BRPI0913990A2 - complexos de metal de transição de piridildiamido, produção e uso deste - Google Patents
complexos de metal de transição de piridildiamido, produção e uso desteInfo
- Publication number
- BRPI0913990A2 BRPI0913990A2 BRPI0913990A BRPI0913990A BRPI0913990A2 BR PI0913990 A2 BRPI0913990 A2 BR PI0913990A2 BR PI0913990 A BRPI0913990 A BR PI0913990A BR PI0913990 A BRPI0913990 A BR PI0913990A BR PI0913990 A2 BRPI0913990 A2 BR PI0913990A2
- Authority
- BR
- Brazil
- Prior art keywords
- production
- transition metal
- metal complexes
- pyridyldiamide transition
- pyridyldiamide
- Prior art date
Links
- 229910052723 transition metal Inorganic materials 0.000 title 1
- 150000003624 transition metals Chemical class 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D213/36—Radicals substituted by singly-bound nitrogen atoms
- C07D213/38—Radicals substituted by singly-bound nitrogen atoms having only hydrogen or hydrocarbon radicals attached to the substituent nitrogen atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D213/44—Radicals substituted by doubly-bound oxygen, sulfur, or nitrogen atoms, or by two such atoms singly-bound to the same carbon atom
- C07D213/46—Oxygen atoms
- C07D213/48—Aldehydo radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D213/44—Radicals substituted by doubly-bound oxygen, sulfur, or nitrogen atoms, or by two such atoms singly-bound to the same carbon atom
- C07D213/53—Nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/003—Compounds containing elements of Groups 4 or 14 of the Periodic Table without C-Metal linkages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Pyridine Compounds (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Plural Heterocyclic Compounds (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/180,132 US7973116B2 (en) | 2008-07-25 | 2008-07-25 | Pyridyldiamido transition metal complexes, production and use thereof |
| US12/180,132 | 2008-07-25 | ||
| EP08166619 | 2008-10-15 | ||
| EP08166619.0 | 2008-10-15 | ||
| PCT/US2009/046911 WO2010011435A1 (en) | 2008-07-25 | 2009-06-10 | Pyridyldiamido transition metal complexes, production and use thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0913990A2 true BRPI0913990A2 (pt) | 2015-10-20 |
| BRPI0913990B1 BRPI0913990B1 (pt) | 2019-06-18 |
Family
ID=41016769
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0913990-7A BRPI0913990B1 (pt) | 2008-07-25 | 2009-06-10 | Complexo de metal de transição de piridildiamido, processo para preparo de um complexo de piridildiamido, sistema catalisador e processo de polimerização |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US7973116B2 (pt) |
| EP (1) | EP2310399B1 (pt) |
| JP (1) | JP5354814B2 (pt) |
| KR (1) | KR101264504B1 (pt) |
| CN (1) | CN102105480B (pt) |
| BR (1) | BRPI0913990B1 (pt) |
| ES (1) | ES2539455T3 (pt) |
| RU (1) | RU2514405C2 (pt) |
| WO (1) | WO2010011435A1 (pt) |
Families Citing this family (91)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7847099B2 (en) | 2006-09-21 | 2010-12-07 | California Institute Of Technology | Non-metallocene organometallic complexes and related methods and systems |
| US8674040B2 (en) * | 2008-07-25 | 2014-03-18 | Exxonmobil Chemical Patents Inc. | Pyridyldiamido transition metal complexes, production and use thereof |
| US8710163B2 (en) * | 2008-07-25 | 2014-04-29 | Exxonmobil Chemical Patents Inc. | Pyridyldiamido transition metal complexes, production and use thereof |
| US8394902B2 (en) * | 2008-07-25 | 2013-03-12 | Exxonmobil Chemical Patents Inc. | Pyridyldiamido transition metal complexes, production and use thereof |
| CN102421807B (zh) * | 2009-03-06 | 2015-03-18 | 陶氏环球技术有限责任公司 | 催化剂、制备催化剂的方法、制备聚烯烃组合物的方法和聚烯烃组合物 |
| US20120016092A1 (en) | 2010-07-14 | 2012-01-19 | Sandor Nagy | Catalysts based on quinoline precursors |
| CN103492397B (zh) * | 2011-03-25 | 2016-11-16 | 埃克森美孚化学专利公司 | 吡啶基二氨基过渡金属络合物，其生产方法和用途 |
