BRPI0919871A2 - processo para preparação de acroleína a partir de glicerol - Google Patents

processo para preparação de acroleína a partir de glicerol

Info

Publication number
BRPI0919871A2
BRPI0919871A2 BRPI0919871A BRPI0919871A BRPI0919871A2 BR PI0919871 A2 BRPI0919871 A2 BR PI0919871A2 BR PI0919871 A BRPI0919871 A BR PI0919871A BR PI0919871 A BRPI0919871 A BR PI0919871A BR PI0919871 A2 BRPI0919871 A2 BR PI0919871A2
Authority
BR
Brazil
Prior art keywords
glycerol
preparing acrolein
acrolein
preparing
Prior art date
Application number
BRPI0919871A
Other languages
English (en)
Inventor
Jean-Luc Dubois
Original Assignee
Arkema France
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arkema France filed Critical Arkema France
Publication of BRPI0919871A2 publication Critical patent/BRPI0919871A2/pt
Publication of BRPI0919871B1 publication Critical patent/BRPI0919871B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/52—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition by dehydration and rearrangement involving two hydroxy groups in the same molecule
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/682—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium, tantalum or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00004—Scale aspects
    • B01J2219/00006—Large-scale industrial plants
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00—Chemistry of hydrocarbon compounds
    • Y10S585/8995—Catalyst and recycle considerations
    • Y10S585/906—Catalyst preservation or manufacture, e.g. activation before use

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
BRPI0919871-7A 2008-10-24 2009-10-05 Processes for the preparation of acrolein, acrylic acid and acrylonyryl from glycerol and the use of a catalytic system ??? BRPI0919871B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP08167478A EP2179981A1 (en) 2008-10-24 2008-10-24 Process for manufacturing acrolein from glycerol
EP08167478.0 2008-10-24
PCT/EP2009/062897 WO2010046227A1 (en) 2008-10-24 2009-10-05 Process for manufacturing acrolein from glycerol

Publications (2)

Publication Number Publication Date
BRPI0919871A2 true BRPI0919871A2 (pt) 2015-12-15
BRPI0919871B1 BRPI0919871B1 (pt) 2017-12-19

Family

ID=40386024

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0919871-7A BRPI0919871B1 (pt) 2008-10-24 2009-10-05 Processes for the preparation of acrolein, acrylic acid and acrylonyryl from glycerol and the use of a catalytic system ???

Country Status (8)

Country Link
US (1) US8378136B2 (pt)
EP (2) EP2179981A1 (pt)
JP (1) JP5762963B2 (pt)
KR (1) KR101711220B1 (pt)
CN (2) CN102197015A (pt)
BR (1) BRPI0919871B1 (pt)
MY (1) MY152299A (pt)
WO (1) WO2010046227A1 (pt)

