BRPI0815440A2 - 5-substituidos 2- (alcoximetil) furanos - Google Patents

5-substituidos 2- (alcoximetil) furanos

Info

Publication number: BRPI0815440A2
Authority: BR; Brazil
Prior art keywords: alkoxymethyl; furans; substituted
Prior art date: 2007-09-07

Application number

BRPI0815440A

Other languages

English (en)

Inventor

Johannes Maria Gruter Gerardus

Original Assignee

Furanix Technologies Bv

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2007-09-07

Filing date

2008-09-05

Publication date

2017-05-30

2008-09-05 Application filed by Furanix Technologies Bv filed Critical Furanix Technologies Bv

2017-05-30 Publication of BRPI0815440A2 publication Critical patent/BRPI0815440A2/pt

2017-10-03 Publication of BRPI0815440A8 publication Critical patent/BRPI0815440A8/pt

2018-11-13 Publication of BRPI0815440B1 publication Critical patent/BRPI0815440B1/pt

Links

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
- C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
- C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D307/38—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D307/40—Radicals substituted by oxygen atoms
- C07D307/42—Singly bound oxygen atoms
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
- C10L1/023—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for spark ignition
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
- C10L1/026—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for compression ignition
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1011—Biomass
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/40—Characteristics of the process deviating from typical ways of processing
- C10G2300/44—Solvents
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Furan Compounds (AREA)
Liquid Carbonaceous Fuels (AREA)

BRPI0815440-6A 2007-09-07 2008-09-05 5-substituidos 2- (alcoximetil) furanos BRPI0815440B1 (pt)

Applications Claiming Priority (5)

Application Number	Priority Date	Filing Date	Title
EP07075777.8		2007-09-07
EP07075777		2007-09-07
EP08075504		2008-05-19
EP08075504-4		2008-05-19
PCT/EP2008/007423 WO2009030509A2 (en)	2007-09-07	2008-09-05	5-substituted 2-(alkoxymethyl)furans

Publications (3)

Publication Number	Publication Date
BRPI0815440A2 true BRPI0815440A2 (pt)	2017-05-30
BRPI0815440A8 BRPI0815440A8 (pt)	2017-10-03
BRPI0815440B1 BRPI0815440B1 (pt)	2018-11-13

Family

ID=40303739

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
BRPI0815440-6A BRPI0815440B1 (pt)	2007-09-07	2008-09-05	5-substituidos 2- (alcoximetil) furanos

Country Status (14)

Country	Link
US (1)	US8231693B2 (pt)
EP (2)	EP2197863B1 (pt)
JP (1)	JP5584122B2 (pt)
KR (1)	KR101530567B1 (pt)
CN (2)	CN102994172B (pt)
AP (1)	AP2010005180A0 (pt)
AU (1)	AU2008295004B2 (pt)
BR (1)	BRPI0815440B1 (pt)
CA (1)	CA2697717C (pt)
EA (2)	EA201101559A1 (pt)
MX (1)	MX2010002605A (pt)
MY (1)	MY147991A (pt)
WO (1)	WO2009030509A2 (pt)
ZA (1)	ZA201001901B (pt)