| CN103946228A (zh) * | 2011-09-20 | 2014-07-23 | 道康宁公司 | 含钴硅氢加成催化剂及含有该催化剂的组合物 |
| CN102603810B (zh) * | 2012-01-29 | 2015-08-05 | 中国科学院长春应用化学研究所 | 稀土配合物及其制备方法、聚合用催化体系及其制备方法、聚合物的制备方法 |
| US9102773B2 (en) * | 2013-02-06 | 2015-08-11 | Exxonmobil Chemical Patents Inc. | Process for controlling molecular weight of polyolefins prepared using pyridyl diamide catalyst systems |
| SG11201505361VA (en) * | 2013-02-06 | 2015-08-28 | Exxonmobil Chem Patents Inc | Process for controlling molecular weight of polyolefins prepared using pyridyl diamide catalyst systems |
| CN105008416B (zh) * | 2013-03-06 | 2017-08-01 | 埃克森美孚化学专利公司 | 利用吡啶基二氨基催化剂的聚烯烃聚合中可逆的链转移 |
| CN105143278B (zh) * | 2013-04-23 | 2017-08-29 | 埃克森美孚化学专利公司 | 吡啶基二胺金属催化剂和制备聚烯烃的方法 |
| WO2015073145A1 (en) * | 2013-11-15 | 2015-05-21 | Exxonmobil Chemical Patents Inc. | Pyridyldiamido transition metal complexes, production and use thereof |
| CN111875630B (zh) * | 2013-11-15 | 2023-02-10 | 埃克森美孚化学专利公司 | 吡啶基二氨基过渡金属络合物，其的生产和用途 |
| CN105745231B (zh) * | 2013-11-15 | 2019-09-13 | 埃克森美孚化学专利公司 | 由吡啶基二氨基过渡金属络合物制备聚合物的方法及其用途 |
| US9315593B2 (en) | 2013-11-15 | 2016-04-19 | Exxonmobil Chemical Patents Inc. | Catalyst systems comprising pyridyldiamido transition metal complexes and chain transfer agent and use thereof |
| US9290519B2 (en) | 2013-11-15 | 2016-03-22 | Exxonmobil Chemical Patents Inc. | Pyridyldiamido transition metal complexes, production and use thereof |
| WO2015073157A1 (en) | 2013-11-15 | 2015-05-21 | Exxonmobil Chemical Patents Inc. | Process to produce polymers from pyridyldiamido transition metal complexes and use thereof |
| US9260552B2 (en) | 2013-11-15 | 2016-02-16 | Exxonmobil Chemical Patents Inc. | Process to produce polymers from pyridyldiamido transition metal complexes and use thereof |
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| US9315526B2 (en) | 2014-03-03 | 2016-04-19 | Exxonmobil Chemical Patents Inc. | Pyridyldiamido transition metal complexes, production and use thereof |
| CN106029675B (zh) * | 2014-03-03 | 2019-11-19 | 埃克森美孚化学专利公司 | 吡啶基二氨基过渡金属络合物、其制备和用途 |
| CN106132924B (zh) * | 2014-03-31 | 2019-03-19 | 埃克森美孚化学专利公司 | 亚苯基桥连的salalen催化剂 |
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| US10059724B2 (en) * | 2014-09-17 | 2018-08-28 | Versalis S.P.A. | Pyridine complex of zirconium, catalytic system comprising said pyridine complex of zirconium and process of (co)polymerization of conjugated dienes |
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| CN105693726B (zh) * | 2014-11-25 | 2017-10-03 | 中国科学院大连化学物理研究所 | 一种吡啶基桥联双吡唑苯并二咪唑化合物及其合成方法 |
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| CN107922441A (zh) * | 2015-06-30 | 2018-04-17 | 埃克森美孚化学专利公司 | 三齿双阴离子cnn配体的过渡金属络合物及其生产和用途 |
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| US12202920B2 (en) | 2019-01-08 | 2025-01-21 | ExxonMobil Engineering & Technology Company | Olefin polymerization processes featuring in situ blending of an oil extension |
| CN109851700B (zh) * | 2019-03-11 | 2021-07-27 | 中国科学院青岛生物能源与过程研究所 | 一种三齿吡啶亚胺铁系催化剂及其制备方法与应用 |
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| WO2020190510A1 (en) | 2019-03-21 | 2020-09-24 | Exxonmobil Chemical Patents Inc. | Methods for improving gas phase polymerization |
| US11180580B2 (en) | 2019-03-29 | 2021-11-23 | Exxonmobil Chemical Patents Inc. | Benzazole and pseudoindole diamido transition metal complexes and use thereof in olefin polymerization |
| US12466902B2 (en) | 2019-08-02 | 2025-11-11 | Exxonmobil Chemical Patents Inc. | Non-coordinating anion type activators for use with polyolefin polymerization catalysts |
| JP7834019B2 (ja) | 2019-08-27 | 2026-03-23 | シェブロン オロナイト カンパニー リミティド ライアビリティ カンパニー | エチレンコポリマー及び粘度調整剤としての使用 |
| WO2021119089A1 (en) | 2019-12-11 | 2021-06-17 | Exxonmobil Chemical Patents Inc. | Processes for introduction of liquid activators in olefin polymerization reactions |
