BRPI0910281A2 - pirólise catalítica de biomassa sólida e compostos biocombustíveis, aromáticos e olefínicos relacionados - Google Patents

pirólise catalítica de biomassa sólida e compostos biocombustíveis, aromáticos e olefínicos relacionados

Info

Publication number
BRPI0910281A2
BRPI0910281A2 BRPI0910281A BRPI0910281A BRPI0910281A2 BR PI0910281 A2 BRPI0910281 A2 BR PI0910281A2 BR PI0910281 A BRPI0910281 A BR PI0910281A BR PI0910281 A BRPI0910281 A BR PI0910281A BR PI0910281 A2 BRPI0910281 A2 BR PI0910281A2
Authority
BR
Brazil
Prior art keywords
biofuel
aromatic
catalytic pyrolysis
solid biomass
olefin compounds
Prior art date
Application number
BRPI0910281A
Other languages
English (en)
Inventor
Geoff Tompsett
George W Huber
Jungho Jae
Torren Carlson
Tushar Vispute
Yu-Ting Cheng
Original Assignee
Univ Massachusetts
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ Massachusetts filed Critical Univ Massachusetts
Publication of BRPI0910281A2 publication Critical patent/BRPI0910281A2/pt
Publication of BRPI0910281B1 publication Critical patent/BRPI0910281B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/002—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal in combination with oil conversion- or refining processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/08—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C10G2300/1014—Biomass of vegetal origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C10G2300/1018—Biomass of animal origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/30—Physical properties of feedstocks or products
    • C10G2300/305—Octane number, e.g. motor octane number [MON], research octane number [RON]
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/30—Aromatics
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/40—Ethylene production

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
BRPI0910281-7A 2008-03-04 2009-03-03 Catalytic pyrolysis of solid biomass and related biofuels, aromatic and olefinic compounds BRPI0910281B1 (pt)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US6800108P 2008-03-04 2008-03-04
US61/068,001 2008-03-04
US9828408P 2008-09-19 2008-09-19
US61/098,284 2008-09-19
PCT/US2009/001382 WO2009111026A2 (en) 2008-03-04 2009-03-03 Catalytic pyrolysis of solid biomass and related biofuels, aromatic, and olefin compounds

Publications (2)

Publication Number Publication Date
BRPI0910281A2 true BRPI0910281A2 (pt) 2015-09-29
BRPI0910281B1 BRPI0910281B1 (pt) 2017-10-24

Family

ID=41054355

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0910281-7A BRPI0910281B1 (pt) 2008-03-04 2009-03-03 Catalytic pyrolysis of solid biomass and related biofuels, aromatic and olefinic compounds

Country Status (12)

Country Link
US (2) US8277643B2 (pt)
EP (1) EP2257612B1 (pt)
JP (1) JP5662168B2 (pt)
CN (2) CN102015969B (pt)
AU (1) AU2009220133B2 (pt)
BR (1) BRPI0910281B1 (pt)
CA (1) CA2753985C (pt)
ES (1) ES2871871T3 (pt)
IL (1) IL207961A0 (pt)
MX (1) MX2010009800A (pt)
NZ (1) NZ588052A (pt)
WO (1) WO2009111026A2 (pt)

Families Citing this family (174)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3252128B1 (en) 2006-04-03 2019-01-02 Pharmatherm Chemicals Inc. Thermal extraction method for producing a taxane extract
US7897798B2 (en) * 2006-08-04 2011-03-01 Mcneff Research Consultants, Inc. Methods and apparatus for producing alkyl esters from lipid feed stocks and systems including same
US8979955B2 (en) * 2007-08-01 2015-03-17 Virginia Tech Intellectual Properties, Inc. Production of pyrolysis oil
US7905990B2 (en) 2007-11-20 2011-03-15 Ensyn Renewables, Inc. Rapid thermal conversion of biomass
WO2010002792A2 (en) * 2008-06-30 2010-01-07 Kior, Inc. Co-processing solid biomass in a conventional petroleum refining process unit
TW201026837A (en) * 2008-09-17 2010-07-16 Bdi Bio Diesel Internat Ag Process for obtaining combustibles and fuels, respectively
US9102877B2 (en) * 2008-11-12 2015-08-11 Sartec Corporation Systems and methods for producing fuels from biomass
US8524959B1 (en) 2009-02-18 2013-09-03 Kior, Inc. Biomass catalytic conversion process and apparatus for use therein
