foliar, apresenta melhores resultados devido a sua característica de fixação, evitando-se as perdas por lavagem natural de chuva logo após a aplicação.-9 / 20applied preferentially via leaf, it presents better results due to its fixation characteristic, avoiding losses due to natural rain washing immediately after application.
[0037] Como todos os nutrientes estão complexados e apresentam alta solubilidade, essa invenção apresenta maior facilidade de mistura e uniformidade em tanques de preparação e de dissolução para aplicação, evitando-se as perdas por precipitação.[0037] As all nutrients are complexed and have high solubility, this invention presents greater ease of mixing and uniformity in preparation and dissolution tanks for application, avoiding losses due to precipitation.
[0038] As vantagens de se usar este fertilizante na forma tripla combinada de Ca 10%, B 2%, Mo 0,01% com aditivos são a alta concentração dos nutrientes, a compatibilidade sinérgica entre os componentes, solubilidade total em água, não deixando resíduos nem entupindo os bicos de aplicadores, melhor dispersibilidade e melhor aderência.[0038] The advantages of using this fertilizer in the combined triple form of Ca 10%, B 2%, Mo 0.01% with additives are the high concentration of nutrients, the synergistic compatibility between the components, total solubility in water, no leaving no residue or clogging the nozzles of applicators, better dispersibility and better adhesion.
[0039] O produto, testado em campo, apresentou excelentes resultados agronômicos, promovendo:[0039] The product, tested in the field, showed excellent agronomic results, promoting:
• Maior uniformidade no processo de germinação;• Greater uniformity in the germination process;
• Alto vigor das plantas;• High vigor of the plants;
• Melhor formação das plantas, devido ao maior desenvolvimento do sistema radicular;• Better formation of plants, due to the greater development of the root system;
• Maior equilíbrio nutricional, com melhor absorção e aproveitamento dos nutrientes e água do solo devido à formação de seu sistema radicular mais profundo e volumoso, as plantas não apresentam sinais de deficiência dos nutrientes, não causando danos à planta e perdas na produção;• Greater nutritional balance, with better absorption and use of nutrients and water from the soil due to the formation of its deeper and bulky root system, the plants show no signs of nutrient deficiency, causing no damage to the plant and losses in production;
• Aumento na quantidade de cloroplastos e produção de clorofila;• Increase in the amount of chloroplasts and chlorophyll production;
• Aumento na atividade metabólica induzindo o sistema imunológico da planta, proporcionando maior resistência a pragas e doenças;• Increase in metabolic activity inducing the plant's immune system, providing greater resistance to pests and diseases;
Petição 870180065230, de 27/07/2018, pág. 16/35Petition 870180065230, of 27/07/2018, p. 16/35
-10/20- • Redução do aborto floral causado por agentes externos e internos;-10 / 20- • Reduction of floral abortion caused by external and internal agents;
• Redução do stress causado por danos ambientais, sanitários e decorrentes do manejo;• Reduction of stress caused by environmental, health and handling damages;
• Melhoria na consistência e na firmeza dos frutos, legumes e tubérculos;• Improvement in the consistency and firmness of fruits, vegetables and tubers;
• Melhoria no processo fisiológico da planta;• Improvement in the plant's physiological process;
• Maior produtividade.• Higher productivity.
[0040] De acordo com cada tipo de cultura, o produto tem sua dosagem recomendada, mostrando-se um produto fácil de usar via aplicação foliar, hidroponia ou fertirrigação, necessitando de baixo investimento para sua aplicação.[0040] According to each type of culture, the product has its recommended dosage, showing itself to be an easy to use product via foliar application, hydroponics or fertigation, requiring low investment for its application.
[0041] A Tabela 1 apresenta recomendações ideais para aplicação do produto, que podem variar em função dos interesses do agricultor.[0041] Table 1 presents ideal recommendations for applying the product, which may vary depending on the interests of the farmer.
Tabela 1 - Recomendações ideais de uso:Table 1 - Ideal recommendations for use:
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-11/20--11 / 20-
Obs.: Dosagem: ml_/ha = mililitro de produto por hectare de cultura mL/L = mililitro de produto por litro de líquido aplicado na cultura [0042] O produto pode ser aplicado em rega, pulverizado, disperso, suportado, ou em qualquer combinação de uso, em culturas simples de leguminosas ou em culturas mistas, podendo também ser aplicado em hidroponia ou fertirrigação.Obs .: Dosage: ml_ / ha = milliliter of product per hectare of culture mL / L = milliliter of product per liter of liquid applied to the crop [0042] The product can be applied in irrigation, sprayed, dispersed, supported, or in any combination of use, in simple leguminous cultures or in mixed cultures, and can also be applied in hydroponics or fertigation.
