CA1029048A - Procede d'alcoylation de l'isoparaffine avec regeneration periodique du catalyseur - Google Patents

Procede d'alcoylation de l'isoparaffine avec regeneration periodique du catalyseur

Info

Publication number
CA1029048A
CA1029048A CA207,763A CA207763A CA1029048A CA 1029048 A CA1029048 A CA 1029048A CA 207763 A CA207763 A CA 207763A CA 1029048 A CA1029048 A CA 1029048A
Authority
CA
Canada
Prior art keywords
catalyst regeneration
alkylation process
isoparaffin alkylation
periodic catalyst
periodic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA207,763A
Other languages
English (en)
Inventor
Chang-Lee Yang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Application granted granted Critical
Publication of CA1029048A publication Critical patent/CA1029048A/fr
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/90—Regeneration or reactivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/12—Noble metals
    • B01J29/126—Y-type faujasite
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/04—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/10—Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using elemental hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/755—Nickel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • C07C2529/068—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/064—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • C07C2529/072—Iron group metals or copper
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00—Chemistry of hydrocarbon compounds
    • Y10S585/8995—Catalyst and recycle considerations
    • Y10S585/906—Catalyst preservation or manufacture, e.g. activation before use

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
CA207,763A 1973-09-27 1974-08-26 Procede d'alcoylation de l'isoparaffine avec regeneration periodique du catalyseur Expired CA1029048A (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US401396A US3893942A (en) 1973-09-27 1973-09-27 Isoparaffin alkylation process with periodic catalyst regeneration

Publications (1)

Publication Number Publication Date
CA1029048A true CA1029048A (fr) 1978-04-04

Family

ID=23587589

Family Applications (1)

Application Number Title Priority Date Filing Date
CA207,763A Expired CA1029048A (fr) 1973-09-27 1974-08-26 Procede d'alcoylation de l'isoparaffine avec regeneration periodique du catalyseur

Country Status (8)

Country Link
US (1) US3893942A (fr)
JP (1) JPS5059303A (fr)
BE (1) BE820398A (fr)
CA (1) CA1029048A (fr)
FR (1) FR2245587B1 (fr)
GB (1) GB1482694A (fr)
IT (1) IT1020880B (fr)
NL (1) NL7412732A (fr)