US8558043B2 (en) * 2009-03-04 2013-10-15 Kior, Inc. Modular biomass treatment unit
US20100282588A1 (en) * 2009-05-07 2010-11-11 Whitton Norman M Thermochemical Processing of Algal Biomass
US20120137572A1 (en) * 2009-05-22 2012-06-07 Kior, Inc. Processing biomass with a hydrogen source
US8063258B2 (en) 2009-05-22 2011-11-22 Kior Inc. Catalytic hydropyrolysis of organophillic biomass
US8623634B2 (en) * 2009-06-23 2014-01-07 Kior, Inc. Growing aquatic biomass, and producing biomass feedstock and biocrude therefrom
US20110011721A1 (en) * 2009-07-16 2011-01-20 Champagne Gary E Vacuum Pyrolytic Gasification And Liquefaction To Produce Liquid And Gaseous Fuels From Biomass
US20110036280A1 (en) * 2009-08-12 2011-02-17 Bruce Toase Waste processing system
EP2473534A1 (en) * 2009-09-01 2012-07-11 O'Connor, Paul Temperature-optimized conversion of lignocellulosic biomass
KR101666089B1 (ko) * 2009-09-09 2016-10-13 아넬로테크, 인코퍼레이티드 임의의 올레핀 재순환과 함께 방향족의 생산을 위한 바이오매스 및 탄화수소성 물질의 촉매 열분해를 위한 시스템 및 방법, 및 촉매 열분해를 위해서 선택된 입자 크기를 지니는 촉매
CN102146010A (zh) * 2010-02-10 2011-08-10 江苏煤化工程研究设计院有限公司 以甲醇为原料生产低碳烯烃及芳烃并联产汽油的工艺
US8519203B2 (en) * 2010-02-17 2013-08-27 Uop Llc Low oxygen biomass-derived pyrolysis oils and methods for producing the same
WO2011103313A2 (en) * 2010-02-17 2011-08-25 Virginia Tech Intellectual Properties, Inc. Production of pyrolysis oil
DE102010014768B4 (de) * 2010-04-13 2021-10-28 Nexxoil Gmbh Verfahren zur thermischen Spaltung hochmolekularer organischer Abfälle
WO2011138356A1 (de) 2010-05-07 2011-11-10 Basf Se Verfahren zur herstellung von synthesegas und wenigstens eines organischen flüssigen oder verflüssigbaren wertstoffs
WO2011138355A2 (de) 2010-05-07 2011-11-10 Basf Se Verfahren zur herstellung von zellstoff und wenigstens einem organischen flüssigen oder verflüssigbaren wertstoff mit abgasrückführung
WO2011138357A1 (de) 2010-05-07 2011-11-10 Basf Se Verfahren zur herstellung wenigstens eines niedermolekularen aromatischen wertstoffs aus einem ligninhaltigen ausgangsmaterial
US8604260B2 (en) 2010-05-18 2013-12-10 Kior, Inc. Biomass pyrolysis conversion process with high olefin production and upgrade
US20110284359A1 (en) 2010-05-20 2011-11-24 Uop Llc Processes for controlling afterburn in a reheater and for controlling loss of entrained solid particles in combustion product flue gas
US20100323435A1 (en) * 2010-06-25 2010-12-23 Boateng Akwasi A Injection System for Bio-fuel Reactor
EP3401410B1 (en) 2010-06-26 2020-12-30 Virdia, Inc. Methods for production of sugar mixtures
US8499702B2 (en) 2010-07-15 2013-08-06 Ensyn Renewables, Inc. Char-handling processes in a pyrolysis system
US8057641B2 (en) 2010-07-19 2011-11-15 Kior Inc. Method and apparatus for pyrolysis of a biomass
US9394487B2 (en) * 2010-07-23 2016-07-19 Inaeris Technologies, Llc Multi-stage biomass conversion
WO2012013735A1 (de) 2010-07-29 2012-02-02 Basf Se Katalysator- und ligninhaltige zusammensetzung und deren verwendung zur herstellung einer aromatenzusammensetzung
US20120029243A1 (en) * 2010-07-29 2012-02-02 Basf Se Catalyst- and lignin-comprising composition and its use for preparing an aromatics composition
IL207945A0 (en) 2010-09-02 2010-12-30 Robert Jansen Method for the production of carbohydrates
JP5707068B2 (ja) * 2010-09-08 2015-04-22 アースリサイクル株式会社 バイオディーゼル燃料油の製造システム
KR101735108B1 (ko) * 2010-09-16 2017-05-15 에스케이이노베이션 주식회사 석탄 또는 나무에서 산출되는 탄화수소 유분으로부터 고부가 방향족 제품 및 올레핀 제품을 제조하는 방법
US8772556B2 (en) 2010-09-22 2014-07-08 Kior, Inc. Bio-oil production with optimal byproduct processing
SG189484A1 (en) 2010-10-22 2013-05-31 Sk Innovation Co Ltd The method for producing valuable aromatics and light paraffins from hydrocarbonaceous oils derived from oil, coal or wood
US9382489B2 (en) 2010-10-29 2016-07-05 Inaeris Technologies, Llc Renewable heating fuel oil
US9447350B2 (en) 2010-10-29 2016-09-20 Inaeris Technologies, Llc Production of renewable bio-distillate
US8628589B2 (en) 2011-02-11 2014-01-14 Kior, Inc. Renewable heating oil
US9062264B2 (en) 2010-10-29 2015-06-23 Kior, Inc. Production of renewable bio-gasoline
