CA1036436A - Traitement tensioactif de la fibre de verre servant au renforcement des ciments hydrauliques - Google Patents

Traitement tensioactif de la fibre de verre servant au renforcement des ciments hydrauliques

Info

Publication number: CA1036436A
Authority: CA; Canada
Prior art keywords: cement; fibers; glass fibers; solution; deposit
Prior art date: 1972-12-29
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA196,664A

Other languages

English (en)

Other versions

CA196664S (en

Inventor

Motochika Kawai

Izuru Shimozawa

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

JAPAN INORGANIC MATERIAL CO

Original Assignee

JAPAN INORGANIC MATERIAL CO

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1972-12-29

Filing date

1974-04-02

Publication date

1978-08-15

1972-12-29 Priority claimed from JP408873A external-priority patent/JPS4876850A/ja

1973-11-20 Priority claimed from JP48130546A external-priority patent/JPS5755664B2/ja

1973-11-20 Priority claimed from JP13054873A external-priority patent/JPS5722903B2/ja

1973-11-20 Priority claimed from JP48130547A external-priority patent/JPS5755665B2/ja

1973-11-20 Priority claimed from JP48130549A external-priority patent/JPS5755666B2/ja

1973-11-20 Priority claimed from JP13054573A external-priority patent/JPS5722902B2/ja

1973-12-21 Priority claimed from JP48143117A external-priority patent/JPS5815450B2/ja

1973-12-21 Priority claimed from JP48143118A external-priority patent/JPS5815451B2/ja

1973-12-27 Priority claimed from JP741919A external-priority patent/JPS5743538B2/ja

1974-03-18 Priority claimed from JP49030823A external-priority patent/JPS50121599A/ja

1974-04-02 Application filed by JAPAN INORGANIC MATERIAL CO filed Critical JAPAN INORGANIC MATERIAL CO