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US4331557A (en) * 1980-05-22 1982-05-25 Phillips Petroleum Company Regeneration of ruthenium-containing catalyst
GB8303051D0 (en) * 1983-02-04 1983-03-09 Ici Plc Inhibition and regeneration of deactivated catalysts
ES8606023A1 (es) * 1983-11-10 1986-04-16 Exxon Research Engineering Co Un procedimiento para reactivar un catalizador de zeolita tipo l que contiene coque
IT1224640B (it) * 1987-11-20 1990-10-18 Vittorio Ragaini Procedimento per la realizzazione di reazioni chimiche in sistemi polifasici e relativa apparecchiatura.
US4956518A (en) * 1988-07-15 1990-09-11 Mobil Oil Corp. Heterogeneous isoparaffin/olefin alkylation
US4918255A (en) * 1988-07-15 1990-04-17 Mobil Oil Corp. Heterogeneous isoparaffin/olefin alkylation with isomerization
US5012033A (en) * 1988-10-06 1991-04-30 Mobil Oil Corp. Isoparaffin-olefin alkylation process and catalyst composition thereof
US4992615A (en) * 1990-01-25 1991-02-12 Mobil Oil Corp. Isoparaffin-olefin alkylation process
US5073665A (en) * 1990-07-31 1991-12-17 Mobil Oil Corp. Process for alkylating olefins and isoparaffins in a fixed bed reactor
US5120897A (en) * 1990-08-20 1992-06-09 Mobil Oil Corporation Isoparaffin/olefin alkylation
US5365010A (en) * 1990-09-26 1994-11-15 Catalytica, Inc. Method for regenerating Lewis acid-promoted transition alumina catalysts used for isoparaffin alkylation by calcination
US5326923A (en) * 1990-09-26 1994-07-05 Catalytica, Inc. Method for regenerating certain acidic hydrocarbon conversion catalysts by solvent extraction
US5157197A (en) * 1990-09-26 1992-10-20 Catalytica, Inc. Isoparaffin alkylation using a lewis acid promoted transition alumina catalyst
US5157196A (en) * 1990-12-24 1992-10-20 Chemical Research & Licensing Company Paraffin alkylation process
US5190904A (en) * 1990-12-24 1993-03-02 Chemical Research & Licensing Company Paraffin alkylation catalyst
US5095167A (en) * 1991-02-04 1992-03-10 Mobil Oil Corporation Isoparaffin:olefin alkylation process
US5254792A (en) * 1991-10-10 1993-10-19 Mobil Oil Corporation Isoparaffin:olefin alkylation in the presence of synthetic porous MCM-49
US5332705A (en) * 1992-06-19 1994-07-26 Exxon Chemical Patents Inc. Regeneration of acetylene converter catalysts by hydrogen stripping
US5304698A (en) * 1992-08-10 1994-04-19 Mobil Oil Corporation Solid catalyzed supercritical isoparaffin-olefin alkylation process
US5310713A (en) * 1993-04-05 1994-05-10 Uop Regeneration of an alkylation catalyst with hydrogen
US5391527A (en) * 1993-04-05 1995-02-21 Uop Regeneration of a modified alkylation catalyst with hydrogen
US5347064A (en) * 1993-04-12 1994-09-13 Mobil Oil Corporation Multiple split feed isoparaffin-olefin alkylation
AU6700794A (en) * 1993-04-22 1994-11-08 Mobil Oil Corporation Isoparaffin/olefin alkylation
US5396016A (en) * 1993-08-19 1995-03-07 Mobil Oil Corp. MCM-36 as a catalyst for upgrading paraffins
US5625113A (en) * 1993-10-28 1997-04-29 Mobil Oil Corporation Isoparaffin/olefin alkylation
US5491277A (en) * 1993-12-28 1996-02-13 Uop Mixed-phase solid bed hydrocarbon alkylation process
ES2119082T3 (es) * 1994-04-28 1998-10-01 Uop Inc Regeneracion periodica con hidrogeno de un catalizador de alquilacion solido desactivado.
CN1068245C (zh) * 1994-05-07 2001-07-11 环球油品公司 用氢气周期性再生失活的固体烷基化催化剂
JP2625380B2 (ja) * 1994-05-09 1997-07-02 ユーオーピー 水素による不活性化固体アルキル化触媒の定期的再生法
US5849976A (en) * 1994-07-27 1998-12-15 Uop Llc Moving bed solid catalyst hydrocarbon alkylation process
JPH10504343A (ja) * 1994-08-15 1998-04-28 インスティテュト カタリザ イメニ ゲー．カー．ボレスコバ シビルスコゴ オトデレニア ロシイスコイ アカデミイ ナウク 高オクタン価ガソリン成分の製造方法および触媒
US5489732A (en) * 1994-10-14 1996-02-06 Uop Fluidized solid bed motor fuel alkylation process
US5824835A (en) * 1995-02-03 1998-10-20 Mobil Oil Corporation Isoparaffin-olefin alkylation process
US5705729A (en) * 1995-11-22 1998-01-06 Mobil Oil Corporation Isoparaffin-olefin alkylation process
DE10124998A1 (de) * 2001-05-22 2003-01-02 Sued Chemie Ag Katalysator für säurekatalysierte Kohlenwasserstoff-Umwandlungen
US20040158113A1 (en) * 2003-02-06 2004-08-12 Girish Srinivas Catalysts and process for converting fuel gases to gasoline
US8603407B2 (en) * 2007-03-21 2013-12-10 Precision Combustion, Inc. Catalytic isobutane alkylation
PL2625251T3 (pl) * 2010-10-06 2021-05-04 Exelus Inc. Wytwarzanie alkilatu wysokooktanowego z etylenu i izobutanu
CA2954346C (fr) * 2014-07-07 2020-06-30 Albemarle Europe Sprl Procede d'alkylation a l'aide d'un catalyseur comprenant des zeolithes contenant des terres rares riches en cerium et un metal d'hydrogenation
US10076739B1 (en) 2014-07-22 2018-09-18 Precision Combustion, Inc. Chemical reactor for use with overly reactive chemicals
JP2016040218A (ja) * 2014-08-13 2016-03-24 Ｊｘ日鉱日石エネルギー株式会社 脱水素化システム、及び脱水素化システムの運転方法
US10253270B2 (en) * 2014-11-04 2019-04-09 Chevron U.S.A. Inc. Alkylation reaction using delaminated zeolite supports as catalysts
WO2016210006A2 (fr) 2015-06-22 2016-12-29 Exelus, Inc. Alkylation catalysée améliorée, catalyseurs d'alkylation et procédés de fabrication de catalyseurs d'alkylation
US20180065900A1 (en) * 2016-09-08 2018-03-08 Alvega Technologies, Inc. Process of Alkylation of Isobutane with Olefins
US10464864B2 (en) 2016-12-20 2019-11-05 Exxonmobil Research And Engineering Company Upgrading ethane-containing light paraffins streams
EP3559169A1 (fr) * 2016-12-20 2019-10-30 ExxonMobil Research and Engineering Company Valorisation de flux de paraffines légères contenant de l'éthane
US11851386B2 (en) 2021-10-15 2023-12-26 Exelus, Inc. Solid-acid catalyzed paraffin alkylation with rare earth-modified molecular sieve adsorbents

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US3197399A (en) * 1962-10-15 1965-07-27 Union Oil Company Of Californa Hydrocracking catalyst activation
US3236792A (en) * 1963-12-12 1966-02-22 Miles Lab Water-dispersible form of dialdehyde polysaccharides and process therefor
US3357915A (en) * 1966-03-28 1967-12-12 Union Oil Co Regeneration of hydrocracking catalysts
US3644565A (en) * 1968-09-18 1972-02-22 Union Oil Co Alkylation process

Also Published As

Publication number Publication date
DE2445881A1 (de) 1975-04-24
BE820398A (fr) 1975-03-26
GB1482694A (en) 1977-08-10
US3893942A (en) 1975-07-08
JPS5059303A (fr) 1975-05-22
FR2245587A1 (fr) 1975-04-25
IT1020880B (it) 1977-12-30
NL7412732A (nl) 1975-04-02
DE2445881B2 (de) 1976-05-26
FR2245587B1 (fr) 1978-05-12

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