[0043] O produto contém, como macronutriente, fontes de Cálcio nas formas de cloreto, acetato, nitrato, citrato, ou suas misturas (0 a 100%). Outros macronutrientes podem ser opcionalmente acrescentados.[0043] The product contains, as a macronutrient, sources of calcium in the forms of chloride, acetate, nitrate, citrate, or their mixtures (0 to 100%). Other macronutrients can be optionally added.
[0044] Como micronutriente, fontes de Molibdênio na forma de molibdatos de sódio, de potássio, de cálcio, trióxido de molibdênio com mistura de sais de molibdato solúveis em água ou a condensação de sais solúveis de molibdato com ácido fosfórico, ácido fosforoso, glicerofosfato ou suas misturas (0 a 100%).[0044] As micronutrient, sources of Molybdenum in the form of sodium, potassium, calcium molybdates, molybdenum trioxide with a mixture of water-soluble molybdate salts or the condensation of soluble molybdate salts with phosphoric acid, phosphoric acid, glycerophosphate or their mixtures (0 to 100%).
[0045] Como micronutriente, fontes de Boro nas formas de ácido ortobórico, perboratos de sódio ou potássio, ou suas misturas (0 a 100%).[0045] As micronutrient, sources of Boron in the forms of orthoboric acid, sodium or potassium perborates, or their mixtures (0 to 100%).
Petição 870180065230, de 27/07/2018, pág. 18/35Petition 870180065230, of 27/07/2018, p. 18/35
-12/20[0046] O produto é formado, basicamente, por Cálcio, Boro, Molibdênio, agentes e aditivos, podendo ser utilizado de forma isolada ou associado a outros fertilizantes.-12/20 [0046] The product is basically formed by Calcium, Boron, Molybdenum, agents and additives, and can be used in isolation or associated with other fertilizers.
[0047] A Tabela 2 apresenta as quantidades de macro e micronutrientes na formulação do produto.[0047] Table 2 shows the amounts of macro and micronutrients in the product formulation.
Tabela 2: Garantias das quantidades de macro e micronutrientes no produtoTable 2: Guarantees of macro and micronutrient quantities in the product
Obs.:Garantias dadas em peso/peso: É a massa do sal (g/L) multiplicada pela garantia do sal (em %) dividido pela densidade do produto (g/L). Exemplo: 567 g/L de cloreto de cálcio x 24% dividido por 1360 g/L que resulta em 10%, que é garantia dada ao agricultor e ao Ministério da Agricultura.Obs.:Warranty given by weight / weight: It is the mass of the salt (g / L) multiplied by the guarantee of the salt (in%) divided by the density of the product (g / L). Example: 567 g / L of calcium chloride x 24% divided by 1360 g / L which results in 10%, which is a guarantee given to the farmer and the Ministry of Agriculture.
Garantias em peso/volume (massa do elemento contido no sal): É garantia do sal (%) multiplicada pela massa do sal adicionado (g/L) dividido por 100. Exemplo: A garantia do cloreto de cálcio é de 24% x a massa total do sal de 560 g/l dividido por 100, que vai resultar na massa do elemento que é de 136,08 g/l.Weight / volume guarantees (mass of the element contained in the salt): It is a guarantee of the salt (%) multiplied by the mass of the added salt (g / L) divided by 100. Example: The guarantee of calcium chloride is 24% x the mass total salt of 560 g / l divided by 100, which will result in the mass of the element which is 136.08 g / l.
[0048] O “PRODUTO FERTILIZANTE LÍQUIDO CONTENDO CÁLCIO, BORO E MOLIBDÊNIO E PROCESSO DE PRODUÇÃO”, objeto desta patente, também contém em sua formulação aditivos que atuam na funcionalidade do produto, no montante entre 10 e 33% em peso do produto, não havendo valor preferencial, dependendo dos interesses do agricultor.[0048] The “LIQUID FERTILIZING PRODUCT CONTAINING CALCIUM, BORON AND MOLYBDENUM AND PRODUCTION PROCESS”, object of this patent, also contains in its formulation additives that act on the product's functionality, in the amount between 10 and 33% by weight of the product, no with preferential value, depending on the interests of the farmer.
