CA1040782A - Composes thermoplastiques a forte resistance aux chocs - Google Patents

Composes thermoplastiques a forte resistance aux chocs

Info

Publication number: CA1040782A
Authority: CA; Canada
Prior art keywords: polystyrene; composition; rubber; matrix; poly
Prior art date: 1973-04-24
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired

Application number

CA169,384A

Other languages

English (en)

Inventor

Gim F. Lee (Jr.)

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

General Electric Co

Original Assignee

General Electric Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1973-04-24

Filing date

1973-04-24

Publication date

1978-10-17

1973-04-24 Application filed by General Electric Co filed Critical General Electric Co

1973-04-24 Priority to CA169,384A priority Critical patent/CA1040782A/fr

1978-10-17 Application granted granted Critical

1978-10-17 Publication of CA1040782A publication Critical patent/CA1040782A/fr

Status Expired legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 96
229920001169 thermoplastic Polymers 0.000 title claims abstract description 8
239000004416 thermosoftening plastic Substances 0.000 title claims abstract description 8
239000004793 Polystyrene Substances 0.000 claims abstract description 101
229920001971 elastomer Polymers 0.000 claims abstract description 101
229920002223 polystyrene Polymers 0.000 claims abstract description 97
239000005060 rubber Substances 0.000 claims abstract description 96
239000011159 matrix material Substances 0.000 claims abstract description 53
229920001955 polyphenylene ether Polymers 0.000 claims abstract description 44
239000002904 solvent Substances 0.000 claims abstract description 11
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 48
-1 hydrocarbon radicals Chemical class 0.000 claims description 43
229920005989 resin Polymers 0.000 claims description 26
239000011347 resin Substances 0.000 claims description 26
KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 15
HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 14
229920002857 polybutadiene Polymers 0.000 claims description 13
239000005062 Polybutadiene Substances 0.000 claims description 11
125000004432 carbon atom Chemical group C* 0.000 claims description 8
229920001577 copolymer Polymers 0.000 claims description 8
229920003244 diene elastomer Polymers 0.000 claims description 8
125000000217 alkyl group Chemical group 0.000 claims description 6
125000005843 halogen group Chemical group 0.000 claims description 6
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 6
229910052736 halogen Inorganic materials 0.000 claims description 5
150000002367 halogens Chemical class 0.000 claims description 5
239000001257 hydrogen Substances 0.000 claims description 5
229910052739 hydrogen Inorganic materials 0.000 claims description 5
125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 5
239000001301 oxygen Substances 0.000 claims description 5
229910052760 oxygen Inorganic materials 0.000 claims description 5
239000004215 Carbon black (E152) Substances 0.000 claims description 3
229910052799 carbon Inorganic materials 0.000 claims description 3
229930195733 hydrocarbon Natural products 0.000 claims description 3
239000004615 ingredient Substances 0.000 claims description 3
125000001424 substituent group Chemical group 0.000 claims description 3
150000003254 radicals Chemical class 0.000 claims 4
150000001555 benzenes Chemical class 0.000 claims 2
150000002430 hydrocarbons Chemical group 0.000 claims 1
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
229920005990 polystyrene resin Polymers 0.000 abstract description 20
238000002156 mixing Methods 0.000 abstract description 12
230000006872 improvement Effects 0.000 abstract description 4
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 65
238000000034 method Methods 0.000 description 26
WCVOGSZTONGSQY-UHFFFAOYSA-N 2,4,6-trichloroanisole Chemical compound COC1=C(Cl)C=C(Cl)C=C1Cl WCVOGSZTONGSQY-UHFFFAOYSA-N 0.000 description 24
239000002245 particle Substances 0.000 description 22
239000000499 gel Substances 0.000 description 9
229920005669 high impact polystyrene Polymers 0.000 description 9
229920000642 polymer Polymers 0.000 description 9
238000006116 polymerization reaction Methods 0.000 description 9
239000008188 pellet Substances 0.000 description 8
238000012360 testing method Methods 0.000 description 7
ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
239000004797 high-impact polystyrene Substances 0.000 description 6
239000000463 material Substances 0.000 description 6
239000000178 monomer Substances 0.000 description 6
229920002554 vinyl polymer Polymers 0.000 description 6
229960001701 chloroform Drugs 0.000 description 5
239000013078 crystal Substances 0.000 description 5
239000000806 elastomer Substances 0.000 description 5
238000009472 formulation Methods 0.000 description 5
230000000704 physical effect Effects 0.000 description 5
239000000047 product Substances 0.000 description 5
CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 4
229920000265 Polyparaphenylene Polymers 0.000 description 4
150000001993 dienes Chemical class 0.000 description 4
239000000243 solution Substances 0.000 description 4
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
239000000654 additive Substances 0.000 description 3
230000007423 decrease Effects 0.000 description 3
230000003247 decreasing effect Effects 0.000 description 3
238000009826 distribution Methods 0.000 description 3
238000005516 engineering process Methods 0.000 description 3
239000000835 fiber Substances 0.000 description 3
239000000126 substance Substances 0.000 description 3
229920003051 synthetic elastomer Polymers 0.000 description 3
239000005061 synthetic rubber Substances 0.000 description 3
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