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WO2009077606A2 (en) *	2007-12-19	2009-06-25	Shell Internationale Research Maatschappij B.V.	Gasoline composition and process for the preparation of alkylfurfuryl ether
EP2128226A1 (en) *	2008-05-19	2009-12-02	Furanix Technologies B.V	Fuel component
ES2566649T3 (es)	2008-10-30	2016-04-14	Archer Daniels Midland Company	Reducción de éteres de HMF con un catalizador metálico
MX2012004146A (es)	2009-10-07	2012-05-08	Furanix Technologies Bv	Metodo para la preparacion de acido 2,5 furandicarboxilicoy esteres del mismo.
US8236973B2 (en)	2009-11-05	2012-08-07	Battelle Memorial Institute	Adsorption separation processes for ionic liquid catalytic processes
US8324409B2 (en)	2010-04-23	2012-12-04	The Board Of Trustees Of The University Of Illinois	Efficient method for preparing 2,5-dimethylfuran
CN102453559A (zh) *	2010-10-27	2012-05-16	中国科学院大连化学物理研究所	一种用于发动机节能减排的燃油添加剂及应用
CA2820940C (en) *	2010-12-16	2018-05-29	Archer Daniels Midland Company	Preparation of aminomethyl furan and alkoxymethyl furan derivatives fro m carbohydrates
NL2007509C2 (en)	2011-09-30	2012-07-11	Stichting Dienst Landbouwkundi	Process for the preparation of a benzene derivative.
CN102442982B (zh) *	2011-12-06	2014-03-19	中国科学院青岛生物能源与过程研究所	一种由糖制备呋喃二甲醇二烷基醚的方法
US20130296585A1 (en) *	2012-03-30	2013-11-07	Basf Corporation	Catalyst For Tetrahydrofuran Synthesis
US8969404B2 (en) *	2012-06-22	2015-03-03	Eastman Chemical Company	Purifying crude furan 2,5-dicarboxylic acid by hydrogenation
ES2462872B1 (es)	2012-10-25	2015-03-10	Consejo Superior Investigacion	Catalizador y proceso catalítico para la eterificación/reducción de furfuril derivados a tetrahidro-furfuril éteres
US9469619B2 (en)	2012-10-29	2016-10-18	Samsung Electronics Co., Ltd.	Method of preparing furfural compounds
CN103073526B (zh) *	2012-12-26	2014-12-03	中国科学院宁波材料技术与工程研究所	一种2，5-二取代的四氢呋喃类混合物的制备方法
JP2016522184A (ja) *	2013-04-25	2016-07-28	アーチャー−ダニエルズ−ミッドランドカンパニー	還元されたフラン誘導体の触媒的合成
US9108979B2 (en)	2013-06-06	2015-08-18	California Institute Of Technology	Diels-Alder reactions catalyzed by Lewis acid containing solids: renewable production of bio-plastics
US10538499B2 (en)	2015-04-14	2020-01-21	Dupont Industrial Biosciences Usa, Llc	Processes for producing 2,5-furandicarboxylic acid and derivatives thereof and polymers made therefrom
US10208006B2 (en)	2016-01-13	2019-02-19	Stora Enso Oyj	Processes for the preparation of 2,5-furandicarboxylic acid and intermediates and derivatives thereof
WO2019014382A1 (en)	2017-07-12	2019-01-17	Stora Enso Oyj	PURIFIED PRODUCTS OF THE 2.5-FURANDICARBOXYLIC ACID PATHWAY
CN109734687B (zh) *	2019-01-24	2020-09-15	淮阴师范学院	5-羟甲基糠醛还原醚化制备2,5-二烷氧基甲基呋喃的方法
CN111057594B (zh) *	2019-12-30	2021-10-29	李旭	一种醇基燃料添加剂的制备方法
EP4107238A4 (en) *	2020-02-19	2024-03-13	Council of Scientific & Industrial Research	Metal catalyst and hydrogen gas free approaches for selective reduction of aldehyde to methyl group of different substituted furans
CN111349492B (zh) *	2020-02-28	2021-05-25	浙江糖能科技有限公司	2,5-四氢呋喃二甲醇脂肪酸二酯在柴油添加剂的应用
CN114573527B (zh) *	2022-03-11	2023-08-01	湖南师范大学	一种5-羟甲基糠醛转移加氢制备2,5-二羟甲基呋喃的方法
CN117430572B (zh) *	2023-09-07	2025-09-26	中国科学院宁波材料技术与工程研究所	一种双催化剂协同一步法催化5-羟甲基糠醛制备烷基醚的方法