[0049] Os aditivos ou substâncias diversas utilizados, indicados a seguir em forma isolada, mas podendo também ser usados na forma de suas misturas[0049] The additives or miscellaneous substances used, indicated below in isolation, but may also be used in the form of their mixtures
Petição 870180065230, de 27/07/2018, pág. 19/35Petition 870180065230, of 27/07/2018, p. 19/35
-13 / 20desde que respeitadas as compatibilidades, são agentes com várias funções, especificadas conforme abaixo indicados:-13 / 20 provided that the compatibilities are respected, they are agents with several functions, specified as indicated below:
- agentes de complexação dos macro e micronutrientes: Queratina hidrolisada (de 40 a 80 g/L, de preferência 70 g/L); ou sal sódico do ácido etilenodiaminotetra-acético - EDTA - 2Na ou 3Na (de 0,5 a 3,0 g/L, de preferência 2,0 g/L); ou ácido ascórbico (de 0,5 a 3,0 g/L, de preferência 2,0 g/L); ou ácido cítrico (de 0,5 a 3,0 g/L, de preferência 2,0 g/L); ou ácido etidrônico (de 0,5 a 3,0 g/L, de preferência 2,0 g/L); ou lignossulfonatos de sódio, ou de cálcio ou de magnésio (de 0,5 a 3,0 g/L, de preferência 2,0 g/L); ou sacarose (de 200 g/L a 230 g/L de preferência 227 g/L); ou suas misturas.- complexing agents for macro and micronutrients: hydrolyzed keratin (from 40 to 80 g / L, preferably 70 g / L); or sodium salt of ethylenediaminetetraacetic acid - EDTA - 2Na or 3Na (from 0.5 to 3.0 g / L, preferably 2.0 g / L); or ascorbic acid (from 0.5 to 3.0 g / L, preferably 2.0 g / L); or citric acid (from 0.5 to 3.0 g / L, preferably 2.0 g / L); or etidronic acid (from 0.5 to 3.0 g / L, preferably 2.0 g / L); or sodium, or calcium or magnesium lignosulfonates (from 0.5 to 3.0 g / L, preferably 2.0 g / L); or sucrose (from 200 g / L to 230 g / L preferably 227 g / L); or their mixtures.
- Dispersante do cálcio e complexante do boro: sacarose, na dosagem de 200 a 230 g/L, de preferência 200 a 227 g/L;- Dispersant of calcium and complexing of boron: sucrose, in the dosage of 200 to 230 g / L, preferably 200 to 227 g / L;
- Agentes emulsificantes: usados para o aumento da dispersibilidade do produto na planta e formar emulsão estável, sendo óleo de mamona hidrogenado e etoxilado 40 mol (de 1,0 a 10,0 g/L, de preferência 1 a 8,0 g/L) ou álcool laurílico etoxilado 2 mol (de 5,0 a 10,0 g/L, de preferência 5,0 a 8,0 g/l) ou nonil fenol etoxilado 10 mol (de 1,0 a 10,0 g/L, de preferência 1,0 a 8,0 g/L); ou suas misturas (0 a 100%).- Emulsifying agents: used to increase the dispersibility of the product in the plant and to form a stable emulsion, with hydrogenated and ethoxylated castor oil being 40 mol (from 1.0 to 10.0 g / L, preferably 1 to 8.0 g / L L) or 2 mol ethoxylated lauryl alcohol (from 5.0 to 10.0 g / L, preferably 5.0 to 8.0 g / l) or 10 mol ethoxylated nonyl phenol (from 1.0 to 10.0 g / L, preferably 1.0 to 8.0 g / L); or their mixtures (0 to 100%).