US8377152B2 (en) 2010-10-29 2013-02-19 Kior, Inc. Production of renewable bio-distillate
US9017428B2 (en) 2010-11-16 2015-04-28 Kior, Inc. Two-stage reactor and process for conversion of solid biomass material
AU2011348031A1 (en) * 2010-12-24 2013-06-27 Sapphire Energy, Inc. Production of aromatics from renewable resources
US9617489B2 (en) 2011-02-11 2017-04-11 Inaeris Technologies, Llc Liquid bio-fuels
US9315739B2 (en) 2011-08-18 2016-04-19 Kior, Llc Process for upgrading biomass derived products
US8669405B2 (en) 2011-02-11 2014-03-11 Kior, Inc. Stable bio-oil
US10987661B2 (en) 2011-02-17 2021-04-27 AMG Chemistry and Catalysis Consulting, LLC Alloyed zeolite catalyst component, method for making and catalytic application thereof
US9404045B2 (en) 2011-02-17 2016-08-02 AMG Chemistry and Catalysis Consulting, LLC Alloyed zeolite catalyst component, method for making and catalytic application thereof
US9441887B2 (en) 2011-02-22 2016-09-13 Ensyn Renewables, Inc. Heat removal and recovery in biomass pyrolysis
US8236173B2 (en) 2011-03-10 2012-08-07 Kior, Inc. Biomass pretreatment for fast pyrolysis to liquids
US8921628B2 (en) 2011-03-10 2014-12-30 Kior, Inc. Refractory mixed-metal oxides and spinel compositions for thermo-catalytic conversion of biomass
WO2012137201A1 (en) 2011-04-07 2012-10-11 Hcl Cleantech Ltd. Lignocellulose conversion processes and products
JP2014516769A (ja) * 2011-04-13 2014-07-17 キオール，インク． バイオマスを液体燃料と化学品に熱触媒変換するための改良された触媒
US8841495B2 (en) 2011-04-18 2014-09-23 Gas Technology Institute Bubbling bed catalytic hydropyrolysis process utilizing larger catalyst particles and smaller biomass particles featuring an anti-slugging reactor
JP2014520086A (ja) 2011-05-24 2014-08-21 ビーエーエスエフ ソシエタス・ヨーロピア バイオマスからポリイソシアナートを製造する方法
US8933262B2 (en) 2011-05-24 2015-01-13 Basf Se Process for preparing polyisocyanates from biomass
US8772558B2 (en) * 2011-07-26 2014-07-08 Uop Llc Methods and apparatuses for producing aromatic hydrocarbon-containing effluent
US10427069B2 (en) 2011-08-18 2019-10-01 Inaeris Technologies, Llc Process for upgrading biomass derived products using liquid-liquid extraction
US9145350B2 (en) 2011-08-26 2015-09-29 Polyvalor, Limited Partnership Methods for the valorization of carbohydrates
BR112014004511A2 (pt) * 2011-09-01 2017-03-28 Univ Massachusetts método para produção de um ou mais produtos de hidrocarbonetos fluidos de um material hidrocarbonado sólido"
US9347005B2 (en) 2011-09-13 2016-05-24 Ensyn Renewables, Inc. Methods and apparatuses for rapid thermal processing of carbonaceous material
US10400175B2 (en) 2011-09-22 2019-09-03 Ensyn Renewables, Inc. Apparatuses and methods for controlling heat for rapid thermal processing of carbonaceous material
US9044727B2 (en) 2011-09-22 2015-06-02 Ensyn Renewables, Inc. Apparatuses and methods for controlling heat for rapid thermal processing of carbonaceous material
US10041667B2 (en) 2011-09-22 2018-08-07 Ensyn Renewables, Inc. Apparatuses for controlling heat for rapid thermal processing of carbonaceous material and methods for the same
US9617608B2 (en) 2011-10-10 2017-04-11 Virdia, Inc. Sugar compositions
US9109177B2 (en) 2011-12-12 2015-08-18 Ensyn Renewables, Inc. Systems and methods for renewable fuel
US9222612B2 (en) 2012-01-06 2015-12-29 Vadxx Energy LLC Anti-fouling apparatus for cleaning deposits in pipes and pipe joints
CN104105782A (zh) * 2012-01-06 2014-10-15 Kior股份有限公司 用于转化固体生物质材料的两级反应器和方法
US9206365B2 (en) * 2012-01-10 2015-12-08 Kior, Llc Fungible bio-oil
CZ303747B6 (cs) * 2012-01-30 2013-04-17 Vysoká skola chemicko-technologická v Praze Zpusob úpravy suroviny recyklovanými ionty pro získávání biooleje rychlou pyrolýzou dreva
CZ201262A3 (cs) * 2012-01-30 2013-01-09 Vysoká skola chemicko-technologická v Praze Zpusob úpravy suroviny pro získávání biooleje rychlou pyrolýzou dreva
US10731081B2 (en) * 2012-02-09 2020-08-04 Vadxx Energy LLC Zone-delineated pyrolysis apparatus for conversion of polymer waste
MX371026B (es) * 2012-02-15 2020-01-13 Vadxx Energy LLC Aparato de pirólisis delineado por zonas, de doble etapa.
