BRPI0804704A2 - granulated and encapsulated fertilizer manufacturing process - Google Patents
granulated and encapsulated fertilizer manufacturing process Download PDFInfo
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- BRPI0804704A2 BRPI0804704A2 BRPI0804704-9A BRPI0804704A BRPI0804704A2 BR PI0804704 A2 BRPI0804704 A2 BR PI0804704A2 BR PI0804704 A BRPI0804704 A BR PI0804704A BR PI0804704 A2 BRPI0804704 A2 BR PI0804704A2
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- Prior art keywords
- fertilizers
- granule
- phosphate
- granulated
- encapsulated
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- 239000003337 fertilizer Substances 0.000 title claims abstract description 33
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 15
- 239000008187 granular material Substances 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 15
- 238000000576 coating method Methods 0.000 claims abstract description 14
- 239000011248 coating agent Substances 0.000 claims description 11
- 229910019142 PO4 Inorganic materials 0.000 claims description 9
- 239000004568 cement Substances 0.000 claims description 8
- 239000010452 phosphate Substances 0.000 claims description 8
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 8
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 6
- 239000011707 mineral Substances 0.000 claims description 6
- 239000003292 glue Substances 0.000 claims description 5
- GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 claims description 5
- 239000004137 magnesium phosphate Substances 0.000 claims description 5
- 229910000157 magnesium phosphate Inorganic materials 0.000 claims description 5
- 229960002261 magnesium phosphate Drugs 0.000 claims description 5
- 235000010994 magnesium phosphates Nutrition 0.000 claims description 5
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 4
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 4
- 150000004760 silicates Chemical class 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 235000013311 vegetables Nutrition 0.000 claims description 4
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 3
- 150000003841 chloride salts Chemical class 0.000 claims description 3
- 235000010755 mineral Nutrition 0.000 claims description 3
- 150000002823 nitrates Chemical class 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 3
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 2
- 229920002472 Starch Polymers 0.000 claims description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 2
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 2
- 239000000835 fiber Substances 0.000 claims description 2
- 239000004571 lime Substances 0.000 claims description 2
- 239000001095 magnesium carbonate Substances 0.000 claims description 2
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 2
- 235000014380 magnesium carbonate Nutrition 0.000 claims description 2
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 2
- 235000011118 potassium hydroxide Nutrition 0.000 claims description 2
- 235000019698 starch Nutrition 0.000 claims description 2
- 235000000346 sugar Nutrition 0.000 claims description 2
- 150000008163 sugars Chemical class 0.000 claims description 2
- 239000011593 sulfur Substances 0.000 claims description 2
- 229910052717 sulfur Inorganic materials 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- 239000001506 calcium phosphate Substances 0.000 claims 1
- 229910000389 calcium phosphate Inorganic materials 0.000 claims 1
- 235000011010 calcium phosphates Nutrition 0.000 claims 1
- 239000010440 gypsum Substances 0.000 claims 1
- 229910052602 gypsum Inorganic materials 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 235000001508 sulfur Nutrition 0.000 claims 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims 1
- 238000001035 drying Methods 0.000 abstract description 10
- 235000021317 phosphate Nutrition 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 3
- 239000002689 soil Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000005538 encapsulation Methods 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011505 plaster Substances 0.000 description 2
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 239000004487 encapsulated granule Substances 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- -1 generating a dry Substances 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000010871 livestock manure Substances 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000003415 peat Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229910000160 potassium phosphate Inorganic materials 0.000 description 1
- 235000011009 potassium phosphates Nutrition 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
Landscapes
- Fertilizers (AREA)
Abstract
PROCESSO DE FABRICAçãO DE FERTILIZANTES GRANULADOS E ENCAPSULADOS. A presente invenção refere-se a PROCESSO DE FABRICAçãO DE FERTILIZANTES GRANULADOS E ENCAPSULADOS, composto por uma seqüência de operações que permitem a fabricação de grânulos(1) de fertilizantes(1.1) encapsulados por revestimentos(1.2) secativos, com secagem sem a necessidade de secadores.MANUFACTURING PROCESS OF GRANULATED AND ENCAPSULATED FERTILIZERS. The present invention relates to the process of manufacturing granulated and encapsulated fertilizers, comprising a sequence of operations that allow the manufacture of granules (1) of fertilizers (1.1) encapsulated by drying coatings (1.2) without drying. dryers.
Description
"PROCESSO DE FABRICAÇÃO DE FERTILIZANTES GRANULADOS E ENCAPSULADOS"."PROCESS FOR MAKING GRANULATED AND ENCAPSULATED FERTILIZERS".
