BRPI0810143A2 - Processo para começar uma oxidação em fase gasosa parcial heterogeneamente catalisada de acroleína para ácido acrílico ou de metacroleína para ácido metacrílico em um leito de catalisador fixo - Google Patents
Processo para começar uma oxidação em fase gasosa parcial heterogeneamente catalisada de acroleína para ácido acrílico ou de metacroleína para ácido metacrílico em um leito de catalisador fixoInfo
- Publication number
- BRPI0810143A2 BRPI0810143A2 BRPI0810143-4A2A BRPI0810143A BRPI0810143A2 BR PI0810143 A2 BRPI0810143 A2 BR PI0810143A2 BR PI0810143 A BRPI0810143 A BR PI0810143A BR PI0810143 A2 BRPI0810143 A2 BR PI0810143A2
- Authority
- BR
- Brazil
- Prior art keywords
- reactor
- reaction tubes
- tube
- methacrylic acid
- reaction
- Prior art date
Links
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 title abstract 6
- 238000000034 method Methods 0.000 title abstract 3
- 239000003054 catalyst Substances 0.000 title 1
- 238000006243 chemical reaction Methods 0.000 abstract 15
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 abstract 8
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 4
- STNJBCKSHOAVAJ-UHFFFAOYSA-N Methacrolein Chemical compound CC(=C)C=O STNJBCKSHOAVAJ-UHFFFAOYSA-N 0.000 abstract 4
- 239000007789 gas Substances 0.000 abstract 4
- 239000007788 liquid Substances 0.000 abstract 4
- 239000000203 mixture Substances 0.000 abstract 3
- 230000003647 oxidation Effects 0.000 abstract 3
- 238000007254 oxidation reaction Methods 0.000 abstract 3
- 239000011949 solid catalyst Substances 0.000 abstract 3
- 239000012495 reaction gas Substances 0.000 abstract 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 abstract 1
- 229910001882 dioxygen Inorganic materials 0.000 abstract 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
- B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
- B01J8/067—Heating or cooling the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/888—Tungsten
- B01J23/8885—Tungsten containing also molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
- B01J27/198—Vanadium
- B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/19—Catalysts containing parts with different compositions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
- C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00212—Plates; Jackets; Cylinders
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00212—Plates; Jackets; Cylinders
- B01J2208/00221—Plates; Jackets; Cylinders comprising baffles for guiding the flow of the heat exchange medium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00513—Controlling the temperature using inert heat absorbing solids in the bed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/02—Processes carried out in the presence of solid particles; Reactors therefor with stationary particles
- B01J2208/023—Details
- B01J2208/024—Particulate material
- B01J2208/025—Two or more types of catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/30—Details relating to random packing elements
- B01J2219/302—Basic shape of the elements
- B01J2219/30207—Sphere
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/30—Details relating to random packing elements
- B01J2219/302—Basic shape of the elements
- B01J2219/30215—Toroid or ring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US90795407P | 2007-04-24 | 2007-04-24 | |
| DE102007019597A DE102007019597A1 (de) | 2007-04-24 | 2007-04-24 | Verfahren der Inbetriebnahme einer heterogen katalysierten partiellen Gasphasenoxidation von Acrolein zu Acrylsäure oder von Methacrolein zu Methacrylsäure |
| PCT/EP2008/054720 WO2008128988A2 (de) | 2007-04-24 | 2008-04-18 | Verfahren der inbetriebnahme einer heterogen katalysierten partiellen gasphasenoxidation von acrolein zu acrylsäure oder von methacrolein zu methacrylsäure |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BRPI0810143A2 true BRPI0810143A2 (pt) | 2014-10-29 |
Family
ID=39277795
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0810143-4A2A BRPI0810143A2 (pt) | 2007-04-24 | 2008-04-18 | Processo para começar uma oxidação em fase gasosa parcial heterogeneamente catalisada de acroleína para ácido acrílico ou de metacroleína para ácido metacrílico em um leito de catalisador fixo |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US8076510B2 (pt) |