- Agentes adesivos do produto à planta: têm a função de “fixador” após ser aplicado por via foliar. Podem ser usadas várias misturas de: sacarose (de 200 g/L a 230 g/L, de preferência 227 g/L), ou Polivinilpirrolidona (PVP-K30 ou 90) (de 1,0 a 4,0 g/L, de preferência 3,0 g/L); ou glicerina (de 10 g/L a 20 g/L, de preferência 15 g/L), ou glicerina acetilada (de 10 g/L a 20 g/L, de preferência 15 g/L), ou amido modificado (de 10 g/L a 20 g/L, de preferência 16,5 g/L), ou polietilenoglicol (de 1 g/L a 5 g/L, de preferência 3,5 g/L), ou propilenoglicol (de 10 g/L a 20 g/L, de preferência 20 g/L), ou ésteres de celulose (de 1 g/L a 5 g/L, de preferência 4,5 g/L), ou glucose (de 5 g/L a 20 g/L, de preferência 15 g/L), ou óleo vegetais de soja, ou de milho, ou de canola, ou de amendoim, ou de Nim ou de Melalêuca (de 1,0 a 15,0 g/L, de preferência 10,0 g/L); ou óleo mineral emulsionado (de 1,0 a 10,0 g/L, de preferência 10,0 g/L), ou- Adhesive agents of the product to the plant: they have the function of “fixative” after being applied by foliar way. Various mixtures of: sucrose (from 200 g / L to 230 g / L, preferably 227 g / L), or Polyvinylpyrrolidone (PVP-K30 or 90) (from 1.0 to 4.0 g / L, preferably 3.0 g / L); or glycerin (from 10 g / L to 20 g / L, preferably 15 g / L), or acetylated glycerin (from 10 g / L to 20 g / L, preferably 15 g / L), or modified starch (from 10 g / L to 20 g / L, preferably 16.5 g / L), or polyethylene glycol (from 1 g / L to 5 g / L, preferably 3.5 g / L), or propylene glycol (from 10 g / L to 20 g / L, preferably 20 g / L), or cellulose esters (from 1 g / L to 5 g / L, preferably 4.5 g / L), or glucose (from 5 g / L at 20 g / L, preferably 15 g / L), or vegetable oil from soy, or corn, or canola, or peanut, or Neem or Melaluca (from 1.0 to 15.0 g / L , preferably 10.0 g / L); or emulsified mineral oil (from 1.0 to 10.0 g / L, preferably 10.0 g / L), or
Petição 870180156938, de 29/11/2018, pág. 14/21Petition 870180156938, of 11/29/2018, p. 14/21
-14/20- lecitina de soja (de 1,0 g/L a 2,0 g/L, de preferência 1,7 g/L) , ou sorbitol (de 1,0 g/L a 10,0 g/L, de preferência 5,0 g/L) ou ceramidas (de 2,0 g/L a 5,0 g/L, de preferência 3,0 g/L); ou extrato glicólico ou alcoólico de própolis (de 1,0 g/L a 5 g/L, de preferência 5,0 g/L), extrato natural de alho ou óleo de alho (de 1,0 a 5,0 g/L, de preferência 3,0 g/L), ou suas misturas (de 1,0 a 20 g/L, de preferência-14 / 20- soy lecithin (from 1.0 g / L to 2.0 g / L, preferably 1.7 g / L), or sorbitol (from 1.0 g / L to 10.0 g / L L, preferably 5.0 g / L) or ceramides (from 2.0 g / L to 5.0 g / L, preferably 3.0 g / L); or glycolic or alcoholic extract of propolis (from 1.0 g / L to 5 g / L, preferably 5.0 g / L), natural garlic extract or garlic oil (from 1.0 to 5.0 g / L L, preferably 3.0 g / L), or mixtures thereof (from 1.0 to 20 g / L, preferably
14,5 a 15,5 g/L);14.5 to 15.5 g / L);
- Dispersantes: silicones ou óleos de silicone emulsionados (de 1,0 a 4,0 g/L, de preferência 1,0 a 3,0 g/L);- Dispersants: emulsified silicone or silicone oils (from 1.0 to 4.0 g / L, preferably 1.0 to 3.0 g / L);
- Vitamina A (de 0,1 a 0,3 g/L, de preferência 0,1 a 0,2 g/L), ou vitamina B-5 ( 1,0 a 8,0 g/L, de preferência1,0 a 6,0 g/L), ou vitaminas do complexo B ( 0,1 a 0,5 g/L, de preferência 0,1 a 0,5 g/L) ou vitamina E (0,1 a 0,5 g/L, de preferência 0,1 a 0,2 g/L), como nutrientes orgânicos e usados para ajudar na rápida absorção dos complexos de cálcio, boro e molibdênio quando aplicados via foliar, evitando-se a queima- Vitamin A (from 0.1 to 0.3 g / L, preferably 0.1 to 0.2 g / L), or vitamin B-5 (1.0 to 8.0 g / L, preferably 1, 0 to 6.0 g / L), or B vitamins (0.1 to 0.5 g / L, preferably 0.1 to 0.5 g / L) or vitamin E (0.1 to 0, 5 g / L, preferably 0.1 to 0.2 g / L), as organic nutrients and used to aid in the rapid absorption of calcium, boron and molybdenum complexes when applied via leaf, avoiding burning
- Aditivos orgânicos “naturais” como extrato glicólico ou alcoólico de própolis (de 1,0 a 5,0 g/L, de preferência 4,0 a 5,0 g/L), extrato ou óleo de alho (de 1,0 a 5,0 g/L, de preferência 2,0 a 3,0 g/L),ou óleo de Nim emulsionado (de 1,0 a 15,0 g/L, de preferência 9,0 a 10,0 g/L) ou óleo de melalêuca emulsionado (de 1,0 a 15,0 g/L, de preferência 9,0 a 10,0 g/L), ou suas misturas (0 a 100%). São usados como coadjuvantes para melhorar o sistema adesivo e também por ajudar na ação de “repelente natural” contra insetos em plantas, além de não agredir o meio ambiente.- “Natural” organic additives such as glycolic or alcoholic propolis extract (from 1.0 to 5.0 g / L, preferably 4.0 to 5.0 g / L), garlic extract or oil (from 1.0 at 5.0 g / L, preferably 2.0 to 3.0 g / L), or emulsified neem oil (from 1.0 to 15.0 g / L, preferably 9.0 to 10.0 g / L) or emulsified melaluca oil (from 1.0 to 15.0 g / L, preferably 9.0 to 10.0 g / L), or mixtures thereof (0 to 100%). They are used as adjuvants to improve the adhesive system and also to help in the action of “natural repellent” against insects in plants, in addition to not harming the environment.