WO2013123297A2 (en) 2012-02-17 2013-08-22 Kior, Inc. Catalyst composition with increased bulk active site accessibility for the catalytic thermoconversion of biomass to liquid fuels and chemicals and for upgrading bio-oils
US10155908B2 (en) 2012-03-07 2018-12-18 Research Triangle Institute Catalyst compositions and use thereof in catalytic biomass pyrolysis
PL3415233T3 (pl) * 2012-03-07 2020-06-29 Research Triangle Institute Układ do pirolizy katalitycznej biomasy
US9327208B2 (en) * 2012-04-30 2016-05-03 Kior, Llc Bio-oil fractionation
US9624446B2 (en) 2012-06-19 2017-04-18 Inaeris Technologies, Llc Low temperature property value reducing compositions
US9534181B2 (en) * 2012-06-19 2017-01-03 Inaeris Technologies, Llc Method of using renewable fuel composition
US9670413B2 (en) 2012-06-28 2017-06-06 Ensyn Renewables, Inc. Methods and apparatuses for thermally converting biomass
US9518229B2 (en) 2012-07-20 2016-12-13 Inaeris Technologies, Llc Catalysts for thermo-catalytic conversion of biomass, and methods of making and using
US9534174B2 (en) 2012-07-27 2017-01-03 Anellotech, Inc. Fast catalytic pyrolysis with recycle of side products
DE112013004599T5 (de) * 2012-09-20 2015-06-11 Sekisui Chemical Co., Ltd. Produktivitätsbewertungsverfahren, Produktivitätsbewertungsvorrichtung, Programm und Aufzeichnungsmedium
US9249080B2 (en) 2012-10-17 2016-02-02 Anellotech, Inc. Chemical intermediates by catalytic fast pyrolysis process
CN102936511B (zh) * 2012-11-05 2014-08-27 北京华电光大新能源环保技术有限公司 一种在线催化裂解生物质快速热解产物制备高品位生物油的方法
CN102942947B (zh) * 2012-11-05 2014-09-10 北京华电光大新能源环保技术有限公司 一种催化热解生物质制备btx的方法
EP2928594B1 (en) * 2012-12-04 2024-02-21 Research Triangle Institute Process of catalytic pyrolysis of biomass
CN103896706B (zh) * 2012-12-25 2016-01-06 中国科学院大连化学物理研究所 一种利用葡萄糖制取丙烯的方法
CN103896707B (zh) * 2012-12-25 2016-04-20 中国科学院大连化学物理研究所 一种利用纤维素制取丙烯的方法
BR112015017417B1 (pt) * 2013-01-22 2021-01-19 Anellotech, Inc. reator com injetor de jato de gás para pirólise rápida catalítica
US8895790B2 (en) * 2013-02-12 2014-11-25 Saudi Basic Industries Corporation Conversion of plastics to olefin and aromatic products
US9447332B2 (en) 2013-02-12 2016-09-20 Saudi Basic Industries Corporation Conversion of plastics to olefin and aromatic products using temperature control
US9428695B2 (en) 2013-02-12 2016-08-30 Saudi Basic Industries Corporation Conversion of plastics to olefin and aromatic products with product recycle
CN105307771B (zh) * 2013-03-12 2018-11-13 阿内洛技术股份有限公司 催化快速热解催化剂的再生
US9452422B2 (en) * 2013-03-12 2016-09-27 The Procter & Gamble Company Catalysts and processes for the production of aromatic compounds from lignin
US9522392B2 (en) 2013-03-15 2016-12-20 Inaeris Technologies, Llc Phosphorous promotion of zeolite-containing catalysts
WO2014210150A1 (en) 2013-06-26 2014-12-31 Ensyn Renewables, Inc. Systems and methods for renewable fuel
JP6078882B2 (ja) * 2013-08-02 2017-02-15 国立研究開発法人産業技術総合研究所 炭化水素の製造方法
AU2014318759B2 (en) * 2013-09-11 2018-04-26 Research Triangle Institute Reactive catalytic fast pyrolysis process and system
CN103484142B (zh) * 2013-09-25 2015-02-18 清华大学 一种生物质与塑料共催化热解制备芳烃的方法
US20170247617A1 (en) 2013-09-26 2017-08-31 Biobtx B.V. Process for the Preparation of Aromatic Compounds
CN103626633A (zh) * 2013-11-14 2014-03-12 中国科学院广州能源研究所 一种促进固体催化剂解聚纤维素的方法
US20150166899A1 (en) 2013-12-14 2015-06-18 Anellotech, Inc. Catalysts and Processes for Producing p-xylene from Biomass