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010099596A (ja) * 2008-10-24 2010-05-06 Arkema France グリセリンの脱水反応によるアクロレイン及びアクリル酸の製造用触媒と、その製造法
JP5761940B2 (ja) * 2010-08-02 2015-08-12 旭化成ケミカルズ株式会社 アクリロニトリルの製造方法
JP5881620B2 (ja) 2011-01-28 2016-03-09 日本化薬株式会社 飽和アルデヒドを選択的に低減させる触媒と、その製造方法
WO2012101471A1 (en) 2011-01-28 2012-08-02 Arkema France Improved process for manufacturing acrolein/acrylic acid
FR2975922B1 (fr) 2011-06-06 2013-05-31 Arkema France Reacteur a plaques avec injection in situ
FR2977809B1 (fr) 2011-07-12 2016-01-08 Arkema France Regeneration de catalyseur en continu dans un reacteur a lit fluidise
BR112014001873A2 (pt) 2011-07-29 2017-02-21 Nippon Kayaku Kk catalisador para preparação de acroleína e ácido acrílico por desidratação de glicerina, e seu processo de produção
WO2013017904A1 (en) 2011-07-29 2013-02-07 Arkema France Improved process of dehydration reactions
US8993801B2 (en) 2011-09-16 2015-03-31 Eastman Chemical Company Process for preparing V-Ti-P catalysts for synthesis of 2,3-unsaturated carboxylic acids
US9573119B2 (en) 2011-09-16 2017-02-21 Eastman Chemical Company Process for preparing V—Ti—P catalysts for synthesis of 2,3-unsaturated carboxylic acids
US8981172B2 (en) * 2011-09-16 2015-03-17 Eastman Chemical Company Catalytic dehydration of alcohols and ethers over a ternary mixed oxide
US8883672B2 (en) 2011-09-16 2014-11-11 Eastman Chemical Company Process for preparing modified V-Ti-P catalysts for synthesis of 2,3-unsaturated carboxylic acids
FR2989684B1 (fr) 2012-04-18 2014-10-31 Arkema France Procede de fabrication d'acroleine et/ou d'acide acrylique a partir de glycerol
KR101616528B1 (ko) * 2013-07-16 2016-04-28 주식회사 엘지화학 글리세린 탈수반응용 촉매, 이의 제조 방법 및 아크롤레인의 제조 방법
FR3017617B1 (fr) 2014-02-19 2016-02-12 Arkema France Procede de production d'acide acrylique bio-source
CN103804224B (zh) * 2014-02-20 2015-04-08 河北工业大学 一种催化甘油氨化制备腈类化合物的方法
CN106061934B (zh) * 2014-02-20 2019-05-03 阿科玛股份有限公司 用于生产丙烯酸的方法和系统
CN103801349B (zh) * 2014-03-19 2016-04-27 南京大学 一种vpo催化剂及其在甘油脱水制取丙烯醛中的应用
FR3019545B1 (fr) 2014-04-04 2016-03-11 Arkema France Procede de synthese directe de (meth)acroleine a partir d'ethers et/ou acetals
WO2016099066A1 (ko) * 2014-12-19 2016-06-23 주식회사 엘지화학 글리세린 탈수 반응용 촉매， 이의 제조 방법 및 상기 촉매를 이용한 아크롤레인의 제조 방법
KR101774543B1 (ko) 2014-12-19 2017-09-04 주식회사 엘지화학 글리세린 탈수 반응용 촉매, 이의 제조 방법 및 상기 촉매를 이용한 아크롤레인의 제조 방법
WO2016101958A1 (en) 2014-12-22 2016-06-30 Danmarks Tekniske Universitet Process for reducing the oxygen content of biomass using vanadium-based catalysts
US20160368861A1 (en) 2015-06-19 2016-12-22 Southern Research Institute Compositions and methods related to the production of acrylonitrile
KR102052708B1 (ko) * 2015-12-22 2019-12-09 주식회사 엘지화학 글리세린 탈수 반응용 촉매, 이의 제조 방법 및 상기 촉매를 이용한 아크롤레인의 제조 방법
WO2017111392A1 (ko) * 2015-12-22 2017-06-29 주식회사 엘지화학 글리세린 탈수 반응용 촉매, 이의 제조 방법 및 상기 촉매를 이용한 아크롤레인의 제조 방법
CN106008188B (zh) * 2016-05-30 2018-05-29 浙江工业大学 一种甘油催化脱水制备丙烯醛的新方法
US9708249B1 (en) 2016-08-24 2017-07-18 Southern Research Institute Compositions and methods related to the production of acrylonitrile
CN109305898B (zh) * 2017-07-28 2021-11-30 中国石油化工股份有限公司 甘油脱水制丙烯醛的方法
CA3154623A1 (en) 2019-09-30 2021-04-08 Gevo, Inc. Simultaneous dehydration, dimerization, and metathesis of c2-c5 alcohols
KR20240000547A (ko) 2021-04-23 2024-01-02 게보 인코포레이티드 C1-c5 알코올의 c2-c5 올레핀 혼합물로의 촉매 전환을 위한 시스템 및 방법
EP4700008A1 (en) * 2024-08-18 2026-02-25 Technip Energies France Production of acrolein from glycerol

Family Cites Families (27)