- Agente modificador de reação, para uso com ácido bórico (formando perborato de sódio) para melhoria da solubilidade, como peróxido de hidrogênio em solução a 50 % ou 200 volumes (de 13,5 a 21,0 g/L, preferencialmente de 15,0 a 20,0 g/L) adicionado com hidróxido de sódio ou de potássio em escamas (de 13,5 a 21,0 g/L, de preferência entre 15,0 a 20,0 g/L);- Reaction modifying agent, for use with boric acid (forming sodium perborate) to improve solubility, such as hydrogen peroxide in 50% solution or 200 volumes (from 13.5 to 21.0 g / L, preferably 15 , 0 to 20.0 g / L) added with scaled sodium or potassium hydroxide (from 13.5 to 21.0 g / L, preferably between 15.0 to 20.0 g / L);
- Agente corretor de pH e de viscosidade: solução de hidróxido de amônio (de 87,0 a 110,0 g/L, de preferência entre 90,0 e 100 g/L).- pH and viscosity correction agent: ammonium hydroxide solution (from 87.0 to 110.0 g / L, preferably between 90.0 and 100 g / L).
Petição 870180065230, de 27/07/2018, pág. 21/35Petition 870180065230, of 27/07/2018, p. 21/35
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O fertilizante tem densidade entre 1350 e 1360 g/L e pH entre 6,0 e 6,5.The fertilizer has a density between 1350 and 1360 g / L and a pH between 6.0 and 6.5.
[0050] A formulação de um “PRODUTO FERTILIZANTE LÍQUIDO CONTENDO CÁLCIO, BORO E MOLIBDÊNIO E PROCESSO DE PRODUÇÃO”, recomendada consiste em uma composição líquida para uso isolado ou em conjunto com outros produtos fertilizantes, contendora da forma tripla combinada de Ca (567,0 g/L), B (160 g/L), Mo (0,35 g/L) com os aditivos: agente de complexação dos macro e micronutrientes (de 200 a 230 g/L), dispersante do Cálcio e complexante do Boro (sacarose de 200 a 230 g/L), agente emulsificante (de 1,0 a 8,0 g/L), agente complexante ( EDTA 2Na de 0,5 a 2,0 g/L), agente adesivo do produto à planta (de 1,0 a 20,0 g/L), agente dispersante (de 1,0 a 8,0 g/L), aditivos orgânicos usados para melhoria do sistema adesivo e ação repelente de insetos (de 0,1 a 15,0 g/L), agente modificador de reação (de 10,0 a 20,0, g/L), agente corretor de pH e de viscosidade (hidróxido de amônio,de 100,0 a 110,0 g/L).[0050] The formulation of a “LIQUID FERTILIZING PRODUCT CONTAINING CALCIUM, BORON AND MOLYBDENUM AND PRODUCTION PROCESS”, recommended consists of a liquid composition for use alone or in conjunction with other fertilizers, containing the combined triple form of Ca (567, 0 g / L), B (160 g / L), Mo (0.35 g / L) with additives: complexing agent of macro and micronutrients (from 200 to 230 g / L), dispersant of calcium and complexing of Boron (sucrose from 200 to 230 g / L), emulsifying agent (from 1.0 to 8.0 g / L), complexing agent (EDTA 2Na from 0.5 to 2.0 g / L), adhesive product to the plant (from 1.0 to 20.0 g / L), dispersing agent (from 1.0 to 8.0 g / L), organic additives used to improve the adhesive system and insect repellent action (from 0.1 to 15.0 g / L), reaction modifying agent (from 10.0 to 20.0, g / L), pH and viscosity correcting agent (ammonium hydroxide, from 100.0 to 110.0 g / L).
