CA1037198A - Polymerisation massive de polymeres et de copolymeres d'halogenure de vinyle qui incorporent des stabilisants a cette fin - Google Patents

Polymerisation massive de polymeres et de copolymeres d'halogenure de vinyle qui incorporent des stabilisants a cette fin

Info

Publication number: CA1037198A
Authority: CA; Canada
Prior art keywords: monomers; monomer; stage; vinyl; polymer
Prior art date: 1973-12-26
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA215,170A

Other languages

English (en)

Other versions

CA215170S (en

Inventor

Gilbert Witschard

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Occidental Chemical Corp

Original Assignee

Hooker Chemicals and Plastics Corp

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1973-12-26

Filing date

1974-12-03

Publication date

1978-08-22

1974-12-03 Application filed by Hooker Chemicals and Plastics Corp filed Critical Hooker Chemicals and Plastics Corp

1978-08-22 Application granted granted Critical

1978-08-22 Publication of CA1037198A publication Critical patent/CA1037198A/fr

Status Expired legal-status Critical Current

Links

-1 vinyl halide Chemical class 0.000 title claims abstract description 51
229920000642 polymer Polymers 0.000 title claims abstract description 40
239000003381 stabilizer Substances 0.000 title claims abstract description 36
229920002554 vinyl polymer Polymers 0.000 title claims abstract description 31
229920001577 copolymer Polymers 0.000 title claims abstract description 26
238000012662 bulk polymerization Methods 0.000 title claims description 21
238000000034 method Methods 0.000 claims abstract description 50
238000006116 polymerization reaction Methods 0.000 claims abstract description 25
229920000578 graft copolymer Polymers 0.000 claims abstract description 10
239000000178 monomer Substances 0.000 claims description 70
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims description 21
150000003839 salts Chemical class 0.000 claims description 18
239000000203 mixture Substances 0.000 claims description 16
229920000915 polyvinyl chloride Polymers 0.000 claims description 13
239000004800 polyvinyl chloride Substances 0.000 claims description 13
229920001519 homopolymer Polymers 0.000 claims description 10
229910052751 metal Inorganic materials 0.000 claims description 10
239000002184 metal Substances 0.000 claims description 10
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 9
229910052791 calcium Inorganic materials 0.000 claims description 9
239000011575 calcium Substances 0.000 claims description 9
XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 8
238000013019 agitation Methods 0.000 claims description 7
235000014113 dietary fatty acids Nutrition 0.000 claims description 7
229930195729 fatty acid Natural products 0.000 claims description 7
239000000194 fatty acid Substances 0.000 claims description 7
150000004665 fatty acids Chemical class 0.000 claims description 7
CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 6
239000008116 calcium stearate Substances 0.000 claims description 6
235000013539 calcium stearate Nutrition 0.000 claims description 6
239000004593 Epoxy Substances 0.000 claims description 5
229910052788 barium Inorganic materials 0.000 claims description 5
DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 5
229910052793 cadmium Inorganic materials 0.000 claims description 5
BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 5
125000004432 carbon atom Chemical group C* 0.000 claims description 5
238000006243 chemical reaction Methods 0.000 claims description 5
150000001875 compounds Chemical class 0.000 claims description 5
230000000379 polymerizing effect Effects 0.000 claims description 5
238000002360 preparation method Methods 0.000 claims description 5
229910052718 tin Inorganic materials 0.000 claims description 5
FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 4
HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
150000001735 carboxylic acids Chemical class 0.000 claims description 4
229910052749 magnesium Inorganic materials 0.000 claims description 4
239000011777 magnesium Substances 0.000 claims description 4
229920001291 polyvinyl halide Polymers 0.000 claims description 4
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239000011701 zinc Substances 0.000 claims description 4
ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 3
WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 3
229910052712 strontium Inorganic materials 0.000 claims description 3
CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 3
239000000944 linseed oil Substances 0.000 claims description 2
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239000011541 reaction mixture Substances 0.000 claims 8
QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims 1
238000002845 discoloration Methods 0.000 abstract description 6
239000004611 light stabiliser Substances 0.000 abstract description 4
239000012760 heat stabilizer Substances 0.000 abstract description 3
229920005989 resin Polymers 0.000 description 13
239000011347 resin Substances 0.000 description 13
AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 11
239000000463 material Substances 0.000 description 10
150000002148 esters Chemical class 0.000 description 7
OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 6
239000003054 catalyst Substances 0.000 description 6
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 6
OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 6
