CA1038165A - Procede de fabrication de gaz combustible - Google Patents

Procede de fabrication de gaz combustible

Info

Publication number: CA1038165A
Authority: CA; Canada
Prior art keywords: sulfur; process according; gaseous mixture; gasifying; gaseous
Prior art date: 1974-08-26
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA222,596A

Other languages

English (en)

Other versions

CA222596S (en

Inventor

Mark A. Paisley

Norbert J. Kertamus

Warnie L. Sage

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Babcock and Wilcox Co

Original Assignee

Babcock and Wilcox Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1974-08-26

Filing date

1975-03-18

Publication date

1978-09-12

1975-03-18 Application filed by Babcock and Wilcox Co filed Critical Babcock and Wilcox Co

1978-09-12 Application granted granted Critical

1978-09-12 Publication of CA1038165A publication Critical patent/CA1038165A/fr

Status Expired legal-status Critical Current

Links

239000002737 fuel gas Substances 0.000 title abstract description 11
238000004519 manufacturing process Methods 0.000 title abstract description 6
RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims abstract description 65
238000000034 method Methods 0.000 claims abstract description 22
239000000571 coke Substances 0.000 claims abstract description 10
AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 claims description 28
239000008246 gaseous mixture Substances 0.000 claims description 27
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 26
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 17
229910052760 oxygen Inorganic materials 0.000 claims description 17
239000001301 oxygen Substances 0.000 claims description 17
NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 15
229910002091 carbon monoxide Inorganic materials 0.000 claims description 12
229910052757 nitrogen Inorganic materials 0.000 claims description 12
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 11
239000011593 sulfur Substances 0.000 claims description 10
229910052717 sulfur Inorganic materials 0.000 claims description 10
239000000446 fuel Substances 0.000 claims description 6
238000010438 heat treatment Methods 0.000 claims description 5
239000007787 solid Substances 0.000 claims description 5
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 3
239000001257 hydrogen Substances 0.000 claims description 3
229910052739 hydrogen Inorganic materials 0.000 claims description 3
239000003054 catalyst Substances 0.000 claims description 2
239000002826 coolant Substances 0.000 claims description 2
XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 claims 8
229910052815 sulfur oxide Inorganic materials 0.000 claims 8
229940044609 sulfur dioxide Drugs 0.000 description 27
235000010269 sulphur dioxide Nutrition 0.000 description 27
239000007789 gas Substances 0.000 description 14
238000006243 chemical reaction Methods 0.000 description 13
239000003245 coal Substances 0.000 description 9
238000002309 gasification Methods 0.000 description 9
239000012530 fluid Substances 0.000 description 7
239000002245 particle Substances 0.000 description 6
229960005349 sulfur Drugs 0.000 description 5
235000001508 sulfur Nutrition 0.000 description 5
238000002485 combustion reaction Methods 0.000 description 4
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
230000003197 catalytic effect Effects 0.000 description 3
238000011084 recovery Methods 0.000 description 3
238000000926 separation method Methods 0.000 description 3
QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
239000003795 chemical substances by application Substances 0.000 description 2
239000003034 coal gas Substances 0.000 description 2
238000010494 dissociation reaction Methods 0.000 description 2
230000005593 dissociations Effects 0.000 description 2
230000007613 environmental effect Effects 0.000 description 2
239000007788 liquid Substances 0.000 description 2
CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
239000000395 magnesium oxide Substances 0.000 description 2
AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
239000000203 mixture Substances 0.000 description 2
239000003345 natural gas Substances 0.000 description 2
239000007800 oxidant agent Substances 0.000 description 2
230000003647 oxidation Effects 0.000 description 2
238000007254 oxidation reaction Methods 0.000 description 2
239000002002 slurry Substances 0.000 description 2
NINIDFKCEFEMDL-IGMARMGPSA-N sulfur-32 atom Chemical compound [32S] NINIDFKCEFEMDL-IGMARMGPSA-N 0.000 description 2
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
230000001154 acute effect Effects 0.000 description 1
239000011230 binding agent Substances 0.000 description 1
239000006227 byproduct Substances 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
238000010924 continuous production Methods 0.000 description 1
239000013078 crystal Substances 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000008025 crystallization Effects 0.000 description 1
230000007423 decrease Effects 0.000 description 1
239000003085 diluting agent Substances 0.000 description 1
230000000694 effects Effects 0.000 description 1
230000005611 electricity Effects 0.000 description 1
239000002803 fossil fuel Substances 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
QENHCSSJTJWZAL-UHFFFAOYSA-N magnesium sulfide Chemical compound [Mg+2].[S-2] QENHCSSJTJWZAL-UHFFFAOYSA-N 0.000 description 1
JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
229940099990 ogen Drugs 0.000 description 1
239000008188 pellet Substances 0.000 description 1
230000001105 regulatory effect Effects 0.000 description 1
230000002441 reversible effect Effects 0.000 description 1
230000002459 sustained effect Effects 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/54—Gasification of granular or pulverulent fuels by the Winkler technique, i.e. by fluidisation
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
- C10J3/06—Continuous processes
- C10J3/14—Continuous processes using gaseous heat-carriers
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
- C10J3/20—Apparatus; Plants
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/46—Gasification of granular or pulverulent flues in suspension
- C10J3/48—Apparatus; Plants
- C10J3/482—Gasifiers with stationary fluidised bed
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/78—High-pressure apparatus
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/82—Gas withdrawal means
- C10J3/84—Gas withdrawal means with means for removing dust or tar from the gas
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0943—Coke
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0956—Air or oxygen enriched air
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0983—Additives
- C10J2300/0993—Inert particles, e.g. as heat exchange medium in a fluidized or moving bed, heat carriers, sand
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/1603—Integration of gasification processes with another plant or parts within the plant with gas treatment
- C10J2300/1606—Combustion processes
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1807—Recycle loops, e.g. gas, solids, heating medium, water