[0051] O processo de produção de “PRODUTO FERTILIZANTE LÍQUIDO CONTENDO CÁLCIO, BORO E MOLIBDÊNIO E PROCESSO DE PRODUÇÃO” consiste na mistura ordenada de diversas matérias primas, conforme procedimento a seguir descrito:[0051] The production process of “LIQUID FERTILIZING PRODUCT CONTAINING CALCIUM, BORON AND MOLYBDENUM AND PRODUCTION PROCESS” consists of the ordered mixture of several raw materials, according to the procedure described below:
[0052] Em um tanque, preferencialmente de aço inoxidável e fundo cônico, encamisado para entrada de água fria e contendo aquecimento indireto de vapor ou resistência elétrica, com termômetro para controle da temperatura, provido de agitador mecânico com controle da rotação, hélice tipo naval, injetor de líquido pelo fundo através de bomba e saída de produto líquido pelo fundo do reator com válvula de esfera, efetuar as operações de mistura na ordem indicada:[0052] In a tank, preferably of stainless steel and tapered bottom, jacketed for the entry of cold water and containing indirect steam heating or electrical resistance, with a thermometer for temperature control, equipped with a mechanical stirrer with rotation control, naval type propeller , liquid injector through the bottom through a pump and liquid product outlet through the bottom of the ball valve reactor, perform the mixing operations in the order indicated:
1. Acionar o agitador entre 500 a 2000 rpm, preferencialmente entre 800 a 1200 rpm e adicionar água (de 80 a 160 mL/L) potável ou destilada ou deionizada, preferencialmente água (100 a 150 mL/L) potável;1. Activate the stirrer between 500 to 2000 rpm, preferably between 800 to 1200 rpm and add drinking or distilled or deionized water (from 80 to 160 mL / L), preferably drinking water (100 to 150 mL / L);
Petição 870180065230, de 27/07/2018, pág. 22/35Petition 870180065230, of 27/07/2018, p. 22/35
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2. Adicionar lentamente hidróxido de sódio ou potássio e deixar por alguns minutos sem aquecimento e baixa rotação entre 80 e 200 rpm, de preferência entre 80 e 160 rpm;2. Slowly add sodium or potassium hydroxide and leave for a few minutes without heating and low rotation between 80 and 200 rpm, preferably between 80 and 160 rpm;
3. A seguir, adicionar o ácido bórico ou ortobórico (fonte de boro) para reagir com a base, formando “flocos” de metaborato de sódio ou potássio;3. Next, add the boric or ortho-boric acid (boron source) to react with the base, forming “flakes” of sodium or potassium metaborate;
4. Adicionar peróxido de hidrogênio para formar perborato de sódio ou potássio, que é mais solúvel, e aquecer a mistura entre 40 e 95 °C, preferencialmente entre 50 e 75 °C;4. Add hydrogen peroxide to form sodium or potassium perborate, which is more soluble, and heat the mixture between 40 and 95 ° C, preferably between 50 and 75 ° C;
5. Adicionar o agente dispersante de Cálcio, dissolvendo-o sob agitação constante entre 1000 e 2000 rpm, preferencialmente entre 1000 e 1570 rpm;5. Add the calcium dispersing agent, dissolving it under constant agitation between 1000 and 2000 rpm, preferably between 1000 and 1570 rpm;
6. Adicionar o agente complexante;6. Add the complexing agent;
7. Adicionar lentamente a fonte de Cálcio, mantendo a temperatura entre 40 e 95° C, de preferência entre 40 e 80 °C por um período de 20 a 60 minutos, de preferência entre 20 e 45 minutos;7. Add the Calcium source slowly, keeping the temperature between 40 and 95 ° C, preferably between 40 and 80 ° C for a period of 20 to 60 minutes, preferably between 20 and 45 minutes;
8. Resfriar a mistura até a temperatura ambiente, sob agitação constante de 500 a 1000 rpm, preferencialmente entre 500 a 550 rpm, injetar pelo fundo do tanque uma solução de hidróxido de amônio, com a finalidade de diminuir a viscosidade e corrigir o pH entre 4,00 e 6,00, de preferência pH entre 5,00 e 6,00;8. Cool the mixture to room temperature, under constant agitation from 500 to 1000 rpm, preferably between 500 to 550 rpm, inject into the bottom of the tank a solution of ammonium hydroxide, in order to decrease the viscosity and correct the pH between 4.00 and 6.00, preferably pH between 5.00 and 6.00;
9. Adicionar lentamente os diversos aditivos, que devem ser preparados separadamente, sob temperatura ambiente e baixa rotação, entre 50 e 200 rpm, de preferência entre 50 e 100 rpm;9. Slowly add the various additives, which must be prepared separately, at room temperature and low rotation, between 50 and 200 rpm, preferably between 50 and 100 rpm;
Petição 870180065230, de 27/07/2018, pág. 23/35Petition 870180065230, of 27/07/2018, p. 23/35