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239000002253 acid Substances 0.000 description 5
239000006185 dispersion Substances 0.000 description 5
239000003999 initiator Substances 0.000 description 5
238000002156 mixing Methods 0.000 description 5
QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 5
230000006641 stabilisation Effects 0.000 description 5
238000011105 stabilization Methods 0.000 description 5
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 5
OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 4
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SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 3
150000007513 acids Chemical class 0.000 description 3
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
239000003921 oil Substances 0.000 description 3
235000019198 oils Nutrition 0.000 description 3
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
DNJRKFKAFWSXSE-UHFFFAOYSA-N 1-chloro-2-ethenoxyethane Chemical compound ClCCOC=C DNJRKFKAFWSXSE-UHFFFAOYSA-N 0.000 description 2
OZCMOJQQLBXBKI-UHFFFAOYSA-N 1-ethenoxy-2-methylpropane Chemical compound CC(C)COC=C OZCMOJQQLBXBKI-UHFFFAOYSA-N 0.000 description 2
UZKWTJUDCOPSNM-UHFFFAOYSA-N 1-ethenoxybutane Chemical compound CCCCOC=C UZKWTJUDCOPSNM-UHFFFAOYSA-N 0.000 description 2
OVGRCEFMXPHEBL-UHFFFAOYSA-N 1-ethenoxypropane Chemical compound CCCOC=C OVGRCEFMXPHEBL-UHFFFAOYSA-N 0.000 description 2
DSSAWHFZNWVJEC-UHFFFAOYSA-N 3-(ethenoxymethyl)heptane Chemical compound CCCCC(CC)COC=C DSSAWHFZNWVJEC-UHFFFAOYSA-N 0.000 description 2
WVLIQUPRRVSTGK-UHFFFAOYSA-N 6-(1,3-dioxopropan-2-yl)pyridine-2-carboxylic acid Chemical compound OC(=O)C1=CC=CC(C(C=O)C=O)=N1 WVLIQUPRRVSTGK-UHFFFAOYSA-N 0.000 description 2
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
102100024133 Coiled-coil domain-containing protein 50 Human genes 0.000 description 2
NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 2
229920000181 Ethylene propylene rubber Polymers 0.000 description 2
101000910772 Homo sapiens Coiled-coil domain-containing protein 50 Proteins 0.000 description 2
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
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SJNALLRHIVGIBI-UHFFFAOYSA-N allyl cyanide Chemical compound C=CCC#N SJNALLRHIVGIBI-UHFFFAOYSA-N 0.000 description 2
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GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
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KETWBQOXTBGBBN-UHFFFAOYSA-N hex-1-enylbenzene Chemical compound CCCCC=CC1=CC=CC=C1 KETWBQOXTBGBBN-UHFFFAOYSA-N 0.000 description 2
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RZBBHEJLECUBJT-UHFFFAOYSA-N 6-methylheptyl 2-sulfanylacetate Chemical compound CC(C)CCCCCOC(=O)CS RZBBHEJLECUBJT-UHFFFAOYSA-N 0.000 description 1
QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
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NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
239000004342 Benzoyl peroxide Substances 0.000 description 1
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239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
WBYWAXJHAXSJNI-SREVYHEPSA-N Cinnamic acid Chemical compound OC(=O)\C=C/C1=CC=CC=C1 WBYWAXJHAXSJNI-SREVYHEPSA-N 0.000 description 1
IEPRKVQEAMIZSS-UHFFFAOYSA-N Di-Et ester-Fumaric acid Natural products CCOC(=O)C=CC(=O)OCC IEPRKVQEAMIZSS-UHFFFAOYSA-N 0.000 description 1
IEPRKVQEAMIZSS-WAYWQWQTSA-N Diethyl maleate Chemical compound CCOC(=O)\C=C/C(=O)OCC IEPRKVQEAMIZSS-WAYWQWQTSA-N 0.000 description 1
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VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical class OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 1
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239000004609 Impact Modifier Substances 0.000 description 1
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CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
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239000006057 Non-nutritive feed additive Substances 0.000 description 1
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150000001408 amides Chemical class 0.000 description 1
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150000008064 anhydrides Chemical class 0.000 description 1
AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 description 1
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235000019400 benzoyl peroxide Nutrition 0.000 description 1
150000001642 boronic acid derivatives Chemical class 0.000 description 1
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CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
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KZJNRSVWTFBHGW-UHFFFAOYSA-J calcium dichlorozinc dichloride Chemical compound Cl[Ca]Cl.Cl[Zn]Cl KZJNRSVWTFBHGW-UHFFFAOYSA-J 0.000 description 1
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239000002738 chelating agent Substances 0.000 description 1
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MEGHWIAOTJPCHQ-UHFFFAOYSA-N ethenyl butanoate Chemical compound CCCC(=O)OC=C MEGHWIAOTJPCHQ-UHFFFAOYSA-N 0.000 description 1
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239000005038 ethylene vinyl acetate Substances 0.000 description 1
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230000004927 fusion Effects 0.000 description 1
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239000000314 lubricant Substances 0.000 description 1
235000019359 magnesium stearate Nutrition 0.000 description 1
VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
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ZTZJVAOTIOAZGZ-UHFFFAOYSA-N methyl 2-fluoroacrylate Chemical compound COC(=O)C(F)=C ZTZJVAOTIOAZGZ-UHFFFAOYSA-N 0.000 description 1
NKHAVTQWNUWKEO-IHWYPQMZSA-N methyl hydrogen fumarate Chemical compound COC(=O)\C=C/C(O)=O NKHAVTQWNUWKEO-IHWYPQMZSA-N 0.000 description 1
WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
239000011707 mineral Substances 0.000 description 1
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229940005650 monomethyl fumarate Drugs 0.000 description 1
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125000005609 naphthenate group Chemical group 0.000 description 1
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150000002825 nitriles Chemical class 0.000 description 1
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235000014571 nuts Nutrition 0.000 description 1
DNKKFPSVEAVFCX-UHFFFAOYSA-N oct-3-enenitrile Chemical compound CCCCC=CCC#N DNKKFPSVEAVFCX-UHFFFAOYSA-N 0.000 description 1
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RQFLGKYCYMMRMC-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O.CCCCCCCCCCCCCCCCCC(O)=O RQFLGKYCYMMRMC-UHFFFAOYSA-N 0.000 description 1
OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 description 1
229960002446 octanoic acid Drugs 0.000 description 1
SRSFOMHQIATOFV-UHFFFAOYSA-N octanoyl octaneperoxoate Chemical compound CCCCCCCC(=O)OOC(=O)CCCCCCC SRSFOMHQIATOFV-UHFFFAOYSA-N 0.000 description 1
NZIDBRBFGPQCRY-UHFFFAOYSA-N octyl 2-methylprop-2-enoate Chemical compound CCCCCCCCOC(=O)C(C)=C NZIDBRBFGPQCRY-UHFFFAOYSA-N 0.000 description 1
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
UIAMCVSNZQYIQS-KTKRTIGZSA-N oleonitrile Chemical compound CCCCCCCC\C=C/CCCCCCCC#N UIAMCVSNZQYIQS-KTKRTIGZSA-N 0.000 description 1
150000007524 organic acids Chemical class 0.000 description 1
235000005985 organic acids Nutrition 0.000 description 1
239000011368 organic material Substances 0.000 description 1
239000012074 organic phase Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
HVAMZGADVCBITI-UHFFFAOYSA-M pent-4-enoate Chemical compound [O-]C(=O)CCC=C HVAMZGADVCBITI-UHFFFAOYSA-M 0.000 description 1
150000004965 peroxy acids Chemical class 0.000 description 1
JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
150000007965 phenolic acids Chemical class 0.000 description 1
229910000073 phosphorus hydride Inorganic materials 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
239000002685 polymerization catalyst Substances 0.000 description 1
239000000843 powder Substances 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
238000003825 pressing Methods 0.000 description 1
PDBWEHKCAUAROT-UHFFFAOYSA-N prop-1-en-2-yl butanoate Chemical compound CCCC(=O)OC(C)=C PDBWEHKCAUAROT-UHFFFAOYSA-N 0.000 description 1
NLDFTWSUPLJCQD-UHFFFAOYSA-N prop-1-en-2-yl propanoate Chemical compound CCC(=O)OC(C)=C NLDFTWSUPLJCQD-UHFFFAOYSA-N 0.000 description 1
CAEWJEXPFKNBQL-UHFFFAOYSA-N prop-2-enyl carbonochloridate Chemical compound ClC(=O)OCC=C CAEWJEXPFKNBQL-UHFFFAOYSA-N 0.000 description 1
OTRMXXQNSIVZNR-UHFFFAOYSA-N prop-2-enyl nitrate Chemical compound [O-][N+](=O)OCC=C OTRMXXQNSIVZNR-UHFFFAOYSA-N 0.000 description 1
BWJUFXUULUEGMA-UHFFFAOYSA-N propan-2-yl propan-2-yloxycarbonyloxy carbonate Chemical compound CC(C)OC(=O)OOC(=O)OC(C)C BWJUFXUULUEGMA-UHFFFAOYSA-N 0.000 description 1
238000007342 radical addition reaction Methods 0.000 description 1
239000012429 reaction media Substances 0.000 description 1
229960004889 salicylic acid Drugs 0.000 description 1
239000000243 solution Substances 0.000 description 1
235000015096 spirit Nutrition 0.000 description 1
229910001220 stainless steel Inorganic materials 0.000 description 1
239000010935 stainless steel Substances 0.000 description 1
239000008117 stearic acid Substances 0.000 description 1
125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
150000003440 styrenes Chemical class 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
238000010557 suspension polymerization reaction Methods 0.000 description 1
230000002195 synergetic effect Effects 0.000 description 1
OPQYOFWUFGEMRZ-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOC(=O)C(C)(C)C OPQYOFWUFGEMRZ-UHFFFAOYSA-N 0.000 description 1
229920006029 tetra-polymer Polymers 0.000 description 1
CWERGRDVMFNCDR-UHFFFAOYSA-M thioglycolate(1-) Chemical compound [O-]C(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-M 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
238000012546 transfer Methods 0.000 description 1
LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 1
WGKLOLBTFWFKOD-UHFFFAOYSA-N tris(2-nonylphenyl) phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(OC=1C(=CC=CC=1)CCCCCCCCC)OC1=CC=CC=C1CCCCCCCCC WGKLOLBTFWFKOD-UHFFFAOYSA-N 0.000 description 1
QQBLOZGVRHAYGT-UHFFFAOYSA-N tris-decyl phosphite Chemical compound CCCCCCCCCCOP(OCCCCCCCCCC)OCCCCCCCCCC QQBLOZGVRHAYGT-UHFFFAOYSA-N 0.000 description 1
229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
238000013022 venting Methods 0.000 description 1
KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 description 1
150000008127 vinyl sulfides Chemical class 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/02—Monomers containing chlorine
- C08F14/04—Monomers containing two carbon atoms
- C08F14/06—Vinyl chloride
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Compositions Of Macromolecular Compounds (AREA)
Polymerisation Methods In General (AREA)
Graft Or Block Polymers (AREA)

