BRPI1011807A2 - método para fabricação de poliéteres de polióis com grupos terminais hidroxilia primários - Google Patents

método para fabricação de poliéteres de polióis com grupos terminais hidroxilia primários

Info

Publication number: BRPI1011807A2
Authority: BR; Brazil
Prior art keywords: end group; primary hydroxyl; hydroxyl end; making primary; polyol polyethers
Prior art date: 2009-07-03

Application number

BRPI1011807A

Other languages

English (en)

Inventor

Erika Bauer

Hartmut Nefzger

Jörg Hofmann

Klaus Lorenz

Norbert Hahn

Original Assignee

Bayer Materialscience Ag

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2009-07-03

Filing date

2010-06-30

Publication date

2016-05-31

Family has litigation

First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=42942287&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=BRPI1011807(A2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.

2010-06-30 Application filed by Bayer Materialscience Ag filed Critical Bayer Materialscience Ag

2016-05-31 Publication of BRPI1011807A2 publication Critical patent/BRPI1011807A2/pt

Links

-1 hydroxyl end group polyol Chemical class 0.000 title 1
229920000570 polyether Polymers 0.000 title 1
229920005862 polyol Polymers 0.000 title 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4887—Polyethers containing carboxylic ester groups derived from carboxylic acids other than acids of higher fatty oils or other than resin acids
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/08—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
- C07C69/67—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids
- C07C69/708—Ethers
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
- C07C69/73—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of unsaturated acids
- C07C69/734—Ethers
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/74—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring
- C07C69/757—Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a ring other than a six-membered aromatic ring having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
- C07C69/80—Phthalic acid esters
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/76—Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
- C07C69/80—Phthalic acid esters
- C07C69/82—Terephthalic acid esters
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4866—Polyethers having a low unsaturation value
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2603—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
- C08G65/2615—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen the other compounds containing carboxylic acid, ester or anhydride groups
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2645—Metals or compounds thereof, e.g. salts
- C08G65/2663—Metal cyanide catalysts, i.e. DMC's
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2669—Non-metals or compounds thereof
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2669—Non-metals or compounds thereof
- C08G65/2672—Nitrogen or compounds thereof
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/32—Polymers modified by chemical after-treatment
- C08G65/329—Polymers modified by chemical after-treatment with organic compounds
- C08G65/331—Polymers modified by chemical after-treatment with organic compounds containing oxygen
- C08G65/332—Polymers modified by chemical after-treatment with organic compounds containing oxygen containing carboxyl groups, or halides, or esters thereof
- C08G65/3324—Polymers modified by chemical after-treatment with organic compounds containing oxygen containing carboxyl groups, or halides, or esters thereof cyclic
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/32—Polymers modified by chemical after-treatment
- C08G65/329—Polymers modified by chemical after-treatment with organic compounds
- C08G65/331—Polymers modified by chemical after-treatment with organic compounds containing oxygen
- C08G65/332—Polymers modified by chemical after-treatment with organic compounds containing oxygen containing carboxyl groups, or halides, or esters thereof
- C08G65/3324—Polymers modified by chemical after-treatment with organic compounds containing oxygen containing carboxyl groups, or halides, or esters thereof cyclic
- C08G65/3326—Polymers modified by chemical after-treatment with organic compounds containing oxygen containing carboxyl groups, or halides, or esters thereof cyclic aromatic

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
General Chemical & Material Sciences (AREA)
Toxicology (AREA)
Polyethers (AREA)

BRPI1011807A 2009-07-03 2010-06-30 método para fabricação de poliéteres de polióis com grupos terminais hidroxilia primários BRPI1011807A2 (pt)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE200910031584 DE102009031584A1 (de)	2009-07-03	2009-07-03	Verfahren zur Herstellung von Polyetherpolyolen mit primären Hydroxyl-Endgruppen
PCT/EP2010/003958 WO2011000560A1 (de)	2009-07-03	2010-06-30	Verfahren zur herstellung von polyetherpolyolen mit primären hydroxyl-endgruppen

Publications (1)

Publication Number	Publication Date
BRPI1011807A2 true BRPI1011807A2 (pt)	2016-05-31

Family

ID=42942287

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
BRPI1011807A BRPI1011807A2 (pt)	2009-07-03	2010-06-30	método para fabricação de poliéteres de polióis com grupos terminais hidroxilia primários

Country Status (12)