| EP (1) | EP2150518B1 (pt) |
| JP (1) | JP5295221B2 (pt) |
| CN (1) | CN101679182B (pt) |
| AT (1) | ATE487687T1 (pt) |
| BR (1) | BRPI0810143A2 (pt) |
| DE (2) | DE102007019597A1 (pt) |
| RU (1) | RU2479569C2 (pt) |
| WO (1) | WO2008128988A2 (pt) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102007025869A1 (de) | 2007-06-01 | 2008-07-03 | Basf Se | Verfahren der Wiederbeschickung der Reaktionsrohre eines Rohrbündelreaktors mit einem neuen Katalysatorfestbett |
| DE102007028333A1 (de) | 2007-06-15 | 2008-12-18 | Basf Se | Verfahren zum Einbringen einer wenigstens einer Produktionscharge von ringförmigen Schalenkatalysatoren K entnommenen Teilmenge in ein Reaktionsrohr eines Rohrbündelreaktors |
| DE102008041573A1 (de) | 2008-08-26 | 2010-03-04 | Basf Se | Verfahren zur Auftrennung von in einem Produktgasgemisch einer partiellen heterogen katalysierten Gasphasenoxidation einer C3-Vorläuferverbindung der Acrylsäure als Hauptbestandteil enhaltener Acrylsäure und als Nebenprodukt enthaltenem Glyoxal |
| DE102008040799A1 (de) | 2008-07-28 | 2008-12-11 | Basf Se | Verfahren zur Auftrennung von in einem Produktgasgemisch einer partiellen heterogen katalysierten Gasphasenoxidation einer C3-Vorläuferverbindung der Acrylsäure als Hauptbestandteil enthaltener Acrylsäure und als Nebenprodukt enthaltenem Glyoxal |
| JP2011529094A (ja) | 2008-07-28 | 2011-12-01 | ビーエーエスエフ ソシエタス・ヨーロピア | アクリル酸のｃ３前駆体化合物のガス状生成混合物から主生成物として含有されるアクリル酸および副生成物として含有されるグリオキサールを分離する方法 |
| WO2011102828A1 (en) * | 2010-02-16 | 2011-08-25 | Multi-Chem Group, Llc | Method and apparatus for remotely monitoring acrolein temperature in storage tanks |
| DE102011076931A1 (de) | 2011-06-03 | 2012-12-06 | Basf Se | Wässrige Lösung, enthaltend Acrylsäure und deren konjugierte Base |
| FR2975922B1 (fr) * | 2011-06-06 | 2013-05-31 | Arkema France | Reacteur a plaques avec injection in situ |
| DE102012207811A1 (de) | 2012-05-10 | 2012-07-12 | Basf Se | Verfahren der heterogen katalysierten Gasphasenpartialoxidation von (Meth)acrolein zu (Meth)acrylsäure |
| US9440903B2 (en) * | 2012-09-24 | 2016-09-13 | Arkema Inc. | Shell and tube oxidation reactor with improved resistance to fouling |
| DE102013202048A1 (de) | 2013-02-07 | 2013-04-18 | Basf Se | Verfahren zur Herstellung einer katalytisch aktiven Masse, die ein Gemisch aus einem die Elemente Mo und V enthaltenden Multielementoxid und wenigstens einem Oxid des Molybdäns ist |
| JP2017535643A (ja) | 2014-11-03 | 2017-11-30 | アーケマ・インコーポレイテッド | ポリマーフレーク及び粉体の密度を高めるためのプロセス |
| ES2881297T3 (es) * | 2017-02-10 | 2021-11-29 | Technobell D O O Koper | Reactor tubular de doble zona mejorado y método para llevar a cabo la producción de anhídrido maleico mediante la oxidación de n-butano |
| US12343708B2 (en) | 2020-04-21 | 2025-07-01 | Basf Se | Method for producing a catalytically active multi-element oxide containing the elements Mo, W, V and Cu |
| US20240091756A1 (en) | 2020-10-29 | 2024-03-21 | Basf Se | Method for producing a core-shell catalyst |
| US20240424466A1 (en) * | 2021-06-16 | 2024-12-26 | Basf Se | Process for shutting-down and heating up a tubular reactor for a catalytic gas phase reaction |
| JP2025541831A (ja) | 2022-12-07 | 2025-12-23 | ベーアーエスエフ・エスエー | 元素Ｍｏ、Ｗ、Ｖ、Ｃｕ、およびＳｂを含有する触媒活性多元素酸化物を製造するための方法 |
| WO2025125092A1 (de) | 2023-12-14 | 2025-06-19 | Basf Se | Verfahren zur herstellung eines die elemente mo, w, v, cu und sb enthaltenden katalytisch aktiven multielementoxids |
| WO2026017456A1 (de) | 2024-07-15 | 2026-01-22 | Basf Se | Verfahren zur herstellung eines katalysators umfassend eine wasserbehandlung |
Family Cites Families (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4431949A1 (de) | 1994-09-08 | 1995-03-16 | Basf Ag | Verfahren zur katalytischen Gasphasenoxidation von Acrolein zu Acrylsäure |
| JP3948837B2 (ja) * | 1998-08-10 | 2007-07-25 | 株式会社日本触媒 | アクリル酸の製造方法 |
| JP3559456B2 (ja) | 1998-09-18 | 2004-09-02 | 株式会社日本触媒 | 接触気相酸化方法及び多管式反応器 |
| JP3486565B2 (ja) * | 1998-12-25 | 2004-01-13 | 三菱レイヨン株式会社 | メタクリル酸の製造方法 |