CA215,170A 1973-12-26 1974-12-03 Polymerisation massive de polymeres et de copolymeres d'halogenure de vinyle qui incorporent des stabilisants a cette fin Expired CA1037198A (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US43099373A	1973-12-26	1973-12-26

Publications (1)

Publication Number	Publication Date
CA1037198A true CA1037198A (fr)	1978-08-22

Family

ID=23709969

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA215,170A Expired CA1037198A (fr)	1973-12-26	1974-12-03	Polymerisation massive de polymeres et de copolymeres d'halogenure de vinyle qui incorporent des stabilisants a cette fin

Country Status (10)

Country	Link
JP (1)	JPS5137311B2 (fr)
BE (1)	BE823474A (fr)
BR (1)	BR7410717D0 (fr)
CA (1)	CA1037198A (fr)
DE (1)	DE2458926A1 (fr)
ES (1)	ES433284A1 (fr)
FR (1)	FR2256178B1 (fr)
GB (1)	GB1463737A (fr)
IT (1)	IT1028038B (fr)
NL (1)	NL7416545A (fr)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3122614A1 (de) *	1981-06-06	1983-01-05	Hoechst Ag, 6000 Frankfurt	"verfahren zur polymerisation von vinylchlorid in der masse"
KR102105041B1 (ko)	2016-09-26	2020-04-28	주식회사 엘지화학	염화비닐계 중합체의 제조방법, 염화비닐계 중합체 및 염화비닐계 중합체 조성물
KR102765736B1 (ko) *	2020-06-17	2025-02-12	주식회사 엘지화학	염화비닐계 중합체 복합체의 제조방법