WO2015095498A1 (en) * 2013-12-18 2015-06-25 Battelle Memorial Institute Lignin-enriched biomass pyrolysis
WO2015094500A2 (en) 2013-12-20 2015-06-25 Exxonmobil Chemical Patents Inc. Production of para-xylene
US20150252268A1 (en) * 2014-01-10 2015-09-10 Proton Power, Inc. Methods, systems, and devices for liquid hydrocarbon fuel production, hydrocarbon chemical production, and aerosol capture
WO2015106251A1 (en) * 2014-01-13 2015-07-16 Kior, Inc. Renewable heating fuel oil
EP3102324B1 (en) * 2014-02-07 2021-09-22 BASF Corporation Catalyst for fast pyrolysis of an oxygen-containing feedstock
CN104059682B (zh) * 2014-06-24 2016-06-08 东南大学 生物质选择性热解-梯级转化制备航空燃油的装置和方法
ES3057332T3 (en) 2014-07-01 2026-02-27 Anellotech Inc Improved processes for recovering valuable components from a catalytic fast pyrolysis process
CN106661463B (zh) 2014-07-01 2019-04-16 阿内洛技术股份有限公司 经由催化快速热解工艺将生物质转化成具有低硫、氮和烯烃含量的btx的工艺
CN105441109B (zh) * 2014-08-20 2017-02-15 中国科学技术大学 一种利用木质素定向合成航空煤油芳香组分的方法
US10927498B2 (en) * 2014-09-22 2021-02-23 Huntsman International Llc Process for the preparation of aromatic compounds
MX357968B (es) 2014-11-03 2018-08-01 Anellotech Inc Proceso mejorado para recuperar monoxido de carbono de un producto de pirolisis rapida catalitica.
KR20170088835A (ko) * 2014-11-17 2017-08-02 아넬로테크, 인코퍼레이티드 촉매의 고속 열분해 공정 및 숯 조성물에서 숯을 처리하는 방법
CN107207968A (zh) * 2014-11-20 2017-09-26 安耐罗技术股份有限公司 改进的催化快速热解工艺
CN104531194B (zh) * 2014-12-19 2018-01-23 东北林业大学 一种木塑复合材料催化裂解制备苯系液相产物的方法
US11078548B2 (en) 2015-01-07 2021-08-03 Virdia, Llc Method for producing xylitol by fermentation
KR20160104207A (ko) 2015-02-26 2016-09-05 순천대학교 산학협력단 바이오매스로부터 나노 기공을 가지는 산성 고체 촉매를 이용한 바이오 오일의 제조방법
BR112017019379A2 (pt) * 2015-04-16 2018-06-05 Anellotech Inc intermediários químicos derivados de biomassa
US10000703B2 (en) 2015-05-08 2018-06-19 Anellotech, Inc. Catalytic fast pyrolysis process
US10358606B2 (en) 2015-06-19 2019-07-23 China Petroleum & Chemical Corporation Process for producing aromatics, p-xylene and terephthalic acid
CN106316768B (zh) * 2015-06-19 2019-05-14 中国石油化工股份有限公司 高选择性制备二甲苯的方法
AU2016285471B2 (en) * 2015-06-30 2021-10-28 Anellotech, Inc. Improved catalytic fast pyrolysis process with impurity removal
CN105038833B (zh) * 2015-07-07 2017-12-05 大连理工大学 一种木质素流化床催化热解制轻质芳烃的方法
US10337726B2 (en) 2015-08-21 2019-07-02 Ensyn Renewables, Inc. Liquid biomass heating system
CA2999983A1 (en) 2015-09-25 2017-03-30 Inaeris Technologies, Llc Catalyst addition to a circulating fluidized bed reactor
WO2017053796A1 (en) * 2015-09-25 2017-03-30 Inaeris Technologies, Llc Use of cooling media in biomass conversion process
US20210214622A1 (en) * 2015-11-23 2021-07-15 Inaeris Technologies, Llc Process of upgrading light hydrocarbons and oxygenates produced during catalytic pyrolysis of biomass
MY191010A (en) 2016-02-05 2022-05-28 Anellotech Inc Chemicals and fuel blendstocks by a catalytic fast pyrolysis process
WO2017139491A1 (en) * 2016-02-10 2017-08-17 Primus Green Energy Inc. Single-loop octane enrichment
FR3051799B1 (fr) 2016-05-31 2018-06-15 IFP Energies Nouvelles Procede de production de btx par pyrolyse catalytique a partir de biomasse avec injection de composes oxygenes
FR3051800B1 (fr) 2016-05-31 2018-06-15 IFP Energies Nouvelles Procede de production de btx par pyrolyse catalytique a partir de biomasse sans recycle de composes oxygenes
NL2017044B1 (en) * 2016-06-24 2018-01-19 Biobtx B V Process for the preparation of low molecular weight aromatics (BTX) and biofuels from biomass.