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JPS49117458A (pt) *	1973-03-20	1974-11-09
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EP0082689A3 (en) *	1981-12-22	1984-09-26	The British Petroleum Company p.l.c.	Fuel composition
JPS59190984A (ja) *	1983-04-11	1984-10-29	Kao Corp	フルフリルアルコ−ルの製造法
US4837368A (en)	1988-02-01	1989-06-06	Eastman Kodak Company	Low pressure catalytic hydrogenation of carbonyl-containing compounds and supported catalysts therefor
US5185476A (en)	1988-07-15	1993-02-09	Eastman Kodak Company	Low pressure catalytic hydrogenation of carbonyl-containing compounds and supported catalysts therefor
DE3826073A1 (de)	1988-07-30	1990-02-01	Hoechst Ag	Verfahren zur oxidation von 5-hydroxymethylfurfural
US4929777A (en)	1989-02-13	1990-05-29	Eastman Kodak Company	Catalyst compositions and the use thereof in the hydrogenation of carboxylic acid esters
FR2669634B1 (fr)	1990-11-22	1994-06-10	Furchim	Procede de fabrication d'acide 2-5-furane dicarboxylique.
JPH0532981A (ja) *	1991-08-01	1993-02-09	Cosmo Sogo Kenkyusho:Kk	燃料油組成物
US5308365A (en)	1993-08-31	1994-05-03	Arco Chemical Technology, L.P.	Diesel fuel
DE4403187C1 (de) *	1994-02-02	1995-09-28	Degussa	Geformter Kupfer-Katalysator für die selektive Hydrierung von Furfural zu Furfurylalkohol
US5491180A (en) *	1994-08-17	1996-02-13	Kao Corporation	Binder composition for mold making, binder/curing agent composition for mold making, sand composition for mold making, and process of making mold
FR2814173B1 (fr) *	2000-09-15	2005-09-16	Inst Francais Du Petrole	Compositions de carburants diesel contenant des composes oxygenes derives du tetrahydrofurfuryle
US7393963B2 (en) *	2004-12-10	2008-07-01	Archer-Daniels-Midland Company	Conversion of 2,5-(hydroxymethyl)furaldehyde to industrial derivatives, purification of the derivatives, and industrial uses therefor
WO2009077606A2 (en) *	2007-12-19	2009-06-25	Shell Internationale Research Maatschappij B.V.	Gasoline composition and process for the preparation of alkylfurfuryl ether

2008
- 2008-09-05 EA EA201101559A patent/EA201101559A1/ru unknown
- 2008-09-05 EP EP08801989A patent/EP2197863B1/en not_active Not-in-force
- 2008-09-05 JP JP2010523344A patent/JP5584122B2/ja not_active Expired - Fee Related
- 2008-09-05 US US12/594,189 patent/US8231693B2/en not_active Expired - Fee Related
- 2008-09-05 AP AP2010005180A patent/AP2010005180A0/xx unknown
- 2008-09-05 WO PCT/EP2008/007423 patent/WO2009030509A2/en not_active Ceased
- 2008-09-05 MY MYPI2010000979A patent/MY147991A/en unknown
- 2008-09-05 BR BRPI0815440-6A patent/BRPI0815440B1/pt not_active IP Right Cessation
- 2008-09-05 EA EA201070344A patent/EA017997B1/ru not_active IP Right Cessation
- 2008-09-05 CA CA2697717A patent/CA2697717C/en not_active Expired - Fee Related
- 2008-09-05 MX MX2010002605A patent/MX2010002605A/es active IP Right Grant
- 2008-09-05 CN CN201210326624.3A patent/CN102994172B/zh not_active Expired - Fee Related
- 2008-09-05 AU AU2008295004A patent/AU2008295004B2/en not_active Ceased
- 2008-09-05 EP EP12166981.6A patent/EP2487170B1/en not_active Not-in-force
- 2008-09-05 CN CN2008801061819A patent/CN101821248B/zh not_active Expired - Fee Related
- 2008-09-05 KR KR1020107007503A patent/KR101530567B1/ko not_active Expired - Fee Related
2010
- 2010-03-17 ZA ZA2010/01901A patent/ZA201001901B/en unknown