1974
- 1974-12-03 CA CA215,170A patent/CA1037198A/fr not_active Expired
- 1974-12-06 GB GB5291574A patent/GB1463737A/en not_active Expired
- 1974-12-12 DE DE19742458926 patent/DE2458926A1/de active Pending
- 1974-12-17 BE BE151610A patent/BE823474A/fr unknown
- 1974-12-17 FR FR7441505A patent/FR2256178B1/fr not_active Expired
- 1974-12-18 NL NL7416545A patent/NL7416545A/xx not_active Application Discontinuation
- 1974-12-20 BR BR1071774A patent/BR7410717D0/pt unknown
- 1974-12-23 ES ES433284A patent/ES433284A1/es not_active Expired
- 1974-12-24 JP JP751069A patent/JPS5137311B2/ja not_active Expired
- 1974-12-24 IT IT3100574A patent/IT1028038B/it active

Also Published As

Publication number	Publication date
IT1028038B (it)	1979-01-30
FR2256178A1 (fr)	1975-07-25
GB1463737A (en)	1977-02-09
BE823474A (fr)	1975-06-17
JPS5097678A (fr)	1975-08-02
DE2458926A1 (de)	1975-07-10
BR7410717D0 (pt)	1975-09-02
JPS5137311B2 (fr)	1976-10-14
ES433284A1 (es)	1977-03-01
NL7416545A (nl)	1975-06-30
FR2256178B1 (fr)	1979-01-05

Publication	Publication Date	Title
US4371659A (en)	1983-02-01	Preparation of aqueous polymer dispersions having a polymer content of up to 75% by weight
US3488328A (en)	1970-01-06	Method for the suspension polymerization of vinyl chloride
US3696085A (en)	1972-10-03	Process for producing polymers of tertiary amides
KR101784548B1 (ko)	2017-10-11	염화비닐계 중합체 및 이의 제조방법
US2483960A (en)	1949-10-04	Polymerization of vinyl halides in an aqueous dispersion
CA2353753C (fr)	2009-09-29	Procede ameliore de production de poly(chlorure de vinyle)
US4143224A (en)	1979-03-06	Process for the manufacture of suspension polymers of vinyl chloride
US5883209A (en)	1999-03-16	Vinyl chloride polymerization with carboxylic acid ester of polyol and suspension agents
US4007235A (en)	1977-02-08	Method of preparing vinyl halide polymers and copolymers with polyolefins
GB1577030A (en)	1980-10-15	Preparation of vinyl halide polymers
US4137216A (en)	1979-01-30	Post bulk polymerization process for polyvinyl halide and composition thereof
US4139697A (en)	1979-02-13	Color stabilization of vinyl chloride resins
US4361683A (en)	1982-11-30	Termination of vinyl halide polymerization
US3627853A (en)	1971-12-14	Chlorination of vinyl chloride block copolymers
US3836510A (en)	1974-09-17	Vinyl halide terpolymer and bulk process for preparation
US3812086A (en)	1974-05-21	Process for polymerizing vinyl chloride
US4460754A (en)	1984-07-17	Process for the mass polymerization of vinyl chloride
US3804814A (en)	1974-04-16	Vinyl chloride copolymers suitable for crosslinking
US3810958A (en)	1974-05-14	Method of obtaining small particle size polymers and copolymers of vinyl chloride by bulk polymerization
DE2458926A1 (de)	1975-07-10	Verfahren zur herstellung von stabilisierten vinylhalogenidpolymeren und -copolymeren
US3816565A (en)	1974-06-11	Particle size control of bulk polymerized vinyl chloride polymers and copolymers
DE2121393A1 (de)	1972-04-06	Verfahren zur Herstellung von Vinylchloridpolymerisaten
US3666735A (en)	1972-05-30	Process for improving plasticizer absorption of polyvinyl halides
AT320276B (de)	1975-02-10	Vzh von vinylchloridpolymerisaten
US4003962A (en)	1977-01-18	Method of preparing an easy processing polyvinyl halide by an in-process reaction