CA1034964A - Reactions d'aromatisation - Google Patents

Reactions d'aromatisation

Info

Publication number
CA1034964A
CA1034964A CA205,744A CA205744A CA1034964A CA 1034964 A CA1034964 A CA 1034964A CA 205744 A CA205744 A CA 205744A CA 1034964 A CA1034964 A CA 1034964A
Authority
CA
Canada
Prior art keywords
aromatization reactions
aromatization
reactions
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA205,744A
Other languages
English (en)
Other versions
CA205744S (en
Inventor
Clarence D. Chang
Anthony J. Silvestri
Robert L. Smith
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mobil Oil AS
Original Assignee
Mobil Oil AS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil AS filed Critical Mobil Oil AS
Application granted granted Critical
Publication of CA1034964A publication Critical patent/CA1034964A/fr
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
    • C10G3/49—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing iron group metals, noble metals or copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing iron group metals, noble metals or copper
    • C07C2529/44—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing iron group metals, noble metals or copper
    • C07C2529/46—Iron group metals or copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4006—Temperature
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/30—Aromatics
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
CA205,744A 1973-08-09 1974-07-26 Reactions d'aromatisation Expired CA1034964A (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US387218A US3894103A (en) 1973-08-09 1973-08-09 Aromatization reactions

Publications (1)

Publication Number Publication Date
CA1034964A true CA1034964A (fr) 1978-07-18

Family

ID=23528979

Family Applications (1)

Application Number Title Priority Date Filing Date
CA205,744A Expired CA1034964A (fr) 1973-08-09 1974-07-26 Reactions d'aromatisation

Country Status (3)

Country Link
US (1) US3894103A (fr)
CA (1) CA1034964A (fr)
ZA (1) ZA745127B (fr)

Families Citing this family (57)