ZGHFDIIVVIFNPS-UHFFFAOYSA-N 3-Methyl-3-buten-2-one Chemical compound CC(=C)C(C)=O ZGHFDIIVVIFNPS-UHFFFAOYSA-N 0.000 description 2
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
230000000996 additive effect Effects 0.000 description 2
239000003054 catalyst Substances 0.000 description 2
239000012986 chain transfer agent Substances 0.000 description 2
229920001519 homopolymer Polymers 0.000 description 2
238000007654 immersion Methods 0.000 description 2
150000002500 ions Chemical class 0.000 description 2
239000000155 melt Substances 0.000 description 2
238000010128 melt processing Methods 0.000 description 2
238000000465 moulding Methods 0.000 description 2
229920003052 natural elastomer Polymers 0.000 description 2
229920001194 natural rubber Polymers 0.000 description 2
229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 2
230000000379 polymerizing effect Effects 0.000 description 2
230000001376 precipitating effect Effects 0.000 description 2
238000010561 standard procedure Methods 0.000 description 2
229920003048 styrene butadiene rubber Polymers 0.000 description 2
239000000725 suspension Substances 0.000 description 2
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
JDCCCHBBXRQRGU-UHFFFAOYSA-N 5-phenylpenta-2,4-dienenitrile Chemical compound N#CC=CC=CC1=CC=CC=C1 JDCCCHBBXRQRGU-UHFFFAOYSA-N 0.000 description 1
239000004342 Benzoyl peroxide Substances 0.000 description 1
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
229920001368 Crepe rubber Polymers 0.000 description 1
101100536931 Escherichia coli (strain K12) thiD gene Proteins 0.000 description 1
101100159279 Escherichia coli (strain K12) yajL gene Proteins 0.000 description 1
244000228957 Ferula foetida Species 0.000 description 1
108010010803 Gelatin Proteins 0.000 description 1
244000043261 Hevea brasiliensis Species 0.000 description 1
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
239000004952 Polyamide Substances 0.000 description 1
239000004721 Polyphenylene oxide Substances 0.000 description 1
229920007962 Styrene Methyl Methacrylate Polymers 0.000 description 1
239000002174 Styrene-butadiene Substances 0.000 description 1
238000013019 agitation Methods 0.000 description 1
XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
239000012736 aqueous medium Substances 0.000 description 1
150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
239000011324 bead Substances 0.000 description 1
235000019400 benzoyl peroxide Nutrition 0.000 description 1
238000012662 bulk polymerization Methods 0.000 description 1
MPMBRWOOISTHJV-UHFFFAOYSA-N but-1-enylbenzene Chemical compound CCC=CC1=CC=CC=C1 MPMBRWOOISTHJV-UHFFFAOYSA-N 0.000 description 1
MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
229940000425 combination drug Drugs 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
239000007859 condensation product Substances 0.000 description 1
239000010949 copper Substances 0.000 description 1
229910052802 copper Inorganic materials 0.000 description 1
239000003431 cross linking reagent Substances 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
230000001419 dependent effect Effects 0.000 description 1
238000010790 dilution Methods 0.000 description 1
239000012895 dilution Substances 0.000 description 1
238000002845 discoloration Methods 0.000 description 1
239000012153 distilled water Substances 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000007720 emulsion polymerization reaction Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
238000001914 filtration Methods 0.000 description 1
239000003063 flame retardant Substances 0.000 description 1
238000005227 gel permeation chromatography Methods 0.000 description 1
239000008273 gelatin Substances 0.000 description 1
229920000159 gelatin Polymers 0.000 description 1
235000019322 gelatine Nutrition 0.000 description 1
235000011852 gelatine desserts Nutrition 0.000 description 1
229920000578 graft copolymer Polymers 0.000 description 1
150000008282 halocarbons Chemical class 0.000 description 1
238000010438 heat treatment Methods 0.000 description 1
239000002638 heterogeneous catalyst Substances 0.000 description 1
238000000703 high-speed centrifugation Methods 0.000 description 1
230000003301 hydrolyzing effect Effects 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
239000003112 inhibitor Substances 0.000 description 1
239000003999 initiator Substances 0.000 description 1
238000001746 injection moulding Methods 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
ADFPJHOAARPYLP-UHFFFAOYSA-N methyl 2-methylprop-2-enoate;styrene Chemical compound COC(=O)C(C)=C.C=CC1=CC=CC=C1 ADFPJHOAARPYLP-UHFFFAOYSA-N 0.000 description 1
238000012986 modification Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
229910052757 nitrogen Inorganic materials 0.000 description 1
210000004940 nucleus Anatomy 0.000 description 1
208000021596 pentasomy X Diseases 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
239000000049 pigment Substances 0.000 description 1
239000004014 plasticizer Substances 0.000 description 1
229920001084 poly(chloroprene) Polymers 0.000 description 1
229920002647 polyamide Polymers 0.000 description 1
229920001195 polyisoprene Polymers 0.000 description 1
229920000098 polyolefin Polymers 0.000 description 1
229920006380 polyphenylene oxide Polymers 0.000 description 1
230000035484 reaction time Effects 0.000 description 1
239000012744 reinforcing agent Substances 0.000 description 1
239000011342 resin composition Substances 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
239000004094 surface-active agent Substances 0.000 description 1
238000010557 suspension polymerization reaction Methods 0.000 description 1
229920001897 terpolymer Polymers 0.000 description 1
229920005992 thermoplastic resin Polymers 0.000 description 1
239000010936 titanium Substances 0.000 description 1
229910052719 titanium Inorganic materials 0.000 description 1
238000001291 vacuum drying Methods 0.000 description 1