CN106518594A (zh) * 2016-09-18 2017-03-22 安徽理工大学 一种催化裂解甲壳素制备萘、甲基萘的方法
US10472467B2 (en) * 2016-09-20 2019-11-12 Dow Global Technologies Llc Polymers having intrinsic microporosity including sub-units with troger's base and spirobisindane moieties
CA3048681A1 (en) 2016-12-29 2018-07-05 Ensyn Renewables, Inc. Demetallization of liquid biomass
CN110139915B (zh) 2017-01-05 2021-12-14 沙特基础全球技术有限公司 废塑料通过热解向如苯和二甲苯的高价值产物的转化
WO2018127817A1 (en) 2017-01-05 2018-07-12 Sabic Global Technologies, B.V. Conversion of waste plastic to propylene and cumene
JP6956187B2 (ja) 2017-01-05 2021-11-02 サビック グローバル テクノロジーズ ベスローテン フェンノートシャップ 廃棄プラスチックのプロピレンおよびクメンへの変換
US11401474B2 (en) * 2017-04-13 2022-08-02 Alliance For Sustainable Energy, Llc Systems and methods for producing fuel intermediates
US10239812B2 (en) 2017-04-27 2019-03-26 Sartec Corporation Systems and methods for synthesis of phenolics and ketones
CN107345147B (zh) * 2017-06-27 2019-03-29 浙江大学 一种含油污泥制备高含量芳香烃产物的方法
WO2019022743A1 (en) 2017-07-27 2019-01-31 Anellotech, Inc. EFFICIENT RECOVERY OF VALUABLE CONSTITUENTS IN A CATALYTIC PYROLYSIS EFFLUENT OF BIOMASS
US10696923B2 (en) 2018-02-07 2020-06-30 Sartec Corporation Methods and apparatus for producing alkyl esters from lipid feed stocks, alcohol feedstocks, and acids
US10544381B2 (en) 2018-02-07 2020-01-28 Sartec Corporation Methods and apparatus for producing alkyl esters from a reaction mixture containing acidified soap stock, alcohol feedstock, and acid
CN109622002B (zh) * 2018-12-17 2021-12-21 西北大学 一种用于提高btx产率的催化剂的制备方法
CN110129075A (zh) * 2019-03-28 2019-08-16 扬州工业职业技术学院 一种降低含水量的木薯热裂解方法
JP7421284B2 (ja) 2019-08-09 2024-01-24 ＪＤＩ Ｄｅｓｉｇｎ ａｎｄ Ｄｅｖｅｌｏｐｍｅｎｔ 合同会社 表示パネル、および、表示パネルの製造方法
CN110358568A (zh) * 2019-08-29 2019-10-22 郑州大学 一种生物质制备生物油的方法及其催化剂
US11713419B2 (en) 2020-06-04 2023-08-01 T.En Process Technology, Inc. Systems and methods for producing lignocellulosic alkanes
CN112760118A (zh) * 2020-12-15 2021-05-07 中国科学院广州能源研究所 一种混杂布碎热解制备富芳烃化合物的方法
US20220195140A1 (en) * 2020-12-23 2022-06-23 Uop Llc Conversion of plastics to monomers by acidic catalytic pyrolysis
US12018212B2 (en) * 2021-04-27 2024-06-25 Uop Llc Plastics pyrolysis process with quench
WO2022255135A1 (ja) * 2021-05-31 2022-12-08 Dic株式会社 フタロシアニン化合物
US12325832B2 (en) 2021-06-23 2025-06-10 Saudi Arabian Oil Company Method of producing pyrolysis products from a mixed plastics stream and integration of the same in a refinery
CA3234163A1 (en) 2021-11-17 2023-05-25 Matthieu DREILLARD Renewable diesel production from catalytic pyrolysis feedstock
US20250011655A1 (en) 2021-11-17 2025-01-09 IFP Energies Nouvelles Renewable jet production from catalytic pyrolysis feedstock
US12084619B2 (en) 2022-01-31 2024-09-10 Saudi Arabian Oil Company Processes and systems for producing fuels and petrochemical feedstocks from a mixed plastics stream
US11692139B1 (en) 2022-02-10 2023-07-04 Saudi Arabian Oil Company Method of producing pyrolysis products from a mixed plastics stream
US11807815B2 (en) 2022-02-16 2023-11-07 Saudi Arabian Oil Company Method of producing plastic pyrolysis products from a mixed plastics stream
JP2023124313A (ja) * 2022-02-25 2023-09-06 Ｕｂｅ三菱セメント株式会社 液体燃料の製造方法、燃焼炉用燃料、固体燃料の製造方法、及びセメントクリンカーの製造方法