* Cited by examiner, † Cited by third party
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US4011278A (en) * 1963-02-27 1977-03-08 Mobil Oil Corporation Conversion of polar compounds using a zsm-5 zeolite catalyst
US4013732A (en) * 1975-10-17 1977-03-22 Mobil Oil Corporation Conversion of methanol to gasoline with minimum durene production
US4052472A (en) * 1976-01-16 1977-10-04 Mobil Oil Corporation Mordenite conversion of alkanols to penta- and hexamethyl benzenes
US4025571A (en) * 1976-05-12 1977-05-24 Mobil Oil Corporation Manufacture of hydrocarbons
US4025572A (en) * 1976-05-12 1977-05-24 Mobil Oil Corporation Manufacture of hydrocarbons
US4518703A (en) * 1979-02-16 1985-05-21 Union Oil Company Of California Crystalline silica catalysts
NL190156C (nl) * 1979-03-14 1993-11-16 Shell Int Research Werkwijze voor de bereiding van een aromatisch koolwaterstofmengsel.
US4424401A (en) 1980-08-12 1984-01-03 The Broken Hill Proprietary Company Limited Aromatization of acetylene
US4347395A (en) * 1981-04-13 1982-08-31 Mobil Oil Corporation Conversion of paraffinic hydrocarbons to aromatics over zeolite catalysts
US4769504A (en) * 1987-03-04 1988-09-06 The United States Of America As Represented By The United States Department Of Energy Process for converting light alkanes to higher hydrocarbons
US4864073A (en) * 1988-05-03 1989-09-05 Mobil Oil Corporation Processes for converting methane to higher molecular weight hydrocarbons via sulfur-containing intermediates
US4864074A (en) * 1988-05-03 1989-09-05 Mobil Oil Corporation Process for converting methane to higher molecular weight hydrocarbons via sulfur-containing intermediates
US4992611A (en) * 1989-12-13 1991-02-12 Mobil Oil Corp. Direct conversion of C1 -C4 oxygenates to low aromatic distillate range hydrocarbons
US5164076A (en) * 1991-01-22 1992-11-17 Uop Process for the adsorption of hydrogen sulfide with clinoptilolite molecular sieves
US7838708B2 (en) 2001-06-20 2010-11-23 Grt, Inc. Hydrocarbon conversion process improvements
JP2007525477A (ja) 2003-07-15 2007-09-06 ジーアールティー インコーポレイテッド 炭化水素の合成
US20050171393A1 (en) 2003-07-15 2005-08-04 Lorkovic Ivan M. Hydrocarbon synthesis
US8173851B2 (en) 2004-04-16 2012-05-08 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US7674941B2 (en) 2004-04-16 2010-03-09 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons
US7244867B2 (en) 2004-04-16 2007-07-17 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US20080275284A1 (en) 2004-04-16 2008-11-06 Marathon Oil Company Process for converting gaseous alkanes to liquid hydrocarbons
US8642822B2 (en) 2004-04-16 2014-02-04 Marathon Gtf Technology, Ltd. Processes for converting gaseous alkanes to liquid hydrocarbons using microchannel reactor
US20060100469A1 (en) * 2004-04-16 2006-05-11 Waycuilis John J Process for converting gaseous alkanes to olefins and liquid hydrocarbons
SG187456A1 (en) 2006-02-03 2013-02-28 Grt Inc Separation of light gases from halogens
AP2673A (en) 2006-02-03 2013-05-23 Grt Inc Continuous process for converting natural gas to liquid hydrocarbons
MX2009012581A (es) 2007-05-24 2010-03-15 Grt Inc Reactor de zonas que incorpora captura y liberacion de haluro de hidrogeno reversible.
WO2009021727A1 (fr) * 2007-08-13 2009-02-19 Saudi Basic Industries Corporation Composition de catalyseur et procédé pour convertir des composés oxygénés aliphatiques en produits aromatiques
US20090312586A1 (en) * 2008-06-13 2009-12-17 Marathon Gtf Technology, Ltd. Hydrogenation of multi-brominated alkanes
US8282810B2 (en) 2008-06-13 2012-10-09 Marathon Gtf Technology, Ltd. Bromine-based method and system for converting gaseous alkanes to liquid hydrocarbons using electrolysis for bromine recovery
US8273929B2 (en) 2008-07-18 2012-09-25 Grt, Inc. Continuous process for converting natural gas to liquid hydrocarbons
IT1393109B1 (it) 2009-02-26 2012-04-11 Eni Spa Procedimento per la conversione diretta di composti ossigenati a idrocarburi liquidi a ridotto tenore di aromatici
US20110015458A1 (en) * 2009-07-15 2011-01-20 Marathon Gtf Technology, Ltd. Conversion of hydrogen bromide to elemental bromine
US8367884B2 (en) 2010-03-02 2013-02-05 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8198495B2 (en) * 2010-03-02 2012-06-12 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
IT1400226B1 (it) 2010-04-15 2013-05-24 Eni Spa Procedimento per la produzione di idrocarburi liquidi a basso contenuto di composti aromatici
US8815050B2 (en) 2011-03-22 2014-08-26 Marathon Gtf Technology, Ltd. Processes and systems for drying liquid bromine
US8436220B2 (en) 2011-06-10 2013-05-07 Marathon Gtf Technology, Ltd. Processes and systems for demethanization of brominated hydrocarbons
US8829256B2 (en) 2011-06-30 2014-09-09 Gtc Technology Us, Llc Processes and systems for fractionation of brominated hydrocarbons in the conversion of natural gas to liquid hydrocarbons
JP5798821B2 (ja) 2011-07-15 2015-10-21 三菱重工業株式会社 メタノールからガソリンを製造するともに発電する方法およびシステム
JP5812781B2 (ja) 2011-09-21 2015-11-17 三菱重工業株式会社 メタノールからガソリンと水素を製造する方法および装置
US8802908B2 (en) 2011-10-21 2014-08-12 Marathon Gtf Technology, Ltd. Processes and systems for separate, parallel methane and higher alkanes' bromination
US8962902B2 (en) 2011-11-23 2015-02-24 Virent, Inc. Dehydrogenation of alkanols to increase yield of aromatics
US8969640B2 (en) 2011-11-23 2015-03-03 Virent, Inc. Dehydrogenation of alkanols to increase yield of aromatics
US9193641B2 (en) 2011-12-16 2015-11-24 Gtc Technology Us, Llc Processes and systems for conversion of alkyl bromides to higher molecular weight hydrocarbons in circulating catalyst reactor-regenerator systems
US9873644B2 (en) 2013-05-22 2018-01-23 Virent, Inc. Hydrogenation of carboxylic acids to increase yield of aromatics
US9873836B2 (en) 2013-05-22 2018-01-23 Virent, Inc. Process for converting biomass to aromatic hydrocarbons
CA2925992C (fr) 2013-12-20 2020-08-11 Exxonmobil Research And Engineering Company Catalyseur de conversion selective d'oxygenats en aromatiques
WO2015094696A1 (fr) 2013-12-20 2015-06-25 Exxonmobil Chemical Patents Inc. Procédé pour convertir des composés oxygénés en hydrocarbures aromatiques
US9783463B2 (en) 2014-09-30 2017-10-10 Exxonmobil Chemical Patents Inc. Conversion of acetylene and methanol to aromatics
US9732013B2 (en) 2014-09-30 2017-08-15 Exxonmobil Chemical Patents Inc. Production of aromatics from methanol and co-feeds
US9957203B2 (en) 2014-11-21 2018-05-01 Exxonmobil Chemical Patents Inc. Production of aromatics from methanol using selective hydrogen combustion
US10196325B2 (en) 2015-01-15 2019-02-05 Exxonmobil Chemical Patents Inc. Process for converting syngas to aromatics and catalyst system suitable therefor
US10059638B2 (en) 2015-03-31 2018-08-28 Exxonmobil Chemical Patents Inc. Oxygenated hydrocarbon conversion zoned method
US10059641B2 (en) 2015-09-25 2018-08-28 Exxonmobil Chemical Patents Inc. Conversion of non-aromatic hydrocarbon
US10647640B2 (en) 2016-01-29 2020-05-12 Exxonmobil Chemical Patents Inc. Process for converting alkanes to para-xylene
WO2018217337A1 (fr) 2017-05-22 2018-11-29 Exxonmobil Chemical Patents Inc. Formation et méthylation de produits aromatiques intégrés
WO2026060277A1 (fr) 2024-09-13 2026-03-19 Virent, Inc. Production de diesel renouvelable à consommation d'hydrogène et libération de glycérol réduites

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US3728408A (en) * 1969-05-05 1973-04-17 Mobil Oil Corp Conversion of polar compounds using highly siliceous zeolite-type catalysts
US3755483A (en) * 1972-04-28 1973-08-28 Mobil Oil Vapor phase alkylation in presence of crystalline aluminosilicate catalyst
US3751506A (en) * 1972-05-12 1973-08-07 Mobil Oil Corp Vapor-phase alkylation in presence of crystalline aluminosilicate catalyst
US3751504A (en) * 1972-05-12 1973-08-07 Mobil Oil Corp Vapor-phase alkylation in presence of crystalline aluminosilicate catalyst with separate transalkylation

Also Published As

Publication number Publication date
US3894103A (en) 1975-07-08
ZA745127B (en) 1976-03-31

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