A presente invenção refere-se a "PROCESSO DEFABRICAÇÃO DE FERTILIZANTES GRANULADOS EENCAPSULADOS", composto por uma seqüência de operaçõesque permitem a fabricação de grânulos de fertilizantesencapsulados por revestimentos secativos, com secagem sem anecessidade de secadores.The present invention relates to "DEENGRATED PROCESS OF GRANULATED AND ENCAPSULATED FERTILIZERS", comprising a sequence of operations that allow the manufacture of encapsulated fertilizer granules by drying coatings, drying without the need for dryers.
O estado da técnica apresenta nesta área fertilizanteslíquidos, ou em pó, ou granulados, mas, sem um encapsulamento.The state of the art has liquid or powdered or granulated fertilizers in this area, but without encapsulation.
O processo de secagem definido pelo estado da técnicademanda aquecimento e conseqüentemente elevados gastos comenergia. Por haver aquecimento, consequentemente existe anecessidade de resfriador, encarecendo o processo, haja visto oelevado custo deste conjunto de equipamentos para aquecimento eresfriamento.The drying process is defined by the state of the art of heating demand and consequently high energy costs. Because there is heating, consequently there is a need for chiller, making the process more expensive, having seen the high cost of this set of equipment for heating and cooling.
O estado da técnica não apresenta uma solução que produzassecagem a frio.The state of the art does not provide a solution that produces cold drying.
O estado da técnica também apresenta fertilizantesrevestidos por membrana semi-permeável, chamados de "slowrelease", mas este revestimento não possui efeito fertilizante.The state of the art also features semipermeable membrane coated fertilizers, called "slowrelease", but this coating has no fertilizing effect.
Para a melhor compreensão da presente invenção, é feita emseguida, uma descrição detalhada da invenção "PROCESSO DEFABRICAÇÃO DE FERTILIZANTES GRANULADOS EENCAPSULADOS", fazendo-se referências aos desenhos anexos,sendo:For a better understanding of the present invention, the following is a detailed description of the invention "DEFABRICATION PROCESS OF EENCAPSULULATED GRANULATED FERTILIZERS", with reference to the accompanying drawings, as follows:
- A figura 1 apresentando o desenho esquemático dainvenção "PROCESSO DE FABRICAÇÃO DE FERTILIZANTESGRANULADOS E ENCAPSULADOS".- Figure 1 showing the schematic drawing of the invention "Process of Manufacturing of Greased and Encapsulated Fertilizers".
A figura 2 mostra da invenção "PROCESSO DEFABRICAÇÃO DE FERTILIZANTES GRANULADOS EENCAPSULADOS", o desenho esquemátjco de um grânulo(1).Figure 2 shows of the invention "PROCESS OF MANUFACTURING GRANULATED AND ENCAPSULATED FERTILIZERS", the schematic drawing of a granule (1).
Conforme as figuras de 1 e 2 a presente invençãodenominada "PROCESSO DE FABRICAÇÃO DE FERTILIZANTESGRANULADOS E ENCAPSULADOS", apresenta como produtofinal um grânulo(1).According to Figures 1 and 2, the present invention, known as the "Process of Manufacturing Granulated and Encapsulated Fertilizers", has as its final product a granule (1).
Na invenção "PROCESSO DE FABRICAÇÃO DEFERTILIZANTES GRANULADOS E ENCAPSULADOS", descreve-se uma seqüência de operações que consiste em granularfertilizantes(1.1.1) com colas(1.1.2) animais, e/ou vegetais, e/ousintéticas e, também por encapsulamento ou revestimento(1.2),com produtos secativos, aproveitando-se dos seus princípios dereação de hidratação e/ou cristalização e reação química, fazendo-se a secagem sem a necessidade de secadores.In the invention "PROCESS OF MANUFACTURING GRANULATED AND ENCAPSULATED DEFERTILIZERS", a sequence of operations consisting of granularfertilizers (1.1.1) with animal, and / or vegetable, and / or synthetic glues and also by encapsulation is described. or coating (1.2) with drying products, taking advantage of its principles of hydration and / or crystallization and chemical reaction, drying without the need for dryers.
Os fertilizantes( 1.1.1) a serem revestidos podem ser dediversas naturezas tais como os orgânicos, os minerais, osquímicos e os organo-minerais.The fertilizers (1.1.1) to be coated may be of various natures such as organic, mineral, chemical and organo-mineral.
Entendem-se como fertilizantes orgânicos os advindos demateriais orgânicos tais como a turfa, os estercos, Iodos orgânicose os restos vegetais.Organic fertilizers are those derived from organic materials such as peat, manure, organic sludge and vegetable debris.