Landscapes

Chemical & Material Sciences (AREA)
Engineering & Computer Science (AREA)
Combustion & Propulsion (AREA)
Oil, Petroleum & Natural Gas (AREA)
Organic Chemistry (AREA)
Industrial Gases (AREA)

CA222,596A 1974-08-26 1975-03-18 Procede de fabrication de gaz combustible Expired CA1038165A (fr)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US500817A US3904387A (en)	1974-08-26	1974-08-26	Fuel gas manufacture

Publications (1)

Publication Number	Publication Date
CA1038165A true CA1038165A (fr)	1978-09-12

Family

ID=23991069

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA222,596A Expired CA1038165A (fr)	1974-08-26	1975-03-18	Procede de fabrication de gaz combustible

Country Status (2)

Country	Link
US (1)	US3904387A (fr)
CA (1)	CA1038165A (fr)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4483693A (en) *	1974-11-20	1984-11-20	The Ralph M. Parsons Co.	Reforming of hydrocarbons in the presence of sulfur
US4396594A (en) *	1981-12-28	1983-08-02	Rockwell International Corporation	Sulfur dioxide reduction process
US4917024A (en) *	1989-05-24	1990-04-17	Florida Institute Of Phosphate Research	Coal fired power plant with pollution control and useful byproducts
US6024932A (en) *	1993-05-11	2000-02-15	Gas Research Institute	Method for the conversion of gypsum to elemental sulfur
US5686056A (en) *	1996-02-05	1997-11-11	Bechtel Group, Inc.	Methods and apparatus for purifying hydrogen sulfide
US8052949B2 (en)	2009-05-11	2011-11-08	Thermo Fisher Scientific Inc.	Generation of sulfur trioxide and sulfuric acid
US7901646B2 (en) *	2009-08-05	2011-03-08	General Electric Company	System and method for sulfur recovery
WO2017147681A1 (fr)	2016-03-04	2017-09-08	Bogdan Wojak	Procédés et systèmes de capture et d'utilisation de carbone (ccu) à l'aide de soufre

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3745109A (en) *	1970-10-01	1973-07-10	North American Rockwell	Hydrocarbon conversion process
GB1384711A (en) *	1971-03-19	1975-02-19	Exxon Research Engineering Co	Production of combustible gases
US3840354A (en) *	1972-03-23	1974-10-08	Us Interior	Three-stage gasification of coal

1974
- 1974-08-26 US US500817A patent/US3904387A/en not_active Expired - Lifetime
1975
- 1975-03-18 CA CA222,596A patent/CA1038165A/fr not_active Expired

Also Published As

Publication number	Publication date
US3904387A (en)	1975-09-09

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US4588850A (en)	1986-05-13	Process for the production of acetylene and synthesis or reduction gas from coal in an electric arc process
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US4927430A (en)	1990-05-22	Method for producing and treating coal gases
US5213587A (en)	1993-05-25	Refining of raw gas
Fercher et al.	1998	Two years experience with the FICFB-gasification process
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US3236589A (en)	1966-02-22	Method of working up cellulose waste liquor containing sodium and sulfur
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US4669270A (en)	1987-06-02	Power generating station with a high-temperature reactor and a plant for manufacturing chemical raw materials
JPS6150995B2 (fr)	1986-11-06
US4089659A (en)	1978-05-16	Process for producing a lean gas by the gasification of a fuel mainly in lump form
HK1198257A1 (en)	2015-03-20	Countercurrent gasification using synthesis gas as the working medium
WO2003080503A1 (fr)	2003-10-02	Production de gaz de synthese avec faible consommation d'eau
US4556421A (en)	1985-12-03	Method of operating a synthesis gas-ore reduction process
EP0305047B1 (fr)	1993-02-17	Désulfuration de gaz de synthèse à haute température
US4183733A (en)	1980-01-15	Hydro gas plant with utilization of the residual coke
JP2008069017A (ja)	2008-03-27	水素製造方法