1978-08-15 Publication of CA1036436A publication Critical patent/CA1036436A/fr

1978-08-15 Application granted granted Critical

Status Expired legal-status Critical Current

Links

239000003365 glass fiber Substances 0.000 title claims abstract description 65
239000011396 hydraulic cement Substances 0.000 title claims abstract description 14
230000003014 reinforcing effect Effects 0.000 title claims description 8
238000004381 surface treatment Methods 0.000 title description 2
239000000243 solution Substances 0.000 claims abstract description 82
238000005260 corrosion Methods 0.000 claims abstract description 66
239000007864 aqueous solution Substances 0.000 claims abstract description 20
NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 12
239000002253 acid Substances 0.000 claims abstract description 11
150000003839 salts Chemical class 0.000 claims abstract description 8
229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 6
239000010936 titanium Substances 0.000 claims abstract description 6
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 5
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract description 4
229910052735 hafnium Inorganic materials 0.000 claims abstract description 3
VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims abstract 2
229910052719 titanium Inorganic materials 0.000 claims abstract 2
229910052726 zirconium Inorganic materials 0.000 claims abstract 2
239000000835 fiber Substances 0.000 claims description 65
239000004568 cement Substances 0.000 claims description 52
MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 48
238000000034 method Methods 0.000 claims description 23
229910000449 hafnium oxide Inorganic materials 0.000 claims description 11
WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 claims description 11
229910001928 zirconium oxide Inorganic materials 0.000 claims description 11
OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 10
RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 9
150000003754 zirconium Chemical class 0.000 claims description 9
-1 alkali metal salts Chemical class 0.000 claims description 8
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 7
150000002362 hafnium Chemical class 0.000 claims description 7
239000011259 mixed solution Substances 0.000 claims description 7
150000003608 titanium Chemical class 0.000 claims description 7
229910052783 alkali metal Inorganic materials 0.000 claims description 5
239000000463 material Substances 0.000 claims description 5
229910044991 metal oxide Inorganic materials 0.000 claims description 4
150000004706 metal oxides Chemical class 0.000 claims description 4
UEZVMMHDMIWARA-UHFFFAOYSA-N Metaphosphoric acid Chemical compound OP(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-N 0.000 claims description 3
XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 claims description 3
229940005657 pyrophosphoric acid Drugs 0.000 claims description 3
150000001875 compounds Chemical class 0.000 claims description 2
230000002401 inhibitory effect Effects 0.000 claims description 2
229910052751 metal Inorganic materials 0.000 claims 2
239000002184 metal Substances 0.000 claims 2
150000002739 metals Chemical class 0.000 claims 2
230000007797 corrosion Effects 0.000 abstract description 59
239000003513 alkali Substances 0.000 abstract description 43
238000000576 coating method Methods 0.000 abstract description 21
239000000203 mixture Substances 0.000 abstract description 14
239000011248 coating agent Substances 0.000 abstract description 8
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract description 5
229910019142 PO4 Inorganic materials 0.000 abstract description 4
239000010452 phosphate Substances 0.000 abstract description 4
230000002787 reinforcement Effects 0.000 abstract description 3
235000021317 phosphate Nutrition 0.000 abstract 1
239000005361 soda-lime glass Substances 0.000 description 15
239000011521 glass Substances 0.000 description 9
239000012266 salt solution Substances 0.000 description 7
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
PDPJQWYGJJBYLF-UHFFFAOYSA-J hafnium tetrachloride Chemical compound Cl[Hf](Cl)(Cl)Cl PDPJQWYGJJBYLF-UHFFFAOYSA-J 0.000 description 5
XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 5
239000011398 Portland cement Substances 0.000 description 4
239000000047 product Substances 0.000 description 4
DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 description 4
KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
229910010066 TiC14 Inorganic materials 0.000 description 3
AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 3
239000004567 concrete Substances 0.000 description 3
230000001965 increasing effect Effects 0.000 description 3
239000004570 mortar (masonry) Substances 0.000 description 3
238000009864 tensile test Methods 0.000 description 3
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
208000012886 Vertigo Diseases 0.000 description 2
239000000920 calcium hydroxide Substances 0.000 description 2
229910001861 calcium hydroxide Inorganic materials 0.000 description 2
238000004519 manufacturing process Methods 0.000 description 2
UJVRJBAUJYZFIX-UHFFFAOYSA-N nitric acid;oxozirconium Chemical compound [Zr]=O.O[N+]([O-])=O.O[N+]([O-])=O UJVRJBAUJYZFIX-UHFFFAOYSA-N 0.000 description 2
239000011505 plaster Substances 0.000 description 2
238000009987 spinning Methods 0.000 description 2
239000000126 substance Substances 0.000 description 2
LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 2
OERNJTNJEZOPIA-UHFFFAOYSA-N zirconium nitrate Chemical compound [Zr+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O OERNJTNJEZOPIA-UHFFFAOYSA-N 0.000 description 2
ZXAUZSQITFJWPS-UHFFFAOYSA-J zirconium(4+);disulfate Chemical compound [Zr+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZXAUZSQITFJWPS-UHFFFAOYSA-J 0.000 description 2
ABAFKQHGFDZEJO-UHFFFAOYSA-N 4,6,6-trimethylbicyclo[3.1.1]heptane-4-carbaldehyde Chemical compound C1C2C(C)(C)C1CCC2(C)C=O ABAFKQHGFDZEJO-UHFFFAOYSA-N 0.000 description 1
235000008733 Citrus aurantifolia Nutrition 0.000 description 1
229910003865 HfCl4 Inorganic materials 0.000 description 1
241000186704 Pinales Species 0.000 description 1
235000011941 Tilia x europaea Nutrition 0.000 description 1
LCKIEQZJEYYRIY-UHFFFAOYSA-N Titanium ion Chemical compound [Ti+4] LCKIEQZJEYYRIY-UHFFFAOYSA-N 0.000 description 1
229910008159 Zr(SO4)2 Inorganic materials 0.000 description 1
229910008334 ZrO(NO3)2 Inorganic materials 0.000 description 1
230000001464 adherent effect Effects 0.000 description 1
238000009835 boiling Methods 0.000 description 1
238000005520 cutting process Methods 0.000 description 1
230000007423 decrease Effects 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
230000000694 effects Effects 0.000 description 1
230000002708 enhancing effect Effects 0.000 description 1
239000012530 fluid Substances 0.000 description 1
NXKAMHRHVYEHER-UHFFFAOYSA-J hafnium(4+);disulfate Chemical compound [Hf+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O NXKAMHRHVYEHER-UHFFFAOYSA-J 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
230000003301 hydrolyzing effect Effects 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
239000004571 lime Substances 0.000 description 1
VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
239000000347 magnesium hydroxide Substances 0.000 description 1
229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
239000011159 matrix material Substances 0.000 description 1
239000000155 melt Substances 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
229910000160 potassium phosphate Inorganic materials 0.000 description 1
235000011009 potassium phosphates Nutrition 0.000 description 1
235000019353 potassium silicate Nutrition 0.000 description 1
239000001488 sodium phosphate Substances 0.000 description 1
229910000162 sodium phosphate Inorganic materials 0.000 description 1
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
239000006228 supernatant Substances 0.000 description 1
239000000725 suspension Substances 0.000 description 1
RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
GBNDTYKAOXLLID-UHFFFAOYSA-N zirconium(4+) ion Chemical compound [Zr+4] GBNDTYKAOXLLID-UHFFFAOYSA-N 0.000 description 1