Fertilizantes minerais são os obtidos de lavras, processandoem rochas moídas tais como silicatos, fosfatos, carbonatos.Já os fertilizantes químicos são os que são constituídos decomponentes químicos obtidos por processo de fabricação taiscomo sulfatos, nitratos, cloretos, fosfo-gesso, uréia, óxidos ehidróxidos.Por fim os organo-minerais são os fertilizantes compostospela mistura nas mais diversas dosagens dos três tipos descritosacima.Mineral fertilizers are those obtained from mines, processing ground rocks such as silicates, phosphates, carbonates. Chemical fertilizers are those made up of chemical components obtained by manufacturing processes such as sulphates, nitrates, chlorides, phosphate plaster, urea, oxides and hydroxides. Finally, organo-minerals are the fertilizers composed by the mixture in the most diverse dosages of the three types described above.
Na invenção "PROCESSO DE FABRICAÇÃO DEFERTILIZANTES GRANULADOS E ENCAPSULADOS", osrevestimentos(1.2) utilizados para encapsular os grânulos defertilizantes são das seguintes naturezas:In the invention "GRANULATED AND ENCAPSULATED DEFERTILIZING PROCESS", the coatings (1.2) used to encapsulate the deferring granules are of the following nature:
a) Principalmente o cimento à base de fosfatos do tipofosfato de cálcio, fosfato de potássio, fosfato desílica e fosfato de magnésio.(a) mainly phosphate-based cement of calcium tipophosphate, potassium phosphate, desylate phosphate and magnesium phosphate.
b) Cimentos dos tipos Portland, pozolânicos, e Sorel;(b) Portland, pozzolanic, and Sorel cements;
c) Gesso ou cal virgem;(c) plaster or virgin lime;
d) Enxofre;d) sulfur;
e) Magnesita;e) Magnesite;
f) Sulfatosf) Sulfates
g) Nitratos;g) nitrates;
h) Cloretos;h) Chlorides;
i) Silicatos;(i) silicates;
j) Carbonatos;j) carbonates;
k) Amidos;k) Starches;
I) Fibras vegetais;I) vegetable fibers;
m) Sais;m) salts;
n) Açúcares;n) sugars;
o) Argilas;o) Clays;
p) Carboximetilcelulose, dita CMC;p) Carboxymethylcellulose, said CMC;
q) Potassa cáustica.q) Caustic Potash.
O cimento fosfato-magnesiano, dito MAP, sigla da línguainglesa de Magnesium Phosphate Cement é obtido da reação entreóxido de magnésio e fosfato solúvel, assim como fosfato amônicomonobásico (NH4H2PO4), como também o sal mono ou dibásico; ouainda uma solução de fertilizante conhecida como 10-34-0 (nadesignação NPK) pode também ser usada.Magnesium phosphate cement, referred to as MAP, acronym for Magnesium Phosphate Cement's lingual tongue, is obtained from the reaction between magnesium oxide and soluble phosphate, as well as ammonic monobasic phosphate (NH4H2PO4), as well as mono- or dibasic salt; or a fertilizer solution known as 10-34-0 (NPK designation) may also be used.
Estes cimentos magnesianos possuem uma rápida secageme rápido alcance de resistência à pressão, chegando à ordem de2.900PSI em uma hora de cura e de 8.000PSI em cura total.These magnesian cements have a fast drying and fast pressure resistance range, reaching the order of 2,900PSI in one hour of cure and 8,000PSI in total cure.
A principal vantagem de se produzir fertilizantes granulados erevestidos é a de haver controle da liberação mais lenta ou maisrápida dos componentes no solo. Por exemplo, uma liberação maislenta proporciona de maior rendimento, pois, chuvas não fazem alavagem do solo e há um maior tempo para que solo faça aabsorção dos fertilizantes.The main advantage of producing coated and granulated fertilizers is that slower or faster release of the components in the soil is controlled. For example, slower release yields higher yields because rainfall does not leverage the soil and there is a longer time for soil to absorb fertilizer.
A grande vantagem de se utilizar cimento magnesiano comorevestimento de um grânulo(1) de fertilizante é de que o própriorevestimento ser também um fertilizante, pois contém fósforo,magnésio e nitrogênio fornecido pela amônia.The great advantage of using magnesian cement with coating of a fertilizer granule (1) is that the coating itself is also a fertilizer because it contains phosphorus, magnesium and nitrogen supplied by ammonia.