Also Published As

Publication number	Publication date
ZA201001901B (en)	2010-12-29
CN101821248B (zh)	2012-10-24
EP2197863A2 (en)	2010-06-23
EA201070344A1 (ru)	2010-10-29
EP2487170A1 (en)	2012-08-15
EA201101559A1 (ru)	2012-04-30
CA2697717A1 (en)	2009-03-12
WO2009030509A4 (en)	2009-08-13
EP2487170B1 (en)	2015-02-18
MX2010002605A (es)	2010-04-01
WO2009030509A3 (en)	2009-06-18
AU2008295004B2 (en)	2013-02-21
CA2697717C (en)	2016-11-22
KR101530567B1 (ko)	2015-06-22
AU2008295004A1 (en)	2009-03-12
US8231693B2 (en)	2012-07-31
MY147991A (en)	2013-02-28
JP5584122B2 (ja)	2014-09-03
AP2010005180A0 (en)	2010-04-30
CN102994172A (zh)	2013-03-27
BRPI0815440A8 (pt)	2017-10-03
BRPI0815440B1 (pt)	2018-11-13
JP2010538032A (ja)	2010-12-09
KR20100070346A (ko)	2010-06-25
CN101821248A (zh)	2010-09-01
WO2009030509A2 (en)	2009-03-12
EP2197863B1 (en)	2012-11-07
CN102994172B (zh)	2014-12-10
US20110302826A1 (en)	2011-12-15
EA017997B1 (ru)	2013-04-30

Legal Events

Date	Code	Title	Description
2017-10-03	B15K	Others concerning applications: alteration of classification	Ipc: C07D 307/42 (1974.07), C10L 1/02 (1968.09)
2017-10-10	B07A	Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
2018-09-04	B09A	Decision: intention to grant [chapter 9.1 patent gazette]
2018-11-13	B16A	Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]	Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 13/11/2018, OBSERVADAS AS CONDICOES LEGAIS.
2021-08-10	B21F	Lapse acc. art. 78, item iv - on non-payment of the annual fees in time	Free format text: REFERENTE A 13A ANUIDADE.
2021-11-30	B24J	Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)	Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2640 DE 10-08-2021 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.

Publication	Publication Date	Title
ZA201001901B (en)	2010-12-29	5-substituted 2-(alkoxymethyl)furans
BRPI0811578A2 (pt)	2014-12-09	Tetramatos substituídos por 3-(2-alcóxi-fenila)
HRP20181600T1 (hr)	2018-11-30	Kontrola ektoparazita
EP2170350A4 (en)	2011-09-28	SUBSTITUTED IMIDAZOHETEROCYCLES
ATE542825T1 (de)	2012-02-15	Substituierte piperidino-dihydrothienopyrimidine
HRP20150509T1 (xx)	2015-06-19	Herbicidni pripravci
DK2238132T3 (da)	2012-10-22	Insekticidforbindelser
ATE544742T1 (de)	2012-02-15	Insektizide arylpyrrolidine
HRP20170963T1 (hr)	2017-09-22	Modificirani saharidi
BRPI0814926A2 (pt)	2015-02-03	Herbicidas
BRPI0815670A2 (pt)	2015-02-18	Inseticidas
BRPI0815651A2 (pt)	2015-02-18	Herbicidas
BRPI0906705A2 (pt)	2015-06-30	Composto heterocíclicos
BRPI0806537A2 (pt)	2014-04-22	Indazóis substituídos por 5-piridinona
BRPI0915047A2 (pt)	2015-08-11	Composição herbicida
BRPI0811939A2 (pt)	2014-11-25	Tiazóis substituídos por heteroarila
BRPI0820779A2 (pt)	2015-06-16	Derivados de 4-amino-pirimidina
HRP20150932T1 (xx)	2015-10-09	Heterocikliäśki spojevi
BRPI0806506A2 (pt)	2014-04-22	Indazóis substituídos por 5-furopiridinona
BR112012010238A2 (pt)	2015-09-29	compostos heterocíclicos pesticidas
ATE515503T1 (de)	2011-07-15	Antiparasitische benzofuranmittel
IT1393655B1 (it)	2012-05-08	Composizione pesticida
BRPI0816208A2 (pt)	2016-07-19	herbicidas
ATE532773T1 (de)	2011-11-15	Insektizide pyrimidinyl-aryl-hydrazone
IT1393650B1 (it)	2012-05-08	Composizione pesticida