WO2023215421A1 (en) * 2022-05-03 2023-11-09 Anellotech, Inc. High efficiency process for separating fillers from catalyst and gases in a catalytic fluidized bed pyrolysis process of plastics
FI130639B1 (en) * 2022-06-29 2024-01-03 Resiclo Oy Method for producing isomerized hydrocarbons from mixed plastics
WO2024219646A1 (en) * 2023-04-19 2024-10-24 Sk Innovation Co., Ltd. Method and system for producing refined hydrocarbons from waste plastics
US20240352327A1 (en) * 2023-04-19 2024-10-24 Sk Innovation Co., Ltd. Method and system for producing refined hydrocarbons from waste plastics
US20240352323A1 (en) * 2023-04-19 2024-10-24 Sk Innovation Co., Ltd. Method and system for producing refined hydrocarbons from waste plastics
US20240352325A1 (en) * 2023-04-19 2024-10-24 Sk Innovation Co., Ltd. Method and system for producing refined hydrocarbons from waste plastics
WO2024219756A1 (en) * 2023-04-19 2024-10-24 Sk Innovation Co., Ltd. Method and system for producing refined hydrocarbons from waste plastics
US20240351870A1 (en) * 2023-04-19 2024-10-24 Sk Innovation Co., Ltd. Method and system for producing syngas containing hydrogen from waste plastic pyrolysis oil
US20240384184A1 (en) * 2023-05-18 2024-11-21 Sk Innovation Co., Ltd. Method of Refining Waste Plastic Pyrolysis Oil Using Waste Tire Pyrolysis Oil and Molybdenum-Based Hydrotreating Catalyst, and Continuous Operation Method Thereof
WO2025151557A1 (en) 2024-01-09 2025-07-17 Anellotech, Inc. Plastic upgrading using poison resistant core-shell catalysts

Family Cites Families (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3998898A (en) * 1973-08-09 1976-12-21 Mobil Oil Corporation Manufacture of gasoline
US4058576A (en) * 1974-08-09 1977-11-15 Mobil Oil Corporation Conversion of methanol to gasoline components
US3931349A (en) * 1974-09-23 1976-01-06 Mobil Oil Corporation Conversion of methanol to gasoline components
US3936353A (en) * 1974-12-20 1976-02-03 Mobil Oil Corporation Conversion of carbohydrate materials to petroleum type hydrocarbons
US4035430A (en) * 1976-07-26 1977-07-12 Mobil Oil Corporation Conversion of methanol to gasoline product
US4300009A (en) * 1978-12-28 1981-11-10 Mobil Oil Corporation Conversion of biological material to liquid fuels
US4483764A (en) * 1981-11-13 1984-11-20 Standard Oil Company (Indiana) Hydrocarbon conversion process
IT1152998B (it) * 1982-07-01 1987-01-14 Anic Spa Procedimento per la preparazione di allumino-silicati cristallini porosi
US4503278A (en) * 1982-09-30 1985-03-05 Mobil Oil Corporation Process for converting carbohydrates to hydrocarbons
US4549031A (en) * 1984-01-30 1985-10-22 Mobil Oil Corporation Conversion of carbohydrates
US4933283A (en) * 1985-05-15 1990-06-12 Mobil Oil Corporation Process for converting cellulosic materials to hydrocarbon products
US4948495A (en) * 1988-07-26 1990-08-14 The United States Of America As Represented By The United States Department Of Energy High liquid yield process for retorting various organic materials including oil shale
US5792340A (en) * 1990-01-31 1998-08-11 Ensyn Technologies, Inc. Method and apparatus for a circulating bed transport fast pyrolysis reactor system