O grânulo(1) produzido pela invenção "PROCESSO DEFABRICAÇÃO DE FERTILIZANTES GRANULADOS EENCAPSULADOS", é de fabricação muito econômica eecologicamente limpa, pois, não demanda aquecimento ou queimade combustíveis para secagem.The granule (1) produced by the invention "DEFABRICATION PROCESS OF EENCAPSULULATED GRANULATED FERTILIZERS" is very economically and ecologically clean to manufacture, as it does not require heating or burning fuels for drying.
A qualidade do grânulo é muito maior, pois, possui maiorresistência mecânica, mais esférico e homogêneo.The quality of the granule is much higher because it has higher mechanical strength, more spherical and homogeneous.
O próprio revestimento é útil às plantas, tal como o cimento àbase de fosfato de magnésio, fornecendo fósforo e magnésio,muito bem demonstrado em estudos amplamente divulgados naárea de especialização agrícola.A invenção "PROCESSO DE FABRICAÇÃO DEFERTILIZANTES GRANULADOS E ENCAPSULADOS" consisteem introduzir fertilizantes( 1.1.1) e cola(1.1.2) dos tipos descritosacima em um granulador(IO) do tipo tambor, ou tipo pratopelotizador, ou de pinos ou pás tipo turbo, ou ainda por bateladas.The coating itself is useful to plants, such as magnesium phosphate-based cement, providing phosphorus and magnesium, which has been well demonstrated in studies widely reported in the field of agricultural specialization. 1.1.1) and glue (1.1.2) of the types described above in a drum type, Io-propellant type granulator (IO), or turbo-type pins or blades, or in batches.
Os grânulos úmidos de fertilizante e cola(1.1) que saem desteprimeiro granulador são então introduzidos em um segundogranulador(11) juntamente com um ou mais dos produtos derevestimento também citados acima, gerando um grânulo(1),encapsulado e seco, composto de um núcleo(1.1) de fertilizante ecola, com um revestimento(1.2).The wet fertilizer and glue granules (1.1) that come out of this first granulator are then introduced into a second granulator (11) together with one or more of the above-mentioned coating products, generating a dry, encapsulated granule (1) composed of a core. (1.1) of ecola fertilizer, with a coating (1.2).
Estes grânulos(1) são elevados por transportador decanecas(12) até peneira(13) que efetuará a separação de finospara recirculação(14) e de produto acabado para transportador(15)que leva ao armazenamento.These granules (1) are lifted by decanter conveyor (12) to sieve (13) which will separate fines for recirculation (14) and finished conveyor product (15) leading to storage.
Portanto os grânulos(1) são compostos de núcleo defertilizante(1.1.1) e cola(1.1.2) e externamente derevestimento(1.2).Therefore the granules (1) are composed of defertilizing core (1.1.1) and glue (1.1.2) and externally coating (1.2).
Claims (4)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BRPI0804704-9A BRPI0804704A2 (en) | 2008-10-17 | 2008-10-17 | granulated and encapsulated fertilizer manufacturing process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BRPI0804704-9A BRPI0804704A2 (en) | 2008-10-17 | 2008-10-17 | granulated and encapsulated fertilizer manufacturing process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BRPI0804704A2 true BRPI0804704A2 (en) | 2010-10-05 |
Family
ID=42801146
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0804704-9A BRPI0804704A2 (en) | 2008-10-17 | 2008-10-17 | granulated and encapsulated fertilizer manufacturing process |
Country Status (1)
| Country | Link |
|---|---|
| BR (1) | BRPI0804704A2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016058067A1 (en) * | 2014-10-13 | 2016-04-21 | Bma Agro Comércio De Fertilizantes Eireli - Me | Use of thermophosphate as a slow-release fertilizer coating |
| WO2018058212A1 (en) * | 2016-09-27 | 2018-04-05 | Mineração Curimbaba Ltda | Use of thermophosphates for coating seeds |
| CN111454093A (en) * | 2020-05-26 | 2020-07-28 | 浙江科技学院 | A kind of stable organic-inorganic special fertilizer for rice prepared by using biogas residue and preparation method thereof |
-
2008
- 2008-10-17 BR BRPI0804704-9A patent/BRPI0804704A2/en not_active IP Right Cessation
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2016058067A1 (en) * | 2014-10-13 | 2016-04-21 | Bma Agro Comércio De Fertilizantes Eireli - Me | Use of thermophosphate as a slow-release fertilizer coating |
| WO2018058212A1 (en) * | 2016-09-27 | 2018-04-05 | Mineração Curimbaba Ltda | Use of thermophosphates for coating seeds |
| CN111454093A (en) * | 2020-05-26 | 2020-07-28 | 浙江科技学院 | A kind of stable organic-inorganic special fertilizer for rice prepared by using biogas residue and preparation method thereof |
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