Landscapes

Surface Treatment Of Glass Fibres Or Filaments (AREA)

CA196,664A 1972-12-29 1974-04-02 Traitement tensioactif de la fibre de verre servant au renforcement des ciments hydrauliques Expired CA1036436A (fr)

Applications Claiming Priority (10)

Application Number	Priority Date	Filing Date	Title
JP408873A JPS4876850A (fr)	1972-01-03	1972-12-29
JP13054873A JPS5722903B2 (fr)	1973-11-20	1973-11-20
JP48130547A JPS5755665B2 (fr)	1973-11-20	1973-11-20
JP48130546A JPS5755664B2 (fr)	1973-11-20	1973-11-20
JP48130549A JPS5755666B2 (fr)	1973-11-20	1973-11-20
JP13054573A JPS5722902B2 (fr)	1973-11-20	1973-11-20
JP48143117A JPS5815450B2 (ja)	1973-12-21	1973-12-21	ジルコニア成分の少ないガラス繊維の耐セメントアルカリ性増強方法
JP48143118A JPS5815451B2 (ja)	1973-12-21	1973-12-21	ソ−ダセツカイガラスケイノガラスセンイオタイセメントアルカリセイニスルホウホウ
JP741919A JPS5743538B2 (fr)	1973-12-27	1973-12-27
JP49030823A JPS50121599A (fr)	1974-03-18	1974-03-18

Publications (1)

Publication Number	Publication Date
CA1036436A true CA1036436A (fr)	1978-08-15

Family

ID=27579469

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA196,664A Expired CA1036436A (fr)	1972-12-29	1974-04-02	Traitement tensioactif de la fibre de verre servant au renforcement des ciments hydrauliques

Country Status (1)

Country	Link
CA (1)	CA1036436A (fr)

1974
- 1974-04-02 CA CA196,664A patent/CA1036436A/fr not_active Expired

Publication	Publication Date	Title
US3854986A (en)	1974-12-17	Method of making mineral fibers of high corrosion resistance and fibers produced
US3736162A (en)	1973-05-29	Cements containing mineral fibers of high corrosion resistance
EP0866777B1 (fr)	2000-08-09	Fibres vitreuses synthetiques et leur production et utilisation
US4046948A (en)	1977-09-06	Acid resistant glass fibers
US4933307A (en)	1990-06-12	Silica-rich porous substrates with reduced tendencies for breaking or cracking
EP0011249B1 (fr)	1982-06-30	Fabrication et composition de fibres minérales pour la microarmature de liants ou de matériaux de construction
US5714244A (en)	1998-02-03	Method for protecting a porous carbon-containing material from oxidation, and material obtained thereby
US4063001A (en)	1977-12-13	Method of preparing acid resistant glass fibers
AU594685B2 (en)	1990-03-15	Method of forming phosphate coatings on zinc
EP1963420A2 (fr)	2008-09-03	Colle pour fibres, renforcements collés et articles renforcés avec des renforcements collés
US3232782A (en)	1966-02-01	High temperature resistant vitreous material and method of producing same
US4078939A (en)	1978-03-14	Reinforcing glass fibers of ZnO-MgO-Al2 O3 -SiO2 -TiO2
Friedrich et al.	2000	Investigation of chemically treated basalt and glass fibres
CA1036436A (fr)	1978-08-15	Traitement tensioactif de la fibre de verre servant au renforcement des ciments hydrauliques
DE2657334A1 (de)	1977-06-30	Verfahren zur behandlung von verstaerkungsmaterialien zur verbesserung der haftung zwischen ihnen und kunststoffgrundmaterialien sowie nach ihm behandelte verstaerkungsmaterialien
Gutnikov et al.	2019	Correlation of the chemical composition, structure and mechanical properties of basalt continuous fibers
US3493461A (en)	1970-02-03	Glass fiber reinforced polyvinyl chloride resin article and process therefor
GB2042573A (en)	1980-09-24	Titanium dioxide pigment
US4188454A (en)	1980-02-12	Organo silane coupling agents overcoated on aluminum silicate coating on glass fibers
US4188421A (en)	1980-02-12	Process for treating the surface of glass fibre to impart resistance to alkalis
US3503772A (en)	1970-03-31	Sio2-zno treated tio2 pigments for paper laminates
US3861925A (en)	1975-01-21	Alkali-resistant, zirconia-free, fiberizable glass compositions
CA1157325A (fr)	1983-11-22	Methode d'amelioration des proprietes de fibres de ceramique
US3725117A (en)	1973-04-03	Chromium oxide coating for siliceous articles
Cheng et al.	2003	Development of a new alkali resistant coating