US5504259A (en) * 1992-10-29 1996-04-02 Midwest Research Institute Process to convert biomass and refuse derived fuel to ethers and/or alcohols
RU2111203C1 (ru) * 1993-12-01 1998-05-20 Закошанский Владимир Михайлович Способ очистки фенола от органических примесей
JPH07256228A (ja) * 1994-03-22 1995-10-09 Kunio Kato 木材、炭水化物、廃プラスチック類の接触熱分解法
FI104561B (fi) * 1998-02-27 2000-02-29 Fortum Oil And Gas Oy Fortum O Menetelmä hiilipitoisten lähtöaineiden pyrolysoimiseksi
FR2782714B1 (fr) * 1998-08-26 2000-09-29 Inst Francais Du Petrole Procede de coproduction de metaxylene et de paraxylene
FR2795069B1 (fr) * 1999-06-17 2001-08-03 Inst Francais Du Petrole Procede de coproduction et de separation d'ethylbenzene et de paraxylene
FR2807750B1 (fr) * 2000-04-12 2002-06-07 Inst Francais Du Petrole Procede simultane de dismutation et de separation en lit mobile simule de toluene en benzene et xylenes
JP4314546B2 (ja) 2000-05-02 2009-08-19 株式会社Ｉｈｉ 廃プラスチック処理方法および装置
US6495723B1 (en) * 2000-06-21 2002-12-17 Flexsys America Zeolite support loaded with a base material for use in the coupling of aniline and nitrobenzene
GB2383037B (en) * 2001-02-26 2005-05-04 Council Scient Ind Res Substituted calix (4) pyrroles and process for the synthesis of calix (4) pyrroles over molecular sieve catalysts
US7241323B2 (en) 2001-07-10 2007-07-10 Advanced Fuel Research, Inc. Pyrolysis process for producing fuel gas
JP2003050008A (ja) * 2001-08-06 2003-02-21 Sumitomo Heavy Ind Ltd 流動床の温度制御方法及び温度制御装置
JP4267968B2 (ja) 2003-05-15 2009-05-27 三菱重工環境エンジニアリング株式会社 バイオマス処理法
RU2349569C2 (ru) * 2004-07-28 2009-03-20 Мейденся Корпорейшн Способ получения ароматического углеводорода и водорода
KR100659497B1 (ko) 2005-03-25 2006-12-20 한국에너지기술연구원 농임산폐기물의 유동층 열분해 및 가스화 장치와 그 방법
WO2007020068A1 (en) * 2005-08-18 2007-02-22 Haldor Topsøe A/S Process for converting difficultly convertible oxygenates to gasoline
WO2007064014A1 (ja) 2005-11-30 2007-06-07 Nippon Oil Corporation 燃料およびその製造方法
JP4801983B2 (ja) 2005-11-30 2011-10-26 Ｊｘ日鉱日石エネルギー株式会社 流動接触分解を用いたバイオマスの処理方法
EP1970425A1 (en) 2007-02-20 2008-09-17 BIOeCON International Holding N.V. Improved process for converting carbon-based energy carrier material
EP1852493A1 (en) * 2006-05-05 2007-11-07 BIOeCON International Holding N.V. Hydrothermal treatment of carbon-based energy carrier material
BRPI0711314A2 (pt) 2006-05-05 2011-12-06 Bioecon Internat Holding composição de matéria, e, método para preparar um material polimérico
EP1852491A1 (en) 2006-05-05 2007-11-07 BIOeCON International Holding N.V. Mild pyrolysis of carbon-based energy carrier material
EP1878695A1 (en) 2006-07-14 2008-01-16 BIOeCON International Holding N.V. Processing of biomass-derived oxygenates with particles comprising a coke deposit
JP2009543926A (ja) 2006-07-17 2009-12-10 バイオイーコン インターナショナル ホールディング エヌ．ブイ． 修飾されたバイオマスの電磁処理
KR20090051046A (ko) 2006-07-17 2009-05-20 바이오이콘 인터내셔널 홀딩 엔.브이. 미세 입자체 바이오매스의 촉매적 열분해 방법, 및 고체 바이오매스 입자체의 입자 크기를 감소시키는 방법
EP1892280A1 (en) * 2006-08-16 2008-02-27 BIOeCON International Holding N.V. Fluid catalytic cracking of oxygenated compounds
US8202332B2 (en) * 2007-08-01 2012-06-19 Virginia Tech Intellectual Properties Fractional catalytic pyrolysis of biomass

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