Country	Link
US (1)	US9029495B2 (pt)
EP (1)	EP2448996B2 (pt)
JP (1)	JP2012531506A (pt)
KR (1)	KR101744362B1 (pt)
CN (1)	CN102471478B (pt)
BR (1)	BRPI1011807A2 (pt)
CA (1)	CA2767040A1 (pt)
DE (1)	DE102009031584A1 (pt)
ES (1)	ES2432501T5 (pt)
MX (1)	MX2011013699A (pt)
SG (1)	SG177282A1 (pt)
WO (1)	WO2011000560A1 (pt)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO2011075343A1 (en) *	2009-12-17	2011-06-23	Dow Global Technologies Inc.	Ethylene oxide capping of secondary hydroxyl polyols
EP2794798B1 (de)	2011-12-20	2015-11-25	Medical Adhesive Revolution GmbH	Hydroxy-aminopolymer und dessen verwendung in polyharnstoffpolyurethan-gewebeklebstoffen
EP2617748A1 (de)	2012-01-23	2013-07-24	Basf Se	Polyetherester-Polyole und Verfahren zu deren Herstellung
EP3209706B1 (en)	2014-10-22	2018-09-05	Dow Global Technologies LLC	Dual catalyst system for high primary hydroxyl polyols
HUE067017T2 (hu) *	2017-09-14	2024-09-28	Univ Northwestern	Eljárás poliolok gyártására
CN109180928B (zh) *	2018-09-14	2021-02-02	湖北工业大学	一种高纯度单羧基封端的聚乙二醇的制备方法
EP3670557A1 (de) *	2018-12-21	2020-06-24	Covestro Deutschland AG	Verfahren zur herstellung eines polyoxyalkylenpolyesterpolyols
EP3670571A1 (de)	2018-12-21	2020-06-24	Covestro Deutschland AG	Verfahren zur herstellung eines polyester-polyetherpolyol-blockcopolymers
EP3670568A1 (de)	2018-12-21	2020-06-24	Covestro Deutschland AG	Verfahren zur herstellung eines polyesters
CN110540640A (zh) *	2019-09-19	2019-12-06	福建省天骄化学材料有限公司	一种鞋材专用分散剂的制备方法
EP3875510A1 (de) *	2020-03-03	2021-09-08	Covestro Deutschland AG	Verfahren zur herstellung eines etheresterols
EP3889204A1 (de)	2020-04-02	2021-10-06	Covestro Deutschland AG	Verfahren zur herstellung eines polyoxyalkylencarbonatpolyols
CN114369236B (zh) *	2021-11-30	2024-04-12	山东一诺威新材料有限公司	高性能聚酯醚多元醇及其制备方法和应用

Family Cites Families (24)

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GB1063525A (en)	1963-02-14	1967-03-30	Gen Tire & Rubber Co	Organic cyclic oxide polymers, their preparation and tires prepared therefrom
US3829505A (en)	1970-02-24	1974-08-13	Gen Tire & Rubber Co	Polyethers and method for making the same
US3941849A (en)	1972-07-07	1976-03-02	The General Tire & Rubber Company	Polyethers and method for making the same
DE3315381A1 (de)	1983-04-28	1984-10-31	Basf Ag, 6700 Ludwigshafen	Verfahren zur herstellung von polyester- oder polyether-polyester-polyolen
US4487853A (en)	1983-12-27	1984-12-11	Basf Wyandotte Corporation	Low ethylene oxide/high primary hydroxyl content polyether-ester polyols and polyurethane foams based thereon
GB8613701D0 (en)	1986-06-05	1986-07-09	Ici Plc	Polymeric polyols
US5158922A (en)	1992-02-04	1992-10-27	Arco Chemical Technology, L.P.	Process for preparing metal cyanide complex catalyst
US5712216A (en)	1995-05-15	1998-01-27	Arco Chemical Technology, L.P.	Highly active double metal cyanide complex catalysts
US5470813A (en)	1993-11-23	1995-11-28	Arco Chemical Technology, L.P.	Double metal cyanide complex catalysts
US5482908A (en)	1994-09-08	1996-01-09	Arco Chemical Technology, L.P.	Highly active double metal cyanide catalysts
US5545601A (en)	1995-08-22	1996-08-13	Arco Chemical Technology, L.P.	Polyether-containing double metal cyanide catalysts
US5627120A (en)	1996-04-19	1997-05-06	Arco Chemical Technology, L.P.	Highly active double metal cyanide catalysts
US5714428A (en)	1996-10-16	1998-02-03	Arco Chemical Technology, L.P.	Double metal cyanide catalysts containing functionalized polymers
US5763642A (en) *	1997-06-19	1998-06-09	Arco Chemical Technology, L.P.	Low monol polyoxy (higher) alkylene polyols with primary hydroxyl content
US6066683A (en) †	1998-04-03	2000-05-23	Lyondell Chemical Worldwide, Inc.	Molded and slab polyurethane foam prepared from double metal cyanide complex-catalyzed polyoxyalkylene polyols and polyols suitable for the preparation thereof
DE19905611A1 (de)	1999-02-11	2000-08-17	Bayer Ag	Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
US20050085658A1 (en)	1999-10-25	2005-04-21	Geiger Eric J.	Phthalic anhydride based polyester-ether polyols and double metal cyanide catalyst system for preparing same
US7226988B1 (en) †	2001-12-21	2007-06-05	Basf Corporation	Method of forming polyetherols in the presence of carboxy-modified aluminum-based catalysts
US6777533B2 (en) †	2001-12-21	2004-08-17	Basf Corporation	Production of polyetherols using aluminum phosphonate catalysts
US7186867B2 (en) †	2004-04-21	2007-03-06	Basf Aktiengesellschaft	Process for preparing reactive polyether polyols having an ethylene oxide end block
US8933188B2 (en) *	2004-11-12	2015-01-13	Henkel US IP LLC	Low misting laminating adhesives
DE102007002555A1 (de) *	2007-01-17	2008-07-24	Bayer Materialscience Ag	Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen
WO2011075343A1 (en) *	2009-12-17	2011-06-23	Dow Global Technologies Inc.	Ethylene oxide capping of secondary hydroxyl polyols
PL2563834T3 (pl) *	2010-04-29	2019-07-31	Dow Global Technologies Llc	Hybrydowe poliestropolieteropoliole