| RU2285690C2 (ru) * | 2000-06-20 | 2006-10-20 | Басф Акциенгезельшафт | Способ получения акролеина и/или акриловой кислоты |
| EP1460053A4 (en) | 2001-12-27 | 2006-03-22 | Mitsubishi Chem Corp | VAPOR CATALYST OXIDATION PROCESS AND PROCESS FOR PRODUCING (METH) ACROLEIN OR (METH) ACRYLIC ACID |
| CN1607031A (zh) * | 2001-12-28 | 2005-04-20 | 三菱化学株式会社 | 装填催化剂的方法 |
| EP2361899B1 (en) * | 2002-01-11 | 2015-07-22 | Mitsubishi Chemical Corporation | Vapor phase catalytic oxidation method using a multitube reactor of the heat-exchange type |
| CN1330618C (zh) * | 2002-03-11 | 2007-08-08 | 三菱化学株式会社 | 催化气相氧化法 |
| DE10232482A1 (de) * | 2002-07-17 | 2004-01-29 | Basf Ag | Verfahren zum sicheren Betreiben einer kontinuierlichen heterogen katalysierten Gasphasen-Partialoxidation wenigstens einer organischen Verbindung |
| DE10313211A1 (de) | 2003-03-25 | 2004-10-07 | Basf Ag | Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Acrolein zu Acrylsäure |
| DE10313208A1 (de) | 2003-03-25 | 2004-10-07 | Basf Ag | Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propen zu Acrylsäure |
| DE10313214A1 (de) * | 2003-03-25 | 2004-10-07 | Basf Ag | Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Acrolein zu Acrylsäure |
| DE10313213A1 (de) * | 2003-03-25 | 2004-10-07 | Basf Ag | Verfahren der heterogen katalysierten partiellen Gasphasenoxidation von Propen zu Acrylsäure |
| WO2004085365A2 (de) * | 2003-03-25 | 2004-10-07 | Basf Aktiengesellschaft | Verfahren der heterogen katalysierten partiellen gasphasenoxidation von acrolein zu acrylsäure |
| KR101013249B1 (ko) * | 2003-03-25 | 2011-02-09 | 바스프 에스이 | 아크릴산을 형성하기 위한 프로펜의 불균질 촉매화 부분기체상 산화 방법 |
| KR101096355B1 (ko) * | 2003-10-29 | 2011-12-20 | 바스프 에스이 | 아크릴산을 형성하기 위한 아크롤레인의 불균질 촉매된기체 상 부분 산화의 장기 수행 방법 |
| DE10350822A1 (de) * | 2003-10-29 | 2005-06-02 | Basf Ag | Verfahren zum Langzeitbetrieb einer heterogen katalysierten Gasphasenpartialoxidation von Acrolein zu Acrylsäure |
| JP4867129B2 (ja) * | 2003-12-15 | 2012-02-01 | 三菱化学株式会社 | （メタ）アクリル酸または（メタ）アクロレインの製造方法 |
| DE102004025445A1 (de) | 2004-05-19 | 2005-02-10 | Basf Ag | Verfahren zum Langzeitbetrieb einer heterogen katalysierten Gasphasenpartialoxidation wenigstens einer organischen Verbindung |
| US7414149B2 (en) | 2004-11-22 | 2008-08-19 | Rohm And Haas Company | Non-routine reactor shutdown method |
| US7439389B2 (en) * | 2005-03-01 | 2008-10-21 | Basf Aktiengesellschaft | Process for preparing at least one organic target compound by heterogeneously catalyzed gas phase partial oxidation |
| MY140309A (en) * | 2005-03-01 | 2009-12-31 | Basf Ag | Process for preparing at least one organic target compound by heterogeneously catalyzed gas phase partial oxidation |
| EP1734030A1 (de) * | 2006-01-18 | 2006-12-20 | BASF Aktiengesellschaft | Verfahren zum Langzeitbetrieb einer heterogen katalysierten partiellen Gasphasenoxidation einer organischen Ausgangsverbindung |
-
2007
- 2007-04-24 DE DE102007019597A patent/DE102007019597A1/de not_active Withdrawn
-
2008
- 2008-04-18 CN CN200880013699.8A patent/CN101679182B/zh active Active
- 2008-04-18 BR BRPI0810143-4A2A patent/BRPI0810143A2/pt active IP Right Grant
- 2008-04-18 DE DE502008001771T patent/DE502008001771D1/de active Active
- 2008-04-18 RU RU2009142960/04A patent/RU2479569C2/ru active
- 2008-04-18 AT AT08736369T patent/ATE487687T1/de active
- 2008-04-18 JP JP2010504645A patent/JP5295221B2/ja active Active
- 2008-04-18 WO PCT/EP2008/054720 patent/WO2008128988A2/de not_active Ceased
- 2008-04-18 EP EP08736369A patent/EP2150518B1/de active Active
- 2008-04-22 US US12/107,420 patent/US8076510B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| ATE487687T1 (de) | 2010-11-15 |
| EP2150518A2 (de) | 2010-02-10 |
| US20080269521A1 (en) | 2008-10-30 |
| WO2008128988A3 (de) | 2008-12-11 |
| CN101679182A (zh) | 2010-03-24 |
| CN101679182B (zh) | 2013-05-22 |
| WO2008128988A2 (de) | 2008-10-30 |
| EP2150518B1 (de) | 2010-11-10 |
| JP5295221B2 (ja) | 2013-09-18 |
| US8076510B2 (en) | 2011-12-13 |
| RU2009142960A (ru) | 2011-05-27 |
| DE102007019597A1 (de) | 2008-05-15 |
| DE502008001771D1 (de) | 2010-12-23 |
| RU2479569C2 (ru) | 2013-04-20 |
| JP2010525012A (ja) | 2010-07-22 |
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