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Publication number Priority date Publication date Assignee Title
FR695931A (fr) 1929-06-15 1930-12-23 Schering Kahlbaum Ag Procédé de fabrication d'acroléine
US2558520A (en) 1948-01-29 1951-06-26 Us Ind Chemicals Inc Production of acrolein from glycerol
US3925464A (en) * 1971-12-14 1975-12-09 Asahi Glass Co Ltd Process for preparing unsaturated carboxylic acids from the corresponding unsaturated aldehydes
NL7410537A (nl) 1973-08-09 1975-02-11 Montedison Spa Werkwijze voor de bereiding van (alpha),(beta)-onverzadigde
US4298755A (en) 1980-02-25 1981-11-03 Ashland Oil, Inc. Catalytic oxydehydrogenation process
AU527862B2 (en) 1981-01-07 1983-03-24 Ashland Oil, Inc. Oxydehydration catalyst
US4364856A (en) 1981-01-16 1982-12-21 The Standard Oil Company Mixed metal phosphorus oxide coated catalysts for the oxidative dehydrogenation of carboxylic acids
US4366088A (en) 1981-01-26 1982-12-28 Ashland Oil, Inc. Support for a phosphate-containing catalyst
US4381411A (en) 1981-06-22 1983-04-26 The Standard Oil Company Production of methacrolein from isobutyraldehyde utilizing promoted iron phosphorus oxide catalysts
FR2657792B1 (fr) 1990-02-07 1992-05-15 Norsolor Sa Systeme catalytique et son application a l'oxydeshydrogenation d'acides carboxyliques satures.
DE4238493C1 (de) 1992-11-14 1994-04-21 Degussa Verfahren zur Herstellung von Acrolein und dessen Verwendung
DE4238492C2 (de) * 1992-11-14 1995-06-14 Degussa Verfahren zur Herstellung von 1,2- und 1,3-Propandiol
JP5006507B2 (ja) * 2004-01-30 2012-08-22 株式会社日本触媒 アクリル酸の製造方法
FR2882053B1 (fr) * 2005-02-15 2007-03-23 Arkema Sa Procede de deshydratation du glycerol en acrolene
FR2882052B1 (fr) * 2005-02-15 2007-03-23 Arkema Sa Procede de deshydratation du glycerol en acroleine
TWI438187B (zh) * 2005-02-28 2014-05-21 贏創德固賽有限責任公司 丙烯酸和基於可再生原料之吸水聚合物結構及二者之製備方法
FR2897058B1 (fr) 2006-02-07 2008-04-18 Arkema Sa Procede de preparation d'acroleine
US7683220B2 (en) * 2006-03-30 2010-03-23 Nippon Shokubai Co., Ltd. Process for production of acrolein
WO2008052993A2 (en) * 2006-11-01 2008-05-08 Bioecon International Holding N.V. Process for production of acrolein and other oxygenated compounds from glycerol in a transported bed reactor
JPWO2008066079A1 (ja) * 2006-12-01 2010-03-04 株式会社日本触媒 アクリル酸の製造方法
FR2909999B1 (fr) 2006-12-19 2009-04-03 Arkema France Procede de preparation d'acide acrylique a partir de glycerol
FR2912742B1 (fr) * 2007-02-16 2010-03-05 Arkema France Procede de synthese d'acrylonitrile a partir de glycerol
JP4991471B2 (ja) * 2007-05-16 2012-08-01 株式会社日本触媒 グリセリン脱水用触媒、およびアクロレインの製造方法
FR2921361B1 (fr) * 2007-09-20 2012-10-12 Arkema France Procede de fabrication d'acroleine a partir de glycerol
FR2925490B1 (fr) * 2007-12-20 2009-12-25 Arkema France Procede de synthese d'acroleine a partir de glycerol
CN101225039B (zh) * 2008-01-17 2010-11-10 上海华谊丙烯酸有限公司 一种以甘油为原料制备丙烯酸的方法
JP5130107B2 (ja) * 2008-04-25 2013-01-30 株式会社日本触媒 アクリル酸の製造方法

Also Published As

Publication number Publication date
EP2349969A1 (en) 2011-08-03
JP5762963B2 (ja) 2015-08-12
MY152299A (en) 2014-09-15
EP2179981A1 (en) 2010-04-28
JP2012506398A (ja) 2012-03-15
CN105348054A (zh) 2016-02-24
BRPI0919871B1 (pt) 2017-12-19
CN102197015A (zh) 2011-09-21
KR101711220B1 (ko) 2017-02-28
US8378136B2 (en) 2013-02-19
US20110213174A1 (en) 2011-09-01
KR20110077007A (ko) 2011-07-06
EP2349969B1 (en) 2015-11-25
WO2010046227A1 (en) 2010-04-29

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Legal Events

Date Code Title Description
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]
B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE A 10A ANUIDADE.

B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2534 DE 30-07-2019 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.