| WO2021126523A1 (en) | 2019-12-19 | 2021-06-24 | Exxonmobil Chemical Patents Inc. | Production of impact copolymer polypropylene using metallocene and ziegler-natta catalysts in parallel reactors |
| US12528892B2 (en) | 2020-03-25 | 2026-01-20 | Exxonmobil Chemical Patents Inc. | Alkylation of transition metal coordination catalyst complexes |
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| US20230242745A1 (en) | 2020-06-03 | 2023-08-03 | Exxonmobil Chemical Patents Inc | Process for Production of Thermoplastic Vulcanizates using Supported Catalyst Systems and Compositions Made Therefrom |
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| WO2022035484A1 (en) | 2020-08-10 | 2022-02-17 | Exxonmobil Chemical Patents Inc. | Methods for delivery of non-aromatic solutions to polymerization reactors |
| US12503529B2 (en) | 2021-02-26 | 2025-12-23 | Exxonmobil Chemical Patents Inc. | Polymers of 4-substituted hexadiene and processes for production thereof |
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| WO2025250307A1 (en) | 2024-05-30 | 2025-12-04 | ExxonMobil Technology and Engineering Company | Methods for improving gas phase polymerization |
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| ATE135358T1 (de) | 1990-12-27 | 1996-03-15 | Exxon Chemical Patents Inc | Übergangsmetall-amidoverbindung und katalysatorsystem zur herstellung von isotaktischem propylen |
| US6103657A (en) | 1997-07-02 | 2000-08-15 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst for the production of olefin polymers |
| US6521793B1 (en) | 1998-10-08 | 2003-02-18 | Symyx Technologies, Inc. | Catalyst ligands, catalytic metal complexes and processes using same |
| JP2001048925A (ja) * | 1999-08-13 | 2001-02-20 | Mitsui Chemicals Inc | オレフィンの重合方法 |
| JP2001048910A (ja) * | 1999-09-09 | 2001-02-20 | Mitsui Chemicals Inc | 環状オレフィン系共重合体の製造方法 |
| WO2002046249A2 (en) | 2000-11-07 | 2002-06-13 | Symyx Technologies, Inc. | Methods of copolymerizing ethylene and isobutylene and polymers made thereby |
| EP1444276A1 (en) | 2001-11-06 | 2004-08-11 | Dow Global Technologies, Inc. | Isotactic propylene copolymers, their preparation and use |
| EP1539770B1 (en) | 2002-09-12 | 2006-03-22 | Dow Global Technologies Inc. | Preparation of metal amide complexes |
| EP1543014B1 (en) | 2002-09-12 | 2006-10-04 | Dow Global Technologies Inc. | Preparation of metal complexes |
| US6953764B2 (en) | 2003-05-02 | 2005-10-11 | Dow Global Technologies Inc. | High activity olefin polymerization catalyst and process |
| US7045583B2 (en) | 2003-12-22 | 2006-05-16 | Exxon Mobil Chemical Patents Inc. | Olefin polymerization catalyst system |
| US7317057B2 (en) * | 2004-03-17 | 2008-01-08 | Exxonmobil Chemical Patents Inc. | Catalyst composition and use thereof |
| DE102004020524A1 (de) * | 2004-04-26 | 2005-11-10 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung |
| US7439205B2 (en) * | 2005-11-21 | 2008-10-21 | Fina Technology, Inc. | Tridentate metal catalyst for olefin polymerization |
| WO2007067965A2 (en) | 2005-12-09 | 2007-06-14 | Dow Global Technologies Inc. | Processes of controlling molecular weight distribution in ethylene/alpha-olefin compositions |
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| EP2310399B1 (en) | 2015-04-01 |
| US7973116B2 (en) | 2011-07-05 |
| KR20110031995A (ko) | 2011-03-29 |
| WO2010011435A1 (en) | 2010-01-28 |
| CN102105480A (zh) | 2011-06-22 |
| JP5354814B2 (ja) | 2013-11-27 |
| RU2514405C2 (ru) | 2014-04-27 |
| EP2310399A1 (en) | 2011-04-20 |
| RU2010152298A (ru) | 2012-08-27 |
| ES2539455T3 (es) | 2015-07-01 |
| BRPI0913990B1 (pt) | 2019-06-18 |
| CN102105480B (zh) | 2014-09-17 |
| JP2011529051A (ja) | 2011-12-01 |
| KR101264504B1 (ko) | 2013-05-14 |
| US20100022726A1 (en) | 2010-01-28 |
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