CA1029045A - Procede d'extraction d'hydroperoxydes cycloaliphatiques - Google Patents
Procede d'extraction d'hydroperoxydes cycloaliphatiquesInfo
- Publication number
- CA1029045A CA1029045A CA201,142A CA201142A CA1029045A CA 1029045 A CA1029045 A CA 1029045A CA 201142 A CA201142 A CA 201142A CA 1029045 A CA1029045 A CA 1029045A
- Authority
- CA
- Canada
- Prior art keywords
- par
- que
- hydroperoxyde
- procédé
- caractérisé
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000605 extraction Methods 0.000 title claims abstract description 21
- 150000002432 hydroperoxides Chemical class 0.000 title abstract 2
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 10
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 5
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 claims description 5
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 3
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims 2
- 101150093826 par1 gene Proteins 0.000 claims 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract description 6
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract description 3
- 238000000034 method Methods 0.000 abstract description 3
- PPQREHKVAOVYBT-UHFFFAOYSA-H dialuminum;tricarbonate Chemical compound [Al+3].[Al+3].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O PPQREHKVAOVYBT-UHFFFAOYSA-H 0.000 abstract 2
- 229940118662 aluminum carbonate Drugs 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- -1 pentaméthylene Chemical group 0.000 description 8
- 150000003254 radicals Chemical class 0.000 description 6
- BDAGIHXWWSANSR-UHFFFAOYSA-N Formic acid Chemical compound OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 3
- 229940082150 encore Drugs 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000006677 Appel reaction Methods 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 description 2
- PUAQLLVFLMYYJJ-UHFFFAOYSA-N 2-aminopropiophenone Chemical compound CC(N)C(=O)C1=CC=CC=C1 PUAQLLVFLMYYJJ-UHFFFAOYSA-N 0.000 description 1
- UDKCHVLMFQVBAA-UHFFFAOYSA-M Choline salicylate Chemical compound C[N+](C)(C)CCO.OC1=CC=CC=C1C([O-])=O UDKCHVLMFQVBAA-UHFFFAOYSA-M 0.000 description 1
- 101100421144 Danio rerio selenoo1 gene Proteins 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 101100490479 Lactococcus lactis subsp. lactis (strain IL1403) addA gene Proteins 0.000 description 1
- 101100000975 Lactococcus lactis subsp. lactis (strain IL1403) rexB gene Proteins 0.000 description 1
- 101100202896 Mus musculus Selenoo gene Proteins 0.000 description 1
- 240000001987 Pyrus communis Species 0.000 description 1
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 241001080024 Telles Species 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000010504 bond cleavage reaction Methods 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 101150006061 neur gene Proteins 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 206010037833 rales Diseases 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
- C07C407/003—Separation; Purification; Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/14—The ring being saturated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
- Extraction Or Liquid Replacement (AREA)
Abstract
PRECIS DE LA DIVULGATION:
La présente invention a pour objet un procédé d'extrac-tion d'hydroperoxydes cycloaliphatiques à partir des produits d'oxydation d'hydrocarbures cycloaliphatiques par l'oxygène. Le solvant utilisé est une polyméthylènesulfone ou un carbonate d'al-coylène glycol comportant de 2 à 4 atomes de carbone. Le procédé
permet une meilleure extraction qu'avec les solvants antérieure-ment utilisés.