2009
- 2009-07-03 DE DE200910031584 patent/DE102009031584A1/de not_active Withdrawn
2010
- 2010-06-30 CA CA2767040A patent/CA2767040A1/en not_active Abandoned
- 2010-06-30 MX MX2011013699A patent/MX2011013699A/es unknown
- 2010-06-30 ES ES10729815.0T patent/ES2432501T5/es active Active
- 2010-06-30 US US13/381,130 patent/US9029495B2/en active Active
- 2010-06-30 SG SG2011093952A patent/SG177282A1/en unknown
- 2010-06-30 KR KR1020127000005A patent/KR101744362B1/ko not_active Expired - Fee Related
- 2010-06-30 CN CN201080030088.1A patent/CN102471478B/zh not_active Expired - Fee Related
- 2010-06-30 BR BRPI1011807A patent/BRPI1011807A2/pt not_active IP Right Cessation
- 2010-06-30 EP EP10729815.0A patent/EP2448996B2/de not_active Not-in-force
- 2010-06-30 WO PCT/EP2010/003958 patent/WO2011000560A1/de not_active Ceased
- 2010-06-30 JP JP2012518795A patent/JP2012531506A/ja not_active Withdrawn

Also Published As

Publication number	Publication date
WO2011000560A1 (de)	2011-01-06
ES2432501T3 (es)	2013-12-03
EP2448996B1 (de)	2013-08-28
ES2432501T5 (es)	2017-09-11
US20120196999A1 (en)	2012-08-02
EP2448996B2 (de)	2017-04-12
CN102471478B (zh)	2016-03-09
EP2448996A1 (de)	2012-05-09
SG177282A1 (en)	2012-02-28
KR20120095338A (ko)	2012-08-28
KR101744362B1 (ko)	2017-06-07
CA2767040A1 (en)	2011-01-06
US9029495B2 (en)	2015-05-12
DE102009031584A1 (de)	2011-01-05
JP2012531506A (ja)	2012-12-10
MX2011013699A (es)	2012-02-22
CN102471478A (zh)	2012-05-23

Legal Events

Date	Code	Title	Description
2016-09-20	B08F	Application fees: dismissal - article 86 of industrial property law	Free format text: REFERENTE AS 5A E 6A ANUIDADES.
2017-01-10	B08K	Lapse as no evidence of payment of the annual fee has been furnished to inpi (acc. art. 87)	Free format text: EM VIRTUDE DO ARQUIVAMENTO PUBLICADO NA RPI 2385 DE 20-09-2016 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDO O ARQUIVAMENTO DO PEDIDO DE PATENTE, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.

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GB0911015D0 (en)	2009-08-12	Printing method
HUE037835T2 (hu)	2018-09-28	Eljárás izocianátok elõállítására
BR112012002225A2 (pt)	2017-08-08	máquina para produzir bebidas
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BR112013014282A2 (pt)	2016-09-20	processo para a preparação de polióis de poliéter com grupos finais de hidroxila primária
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