-17/ΣΟΙ 0. Adicionar a fonte de Molibdênio nas mesmas condições de agitação e temperatura;-17 / ΣΟΙ 0. Add the Molybdenum source under the same stirring and temperature conditions;
11. Completar o nível do tanque com água até o volume desejado;11. Complete the tank level with water to the desired volume;
12. Deixar de 10 a 15 horas o produto sob agitação lenta entre12. Leave the product for 10 to 15 hours with slow stirring between
400 a 900 rpm, mantendo a mistura sob injeção de ar comprimido pelo fundo do tanque à velocidade de 30 a 60 L/h e na temperatura ambiente. Após este procedimento, transferir a mistura para outro recipiente, passando por filtro retentor das impurezas;400 to 900 rpm, keeping the mixture under injection of compressed air through the bottom of the tank at a speed of 30 to 60 L / h and at room temperature. After this procedure, transfer the mixture to another container, passing through an impurity retaining filter;
13. Deixar o produto em repouso no mínimo por quinze dias antes de começar a envasar.13. Leave the product to rest for at least fifteen days before starting to fill.
[0053] O processo de preparação em separado dos aditivos (passo 9 do processo de mistura) a serem adicionados ao “PRODUTO FERTILIZANTE LÍQUIDO CONTENDO CÁLCIO, BORO E MOLIBDÊNIO E PROCESSO DE PRODUÇÃO”, objeto desta patente, é realizado em duas fases:[0053] The preparation process separately from the additives (step 9 of the mixing process) to be added to the "LIQUID FERTILIZER PRODUCT CONTAINING CALCIUM, BORON AND MOLYBDENUM AND PRODUCTION PROCESS", object of this patent, is carried out in two stages:
[0054] Preparação da FASE A:[0054] Preparation of PHASE A:
[0055] Em um recipiente preferencialmente cilíndrico, encamisado, com fundo cônico, em aço inox, com aquecimento externo e provido de um agitador mecânico com hélice naval e saída pelo fundo do vaso com válvula em aço inox, adicionar na ordem:[0055] In a preferably cylindrical container, jacketed, with conical bottom, in stainless steel, with external heating and provided with a mechanical stirrer with naval propeller and outlet through the bottom of the vessel with stainless steel valve, add in the order:
1o - o agente emulsificante e aquecer lentamente entre 20 e 50 °C, de preferência entre 20 e 35°C, sem proceder a agitação;1 o - the emulsifying agent and heat slowly between 20 and 50 ° C, preferably between 20 and 35 ° C, without stirring;
2o - aos poucos, adicionar o agente adesivo e aditivo orgânico sob agitação constante de 50 rpm a 150 rpm, de preferência entre 80 e 100 rpm, mantendo a temperatura entre 40 e 50°C, de preferência entre 40 e 45°C, e continuar a agitação por 30 a 60 minutos, de preferência entre 40 e 45 minutos;2 o - gradually add the adhesive and organic additive under constant agitation from 50 rpm to 150 rpm, preferably between 80 and 100 rpm, keeping the temperature between 40 and 50 ° C, preferably between 40 and 45 ° C, and continue stirring for 30 to 60 minutes, preferably between 40 and 45 minutes;
Petição 870180065230, de 27/07/2018, pág. 24/35Petition 870180065230, of 27/07/2018, p. 24/35
-18/20[0056] Preparação da FASE B [0057] Em um recipiente preferencialmente cilíndrico encamisado com fundo cônico de aço inoxidável, com aquecimento externo e entrada de água fria para circulação, com saída pelo fundo do tanque e motor de agitação com hélice naval, adicionar na ordem:-18/20 [0056] Preparation of PHASE B [0057] In a preferably cylindrical jacketed container with stainless steel conical bottom, with external heating and cold water inlet for circulation, with outlet through the bottom of the tank and propeller stirring motor naval, add in order:
1o - O agente complexante e aquecer lentamente sem agitação de 40 a 50°C, de preferência entre 40 e 45°C;1 o - The complexing agent and heat slowly without stirring from 40 to 50 ° C, preferably between 40 and 45 ° C;
2o - solução aquosa de aditivo fixador, mantendo a mesma temperatura e rotação de 100 a 200 rpm, de preferência entre 120 e 150 rpm;2 o - aqueous solution of fixative additive, maintaining the same temperature and rotation from 100 to 200 rpm, preferably between 120 and 150 rpm;
3o - o agente dispersante e aquecer levemente entre 40 e 60 °C, preferencialmente entre 40 e 50 °C, sob agitação de 200 a 500 rpm, preferencialmente entre 250 e 300 rpm, por 10 a 40 minutos, preferencialmente entre 10 e 30 minutos.3 o - the dispersing agent and heat slightly between 40 and 60 ° C, preferably between 40 and 50 ° C, with stirring from 200 to 500 rpm, preferably between 250 and 300 rpm, for 10 to 40 minutes, preferably between 10 and 30 minutes.