Landscapes

Compositions Of Macromolecular Compounds (AREA)

CA169,384A 1973-04-24 1973-04-24 Composes thermoplastiques a forte resistance aux chocs Expired CA1040782A (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA169,384A CA1040782A (fr)	1973-04-24	1973-04-24	Composes thermoplastiques a forte resistance aux chocs

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CA169,384A CA1040782A (fr)	1973-04-24	1973-04-24	Composes thermoplastiques a forte resistance aux chocs

Publications (1)

Publication Number	Publication Date
CA1040782A true CA1040782A (fr)	1978-10-17

Family

ID=4096498

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA169,384A Expired CA1040782A (fr)	1973-04-24	1973-04-24	Composes thermoplastiques a forte resistance aux chocs

Country Status (1)

Country	Link
CA (1)	CA1040782A (fr)

1973
- 1973-04-24 CA CA169,384A patent/CA1040782A/fr not_active Expired

Legal Events

Date	Code	Title	Description
2024-03-25	MKEX	Expiry	Effective date: 19951017

Publication	Publication Date	Title
US4128603A (en)	1978-12-05	Compositions comprising polyphenylene ether and rubber modified polystyrene
US4128602A (en)	1978-12-05	Polyphenylene ether compositions containing rubber modified polystyrene
US3835200A (en)	1974-09-10	Composition of a polyphenylene ether, a rubber styrene graft copolymer and normally rigid block copolymer of a vinyl aromatic compound and a conjugated diene
US3787532A (en)	1974-01-22	Polyphenylene ether compositions
US3994856A (en)	1976-11-30	Composition of a polyphenylene ether and a block copolymer of a vinyl aromatic compound and a conjugated diene
US4167507A (en)	1979-09-11	Composition of a polyphenylene ether and a hydrogenated block copolymer
US3833688A (en)	1974-09-03	Composition of a polyphenylene ether and an acrylic resin in combination with a diene rubber-containing resin
US3819761A (en)	1974-06-25	High impact strength thermoplastic compositions
US4128604A (en)	1978-12-05	Polyphenylene ether compositions
EP0305764B1 (fr)	1994-02-23	Polystyrène de poids moléculaire élevée dans des mélanges avec PPE et HIPS
US3976725A (en)	1976-08-24	High impact strength thermoplastic compositions
CA1201236A (fr)	1986-02-25	Composition de resine de poly(oxyde de phenylene) et de poly(bisphenol tetra-alkyle), ayant une viscosite reduite a l'etat fondu
EP0401690A3 (fr)	1991-12-27	Composition de poly(éther de phénylène) ayant une fluidité à l'état fondu améliorée
US3663661A (en)	1972-05-16	Rubber modified polyphenylene ether and process
EP0337165A2 (fr)	1989-10-18	Compositions à base d'un mélange de polymères contenant un copolymère comme agent de compatibilisation
US4578423A (en)	1986-03-25	Polyblends of polyphenylene oxide and styrene-acrylonitrile polymers having broad acrylonitrile compositional distribution
US3983090A (en)	1976-09-28	Composition of a polyphenylene ether and styrene resin and an acrylic resin in combination with a diene rubber-container resin
US4513120A (en)	1985-04-23	Polyphenylene ether compositions
US4528327A (en)	1985-07-09	Composition of polyphenylene ethers with core-shell rubber-modified polystyrene
US4373064A (en)	1983-02-08	Polyphenylene ether compositions
CA1040782A (fr)	1978-10-17	Composes thermoplastiques a forte resistance aux chocs
CA1167583A (fr)	1984-05-15	Materiel thermoplastique profilable contenant un polymere styrenique et un caoutchouc a reticulations croisees sur lequel sont greffes du styrene et un ether de polyphenylene
US3960811A (en)	1976-06-01	Process for the preparation of an amorphous polyphenylene oxide
EP0564039B1 (fr)	1999-12-29	Composition de polymère thermoplastique à base de polyphénylène éther et un copolymer vinyl aromatique résistant à l'impact
CA1141064A (fr)	1983-02-08	Compositions renfermant du polyphenylene avec un noyau-enveloppe de polystyrene modifie au caoutchouc