La présente invention a pour objet un procédé d'extrac-tion d'hydroperoxydes cycloaliphatiques à partir des produits d'oxydation d'hydrocarbures cycloaliphatiques par l'oxygène. Le solvant utilisé est une polyméthylènesulfone ou un carbonate d'al-coylène glycol comportant de 2 à 4 atomes de carbone. Le procédé
permet une meilleure extraction qu'avec les solvants antérieure-ment utilisés.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7320225A FR2231661B1 (fr) | 1973-06-04 | 1973-06-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1029045A true CA1029045A (fr) | 1978-04-04 |
Family
ID=9120460
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA201,142A Expired CA1029045A (fr) | 1973-06-04 | 1974-05-29 | Procede d'extraction d'hydroperoxydes cycloaliphatiques |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US3956397A (fr) |
| JP (1) | JPS5019737A (fr) |
| AT (1) | AT331208B (fr) |
| BE (1) | BE815901A (fr) |
| BR (1) | BR7404437D0 (fr) |
| CA (1) | CA1029045A (fr) |
| DD (1) | DD111900A5 (fr) |
| DE (1) | DE2426864A1 (fr) |
| FR (1) | FR2231661B1 (fr) |
| GB (1) | GB1450754A (fr) |
| IT (1) | IT1014770B (fr) |
| LU (1) | LU70207A1 (fr) |
| NL (1) | NL7407081A (fr) |
| SU (1) | SU583747A3 (fr) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2955322B1 (fr) * | 2010-01-21 | 2013-09-06 | Rhodia Operations | Procede de fabrication d'un hydroperoxyde d'alkyle |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2430865A (en) * | 1944-02-17 | 1947-11-18 | Union Oil Co | Naphthene peroxides |
| US3256341A (en) * | 1960-12-02 | 1966-06-14 | Union Carbide Corp | Extraction of 1, 2, 3, 4-tetrahydronaphthalene hydroperoxide |
| FR1347591A (fr) * | 1963-02-19 | 1963-12-27 | British Petroleum Co | Procédé de séparation mutuelle d'hydroperoxydes organiques et d'hydrocarbures éthyléniques à partir de mélagnes qui les contiennent |
| FR1491518A (fr) * | 1966-06-30 | 1967-08-11 | Rhone Poulenc Sa | Préparation d'hydroperoxydes |
-
1973
- 1973-06-04 FR FR7320225A patent/FR2231661B1/fr not_active Expired
-
1974
- 1974-05-27 NL NL7407081A patent/NL7407081A/xx not_active Application Discontinuation
- 1974-05-29 CA CA201,142A patent/CA1029045A/fr not_active Expired
- 1974-05-30 BR BR4437/74A patent/BR7404437D0/pt unknown
- 1974-05-31 JP JP49061758A patent/JPS5019737A/ja active Pending
- 1974-05-31 US US05/475,042 patent/US3956397A/en not_active Expired - Lifetime
- 1974-05-31 DD DD178908A patent/DD111900A5/xx unknown
- 1974-05-31 LU LU70207A patent/LU70207A1/xx unknown
- 1974-06-03 SU SU7402030716A patent/SU583747A3/ru active
- 1974-06-03 GB GB2447874A patent/GB1450754A/en not_active Expired
- 1974-06-04 IT IT23602/74A patent/IT1014770B/it active
- 1974-06-04 AT AT458374A patent/AT331208B/de not_active IP Right Cessation
- 1974-06-04 BE BE145065A patent/BE815901A/fr unknown
- 1974-06-04 DE DE19742426864 patent/DE2426864A1/de not_active Withdrawn
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5019737A (fr) | 1975-03-01 |
| DD111900A5 (fr) | 1975-03-12 |
| GB1450754A (en) | 1976-09-29 |
| FR2231661A1 (fr) | 1974-12-27 |
| IT1014770B (it) | 1977-04-30 |
| BE815901A (fr) | 1974-12-04 |
| BR7404437D0 (pt) | 1975-09-02 |
| FR2231661B1 (fr) | 1976-05-07 |
| LU70207A1 (fr) | 1975-02-24 |
| SU583747A3 (ru) | 1977-12-05 |
| NL7407081A (fr) | 1974-12-06 |
| ATA458374A (de) | 1975-11-15 |
| US3956397A (en) | 1976-05-11 |
| DE2426864A1 (de) | 1975-01-02 |
| AT331208B (de) | 1976-08-10 |
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