[0058] Misturar as FASES A e B, agitar de 200 rpm a 500 rpm, preferencialmente entre 300 e 400 rpm, por 30 a 60 minutos, preferencialmente entre 35 e 45 minutos, e esfriar até temperatura ambiente.[0058] Mix PHASES A and B, stir from 200 rpm to 500 rpm, preferably between 300 and 400 rpm, for 30 to 60 minutes, preferably between 35 and 45 minutes, and cool to room temperature.
[0059] Em seguida, adicionar os nutrientes orgânicos sobre a mistura das FASES A e B, em temperatura ambiente e sob agitação de 100 a 300 rpm, preferencialmente de 150 a 200 rpm, por 20 a 60 minutos, preferencialmente de 30 a 60 minutos; .[0059] Then add the organic nutrients over the mixture of PHASES A and B, at room temperature and under agitation from 100 to 300 rpm, preferably from 150 to 200 rpm, for 20 to 60 minutes, preferably from 30 to 60 minutes ; .
[0060] Filtrar e armazenar em recipiente opaco, sob temperatura ambiente, para posteriormente adicioná-la sob a forma de aditivo na mistura do produto fertilizante.[0060] Filter and store in an opaque container, at room temperature, to later add it as an additive in the fertilizer product mixture.
[0061] EXEMPLO DE FORMULAÇÃO PARA A PRODUÇÃO DE 1 LITRO DO FERTILIZANTE:[0061] FORMULATION EXAMPLE FOR THE PRODUCTION OF 1 LITER OF FERTILIZER:
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[0062] Formulação para produção de 100 g de aditivo para adicionar em 1 litro do fertilizante:[0062] Formulation for the production of 100 g of additive to add in 1 liter of the fertilizer:
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[0063] Características do produto obtido[0063] Characteristics of the product obtained
Aspecto: solução líquida homogênea de cor amarela amarronzada pH direto à 25° C: 6,00 a 6,50Aspect: homogeneous brownish yellow liquid solution pH direct at 25 ° C: 6.00 to 6.50
Densidade à 25° C: entre 1,350 e 1,360 kg / LDensity at 25 ° C: between 1.350 and 1.360 kg / L
(1) Não considerar N como fertilizante, pois faz parte do processo de estabilidade das reações químicas presentes na mistura. (1) Do not consider N as a fertilizer, as it is part of the process of stability of the chemical reactions present in the mixture.
Claims (7)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BRPI0804461-9A BRPI0804461B1 (en) | 2008-01-23 | 2008-01-23 | PRODUCT LIQUID FERTILIZER CONTAINING CALCIUM, BORON AND MOLYBDEN AND PRODUCTION PROCESS |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BRPI0804461-9A BRPI0804461B1 (en) | 2008-01-23 | 2008-01-23 | PRODUCT LIQUID FERTILIZER CONTAINING CALCIUM, BORON AND MOLYBDEN AND PRODUCTION PROCESS |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0804461A2 BRPI0804461A2 (en) | 2009-09-15 |
| BRPI0804461B1 true BRPI0804461B1 (en) | 2019-06-18 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0804461-9A BRPI0804461B1 (en) | 2008-01-23 | 2008-01-23 | PRODUCT LIQUID FERTILIZER CONTAINING CALCIUM, BORON AND MOLYBDEN AND PRODUCTION PROCESS |
Country Status (1)
| Country | Link |
|---|---|
| BR (1) | BRPI0804461B1 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104844303B (en) * | 2015-06-05 | 2018-04-10 | 孙雨桢 | A kind of organic composite fertilizer suitable for peanut growth |
| CN104844304B (en) * | 2015-06-05 | 2018-04-06 | 孙雨桢 | A kind of organic composite fertilizer of suitable broad bean growth |
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2008
- 2008-01-23 BR BRPI0804461-9A patent/BRPI0804461B1/en not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| BRPI0804461A2 (en) | 2009-09-15 |
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